Ultrahigh-strength mortar mixed surface-oxidized silicon carbide as a fine aggregate was prepared by means of press-casting followed by curing in an autoclave. The relation between modulus of elssticity up to 111 GPa ...Ultrahigh-strength mortar mixed surface-oxidized silicon carbide as a fine aggregate was prepared by means of press-casting followed by curing in an autoclave. The relation between modulus of elssticity up to 111 GPa and compressive strength up to 360 MPa of mortar mixed silicon carbide was discussed and it was revealed that the contributions of the aggregate hardness and of the interfacial strength between the aggregate and the cement paste on the elasticity of mortar were imporant.展开更多
The unreacted equation of state(EOS) of energetic materials is an important thermodynamic relationship to characterize their high pressure behaviors and has practical importance. The previous experimental and theore...The unreacted equation of state(EOS) of energetic materials is an important thermodynamic relationship to characterize their high pressure behaviors and has practical importance. The previous experimental and theoretical works on the equation of state of several energetic materials including nitromethane, 1,3,5-trinitrohexahydro-1,3,5-triazine(RDX),1,3,5,7-tetranitro-1,3,5,7-tetrazacyclooctane(HMX), hexanitrostilbene(HNS), hexanitrohexaazaisowurtzitane(HNIW or CL-20), pentaerythritol tetranitrate(PETN), 2,6-diamino-3,5-dinitropyrazine-1-oxide(LLM-105), triamino-trinitrobenzene(TATB), 1,1-diamino-2,2-dinitroethene(DADNE or FOX-7), and trinitrotoluene(TNT) are reviewed in this paper. The EOS determined from hydrostatic and non-hydrostatic compressions are discussed and compared. The theoretical results based on ab initio calculations are summarized and compared with the experimental data.展开更多
Recently,many regression models have been presented for prediction of mechanical parameters of rocks regarding to rock index properties.Although statistical analysis is a common method for developing regression models...Recently,many regression models have been presented for prediction of mechanical parameters of rocks regarding to rock index properties.Although statistical analysis is a common method for developing regression models,but still selection of suitable transformation of the independent variables in a regression model is diffcult.In this paper,a genetic algorithm(GA)has been employed as a heuristic search method for selection of best transformation of the independent variables(some index properties of rocks)in regression models for prediction of uniaxial compressive strength(UCS)and modulus of elasticity(E).Firstly,multiple linear regression(MLR)analysis was performed on a data set to establish predictive models.Then,two GA models were developed in which root mean squared error(RMSE)was defned as ftness function.Results have shown that GA models are more precise than MLR models and are able to explain the relation between the intrinsic strength/elasticity properties and index properties of rocks by simple formulation and accepted accuracy.展开更多
The physical vapor deposition method is an effective way to deposit Al2O3 and Er2O3 on 316 L stainless steel substrates acting as tritium permeation barriers in a fusion reactor. The distribution of residual thermal s...The physical vapor deposition method is an effective way to deposit Al2O3 and Er2O3 on 316 L stainless steel substrates acting as tritium permeation barriers in a fusion reactor. The distribution of residual thermal stress is calculated both in Al2O3 and Er2O3 coating systems with planar and rough substrates using finite element analysis. The parameters influencing the thermal stress in the sputter process are analyzed, such as coating and substrate properties, temperature and Young's modulus. This work shows that the thermal stress in Al2O3 and Er2O3 coating systems exhibit a linear relationship with substrate thickness, temperature and Young's modulus.However, this relationship is inversed with coating thickness. In addition, the rough substrate surface can increase the thermal stress in the process of coating deposition. The adhesive strength between the coating and the substrate is evaluated by the shear stress. Due to the higher compressive shear stress, the Al2O3 coating has a better adhesive strength with a 316 L stainless steel substrate than the Er2O3 coating. Furthermore, the analysis shows that it is a useful way to improve adhesive strength with increasing interface roughness.展开更多
Service life of reinforced concrete structures usually was designed on the basis of one selected deteriorating mechanism as for instance carbonation,chloride penetration,and frost action.It could be shown in the meant...Service life of reinforced concrete structures usually was designed on the basis of one selected deteriorating mechanism as for instance carbonation,chloride penetration,and frost action.It could be shown in the meantime by numerous authors,however,that combined actions such as chloride penetration under mechanical load or chloride penetration in combination with freeze-thaw cycles may shorten the service life of reinforced concrete structures more than individual processes acting alone.We have found that chloride penetration is accelerated significantly by freeze-thaw cycles.Frost damage not only reduces mechanical strength and elastic modulus but migration of chloride is facilitated in the damaged pore structure.Chloride penetration can be retarded by the addition of silane emulsion to the fresh concrete.In this way Integral Water Repellent Concrete(IWRC) can be produced.Migration of water and ions dissolved in water can not be prevented by integral water repellent treatment but it is slowed down.The combination of damage mechanisms and the protective measures by integral water repellent treatment have to be taken into consideration in realistic service life prediction and design.展开更多
