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Flexible, Transparent and Conductive Metal Mesh Films with Ultra‑High FoM for Stretchable Heating and Electromagnetic Interference Shielding 被引量:1
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作者 Zibo Chen Shaodian Yang +9 位作者 Junhua Huang Yifan Gu Weibo Huang Shaoyong Liu Zhiqiang Lin Zhiping Zeng Yougen Hu Zimin Chen Boru Yang Xuchun Gui 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第5期201-213,共13页
Despite the growing demand for transparent conductive films in smart and wearable electronics for electromagnetic interference(EMI)shielding,achieving a flexible EMI shielding film,while maintaining a high transmittan... Despite the growing demand for transparent conductive films in smart and wearable electronics for electromagnetic interference(EMI)shielding,achieving a flexible EMI shielding film,while maintaining a high transmittance remains a significant challenge.Herein,a flexible,transparent,and conductive copper(Cu)metal mesh film for EMI shielding is fabricated by self-forming crackle template method and electroplating technique.The Cu mesh film shows an ultra-low sheet resistance(0.18Ω□^(-1)),high transmittance(85.8%@550 nm),and ultra-high figure of merit(>13,000).It also has satisfactory stretchability and mechanical stability,with a resistance increases of only 1.3%after 1,000 bending cycles.As a stretchable heater(ε>30%),the saturation temperature of the film can reach over 110°C within 60 s at 1.00 V applied voltage.Moreover,the metal mesh film exhibits outstanding average EMI shielding effectiveness of 40.4 dB in the X-band at the thickness of 2.5μm.As a demonstration,it is used as a transparent window for shielding the wireless communication electromagnetic waves.Therefore,the flexible and transparent conductive Cu mesh film proposed in this work provides a promising candidate for the next-generation EMI shielding applications. 展开更多
关键词 Metal mesh Transparent conductive film Stretchable heater electromagnetic interference shielding
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Flexible Polydimethylsiloxane Composite with Multi-Scale Conductive Network for Ultra-Strong Electromagnetic Interference Protection 被引量:7
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作者 Jie Li He Sun +5 位作者 Shuang-Qin Yi Kang-Kang Zou Dan Zhang Gan-Ji Zhong Ding-Xiang Yan Zhong-Ming Li 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第1期293-306,共14页
Highly conductive polymer composites(CPCs) with excellent mechanical flexibility are ideal materials for designing excellent electromagnetic interference(EMI) shielding materials,which can be used for the electromagne... Highly conductive polymer composites(CPCs) with excellent mechanical flexibility are ideal materials for designing excellent electromagnetic interference(EMI) shielding materials,which can be used for the electromagnetic interference protection of flexible electronic devices.It is extremely urgent to fabricate ultra-strong EMI shielding CPCs with efficient conductive networks.In this paper,a novel silver-plated polylactide short fiber(Ag@PL ASF,AAF) was fabricated and was integrated with carbon nanotubes(CNT) to construct a multi-scale conductive network in polydimethylsiloxane(PDMS) matrix.The multi-scale conductive network endowed the flexible PDMS/AAF/CNT composite with excellent electrical conductivity of 440 S m-1and ultra-strong EMI shielding effectiveness(EMI SE) of up to 113 dB,containing only 5.0 vol% of AAF and 3.0 vol% of CNT(11.1wt% conductive filler content).Due to its excellent flexibility,the composite still showed 94% and 90% retention rates of EMI SE even after subjected to a simulated aging strategy(60℃ for 7 days) and 10,000 bending-releasing cycles.This strategy provides an important guidance for designing excellent EMI shielding materials to protect the workspace,environment and sensitive circuits against radiation for flexible electronic devices. 展开更多
关键词 Flexible conductive polymer composites Silver-plated polylactide short fiber Carbon nanotube electromagnetic interference shielding Multi-scale conductive network
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Highly Ordered Thermoplastic Polyurethane/Aramid Nanofiber Conductive Foams Modulated by Kevlar Polyanion for Piezoresistive Sensing and Electromagnetic Interference Shielding 被引量:6
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作者 Kunpeng Qian Jianyu Zhou +4 位作者 Miao Miao Hongmin Wu Sineenat Thaiboonrod Jianhui Fang Xin Feng 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第6期335-352,共18页
