In this study, 13 strong-gluten wheat varieties screened by the Key Project of Modern Agricultural Industry Technology System "Study on Industrial Technology for Strong-gluten Wheat from Lime Concretion Black Soil Ar...In this study, 13 strong-gluten wheat varieties screened by the Key Project of Modern Agricultural Industry Technology System "Study on Industrial Technology for Strong-gluten Wheat from Lime Concretion Black Soil Area in the Huanghuai Wheat Region" were used as experimental materials to investigate their bread-making quality, noodle-making quality and other related characteristics. The results showed that more than half of the wheat varieties had better bread-making quality; the bread made from wheat with longer dough mixing time than 3.0 min had better texture, lighter color, and better taste. All these 13 strong-gluten wheat varieties showed good noodle-making quality in color, appearance, smoothness and taste; the differences between varieties were mainly found in palatability and viscoelasticity. Jimai 20, Xinong 979, Zhengmai 7698, Ji'nan 17 and Zhengmai 9023 exhibited excellent bread-making quality; Zhengmai 366, Jimai 20 and Xinong 979 displayed excellent noodle-making quality. Fresh dough sheets made from Zhengmai 366, Jimai 20 and Xinong 979 exhibited slight color variation within 24 h and high peak starch paste viscosity; dry and cooked noodles made from Zhengmai 366, Jimai 20 and Xinong 979 had good quality.展开更多
Carbonate concretions are conspicuous in organic-rich shales and are generally related to decomposition of organic matter.The black shales from the Chang 7 Member of the Upper Triassic Yanchang Formation of the southe...Carbonate concretions are conspicuous in organic-rich shales and are generally related to decomposition of organic matter.The black shales from the Chang 7 Member of the Upper Triassic Yanchang Formation of the southern Ordos Basin host abundant carbonate concretions,which provide a unique record of depositional and early diagenetic conditions of the paleo-lake sediments.However,little attention has been given to the genesis and growth processes of the concretions in these lacustrine petroleum source rocks.New petrographic observations and geochemical analysis show that the concretions are composed of calcite,phosphate fossil fragments,K-NH4-feldspar,quartz,bitumen,and minor Fe-dolomite.Phosphate minerals,mainly carbonate fluorapatite(CFA),show pervasive replacement by calcite,most of which contains phosphorus,ranging in concentration from 0.26 to 2.35 wt%.This suggests that the phosphate minerals are the precursors for concretion growth.Positiveδ13C(+5.6 to+12.4‰V-PDB)signatures and the absence of pyrite indicate that microbial methanogenesis was the dominant driver for concretion growth,rather than bacterial sulfate reduction.Quartz,bitumen,and Fe-dolomite are the last cements that occurred,at deep burial depths and high temperatures.The formation of phosphate minerals might have been induced by upwelling of phosphate-enriched deep water in the Late Triassic paleo-lake,which promoted phytoplankton blooms and further enrichment of organic matter.Extremely slow sedimentation rates of fine-grained detrital minerals,relative to dead organism accumulation,led to the high permeabilities of the organic-rich sediments and rapid concretion growth during shallow burial.The close association of phosphate-bearing carbonate concretions and organic-rich shales reflects that upwelling played a critical role in the formation of the high-quality petroleum source rocks in the Triassic paleo-Ordos lake.展开更多
Under the condition of thick alluvia, there is biggish declination in predicting the coal mining subsidence by commonly strip design method compared with the practical observation, the sinkage is much smaller. Based o...Under the condition of thick alluvia, there is biggish declination in predicting the coal mining subsidence by commonly strip design method compared with the practical observation, the sinkage is much smaller. Based on the method of the probability integral about coal mining subsidence calculation, discussed the surface subsidence calculation and deduced the formulas caused by the clay with dewatering. The results show that the clay dewatering has great impact on surface subsidence. Therefore, the clay dewatering on surface subsidence should not be overlooked.展开更多
To analyze the bacterial communities in lime concretion black soil upon the incorporation of crop residues for two years in wheat-maize system, total DNA was directly extracted and PCR-amplified with the F357GC and R5...To analyze the bacterial communities in lime concretion black soil upon the incorporation of crop residues for two years in wheat-maize system, total DNA was directly extracted and PCR-amplified with the F357GC and R518 primers targeting the 16S rRNA genes of V3 region. The amplified fragments were analyzed by perpendicular DGGE. Analyzing of species richness index S and Shannon diversity index H revealed that there was a high diversity of soil bacterial community compositions among all treatments after incorporation of crop residues and fertilizing under field conditions. Eleven DGGE bands recovered were re-amplified, sequenced. Phylogenetic analysis of the representative DGGE fingerprints identified four groups of the prokaryotic communities in the soil by returning wheat residues and fertilizing under field conditions. The bacterial communities belonged to gamma proteobacterium, Cupriavidus sp, halophilic eubacterium, Acidobacterium sp, Sorangium sp, delta proteobacterium, Streptococcus sp and Streptococcus agalactiae were main bacterial communities. Principal Component Analysis (PCA) showed that there were the differences in DNA profiles among the six treatments. It showed that wheat residue returning, maize residue returning and fertilizing all can improve bacterial diversity in varying degrees. As far as improvement of bacterial diversity was concerned, wheat residue returning was higher than fertilizing, and fertilizing higher than maize residue returning.展开更多
The Early Cambrian Niutitang Formation is characterized by wide distribution of black shales on Yangtze Block,South China.Here we have reported the pyrite concretions in the bottom of the Niutitang Formation deposited...The Early Cambrian Niutitang Formation is characterized by wide distribution of black shales on Yangtze Block,South China.Here we have reported the pyrite concretions in the bottom of the Niutitang Formation deposited in the slope-basin environment of Yangtze Block.The pyrite concretion was mainly composed of pyrite associated with hydrothermal minerals(barite,hyalophane,tetrahedrite),followed by quartz and organic matter.Trace elements Mo and U displayed significant enrichment(enrichment factors > 10),indicating the euxinic bottom water condition.Cu,Ni,and excess Ba concentrations were relatively high,denoting high primary productivity.In-situ sulfur isotope compositions of pyrite concretions δ34Spy) showed little variations(13.2‰–19.4‰) and small fractionations compared to coeval seawater δ34Sso4.Petrological and geochemical analyses indicated the pyrite concretions were formed in the sediment-water interface during the early diagenesis,with H2S diffusing from the euxinic water,and influenced by hydrothermal activity leading to the coexistence of barite,hyalophane,and tetrahedrite.These results imply euxinic bottom water featured by high primary productivity and increasing riverine flux of sulfate from chemical weathering during the Early Cambrian.展开更多