Tubal pregnancy is a common abnormal pregnancy manifestation,and the ordinary conservative treatment of tubal adhesion usually leads to the rupture of fallopian tube,which increases the risk of a second ectopic pregna...Tubal pregnancy is a common abnormal pregnancy manifestation,and the ordinary conservative treatment of tubal adhesion usually leads to the rupture of fallopian tube,which increases the risk of a second ectopic pregnancy.To avoid this symptom,it is suitable to implant a stent to separate the adhesion.Here we prepared the PBAT/PLGA foam as the stent material using supercritical CO_(2) foaming technology.With uniform macroporous structure and thin-wall feature,the foam possessed low compressive modulus in prevention of the possible second injury to the fallopian tube.The introduction of PLGA 50/50 improved the biodegradable capability of the foam,with a mass loss about 20% after a 12-week hydrolysis.After implanted into the ruptured fallopian tube of the rabbit model,the foam displayed excellent biocompatibility,and provided a good support to prevent tubal adhesion.As such,this work provides the foam material as a promising candidate for fallopian tube stent to remedy the tubal adhesion.展开更多
With the rapid development of high-power-density electronic devices,interface thermal resistance has become a critical barrier for effective heat management in high-performance electronic products.Therefore,there is a...With the rapid development of high-power-density electronic devices,interface thermal resistance has become a critical barrier for effective heat management in high-performance electronic products.Therefore,there is an urgent demand for advanced thermal interface materials(TIMs)with high cross-plane thermal conductivity and excellent compressibility to withstand increasingly complex operating conditions.To achieve this aim,a promising strategy involves vertically arranging highly thermoconductive graphene on polymers.However,with the currently available methods,achieving a balance between low interfacial thermal resistance,bidirectional high thermal conductivity,and large-scale production is challenging.Herein,we prepared a graphene framework with continuous filler structures in in-plane and cross-plane directions by bonding corrugated graphene to planar graphene paper.The interface interaction between the graphene paper framework and polymer matrix was enhanced via surface functionalization to reduce the interface thermal resistance.The resulting three-dimensional thermal framework endows the polymer composite material with a cross-plane thermal conductivity of 14.4 W·m^(-1)·K^(-1)and in-plane thermal conductivity of 130W·m^(-1)·K^(-1)when the thermal filler loading is 10.1 wt%,with a thermal conductivity enhancement per 1 wt%filler loading of 831%,outperforming various graphene structures as fillers.Given its high thermal conductivity,low contact thermal resistance,and low compressive modulus,the developed highly thermoconductive composite material demonstrates superior performance in TIM testing compared with TFLEX-700,an advanced commercial TIM,effectively solving the interfacial heat transfer issues in electronic systems.This novel filler structure framework also provides a solution for achieving a balance between efficient thermal management and ease of processing.展开更多
The structural properties of jadeite at high pressures (0.000 1-30 GPa) are investigated using plane-wave pseudopotential density functional theory method. As a function of pressure, the monoclinic cell parameters w...The structural properties of jadeite at high pressures (0.000 1-30 GPa) are investigated using plane-wave pseudopotential density functional theory method. As a function of pressure, the monoclinic cell parameters were calculated and the compressibility coefficients are 0.002 6, 0.002 3 and 0.002 6 GPal, respectively. The bond length, bond angle and distortion variation were studied in order to obtain the information of polyhedral compression. The pressure-volume equation of state was con- sidered in order to obtain the bulk modulus K0. Comparison between the calculated K0 values and the experimental data suggested that the model provides reasonable insights into crystallographic and physical properties of jadeite.展开更多
The aim of this work was to determine the effect of formulation of alginate beads on their mechanical behavior and stiffness when compressed at high speed. The alginate beads were formulated using different types and ...The aim of this work was to determine the effect of formulation of alginate beads on their mechanical behavior and stiffness when compressed at high speed. The alginate beads were formulated using different types and concentrations of alginate and gelling cations and were produced using an extrusiondripping method, Single wet beads were compressed at a speed of 40 mm/min, and their elastic limits were investigated, and the corresponding force versus displacement data were obtained. The Young's moduli of the beads were determined from the force versus displacement data using the Hertz's contact mechanics theory. The alginate beads were found to exhibit plastic behavior when they were compressed beyond 50% with the exception of copper-alginate beads for which yield occured at lower deformation, Alginate beads made of higher guluronic acid contents and gelling cations of higher chemical affinity were found to have greater stiffness. Increasing the concentration of alginate and gelling ions also generated a similar effect. At such a compression speed, the values of Young's modulus of the beads were found to be in the range between 250 and 900 kPa depending on the bead formulation.展开更多
