Thermally stable nano-size ceramic particles are the preferred reinforcements for superalloys as they improve the alloys'microstructural stability and high-temperature properties.In this work,very dense and crack-...Thermally stable nano-size ceramic particles are the preferred reinforcements for superalloys as they improve the alloys'microstructural stability and high-temperature properties.In this work,very dense and crack-free carbidereinforced GTD222(nickel-based superalloy)composites were prepared via selective laser melting(SLM).The distribution of TiC nanoparticles presents a three-dimensional(3D)network structure in the SLMed TiC/GTD222 composite.Mechanical testing revealed that the SLMed TiC/GTD222 composite has superior strength(UTS?1320 MPa,YS?1100 MPa)compared to the SLMed GTD222 superalloy.The GTD22 alloy reinforced with carbide nanoparticles’distinctive microstructure and its excellent mechanical properties for is discussed.展开更多
The development of graphene-based composites with low density,robust absorption,wide bandwidth and thin thickness remained a great challenge in the field of electromagnetic(EM)absorption.In this work,nitrogen-doped re...The development of graphene-based composites with low density,robust absorption,wide bandwidth and thin thickness remained a great challenge in the field of electromagnetic(EM)absorption.In this work,nitrogen-doped reduced graphene oxide/hollow cobalt ferrite(NRGO/hollow CoFe_(2)O_(4))composite aerogels were constructed by a solvothermal and hydrothermal two-step route.Results demonstrated that the as-fabricated composite aerogels had the ultralow density and a unique three-dimensional(3D)network structure,and lots of hollow CoFe_(2)O_(4)microspheres were almost homogeneously distributed on the wrinkled surfaces of lamellar NRGO.Moreover,superior EM absorbing capacity could be achieved by modulating the ferrite structure,addition amounts of hollow CoFe_(2)O_(4)and thicknesses.It was noteworthy that the NRGO/hollow CoFe_(2)O_(4)composite aerogel with the addition amount of ferrite of 15.0 mg pos-sessed the minimum reflection loss of-44.7 dB and maximum absorption bandwidth of 5.2 GHz(from 12.6 to 17.8 GHz)at a very thin thickness of 1.8 mm and filling ratio of 15.0 wt.%.Furthermore,the possible EM attenuation mechanism had been proposed.The results of this work would be helpful for developing RGO-based 3D composites as lightweight,thin and highly efficient EM wave absorbers.展开更多
Polyvinyl alcohol hydrogels have been used in wearable devices due to their good flexibility and biocompatibility.However,due to the low thermal conductivity(κ)of pure hydrogel,its further application in high power d...Polyvinyl alcohol hydrogels have been used in wearable devices due to their good flexibility and biocompatibility.However,due to the low thermal conductivity(κ)of pure hydrogel,its further application in high power devices is limited.To solve this problem,melamine sponge(MS)was used as the skeleton to wrap boron nitride nanosheets(BNNS)through repeated layering assembly,successfully preparing a three-dimensional(3D)boron nitride network(BNNS@MS),and PVA hydrogels were formed in the pores of the network.Due to the existence of the continuous phonon conduction network,the BNNS@MS/PVA exhibited an improvedκ.When the content of BNNS is about 6 wt.%,κof the hydrogel was increased to 1.12 W m^(-1)K^(-1),about two times higher than that of pure hydrogel.The solid heat conduction network and liquid convection network cooperate to achieve good thermal management ability.Combined with its high specific heat capacity,the composites have an important application prospect in the field of wearable flexible electronic thermal management.展开更多
Polyethylene oxide(PEO)-based solid-state electrolytes are considered ideal for electrolyte materials in solid-state lithium metal batteries(SSLMBs).However,practical applications are hindered by the lower conductivit...Polyethylene oxide(PEO)-based solid-state electrolytes are considered ideal for electrolyte materials in solid-state lithium metal batteries(SSLMBs).However,practical applications are hindered by the lower conductivity and poor interfacial stability.Here,we propose a strategy to construct a three-dimensional(3D)fiber network of metal-organic frameworks(MOFs).Composite solid electrolytes(CSEs)with continuous ion transport pathways were fabricated by filling a PEO polymer matrix in fibers containing interconnected MOFs.This 3D fiber network provides a fast Li+transport path and effectively improves the ionic conductivity(1.36×10^(-4) S·cm^(-1),30℃).In addition,the network of interconnected MOFs not only effectively traps the anions,but also provides sufficient mechanical strength to prevent the growth of Li dendrites.Benefiting from the advantages of structural design,the CSEs stabilize the Li/electrolyte interface and extend the cycle life of the Li-symmetric cells to 3000 h.The assembled SSLMBs exhibit excellent cycling performance at both room and high temperatures.In addition,the constructed pouch cells can provide an areal capacity of 0.62 mA·h·cm^(-2),which can still operate under extreme conditions.This work provides a new strategy for the design of CSEs with continuous structure and stable operation of SSLMBs.展开更多