Dear Editor,This letter presents an intelligent small sample defect detection of concrete surface using novel deep learning integrating the improved YOLOv5 based on the Wasserstein GAN(WGAN)enhancement algorithm.The p...Dear Editor,This letter presents an intelligent small sample defect detection of concrete surface using novel deep learning integrating the improved YOLOv5 based on the Wasserstein GAN(WGAN)enhancement algorithm.The proposed method is capable of producing top-notch data sets to address the issues of insufficient samples and substandard quality.展开更多
To promote the production and application of artificial aggregates,save natural sand resources and protect the ecological environment,we evaluated the feasibility of using spherical porous functional aggregates(SPFAs)...To promote the production and application of artificial aggregates,save natural sand resources and protect the ecological environment,we evaluated the feasibility of using spherical porous functional aggregates(SPFAs) formed by basalt saw mud under autoclave curing in ordinary structural concrete.In our work,two types of prewetted functional aggregates were taken as replacements for natural aggregates with different volume substitution rates(0%,5%,10%,15%,20%,25%,and 30%) in the preparation of ordinary structural concrete with water-to-binder ratios(W/B) of 0.48 and 0.33.The effects of the functional aggregate properties and content,W/B,and curing age on the fluidity,density,mechanical properties and autogenous shrinkage of ordinary concrete were analyzed.The experimental results showed that the density of concrete declined at a rate of not more than 5%,and the 28 d compressive strength could reach 31.0-68.2 MPa.Low W/B,long curing age and high-quality functional aggregates were conducive to enhancing the mechanical properties of SPFAs concrete.Through the rolling effects,SPFAs can optimize the particle gradation of aggregate systems and improve the fluidity of concrete,and the water stored inside SPFAs provides an internal curing effect,which prolongs the cement hydration process and considerably reduces the autogenous shrinkage of concrete.SPFAs exhibits high strength and high density,as well as being more cost-effective and ecological,and is expected to be widely employed in ordinary structural concrete.展开更多
The majority of the projectiles used in the hypersonic penetration study are solid flat-nosed cylindrical projectiles with a diameter of less than 20 mm.This study aims to fill the gap in the experimental and analytic...The majority of the projectiles used in the hypersonic penetration study are solid flat-nosed cylindrical projectiles with a diameter of less than 20 mm.This study aims to fill the gap in the experimental and analytical study of the evolution of the nose shape of larger hollow projectiles under hypersonic penetration.In the hypersonic penetration test,eight ogive-nose AerMet100 steel projectiles with a diameter of 40 mm were launched to hit concrete targets with impact velocities that ranged from 1351 to 1877 m/s.Severe erosion of the projectiles was observed during high-speed penetration of heterogeneous targets,and apparent localized mushrooming occurred in the front nose of recovered projectiles.By examining the damage to projectiles,a linear relationship was found between the relative length reduction rate and the initial kinetic energy of projectiles in different penetration tests.Furthermore,microscopic analysis revealed the forming mechanism of the localized mushrooming phenomenon for eroding penetration,i.e.,material spall erosion abrasion mechanism,material flow and redistribution abrasion mechanism and localized radial upsetting deformation mechanism.Finally,a model of highspeed penetration that included erosion was established on the basis of a model of the evolution of the projectile nose that considers radial upsetting;the model was validated by test data from the literature and the present study.Depending upon the impact velocity,v0,the projectile nose may behave as undistorted,radially distorted or hemispherical.Due to the effects of abrasion of the projectile and enhancement of radial upsetting on the duration and amplitude of the secondary rising segment in the pulse shape of projectile deceleration,the predicted DOP had an upper limit.展开更多
Over the past few decades,one of the most significant advances in dam construction has been the inven-tion of the rock-filled concrete(RFC)dam,which is constructed by pouring high-performance self-compacting concrete(...Over the past few decades,one of the most significant advances in dam construction has been the inven-tion of the rock-filled concrete(RFC)dam,which is constructed by pouring high-performance self-compacting concrete(HSCC)to fill the voids in preplaced large rocks.The innovative use of large rocks in dam construction provides engineers with a material that requires less cement consumption and hydration heat while enhancing construction efficiency and environmental friendliness.However,two fundamental scientific issues related to RFC need to be addressed:namely,the pouring compactness and the effect of large rocks on the mechanical and physical properties of RFC.This article provides a timely review of fundamental research and innovations in the design,construction,and quality control of RFCdams.Prospects for next-generation concrete dams are discussed from the perspectives of envi-ronmental friendliness,intrinsic safety,and labor savings.展开更多
Türkiye is located in a seismically active region,where the Anatolian,African,and Arabian tectonic plates converge.High seismic hazards cause the region to be struck repeatedly by major earthquakes.On February 06...Türkiye is located in a seismically active region,where the Anatolian,African,and Arabian tectonic plates converge.High seismic hazards cause the region to be struck repeatedly by major earthquakes.On February 06,2023,a devastating M_(W)7.7 earthquake struck Türkiye at 01:17 am local time(01:17 UTC).In this regard,near and far-field ground motion data within the distance of 120 km are compiled and later characterized to identify the key ground motion intensity measures.Additionally,the vertical components of ground motions were examined to capture the complete three-dimensional nature of the seismic event.Moreover,the effect of Pulse-Like(PL)and Non-Pulse-Like(NPL)ground motion on a representative RC frame structure built as per the Türkiye code was investigated.The results indicate that PL behavior was observed in both horizontal and vertical components of ground motions and PL behavior were noted both near the epicenter and at higher distances from the epicenter.Moreover,the ratio of the peak vertical acceleration to peak horizontal acceleration at certain stations was found to be close to 1.Finally,the non-linear time history analysis of the representative reinforced concrete frame structure for ground motions recorded at stations located equidistant from the epicenter,indicated that PL ground motions led to more significant damage compared to NPL ground motions.展开更多
