Ultrasonic speeds of 4-aminobutyric acid in 0.0041,0.0125 and 0.0207 mol·kg^-1 aqueous salbutamol sulphate（SBS） solutions are measured at 308.15,313.15 and 318.15 K.Isentropic compressibility kS,change in isent...Ultrasonic speeds of 4-aminobutyric acid in 0.0041,0.0125 and 0.0207 mol·kg^-1 aqueous salbutamol sulphate（SBS） solutions are measured at 308.15,313.15 and 318.15 K.Isentropic compressibility kS,change in isentropic compressibility△k S,relative change in isentropic compressibility（ △kS /kS^0） ,apparent molal compressibility kφ,limiting apparent molal compressibility kφ^0 ,transfer limiting apparent molal compressibility k φ^0,hydration number nH,pair and triplet interaction parameters kAS,kASS are estimated.The above parameters are used to interpret the solute-solute and solute-solvent interactions of 4-aminobutyric acid in the aqueous salbutamol sulphate solutions.展开更多
The authors study the compressible limit of the nonlinear Schrdinger equation with different-degree small parameter nonlinearities in small time for initial data with Sobolev regularity before the formation of singula...The authors study the compressible limit of the nonlinear Schrdinger equation with different-degree small parameter nonlinearities in small time for initial data with Sobolev regularity before the formation of singularities in the limit system.On the one hand,the existence and uniqueness of the classical solution are proved for the dispersive perturbation of the quasi-linear symmetric system corresponding to the initial value problem of the above nonlinear Schrdinger equation.On the other hand,in the limit system,it is shown that the density converges to the solution of the compressible Euler equation and the validity of the WKB expansion is justified.展开更多
The aim of this work was to determine the effect of formulation of alginate beads on their mechanical behavior and stiffness when compressed at high speed. The alginate beads were formulated using different types and ...The aim of this work was to determine the effect of formulation of alginate beads on their mechanical behavior and stiffness when compressed at high speed. The alginate beads were formulated using different types and concentrations of alginate and gelling cations and were produced using an extrusiondripping method, Single wet beads were compressed at a speed of 40 mm/min, and their elastic limits were investigated, and the corresponding force versus displacement data were obtained. The Young＇s moduli of the beads were determined from the force versus displacement data using the Hertz＇s contact mechanics theory. The alginate beads were found to exhibit plastic behavior when they were compressed beyond 50% with the exception of copper-alginate beads for which yield occured at lower deformation, Alginate beads made of higher guluronic acid contents and gelling cations of higher chemical affinity were found to have greater stiffness. Increasing the concentration of alginate and gelling ions also generated a similar effect. At such a compression speed, the values of Young＇s modulus of the beads were found to be in the range between 250 and 900 kPa depending on the bead formulation.展开更多
文摘Ultrasonic speeds of 4-aminobutyric acid in 0.0041,0.0125 and 0.0207 mol·kg^-1 aqueous salbutamol sulphate（SBS） solutions are measured at 308.15,313.15 and 318.15 K.Isentropic compressibility kS,change in isentropic compressibility△k S,relative change in isentropic compressibility（ △kS /kS^0） ,apparent molal compressibility kφ,limiting apparent molal compressibility kφ^0 ,transfer limiting apparent molal compressibility k φ^0,hydration number nH,pair and triplet interaction parameters kAS,kASS are estimated.The above parameters are used to interpret the solute-solute and solute-solvent interactions of 4-aminobutyric acid in the aqueous salbutamol sulphate solutions.
基金Project supported by the National Natural Science Foundation of China (Nos.10801102,10771151)the Sichuan Youth Sciences and Technology Foundation (No.07ZQ026-009)the China Postdoctoral Science Foundation
文摘The authors study the compressible limit of the nonlinear Schrdinger equation with different-degree small parameter nonlinearities in small time for initial data with Sobolev regularity before the formation of singularities in the limit system.On the one hand,the existence and uniqueness of the classical solution are proved for the dispersive perturbation of the quasi-linear symmetric system corresponding to the initial value problem of the above nonlinear Schrdinger equation.On the other hand,in the limit system,it is shown that the density converges to the solution of the compressible Euler equation and the validity of the WKB expansion is justified.
基金the Ministry of Higher Education (MOHE),Malaysia for providing financial support under Fundamental Research Grant Scheme
文摘The aim of this work was to determine the effect of formulation of alginate beads on their mechanical behavior and stiffness when compressed at high speed. The alginate beads were formulated using different types and concentrations of alginate and gelling cations and were produced using an extrusiondripping method, Single wet beads were compressed at a speed of 40 mm/min, and their elastic limits were investigated, and the corresponding force versus displacement data were obtained. The Young＇s moduli of the beads were determined from the force versus displacement data using the Hertz＇s contact mechanics theory. The alginate beads were found to exhibit plastic behavior when they were compressed beyond 50% with the exception of copper-alginate beads for which yield occured at lower deformation, Alginate beads made of higher guluronic acid contents and gelling cations of higher chemical affinity were found to have greater stiffness. Increasing the concentration of alginate and gelling ions also generated a similar effect. At such a compression speed, the values of Young＇s modulus of the beads were found to be in the range between 250 and 900 kPa depending on the bead formulation.
