We prepared concretes(RC0, RC30, and RC100) with three different mixes. The poresize distribution parameters of RAC were examined by high-precision mercury intrusion method(MIM) and nuclear magnetic resonance(NMR...We prepared concretes(RC0, RC30, and RC100) with three different mixes. The poresize distribution parameters of RAC were examined by high-precision mercury intrusion method(MIM) and nuclear magnetic resonance(NMR) imaging. A capillary-bundle physical model with random-distribution pores(improved model, IM) was established according to the parameters, and dry-shrinkage strain values were calculated and verified. Results show that in all pore types, capillary pores, and gel pores have the greatest impacts on concrete shrinkage, especially for pores 2.5-50 and 50-100 nm in size. The median radii are 34.2, 31, and 34 nm for RC0, RC30, and RC100, respectively. Moreover, the internal micropore size distribution of RC0 differs from that of RC30 and RC100, and the pore descriptions of MIM and NMR are consistent both in theory and in practice. Compared with the traditional capillary-bundle model, the calculated results of IM have higher accuracy as demonstrated by experimental verifi cation.展开更多
Hydration process, crack potential and setting time of concrete grade C30, C40 and C50 were monitored by using a non-contact electrical resistivity apparatus, a novel plastic ring mould and penetration resistance meth...Hydration process, crack potential and setting time of concrete grade C30, C40 and C50 were monitored by using a non-contact electrical resistivity apparatus, a novel plastic ring mould and penetration resistance methods, respectively. The results show the highest resistivity of C30 at the early stage until a point when C50 accelerated and overtook the others. It has been experimentally confirmed that the crossing point of C30 and C50 corresponds to the final setting time of C50. From resistivity derivative curve, four different stages were observed upon which the hydration process is classified; these are dissolution, induction, acceleration and deceleration periods. Consequently, restrained shrinkage crack and setting time results demonstrated that C50 set and cracked the earliest. The cracking time of all the samples occurred within a reasonable experimental period thus the novel plastic ring is a convenient method for predicting concrete's crack potential. The highest inflection time(t_i) obtained from resistivity curve and the final setting time(t_f) were used with crack time(t_c) in coming up with mathematical models for the prediction of concrete's cracking age for the range of concrete grade considered. Finally, an ANSYS numerical simulation supports the experimental findings in terms of the earliest crack age of C50 and the crack location.展开更多
A new type of concrete expansion agent has been successfully developed for the first time in the world by utilizing an industrial waste residue soda residue and an industrial wasteliquor.Adding 3%-6% of the agent int...A new type of concrete expansion agent has been successfully developed for the first time in the world by utilizing an industrial waste residue soda residue and an industrial wasteliquor.Adding 3%-6% of the agent into Portland cement enables a shrinkage compensating concrete to be prepared.Mortar and concrete containing this expansion agent have better shrinkage compensating and mechanical properties.The raw materials component,production process,technical properties,micro analysis of mortar made with this expansion agent,mechanism of expansion and research results are described in this article.The experimental results show that the new type of concrete expansion agent accords with the standard and its main mineral component is xCaO ySO 3 zAl 2O 3.展开更多
基金Funded by the National Natural Science Foundation of China(51202304)the China Postdoctoral Science Foundation(2014M552320)+1 种基金Scientific,the Technological Talents’Special Funds of Wanzhou District and Scientific and Technological Research Program of Chongqing Municipal Education Commission(KJ1401016)the Youth Project of Chongqing Three Gorges College(13QN-20)
文摘We prepared concretes(RC0, RC30, and RC100) with three different mixes. The poresize distribution parameters of RAC were examined by high-precision mercury intrusion method(MIM) and nuclear magnetic resonance(NMR) imaging. A capillary-bundle physical model with random-distribution pores(improved model, IM) was established according to the parameters, and dry-shrinkage strain values were calculated and verified. Results show that in all pore types, capillary pores, and gel pores have the greatest impacts on concrete shrinkage, especially for pores 2.5-50 and 50-100 nm in size. The median radii are 34.2, 31, and 34 nm for RC0, RC30, and RC100, respectively. Moreover, the internal micropore size distribution of RC0 differs from that of RC30 and RC100, and the pore descriptions of MIM and NMR are consistent both in theory and in practice. Compared with the traditional capillary-bundle model, the calculated results of IM have higher accuracy as demonstrated by experimental verifi cation.
基金Funded by National Natural Science Foundation of China(Nos.51478200 and 51178202)
文摘Hydration process, crack potential and setting time of concrete grade C30, C40 and C50 were monitored by using a non-contact electrical resistivity apparatus, a novel plastic ring mould and penetration resistance methods, respectively. The results show the highest resistivity of C30 at the early stage until a point when C50 accelerated and overtook the others. It has been experimentally confirmed that the crossing point of C30 and C50 corresponds to the final setting time of C50. From resistivity derivative curve, four different stages were observed upon which the hydration process is classified; these are dissolution, induction, acceleration and deceleration periods. Consequently, restrained shrinkage crack and setting time results demonstrated that C50 set and cracked the earliest. The cracking time of all the samples occurred within a reasonable experimental period thus the novel plastic ring is a convenient method for predicting concrete's crack potential. The highest inflection time(t_i) obtained from resistivity curve and the final setting time(t_f) were used with crack time(t_c) in coming up with mathematical models for the prediction of concrete's cracking age for the range of concrete grade considered. Finally, an ANSYS numerical simulation supports the experimental findings in terms of the earliest crack age of C50 and the crack location.
文摘A new type of concrete expansion agent has been successfully developed for the first time in the world by utilizing an industrial waste residue soda residue and an industrial wasteliquor.Adding 3%-6% of the agent into Portland cement enables a shrinkage compensating concrete to be prepared.Mortar and concrete containing this expansion agent have better shrinkage compensating and mechanical properties.The raw materials component,production process,technical properties,micro analysis of mortar made with this expansion agent,mechanism of expansion and research results are described in this article.The experimental results show that the new type of concrete expansion agent accords with the standard and its main mineral component is xCaO ySO 3 zAl 2O 3.