Mineralogical and textural characteristics and organic carbon composition of the carbonate concretions from the upper Doushantuo Formation (ca. 551 Ma) in the eastern Yangtze Gorge area reveal their early diagenetic (...Mineralogical and textural characteristics and organic carbon composition of the carbonate concretions from the upper Doushantuo Formation (ca. 551 Ma) in the eastern Yangtze Gorge area reveal their early diagenetic (shallow) growth in organic-rich shale. High organic carbon content (up to 10%) and abundance of framboidal pyrites in the hosting shale suggest an anoxic or euxinic depositional environment. Well-preserved cardhouse clay fabrics in the concretions suggest their formation at 0-3 m burial depth, likely associated with microbial decomposition of organic matter and anaerobic oxidation of methane. Gases through decomposition of organic matter and/or from methanogenesis created bubbles and cavities, and anaerobic methane oxidation at the sulfate reduction zone resulted in carbonate precipitation, filling in bubbles and cavities to form spherical structures of the concretions. Rock pyrolysis analyses show that the carbonate concretions have lower total organic carbon (TOC) content but higher effective carbon than those in the host rocks. This may be caused by enclosed organic matter in pores of the concretions so that organic matter was protected from further modification during deep burial and maintained high hydrocarbon generating potential even in over-matured source rock. As a microbialite sensu latu, concretions have special growth conditions and may provide important information on the microbial activities in depositional and early burial environments.展开更多
Carbonate concretions provide unique records of ancient biogeochemical processes in marine sediments, and have the potential to reflect seawater chemistry indirectly. In fine-siliciclastic settings, they preferentiall...Carbonate concretions provide unique records of ancient biogeochemical processes in marine sediments, and have the potential to reflect seawater chemistry indirectly. In fine-siliciclastic settings, they preferentially form in organicrich mudstones, owing to a significant fraction of the bicarbonate required for carbonate precipitation resulted from the decomposition of organic matter in sediments. In the Member IV of the Xiamaling Formation(ca. 1.40–1.35 Ga), North China, however, carbonate concretions occur in organic-poor green silty shales(avg. TOC = ~ 0.1 wt%).In order to elucidate the mechanism of the concretion formation and their environmental implications, a thorough study on the petrographic and geochemical compositions of the concretions and their host rocks was conducted.Macro-to microscopic fabrics, including deformed shale laminae surrounding the concretions, "cardhouse"structures of clay minerals and calcite geodes in the concretions, indicate that these concretions are of early diagenetic origin prior to the significant compaction of clay minerals. The carbon isotope compositions of the concretions(-1.7‰ to + 1.5‰) are stable and close to or slightly lower than that of the contemporaneous seawater, indicating that the bicarbonates required for the concretion formation were mainly sourced from seawater by diffusion rather than produced by methanogenesis or anoxic oxidation of methane(AOM); the rare occurrence of authigenic pyrite grains in the concretions likely indicates that bacterial sulfate reduction(BSR) did not play a significant role in their formation either. Almost all the calcite in the concretions has low Mn–Fe in nuclei but high Mn–Fe in rims with average Mn/Fe ratio close to 3.3. The calcite shows positive Ce anomalies(avg. 1.43)and low Y/Ho ratios(avg. 31). This evidence suggests that Mn reduction is the dominant process responsible for the formation of calcite rims while nitrate reduction probably triggered the precipitation of calcite nuclei.Prominence of Mn reduction in the porewater likely indicates that there was sufficient oxygen to support active Mn-redox cycling in the overlying seawater.展开更多
In an attempt to provide more data about the mechanics of transition metal occurrence and translocation in soil environments, Fe-Mn concretions are separated from bulk samples of representative soil types and the elem...In an attempt to provide more data about the mechanics of transition metal occurrence and translocation in soil environments, Fe-Mn concretions are separated from bulk samples of representative soil types and the element contents are determined. The results are reported and discussed in the sense of environmental geochemistry in this article.展开更多
After exposure to freeze-thaw cycles, scanning electron microscopy(SEM) and nuclear magnetic resonance(NMR) were used to test the four mixtures. The microstructure is qualitatively analyzed from the 2D SEM image and t...After exposure to freeze-thaw cycles, scanning electron microscopy(SEM) and nuclear magnetic resonance(NMR) were used to test the four mixtures. The microstructure is qualitatively analyzed from the 2D SEM image and the 3D pore distribution curve before and after freezing and thawing. The fractal dimension is utilized to characterize the two-dimensional topography image and the three-dimensional pore distribution, quantitatively. The results reveal that the surface porosity and volume porosity increase as the freeze-thaw action increases. Self-similarity characteristics exist in micro-damage inside the concrete. In the fractal dimension, it is possible to characterize pore evolution quantitatively. The fractal dimension correlates with pore damage evolution. The fractal dimension effectively quantitatively characterizes micro-damage features at various scales from the local to the global level.展开更多
Monte Carlo simulations were carried out to generate a mesoscale model of concrete with randomly packed aggregates with different shapes and sizes.The mechanical properties of concrete specimens under uniaxial tensile...Monte Carlo simulations were carried out to generate a mesoscale model of concrete with randomly packed aggregates with different shapes and sizes.The mechanical properties of concrete specimens under uniaxial tensile loads were studied using statistical results.The results indicated that the entire process of damage and failure of specimens exhibited mainly two failure types:fracture patternsⅠandⅡ.Furthermore,the influences of the aggregate content ratio,aggregate shape,aggregate size,interfacial transition zone(ITZ)strength,and porosity ratio on the concrete specimens were analyzed.The numerical simulation results showed that the elastic modulus of the concrete specimens increased approximately linearly with the aggregate volume ratio but decreased linearly with the porosity and was not affected by the ITZ strength.The tensile strength decreased with the increases in the aggregate content and porosity of the sample,but increased linearly with the ITZ strength.In addition,the aggregate shape led to a difference in the tensile strength of the concrete.展开更多