文摘Ultrahigh-strength mortar mixed surface-oxidized silicon carbide as a fine aggregate was prepared by means of press-casting followed by curing in an autoclave. The relation between modulus of elssticity up to 111 GPa and compressive strength up to 360 MPa of mortar mixed silicon carbide was discussed and it was revealed that the contributions of the aggregate hardness and of the interfacial strength between the aggregate and the cement paste on the elasticity of mortar were imporant.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11174045 and 11404050)
文摘The unreacted equation of state(EOS) of energetic materials is an important thermodynamic relationship to characterize their high pressure behaviors and has practical importance. The previous experimental and theoretical works on the equation of state of several energetic materials including nitromethane, 1,3,5-trinitrohexahydro-1,3,5-triazine(RDX),1,3,5,7-tetranitro-1,3,5,7-tetrazacyclooctane(HMX), hexanitrostilbene(HNS), hexanitrohexaazaisowurtzitane(HNIW or CL-20), pentaerythritol tetranitrate(PETN), 2,6-diamino-3,5-dinitropyrazine-1-oxide(LLM-105), triamino-trinitrobenzene(TATB), 1,1-diamino-2,2-dinitroethene(DADNE or FOX-7), and trinitrotoluene(TNT) are reviewed in this paper. The EOS determined from hydrostatic and non-hydrostatic compressions are discussed and compared. The theoretical results based on ab initio calculations are summarized and compared with the experimental data.
文摘Recently,many regression models have been presented for prediction of mechanical parameters of rocks regarding to rock index properties.Although statistical analysis is a common method for developing regression models,but still selection of suitable transformation of the independent variables in a regression model is diffcult.In this paper,a genetic algorithm(GA)has been employed as a heuristic search method for selection of best transformation of the independent variables(some index properties of rocks)in regression models for prediction of uniaxial compressive strength(UCS)and modulus of elasticity(E).Firstly,multiple linear regression(MLR)analysis was performed on a data set to establish predictive models.Then,two GA models were developed in which root mean squared error(RMSE)was defned as ftness function.Results have shown that GA models are more precise than MLR models and are able to explain the relation between the intrinsic strength/elasticity properties and index properties of rocks by simple formulation and accepted accuracy.
基金supported by National Natural Science Foundation of China(Nos.11505121 and 51171124)
文摘The physical vapor deposition method is an effective way to deposit Al2O3 and Er2O3 on 316 L stainless steel substrates acting as tritium permeation barriers in a fusion reactor. The distribution of residual thermal stress is calculated both in Al2O3 and Er2O3 coating systems with planar and rough substrates using finite element analysis. The parameters influencing the thermal stress in the sputter process are analyzed, such as coating and substrate properties, temperature and Young's modulus. This work shows that the thermal stress in Al2O3 and Er2O3 coating systems exhibit a linear relationship with substrate thickness, temperature and Young's modulus.However, this relationship is inversed with coating thickness. In addition, the rough substrate surface can increase the thermal stress in the process of coating deposition. The adhesive strength between the coating and the substrate is evaluated by the shear stress. Due to the higher compressive shear stress, the Al2O3 coating has a better adhesive strength with a 316 L stainless steel substrate than the Er2O3 coating. Furthermore, the analysis shows that it is a useful way to improve adhesive strength with increasing interface roughness.
基金Funded by the National Natural Science Foundation of China(51438007)the National Basic Research Program of China(973 Program)(2009CB623203)
文摘Service life of reinforced concrete structures usually was designed on the basis of one selected deteriorating mechanism as for instance carbonation,chloride penetration,and frost action.It could be shown in the meantime by numerous authors,however,that combined actions such as chloride penetration under mechanical load or chloride penetration in combination with freeze-thaw cycles may shorten the service life of reinforced concrete structures more than individual processes acting alone.We have found that chloride penetration is accelerated significantly by freeze-thaw cycles.Frost damage not only reduces mechanical strength and elastic modulus but migration of chloride is facilitated in the damaged pore structure.Chloride penetration can be retarded by the addition of silane emulsion to the fresh concrete.In this way Integral Water Repellent Concrete(IWRC) can be produced.Migration of water and ions dissolved in water can not be prevented by integral water repellent treatment but it is slowed down.The combination of damage mechanisms and the protective measures by integral water repellent treatment have to be taken into consideration in realistic service life prediction and design.