由于空间信息网络(space information network,SIN)具有高动态拓扑、卫星计算和通信资源受限等特点,当群组飞行器需要与卫星快速接入认证以实现信息连续收集或扩大观测范围时,已有协议方案不能完全满足SIN的特点和一些应用需求.为此,提...由于空间信息网络(space information network,SIN)具有高动态拓扑、卫星计算和通信资源受限等特点,当群组飞行器需要与卫星快速接入认证以实现信息连续收集或扩大观测范围时,已有协议方案不能完全满足SIN的特点和一些应用需求.为此,提出一种面向空间信息网,协议组合逻辑(protocol composition logic,PCL)安全的群组多用户快速认证协议(TSNP).基于对称加密体制、密钥分层的思想,TSNP允许群组内完成接入认证的节点向其他用户发送消息,通过计算使得群组内用户拥有与卫星通信的密钥,实现群组内用户高效安全认证或切换.通过PCL模型对TSNP各阶段协议安全属性进行分析,并使用并行和顺序组合方法证明TSNP能保障组合后协议的安全属性.实验结果表明:TSNP一方面减少了对地面管理中心的依赖程度,同时有效降低了卫星计算和通信开销.展开更多
Optimizing the sensor energy is one of the most important concern in Three-Dimensional(3D)Wireless Sensor Networks(WSNs).An improved dynamic hierarchical clustering has been used in previous works that computes optimu...Optimizing the sensor energy is one of the most important concern in Three-Dimensional(3D)Wireless Sensor Networks(WSNs).An improved dynamic hierarchical clustering has been used in previous works that computes optimum clusters count and thus,the total consumption of energy is optimal.However,the computational complexity will be increased due to data dimension,and this leads to increase in delay in network data transmission and reception.For solving the above-mentioned issues,an efficient dimensionality reduction model based on Incremental Linear Discriminant Analysis(ILDA)is proposed for 3D hierarchical clustering WSNs.The major objective of the proposed work is to design an efficient dimensionality reduction and energy efficient clustering algorithm in 3D hierarchical clustering WSNs.This ILDA approach consists of four major steps such as data dimension reduction,distance similarity index introduction,double cluster head technique and node dormancy approach.This protocol differs from normal hierarchical routing protocols in formulating the Cluster Head(CH)selection technique.According to node’s position and residual energy,optimal cluster-head function is generated,and every CH is elected by this formulation.For a 3D spherical structure,under the same network condition,the performance of the proposed ILDA with Improved Dynamic Hierarchical Clustering(IDHC)is compared with Distributed Energy-Efficient Clustering(DEEC),Hybrid Energy Efficient Distributed(HEED)and Stable Election Protocol(SEP)techniques.It is observed that the proposed ILDA based IDHC approach provides better results with respect to Throughput,network residual energy,network lifetime and first node death round.展开更多
基金The authors grateful acknowledge the financial support of the National Natural Science Foundation of China under Projects No.51871147 and 51704195the China Postdoctoral Science Foundation under Project No.19Z102060057+2 种基金the National Science and Technology Major Project under Project No.2017-VI-0013-0085the Science Fund for Creative Research Groups of the National Natural Science Foundation of China under Project No.51821001the Aviation Power Fund under Project No.6141B090324.
文摘Thermally stable nano-size ceramic particles are the preferred reinforcements for superalloys as they improve the alloys'microstructural stability and high-temperature properties.In this work,very dense and crack-free carbidereinforced GTD222(nickel-based superalloy)composites were prepared via selective laser melting(SLM).The distribution of TiC nanoparticles presents a three-dimensional(3D)network structure in the SLMed TiC/GTD222 composite.Mechanical testing revealed that the SLMed TiC/GTD222 composite has superior strength(UTS?1320 MPa,YS?1100 MPa)compared to the SLMed GTD222 superalloy.The GTD22 alloy reinforced with carbide nanoparticles’distinctive microstructure and its excellent mechanical properties for is discussed.
基金supported by the Foundation of Provincial Natural Science Research Project of Anhui Colleges(No.KJ2021ZD0047)the Anhui Provincial Natural Science Foundation(No.2008085J27)+1 种基金the China Postdoctoral Science Foundation(No.2019M652160)the Research Foundation of the Institute of Environment-friendly Materials and Occupational Health(Wuhu),Anhui University of Science and Technology(No.ALW2020YF05).
文摘The development of graphene-based composites with low density,robust absorption,wide bandwidth and thin thickness remained a great challenge in the field of electromagnetic(EM)absorption.In this work,nitrogen-doped reduced graphene oxide/hollow cobalt ferrite(NRGO/hollow CoFe_(2)O_(4))composite aerogels were constructed by a solvothermal and hydrothermal two-step route.Results demonstrated that the as-fabricated composite aerogels had the ultralow density and a unique three-dimensional(3D)network structure,and lots of hollow CoFe_(2)O_(4)microspheres were almost homogeneously distributed on the wrinkled surfaces of lamellar NRGO.Moreover,superior EM absorbing capacity could be achieved by modulating the ferrite structure,addition amounts of hollow CoFe_(2)O_(4)and thicknesses.It was noteworthy that the NRGO/hollow CoFe_(2)O_(4)composite aerogel with the addition amount of ferrite of 15.0 mg pos-sessed the minimum reflection loss of-44.7 dB and maximum absorption bandwidth of 5.2 GHz(from 12.6 to 17.8 GHz)at a very thin thickness of 1.8 mm and filling ratio of 15.0 wt.%.Furthermore,the possible EM attenuation mechanism had been proposed.The results of this work would be helpful for developing RGO-based 3D composites as lightweight,thin and highly efficient EM wave absorbers.