An exquisite mesostructure model was presented to predict the effective elastic modulus of concrete,in which concrete is realized as a four-phase composite material consisting of coarse aggregates,mortar matrix,interf...An exquisite mesostructure model was presented to predict the effective elastic modulus of concrete,in which concrete is realized as a four-phase composite material consisting of coarse aggregates,mortar matrix,interfacial transition zone(ITZ),and initial defects.With the three-dimensional(3D)finite element(FE)simulation,the highly heterogeneous composite elastic behavior of concrete was modeled,and the predicted results were compared with theoretical estimations for validation.Monte Carlo(MC)simulations were performed with the proposed mesostructure model to investigate the various factors of initial defects influencing the elastic modulus of concrete,such as the shape and concentration(pore volume fraction or crack density)of microspores and microcracks.It is found that the effective elastic modulus of concrete decreases with the increase of initial defects concentration,while the distribution and shape characteristics also exert certain influences due to the stress concentration caused by irregular inclusion shape.展开更多
We developed ultra-high performance concrete(UHPC)incorporating mullite sand and brown corundum sand(BCS),and the quartz sand UHPC was utilized to prepare for comparison.The properties of compressive strength,elastic ...We developed ultra-high performance concrete(UHPC)incorporating mullite sand and brown corundum sand(BCS),and the quartz sand UHPC was utilized to prepare for comparison.The properties of compressive strength,elastic modulus,ultrasonic pulse velocity,flexural strength,and toughness were investigated.Scanning electron microscopy and nanoindentation were also conducted to reveal the underlying mechanisms affecting macroscopic performance.Due to the superior interface bonding properties between mullite sand and matrix,the compressive strength and flexural toughness of UHPC have been significantly improved.Mullite sand and BCS aggregates have higher stiffness than quartz sand,contributing to the excellent elastic modulus exhibited by UHPC.The stiffness and volume of aggregates have a more significant impact on the elastic modulus of UHPC than interface performance,and the latter contributes more to the strength of UHPC.This study will provide a reference for developing UHPC with superior elastic modulus for structural engineering.展开更多
This paper explores the performances of a finite element simulation including four concrete models applied to a full-scale reinforced concrete beam subjected to blast loading. Field test data has been used to compare ...This paper explores the performances of a finite element simulation including four concrete models applied to a full-scale reinforced concrete beam subjected to blast loading. Field test data has been used to compare model results for each case. The numerical modelling has been, carried out using the suitable code LS-DYNA. This code integrates blast load routine(CONWEP) for the explosive description and four different material models for the concrete including: Karagozian & Case Concrete, Winfrith, Continuous Surface Cap Model and Riedel-Hiermaier-Thoma models, with concrete meshing based on 10, 15, and 20 mm. Six full-scale beams were tested: four of them used for the initial calibration of the numerical model and two more tests at lower scaled distances. For calibration, field data obtained employing pressure and accelerometers transducers were compared with the results derived from the numerical simulation. Damage surfaces and the shape of rupture in the beams have been used as references for comparison. Influence of the meshing on accelerations has been put in evidence and for some models the shape and size of the damage in the beams produced maximum differences around 15%. In all cases, the variations between material and mesh models are shown and discussed.展开更多
The modification methods of pozzolan slurry combined with sodium silicate and silicon-based additive were respectively adopted to treat recycled coarse brick-mixed aggregate(RCBA)in this study.The compressive strength...The modification methods of pozzolan slurry combined with sodium silicate and silicon-based additive were respectively adopted to treat recycled coarse brick-mixed aggregate(RCBA)in this study.The compressive strength and chloride permeability resistance of recycled aggregate concrete(RAC)before and after modification treatment were tested,and the microstructure of RAC was analyzed by mercury intrusion porosimetry(MIP)and scanning electron microscopy(SEM).The results show that the physical properties of RCBA strengthened by modification treatment are improved,and the compressive strength and chloride permeability resistance of treated RAC are also significantly improved.The modification treatment optimizes the pore size distribution of RAC,which increases the number of gel pores and transition pores,and decreases the number of capillary pores and macro pores.The surface fractal dimension shows a significant correlation with chloride diffusion coefficient,indicating that the variation of chloride permeability of treated RAC is consistent with the microstructure evolution.展开更多
基金Supported by Earmarked Fund for Modern Agro-industry Technology Research System(CARS-03)Special Fund for Seed Industry Construction from Taishan Scholar FoundationNational Science and Technology Major Project for Genetic Improvement of Crop Quality~~
文摘In this study, 13 strong-gluten wheat varieties screened by the Key Project of Modern Agricultural Industry Technology System "Study on Industrial Technology for Strong-gluten Wheat from Lime Concretion Black Soil Area in the Huanghuai Wheat Region" were used as experimental materials to investigate their bread-making quality, noodle-making quality and other related characteristics. The results showed that more than half of the wheat varieties had better bread-making quality; the bread made from wheat with longer dough mixing time than 3.0 min had better texture, lighter color, and better taste. All these 13 strong-gluten wheat varieties showed good noodle-making quality in color, appearance, smoothness and taste; the differences between varieties were mainly found in palatability and viscoelasticity. Jimai 20, Xinong 979, Zhengmai 7698, Ji'nan 17 and Zhengmai 9023 exhibited excellent bread-making quality; Zhengmai 366, Jimai 20 and Xinong 979 displayed excellent noodle-making quality. Fresh dough sheets made from Zhengmai 366, Jimai 20 and Xinong 979 exhibited slight color variation within 24 h and high peak starch paste viscosity; dry and cooked noodles made from Zhengmai 366, Jimai 20 and Xinong 979 had good quality.
