IN-SITU HVEM STUDY ON PHASE TRANSITION OF YBa_2Cu_3O_(7-x) SUPERCONDUCTING COMPOUND IN PROCESS OF HEATING

In-situ HVEM observation on phase transition of the YBa_2Cu_3O_(7-x) superconducting compound in pro- cess of heating was carried out,and high temperature X-ray diffraction analysis in air and X-ray diffraction phase analysis for the sample treated in vacuum condition were made.The results showed that the temperature of phase transition is related to oxygen content in the sample and in general,is 100℃ to 120℃ lower in vacu- um condition than in air.At 320℃ to 350℃ twin bands begin to disappear,and some Cu_2O are formed on the surface of the sample and transit from orthorhombic YBa_2Cu_3O_(7-x) to arthorhombic Y_2BaCuO_5 compound. This transition was completed at about 500℃.Above 900℃,this compound consists of the Y_2BaCuO_5, BaCuO_2,Y_2O_3 and some other minor compounds.No phase transition was observed during cooling the sample.

Compound Heat Transfer Enhancement of a Converging-Diverging Tube with Evenly Spaced Twisted-tapes

Pressure drop and compound heat transfer characteristics of a converging-diverging tube with evenly spaced twisted-tapes （CD-T tube） have been investigated experimentally. Swirl was generated by evenly spaced twisted-tape elements which vary in twist ratio and rotation angle. Space ratio also has an important effect on the characteristics. For comparison, experiments in a smooth circular tube and a converging-diverging （CD） tube with-out twisted-tapes were carried out. The results show that the twisted-tape with twist ratio y=4.72 and rotation angle θ=180° has the best performance among the four types of twisted-tapes presented in this paper. At Reynolds number ranging from 3400 to 20000, when space ratio s=48.6, the heat transfer efficiency index, which increases as the Reynolds number increases, is 0.85-1.21 and 1.07-1.15 compared to that of a smooth circular tube and a CD tube without twisted-tape inserts, respectively.

Heat balance of solar-soil source heat pump compound system

Based on the state-of-the-art studies of solar-soil source heat pump compound system, operation patterns of solar-soil compound system were analyzed, particularly the advantages of parallel operation pattern. It is found that parallel operation pattern is better for solar-soil compound system. Furthermore, the heat balance issue of solar-soil compound system was emphatically analyzed from four aspects, which were annual analysis of heating and cooling load, the heat exchange of ground heat exchanger, capacity determination of solar-assisted heat sottrce and heat balance calculation of solar-soil compound system. Moreover, annual rate of heat balance in a solar-soil source heat pump compound system was calculated with a case study. It is shown that the annual heat unbalance ratio is 19%, which is less than 20%. As a result, the practical solar-soil compound system can basically maintain the heat balance of soil.

Anomalous low-temperature heat capacity in antiperovskite compounds

The low-temperature heat capacities are studied for antiperovskite compounds AX M_3（A = Al, Ga, Cu, Ag, Sn, X = C,N, M = Mn, Fe, Co）. A large peak in（C- γ T）/T^3 versus T is observed for each of a total of 18 compounds investigated,indicating an existence of low-energy phonon mode unexpected by Debye T^3 law. Such a peak is insensitive to the external magnetic field up to 80 k Oe（1 Oe = 79.5775 A·m-1）. For compounds with smaller lattice constant, the peak shifts towards higher temperatures with a reduction of peak height. This abnormal peak in（C- γ T）/T^3 versus T of antiperovskite compound may result from the strongly dispersive acoustic branch due to the heavier A atoms and the optical-like mode from the dynamic rotation of X M_6 octahedron. Such a low-energy phonon mode may not contribute negatively to the normal thermal expansion in AX M_3 compounds, while it is usually concomitant with negative thermal expansion in open-structure material（e.g., ZrW_2O_8, Sc F_3）.

Role of Intraseasonal Oscillation in a Compound Drought and Heat Event over the Middle of the Yangtze River Basin during Midsummer 2018

In late July 2018, a compound drought and heat event(CDHE) occurred in the middle of the Yangtze River basin(MYRB) and caused great damage to the national economy. The CDHE over the MYRB has been documented to be linked with intraseasonal oscillations(ISOs) from different regions. However, specific roles of different ISOs on the development of the CDHE cannot be separated in the observational analysis. By using partial lateral forcing experiments driven by ISO in the Weather Research and Forecasting(WRF) model, we found that the midlatitude ISO generated by a westerly wave train in the upper troposphere played an important role in this heatwave and drought event in the northern MYRB, causing a regional average temperature rise of 1.65°C and intensification of drought over23.49% of the MYRB area. On the other hand, the ISO associated with the Pacific-Japan(PJ)-like teleconnection wave train in the lower troposphere induced a more pronounced impact on the event, causing an average temperature rise of 2.44°C, intensifying drought over 29.62% of the MYRB area. The MYRB was mainly affected by northward warm advection driven by the westward extension of the western North Pacific subtropical high in the early period of the CDHE development. In the late period, because of the establishment of a deep positive geopotential height field through the troposphere leading to intensive local subsidence, there was a remarkable temperature rise and moisture decrease in the MYRB. The results will facilitate a better understanding of the occurrence of CDHE and provide empirical precursory signals for subseasonal forecast of CDHE.

Adsorption of benzene, cyclohexane and hexane on ordered mesoporous carbon

Ordered mesoporous carbon（OMC） with high specific surface area and large pore volume was synthesized and tested for use as an adsorbent for volatile organic compound（VOC）disposal. Benzene, cyclohexane and hexane were selected as typical adsorbates due to their different molecular sizes and extensive utilization in industrial processes. In spite of their structural differences, high adsorption amounts were achieved for all three adsorbates, as the pore size of OMC is large enough for the access of these VOCs. In addition, the unusual bimodal-like pore size distribution gives the adsorbates a higher diffusion rate compared with conventional adsorbents such as activated carbon and carbon molecular sieve. Kinetic analysis suggests that the adsorption barriers mainly originated from the difficulty of VOC vapor molecules entering the pore channels of adsorbents. Therefore, its superior adsorption ability toward VOCs, together with a high diffusion rate, makes the ordered mesoporous carbon a promising potential adsorbent for VOC disposal.