基金the National Natural Science Foundation of China(Nos.52173078,52130303,and 51803151)the Young Elite Scientists Sponsorship Program by CAST(No.2019QNRC001)。
文摘Polyvinyl alcohol hydrogels have been used in wearable devices due to their good flexibility and biocompatibility.However,due to the low thermal conductivity(κ)of pure hydrogel,its further application in high power devices is limited.To solve this problem,melamine sponge(MS)was used as the skeleton to wrap boron nitride nanosheets(BNNS)through repeated layering assembly,successfully preparing a three-dimensional(3D)boron nitride network(BNNS@MS),and PVA hydrogels were formed in the pores of the network.Due to the existence of the continuous phonon conduction network,the BNNS@MS/PVA exhibited an improvedκ.When the content of BNNS is about 6 wt.%,κof the hydrogel was increased to 1.12 W m^(-1)K^(-1),about two times higher than that of pure hydrogel.The solid heat conduction network and liquid convection network cooperate to achieve good thermal management ability.Combined with its high specific heat capacity,the composites have an important application prospect in the field of wearable flexible electronic thermal management.
基金support from the China Postdoctoral Science Foundation(Nos.2022TQ0173 and 2023M731922).
文摘Polyethylene oxide(PEO)-based solid-state electrolytes are considered ideal for electrolyte materials in solid-state lithium metal batteries(SSLMBs).However,practical applications are hindered by the lower conductivity and poor interfacial stability.Here,we propose a strategy to construct a three-dimensional(3D)fiber network of metal-organic frameworks(MOFs).Composite solid electrolytes(CSEs)with continuous ion transport pathways were fabricated by filling a PEO polymer matrix in fibers containing interconnected MOFs.This 3D fiber network provides a fast Li+transport path and effectively improves the ionic conductivity(1.36×10^(-4) S·cm^(-1),30℃).In addition,the network of interconnected MOFs not only effectively traps the anions,but also provides sufficient mechanical strength to prevent the growth of Li dendrites.Benefiting from the advantages of structural design,the CSEs stabilize the Li/electrolyte interface and extend the cycle life of the Li-symmetric cells to 3000 h.The assembled SSLMBs exhibit excellent cycling performance at both room and high temperatures.In addition,the constructed pouch cells can provide an areal capacity of 0.62 mA·h·cm^(-2),which can still operate under extreme conditions.This work provides a new strategy for the design of CSEs with continuous structure and stable operation of SSLMBs.
文摘由于空间信息网络(space information network,SIN)具有高动态拓扑、卫星计算和通信资源受限等特点,当群组飞行器需要与卫星快速接入认证以实现信息连续收集或扩大观测范围时,已有协议方案不能完全满足SIN的特点和一些应用需求.为此,提出一种面向空间信息网,协议组合逻辑(protocol composition logic,PCL)安全的群组多用户快速认证协议(TSNP).基于对称加密体制、密钥分层的思想,TSNP允许群组内完成接入认证的节点向其他用户发送消息,通过计算使得群组内用户拥有与卫星通信的密钥,实现群组内用户高效安全认证或切换.通过PCL模型对TSNP各阶段协议安全属性进行分析,并使用并行和顺序组合方法证明TSNP能保障组合后协议的安全属性.实验结果表明:TSNP一方面减少了对地面管理中心的依赖程度,同时有效降低了卫星计算和通信开销.
文摘Optimizing the sensor energy is one of the most important concern in Three-Dimensional(3D)Wireless Sensor Networks(WSNs).An improved dynamic hierarchical clustering has been used in previous works that computes optimum clusters count and thus,the total consumption of energy is optimal.However,the computational complexity will be increased due to data dimension,and this leads to increase in delay in network data transmission and reception.For solving the above-mentioned issues,an efficient dimensionality reduction model based on Incremental Linear Discriminant Analysis(ILDA)is proposed for 3D hierarchical clustering WSNs.The major objective of the proposed work is to design an efficient dimensionality reduction and energy efficient clustering algorithm in 3D hierarchical clustering WSNs.This ILDA approach consists of four major steps such as data dimension reduction,distance similarity index introduction,double cluster head technique and node dormancy approach.This protocol differs from normal hierarchical routing protocols in formulating the Cluster Head(CH)selection technique.According to node’s position and residual energy,optimal cluster-head function is generated,and every CH is elected by this formulation.For a 3D spherical structure,under the same network condition,the performance of the proposed ILDA with Improved Dynamic Hierarchical Clustering(IDHC)is compared with Distributed Energy-Efficient Clustering(DEEC),Hybrid Energy Efficient Distributed(HEED)and Stable Election Protocol(SEP)techniques.It is observed that the proposed ILDA based IDHC approach provides better results with respect to Throughput,network residual energy,network lifetime and first node death round.