基金This work was supported by the National Natural Science Foundation of China(Program No.41330315)the Natural Science Foundation of Shaanxi Province(Program No.2020JQ-766)+1 种基金the Scientific Research Program Funded by Shaanxi Provincial Education Department(Program No.20JK0838)the Opening Foundation of Shandong Key Laboratory of Depositional Mineralization&Sedimentary Mineral,Shandong University of Science and Technology(Program No.DMSM20190034).
文摘Carbonate concretions are conspicuous in organic-rich shales and are generally related to decomposition of organic matter.The black shales from the Chang 7 Member of the Upper Triassic Yanchang Formation of the southern Ordos Basin host abundant carbonate concretions,which provide a unique record of depositional and early diagenetic conditions of the paleo-lake sediments.However,little attention has been given to the genesis and growth processes of the concretions in these lacustrine petroleum source rocks.New petrographic observations and geochemical analysis show that the concretions are composed of calcite,phosphate fossil fragments,K-NH4-feldspar,quartz,bitumen,and minor Fe-dolomite.Phosphate minerals,mainly carbonate fluorapatite(CFA),show pervasive replacement by calcite,most of which contains phosphorus,ranging in concentration from 0.26 to 2.35 wt%.This suggests that the phosphate minerals are the precursors for concretion growth.Positiveδ13C(+5.6 to+12.4‰V-PDB)signatures and the absence of pyrite indicate that microbial methanogenesis was the dominant driver for concretion growth,rather than bacterial sulfate reduction.Quartz,bitumen,and Fe-dolomite are the last cements that occurred,at deep burial depths and high temperatures.The formation of phosphate minerals might have been induced by upwelling of phosphate-enriched deep water in the Late Triassic paleo-lake,which promoted phytoplankton blooms and further enrichment of organic matter.Extremely slow sedimentation rates of fine-grained detrital minerals,relative to dead organism accumulation,led to the high permeabilities of the organic-rich sediments and rapid concretion growth during shallow burial.The close association of phosphate-bearing carbonate concretions and organic-rich shales reflects that upwelling played a critical role in the formation of the high-quality petroleum source rocks in the Triassic paleo-Ordos lake.
文摘Under the condition of thick alluvia, there is biggish declination in predicting the coal mining subsidence by commonly strip design method compared with the practical observation, the sinkage is much smaller. Based on the method of the probability integral about coal mining subsidence calculation, discussed the surface subsidence calculation and deduced the formulas caused by the clay with dewatering. The results show that the clay dewatering has great impact on surface subsidence. Therefore, the clay dewatering on surface subsidence should not be overlooked.
文摘To analyze the bacterial communities in lime concretion black soil upon the incorporation of crop residues for two years in wheat-maize system, total DNA was directly extracted and PCR-amplified with the F357GC and R518 primers targeting the 16S rRNA genes of V3 region. The amplified fragments were analyzed by perpendicular DGGE. Analyzing of species richness index S and Shannon diversity index H revealed that there was a high diversity of soil bacterial community compositions among all treatments after incorporation of crop residues and fertilizing under field conditions. Eleven DGGE bands recovered were re-amplified, sequenced. Phylogenetic analysis of the representative DGGE fingerprints identified four groups of the prokaryotic communities in the soil by returning wheat residues and fertilizing under field conditions. The bacterial communities belonged to gamma proteobacterium, Cupriavidus sp, halophilic eubacterium, Acidobacterium sp, Sorangium sp, delta proteobacterium, Streptococcus sp and Streptococcus agalactiae were main bacterial communities. Principal Component Analysis (PCA) showed that there were the differences in DNA profiles among the six treatments. It showed that wheat residue returning, maize residue returning and fertilizing all can improve bacterial diversity in varying degrees. As far as improvement of bacterial diversity was concerned, wheat residue returning was higher than fertilizing, and fertilizing higher than maize residue returning.