基金supported by Ministry of Education of the People’s Republic of China-Joint Foundation of China-Japan Friendship Hospital&Beijing University of Chemical Technology(XK2020-12).
文摘Tubal pregnancy is a common abnormal pregnancy manifestation,and the ordinary conservative treatment of tubal adhesion usually leads to the rupture of fallopian tube,which increases the risk of a second ectopic pregnancy.To avoid this symptom,it is suitable to implant a stent to separate the adhesion.Here we prepared the PBAT/PLGA foam as the stent material using supercritical CO_(2) foaming technology.With uniform macroporous structure and thin-wall feature,the foam possessed low compressive modulus in prevention of the possible second injury to the fallopian tube.The introduction of PLGA 50/50 improved the biodegradable capability of the foam,with a mass loss about 20% after a 12-week hydrolysis.After implanted into the ruptured fallopian tube of the rabbit model,the foam displayed excellent biocompatibility,and provided a good support to prevent tubal adhesion.As such,this work provides the foam material as a promising candidate for fallopian tube stent to remedy the tubal adhesion.
基金financially supported by the National Natural Science Foundation of China(Nos.52130303,52327802 and 52173078)National Key R&D Program of China(No.2022YFB3805702)。
文摘With the rapid development of high-power-density electronic devices,interface thermal resistance has become a critical barrier for effective heat management in high-performance electronic products.Therefore,there is an urgent demand for advanced thermal interface materials(TIMs)with high cross-plane thermal conductivity and excellent compressibility to withstand increasingly complex operating conditions.To achieve this aim,a promising strategy involves vertically arranging highly thermoconductive graphene on polymers.However,with the currently available methods,achieving a balance between low interfacial thermal resistance,bidirectional high thermal conductivity,and large-scale production is challenging.Herein,we prepared a graphene framework with continuous filler structures in in-plane and cross-plane directions by bonding corrugated graphene to planar graphene paper.The interface interaction between the graphene paper framework and polymer matrix was enhanced via surface functionalization to reduce the interface thermal resistance.The resulting three-dimensional thermal framework endows the polymer composite material with a cross-plane thermal conductivity of 14.4 W·m^(-1)·K^(-1)and in-plane thermal conductivity of 130W·m^(-1)·K^(-1)when the thermal filler loading is 10.1 wt%,with a thermal conductivity enhancement per 1 wt%filler loading of 831%,outperforming various graphene structures as fillers.Given its high thermal conductivity,low contact thermal resistance,and low compressive modulus,the developed highly thermoconductive composite material demonstrates superior performance in TIM testing compared with TFLEX-700,an advanced commercial TIM,effectively solving the interfacial heat transfer issues in electronic systems.This novel filler structure framework also provides a solution for achieving a balance between efficient thermal management and ease of processing.
基金supported by the National Natural Science Foundation of China(Nos.41172051,40872039 and 90714002)the Specialized Research Fund for the Doctoral Program of Higher Education of China(No.20060491504)
文摘The structural properties of jadeite at high pressures (0.000 1-30 GPa) are investigated using plane-wave pseudopotential density functional theory method. As a function of pressure, the monoclinic cell parameters were calculated and the compressibility coefficients are 0.002 6, 0.002 3 and 0.002 6 GPal, respectively. The bond length, bond angle and distortion variation were studied in order to obtain the information of polyhedral compression. The pressure-volume equation of state was con- sidered in order to obtain the bulk modulus K0. Comparison between the calculated K0 values and the experimental data suggested that the model provides reasonable insights into crystallographic and physical properties of jadeite.
基金the Ministry of Higher Education (MOHE),Malaysia for providing financial support under Fundamental Research Grant Scheme
文摘The aim of this work was to determine the effect of formulation of alginate beads on their mechanical behavior and stiffness when compressed at high speed. The alginate beads were formulated using different types and concentrations of alginate and gelling cations and were produced using an extrusiondripping method, Single wet beads were compressed at a speed of 40 mm/min, and their elastic limits were investigated, and the corresponding force versus displacement data were obtained. The Young's moduli of the beads were determined from the force versus displacement data using the Hertz's contact mechanics theory. The alginate beads were found to exhibit plastic behavior when they were compressed beyond 50% with the exception of copper-alginate beads for which yield occured at lower deformation, Alginate beads made of higher guluronic acid contents and gelling cations of higher chemical affinity were found to have greater stiffness. Increasing the concentration of alginate and gelling ions also generated a similar effect. At such a compression speed, the values of Young's modulus of the beads were found to be in the range between 250 and 900 kPa depending on the bead formulation.