基金supported by the National Natural Science Foundation of China (No.42002148)the Program of Introducing Talents of Discipline to Universities (No.B14031)the Open Fund of the Key Laboratory of Tectonics and Petroleum Resources,Ministry of Education,China University of Geosciences (Nos.TPR-2021-10,TPR-2022-21)。
文摘The Early Cambrian Niutitang Formation is characterized by wide distribution of black shales on Yangtze Block,South China.Here we have reported the pyrite concretions in the bottom of the Niutitang Formation deposited in the slope-basin environment of Yangtze Block.The pyrite concretion was mainly composed of pyrite associated with hydrothermal minerals(barite,hyalophane,tetrahedrite),followed by quartz and organic matter.Trace elements Mo and U displayed significant enrichment(enrichment factors > 10),indicating the euxinic bottom water condition.Cu,Ni,and excess Ba concentrations were relatively high,denoting high primary productivity.In-situ sulfur isotope compositions of pyrite concretions δ34Spy) showed little variations(13.2‰–19.4‰) and small fractionations compared to coeval seawater δ34Sso4.Petrological and geochemical analyses indicated the pyrite concretions were formed in the sediment-water interface during the early diagenesis,with H2S diffusing from the euxinic water,and influenced by hydrothermal activity leading to the coexistence of barite,hyalophane,and tetrahedrite.These results imply euxinic bottom water featured by high primary productivity and increasing riverine flux of sulfate from chemical weathering during the Early Cambrian.
基金supported by the National Natural Science Foundation of China(21978013)the Fundamental Research Funds for the Central in China(XK1802-4)。
文摘Dear Editor,This letter presents an intelligent small sample defect detection of concrete surface using novel deep learning integrating the improved YOLOv5 based on the Wasserstein GAN(WGAN)enhancement algorithm.The proposed method is capable of producing top-notch data sets to address the issues of insufficient samples and substandard quality.
基金Funded by the National Natural Science Foundation of China(No.52378213)the Technology Development Project(No.20201902977180010) of CABR Technology Co.,Ltd。
文摘To promote the production and application of artificial aggregates,save natural sand resources and protect the ecological environment,we evaluated the feasibility of using spherical porous functional aggregates(SPFAs) formed by basalt saw mud under autoclave curing in ordinary structural concrete.In our work,two types of prewetted functional aggregates were taken as replacements for natural aggregates with different volume substitution rates(0%,5%,10%,15%,20%,25%,and 30%) in the preparation of ordinary structural concrete with water-to-binder ratios(W/B) of 0.48 and 0.33.The effects of the functional aggregate properties and content,W/B,and curing age on the fluidity,density,mechanical properties and autogenous shrinkage of ordinary concrete were analyzed.The experimental results showed that the density of concrete declined at a rate of not more than 5%,and the 28 d compressive strength could reach 31.0-68.2 MPa.Low W/B,long curing age and high-quality functional aggregates were conducive to enhancing the mechanical properties of SPFAs concrete.Through the rolling effects,SPFAs can optimize the particle gradation of aggregate systems and improve the fluidity of concrete,and the water stored inside SPFAs provides an internal curing effect,which prolongs the cement hydration process and considerably reduces the autogenous shrinkage of concrete.SPFAs exhibits high strength and high density,as well as being more cost-effective and ecological,and is expected to be widely employed in ordinary structural concrete.
基金the National Natural Science Foundation of China(Grant No.12102050)the Open Fund of State Key Laboratory of Explosion Science and Technology(Grant No.SKLEST-ZZ-21-18).
文摘The majority of the projectiles used in the hypersonic penetration study are solid flat-nosed cylindrical projectiles with a diameter of less than 20 mm.This study aims to fill the gap in the experimental and analytical study of the evolution of the nose shape of larger hollow projectiles under hypersonic penetration.In the hypersonic penetration test,eight ogive-nose AerMet100 steel projectiles with a diameter of 40 mm were launched to hit concrete targets with impact velocities that ranged from 1351 to 1877 m/s.Severe erosion of the projectiles was observed during high-speed penetration of heterogeneous targets,and apparent localized mushrooming occurred in the front nose of recovered projectiles.By examining the damage to projectiles,a linear relationship was found between the relative length reduction rate and the initial kinetic energy of projectiles in different penetration tests.Furthermore,microscopic analysis revealed the forming mechanism of the localized mushrooming phenomenon for eroding penetration,i.e.,material spall erosion abrasion mechanism,material flow and redistribution abrasion mechanism and localized radial upsetting deformation mechanism.Finally,a model of highspeed penetration that included erosion was established on the basis of a model of the evolution of the projectile nose that considers radial upsetting;the model was validated by test data from the literature and the present study.Depending upon the impact velocity,v0,the projectile nose may behave as undistorted,radially distorted or hemispherical.Due to the effects of abrasion of the projectile and enhancement of radial upsetting on the duration and amplitude of the secondary rising segment in the pulse shape of projectile deceleration,the predicted DOP had an upper limit.
基金the support from the Key Program Grant from National Natural Science Foundation of China (52039005)Grant from State Key Laboratory of Hydroscience and Engineering (2022-KY-01).
文摘Over the past few decades,one of the most significant advances in dam construction has been the inven-tion of the rock-filled concrete(RFC)dam,which is constructed by pouring high-performance self-compacting concrete(HSCC)to fill the voids in preplaced large rocks.The innovative use of large rocks in dam construction provides engineers with a material that requires less cement consumption and hydration heat while enhancing construction efficiency and environmental friendliness.However,two fundamental scientific issues related to RFC need to be addressed:namely,the pouring compactness and the effect of large rocks on the mechanical and physical properties of RFC.This article provides a timely review of fundamental research and innovations in the design,construction,and quality control of RFCdams.Prospects for next-generation concrete dams are discussed from the perspectives of envi-ronmental friendliness,intrinsic safety,and labor savings.
文摘Türkiye is located in a seismically active region,where the Anatolian,African,and Arabian tectonic plates converge.High seismic hazards cause the region to be struck repeatedly by major earthquakes.On February 06,2023,a devastating M_(W)7.7 earthquake struck Türkiye at 01:17 am local time(01:17 UTC).In this regard,near and far-field ground motion data within the distance of 120 km are compiled and later characterized to identify the key ground motion intensity measures.Additionally,the vertical components of ground motions were examined to capture the complete three-dimensional nature of the seismic event.Moreover,the effect of Pulse-Like(PL)and Non-Pulse-Like(NPL)ground motion on a representative RC frame structure built as per the Türkiye code was investigated.The results indicate that PL behavior was observed in both horizontal and vertical components of ground motions and PL behavior were noted both near the epicenter and at higher distances from the epicenter.Moreover,the ratio of the peak vertical acceleration to peak horizontal acceleration at certain stations was found to be close to 1.Finally,the non-linear time history analysis of the representative reinforced concrete frame structure for ground motions recorded at stations located equidistant from the epicenter,indicated that PL ground motions led to more significant damage compared to NPL ground motions.
基金the National Natural Science Foundation of China (Grant Nos. 40572019 and 40621002)Prospective Study of China Petroleum and Chemical Corporation (Grant No. G0800-06-ZS-319)+1 种基金Ministry of Education of China (Grant No. NCET-04-0727, ‘the 111 Project’ B07011)National Science Foundation of USA (Grant No. EAR0745825)
文摘Mineralogical and textural characteristics and organic carbon composition of the carbonate concretions from the upper Doushantuo Formation (ca. 551 Ma) in the eastern Yangtze Gorge area reveal their early diagenetic (shallow) growth in organic-rich shale. High organic carbon content (up to 10%) and abundance of framboidal pyrites in the hosting shale suggest an anoxic or euxinic depositional environment. Well-preserved cardhouse clay fabrics in the concretions suggest their formation at 0-3 m burial depth, likely associated with microbial decomposition of organic matter and anaerobic oxidation of methane. Gases through decomposition of organic matter and/or from methanogenesis created bubbles and cavities, and anaerobic methane oxidation at the sulfate reduction zone resulted in carbonate precipitation, filling in bubbles and cavities to form spherical structures of the concretions. Rock pyrolysis analyses show that the carbonate concretions have lower total organic carbon (TOC) content but higher effective carbon than those in the host rocks. This may be caused by enclosed organic matter in pores of the concretions so that organic matter was protected from further modification during deep burial and maintained high hydrocarbon generating potential even in over-matured source rock. As a microbialite sensu latu, concretions have special growth conditions and may provide important information on the microbial activities in depositional and early burial environments.
基金supported by the National Natural Science Foundation of China (No. 41672336)the Fundamental Research Funds for the Central Universities (No. 2652018005 and 2652017050)
文摘Carbonate concretions provide unique records of ancient biogeochemical processes in marine sediments, and have the potential to reflect seawater chemistry indirectly. In fine-siliciclastic settings, they preferentially form in organicrich mudstones, owing to a significant fraction of the bicarbonate required for carbonate precipitation resulted from the decomposition of organic matter in sediments. In the Member IV of the Xiamaling Formation(ca. 1.40–1.35 Ga), North China, however, carbonate concretions occur in organic-poor green silty shales(avg. TOC = ~ 0.1 wt%).In order to elucidate the mechanism of the concretion formation and their environmental implications, a thorough study on the petrographic and geochemical compositions of the concretions and their host rocks was conducted.Macro-to microscopic fabrics, including deformed shale laminae surrounding the concretions, "cardhouse"structures of clay minerals and calcite geodes in the concretions, indicate that these concretions are of early diagenetic origin prior to the significant compaction of clay minerals. The carbon isotope compositions of the concretions(-1.7‰ to + 1.5‰) are stable and close to or slightly lower than that of the contemporaneous seawater, indicating that the bicarbonates required for the concretion formation were mainly sourced from seawater by diffusion rather than produced by methanogenesis or anoxic oxidation of methane(AOM); the rare occurrence of authigenic pyrite grains in the concretions likely indicates that bacterial sulfate reduction(BSR) did not play a significant role in their formation either. Almost all the calcite in the concretions has low Mn–Fe in nuclei but high Mn–Fe in rims with average Mn/Fe ratio close to 3.3. The calcite shows positive Ce anomalies(avg. 1.43)and low Y/Ho ratios(avg. 31). This evidence suggests that Mn reduction is the dominant process responsible for the formation of calcite rims while nitrate reduction probably triggered the precipitation of calcite nuclei.Prominence of Mn reduction in the porewater likely indicates that there was sufficient oxygen to support active Mn-redox cycling in the overlying seawater.
文摘In an attempt to provide more data about the mechanics of transition metal occurrence and translocation in soil environments, Fe-Mn concretions are separated from bulk samples of representative soil types and the element contents are determined. The results are reported and discussed in the sense of environmental geochemistry in this article.
基金Funded by the Key Project of Science and Technology Research in Higher Educational Institutions of Inner Mongolia Autonomous Region (No.NJZZ22518)Inner Mongolia Natural Science Foundation Project (No.2022MS05043)Inner Mongolia Autonomous Region Water Conservancy Research Special Project(No.NSK2016-S11)。
文摘After exposure to freeze-thaw cycles, scanning electron microscopy(SEM) and nuclear magnetic resonance(NMR) were used to test the four mixtures. The microstructure is qualitatively analyzed from the 2D SEM image and the 3D pore distribution curve before and after freezing and thawing. The fractal dimension is utilized to characterize the two-dimensional topography image and the three-dimensional pore distribution, quantitatively. The results reveal that the surface porosity and volume porosity increase as the freeze-thaw action increases. Self-similarity characteristics exist in micro-damage inside the concrete. In the fractal dimension, it is possible to characterize pore evolution quantitatively. The fractal dimension correlates with pore damage evolution. The fractal dimension effectively quantitatively characterizes micro-damage features at various scales from the local to the global level.
基金Funded by the National Natural Science Foundation of China(No.51878113)。
文摘Monte Carlo simulations were carried out to generate a mesoscale model of concrete with randomly packed aggregates with different shapes and sizes.The mechanical properties of concrete specimens under uniaxial tensile loads were studied using statistical results.The results indicated that the entire process of damage and failure of specimens exhibited mainly two failure types:fracture patternsⅠandⅡ.Furthermore,the influences of the aggregate content ratio,aggregate shape,aggregate size,interfacial transition zone(ITZ)strength,and porosity ratio on the concrete specimens were analyzed.The numerical simulation results showed that the elastic modulus of the concrete specimens increased approximately linearly with the aggregate volume ratio but decreased linearly with the porosity and was not affected by the ITZ strength.The tensile strength decreased with the increases in the aggregate content and porosity of the sample,but increased linearly with the ITZ strength.In addition,the aggregate shape led to a difference in the tensile strength of the concrete.
基金Founded by the National Natural Science Foundation of China(No.42002287)the Fundamental Research Funds for the Central Universities,China University of Geosciences(Wuhan)(No.CUG2106335)。
文摘An exquisite mesostructure model was presented to predict the effective elastic modulus of concrete,in which concrete is realized as a four-phase composite material consisting of coarse aggregates,mortar matrix,interfacial transition zone(ITZ),and initial defects.With the three-dimensional(3D)finite element(FE)simulation,the highly heterogeneous composite elastic behavior of concrete was modeled,and the predicted results were compared with theoretical estimations for validation.Monte Carlo(MC)simulations were performed with the proposed mesostructure model to investigate the various factors of initial defects influencing the elastic modulus of concrete,such as the shape and concentration(pore volume fraction or crack density)of microspores and microcracks.It is found that the effective elastic modulus of concrete decreases with the increase of initial defects concentration,while the distribution and shape characteristics also exert certain influences due to the stress concentration caused by irregular inclusion shape.
基金Funed by the National Natural Science Foundation of China(No.U21A20149)the Ecological Environment Scientific Research Project of Anhui Province(No.2023hb0014)+2 种基金the Research Reserve of Anhui Jianzhu University(No.2022XMK01)the Excellent Scientific Research and Innovation Team in Colleges and Universities of Anhui Province(No.2022AH010017)Research on the preparation technology of self compacting concrete with strength grade C100.
文摘We developed ultra-high performance concrete(UHPC)incorporating mullite sand and brown corundum sand(BCS),and the quartz sand UHPC was utilized to prepare for comparison.The properties of compressive strength,elastic modulus,ultrasonic pulse velocity,flexural strength,and toughness were investigated.Scanning electron microscopy and nanoindentation were also conducted to reveal the underlying mechanisms affecting macroscopic performance.Due to the superior interface bonding properties between mullite sand and matrix,the compressive strength and flexural toughness of UHPC have been significantly improved.Mullite sand and BCS aggregates have higher stiffness than quartz sand,contributing to the excellent elastic modulus exhibited by UHPC.The stiffness and volume of aggregates have a more significant impact on the elastic modulus of UHPC than interface performance,and the latter contributes more to the strength of UHPC.This study will provide a reference for developing UHPC with superior elastic modulus for structural engineering.
基金This research has been conducted under SEGTRANS project,funded by the Centre for Industrial Technological Development(CDTI,Government of Spain).
文摘This paper explores the performances of a finite element simulation including four concrete models applied to a full-scale reinforced concrete beam subjected to blast loading. Field test data has been used to compare model results for each case. The numerical modelling has been, carried out using the suitable code LS-DYNA. This code integrates blast load routine(CONWEP) for the explosive description and four different material models for the concrete including: Karagozian & Case Concrete, Winfrith, Continuous Surface Cap Model and Riedel-Hiermaier-Thoma models, with concrete meshing based on 10, 15, and 20 mm. Six full-scale beams were tested: four of them used for the initial calibration of the numerical model and two more tests at lower scaled distances. For calibration, field data obtained employing pressure and accelerometers transducers were compared with the results derived from the numerical simulation. Damage surfaces and the shape of rupture in the beams have been used as references for comparison. Influence of the meshing on accelerations has been put in evidence and for some models the shape and size of the damage in the beams produced maximum differences around 15%. In all cases, the variations between material and mesh models are shown and discussed.
基金Funded by the National Natural Science Foundation of China(No.52078050)the Natural Science Basic Research Plan in Shaanxi Province of China(No.2020JZ-22)。
文摘The modification methods of pozzolan slurry combined with sodium silicate and silicon-based additive were respectively adopted to treat recycled coarse brick-mixed aggregate(RCBA)in this study.The compressive strength and chloride permeability resistance of recycled aggregate concrete(RAC)before and after modification treatment were tested,and the microstructure of RAC was analyzed by mercury intrusion porosimetry(MIP)and scanning electron microscopy(SEM).The results show that the physical properties of RCBA strengthened by modification treatment are improved,and the compressive strength and chloride permeability resistance of treated RAC are also significantly improved.The modification treatment optimizes the pore size distribution of RAC,which increases the number of gel pores and transition pores,and decreases the number of capillary pores and macro pores.The surface fractal dimension shows a significant correlation with chloride diffusion coefficient,indicating that the variation of chloride permeability of treated RAC is consistent with the microstructure evolution.