Highly ordered and uniformly porous structure of conductive foams is a vital issue for various functional purposes such as piezoresistive sensing and electromagnetic interference(EMI) shielding. With the aids of Kevla... Highly ordered and uniformly porous structure of conductive foams is a vital issue for various functional purposes such as piezoresistive sensing and electromagnetic interference(EMI) shielding. With the aids of Kevlar polyanionic chains, thermoplastic polyurethane(TPU) foams reinforced by aramid nanofibers(ANF) with adjustable pore-size distribution were successfully obtained via a nonsolvent-induced phase separation. In this regard, the most outstanding result is the in situ formation of ANF in TPU foams after protonation of Kevlar polyanion during the NIPS process. Furthermore, in situ growth of copper nanoparticles(Cu NPs) on TPU/ANF foams was performed according to the electroless deposition by using the tiny amount of pre-blended Ti_(3)C_(2)T_(x) MXene as reducing agents. Particularly, the existence of Cu NPs layers significantly promoted the storage modulus in 2,932% increments, and the well-designed TPU/ANF/Ti_(3)C_(2)T_(x) MXene(PAM-Cu) composite foams showed distinguished compressive cycle stability. Taking virtues of the highly ordered and elastic porous architectures, the PAM-Cu foams were utilized as piezoresistive sensor exhibiting board compressive interval of 0–344.5 kPa(50% strain) with good sensitivity at 0.46 kPa^(-1). Meanwhile,the PAM-Cu foams displayed remarkable EMI shielding effectiveness at 79.09 dB in X band. This work provides an ideal strategy to fabricate highly ordered TPU foams with outstanding elastic recovery and excellent EMI shielding performance, which can be used as a promising candidate in integration of satisfactory piezoresistive sensor and EMI shielding applications for human–machine interfaces. 展开更多
关键词 Highly ordered conductive foams MXene NANOFIBER Thermoplastic Kevlar polyanion Piezoresistive sensing electromagnetic interference shielding
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Laser-Induced Graphene Conductive Fabric Decorated with Copper Nanoparticles for Electromagnetic Interference Shielding Application 被引量:1
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作者 刘琬玲 陈春晖 +6 位作者 海文清 毕思伊 蒋金华 邵慧奇 邵光伟 付少举 陈南梁 《Journal of Donghua University(English Edition)》 CAS 2023年第6期571-579,共9页
To meet the demands for flexible electromagnetic interference(EMI)shielding materials,a type of conductive fabric is prepared by generating three-dimensional(3D)porous laser-induced graphene(LIG)in situ on the surface... To meet the demands for flexible electromagnetic interference(EMI)shielding materials,a type of conductive fabric is prepared by generating three-dimensional(3D)porous laser-induced graphene(LIG)in situ on the surface of the aramid fabric(AF)and then electroless plating copper.After LIG treatment,the porous AF demonstrates admirable conductivity due to the generation of graphene.The superior surface resistance of the conductive fabric can reach 1.57Ω/sq after copper deposition,and the average EMI shielding effectiveness(SE)can reach 34.3 dB in a frequency range of 8.2 to 12.4 GHz,with the EMW absorption accounting for about 80%.The proposed technology provides a new idea for preparation of flexible EMI shielding materials. 展开更多
关键词 laser-induced graphene(LIG) electroless plating aramid fabric(AF) electromagnetic interference(emi)
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Investigation and Reduction on Conducted Electromagnetic Interference Noise Mechanism for Complex Power Electronics Systems 被引量:4
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作者 YAN Wei ZHAO Yang +4 位作者 WANG Ertrong ZHANG Yuhuan QIU Xiaohui SUN Hongyan CHEN Xueli 《中国电机工程学报》 EI CSCD 北大核心 2012年第30期I0022-I0022,24,共1页
针对复杂电子系统产生的传导EMI噪声,该文分别利用电偶极子模型、电路分析方法和散射参数方法提出了3种传导EMI噪声理论模型及其等效电路,包括因串扰引起的传导噪声模型,因接地不良引起的传导噪声模型,以及因PCB线缆阻抗失配引起的传导... 针对复杂电子系统产生的传导EMI噪声,该文分别利用电偶极子模型、电路分析方法和散射参数方法提出了3种传导EMI噪声理论模型及其等效电路,包括因串扰引起的传导噪声模型,因接地不良引起的传导噪声模型,以及因PCB线缆阻抗失配引起的传导噪声模型。同时,还设计了一种串扰扼流圈以有效抑制因串扰引起的传导EMI噪声。实验结果表明,采用文中方法,某型商用车载导航和刷卡器能够通过GB 9254标准测试,噪声抑制效果分别可达44.8和29.28 dB V,从而验证了方法的有效性。 展开更多
关键词 传导电磁干扰 电力电子系统 噪声机理 共模扼流圈 噪声分离 和差模 emi 电容
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Polypyrrole-Coated Zein/Epoxy Ultrafine Fiber Mats for Electromagnetic Interference Shielding 被引量:1
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作者 丁润龙 戚瑞瑞 +3 位作者 刘飞 刘万双 张礼颖 蒋秋冉 《Journal of Donghua University(English Edition)》 CAS 2023年第4期351-356,共6页
To reduce the environmental pollution and meet the needs for wearable electronic devices, new requirements for electromagnetic interference(EMI) shielding materials include flexibility, biodegradability, and biocompat... To reduce the environmental pollution and meet the needs for wearable electronic devices, new requirements for electromagnetic interference(EMI) shielding materials include flexibility, biodegradability, and biocompatibility. Herein, we reported a polypyrrole-coated zein/epoxy(PPy/ZE) ultrafine fiber mat which was inherently biodegradable and skin-friendly. In addition, it could maintain its ultrafine fibrous structure after coating, which could provide the mat with mechanical compliance, high porosity, and a large specific area for high EMI shielding. With the assistance of the epoxide cross-linking, the breaking stresses of the PPy/ZE fiber mats could achieve 3.3 MPa and 1.4 MPa and the strains were 40.1% and 83.0% in dry and wet states, respectively, which met the needs of various wearable electronic devices. Along with the extension in the PPy treatment duration, more PPy was loaded on the fiber surfaces, which formed more integrated and conductive paths to generate increasing conductivities up to 401.76 S·m^(-1). Moreover, the EMI shielding performance was raised to 26.84 dB. The biobased mats provide a green and efficient choice for EMI shielding materials, which may be a promising strategy to address EMI problems in multiple fields. 展开更多
关键词 polypyrrole(PPy) ZEIN ultrafine fiber mat electromagnetic interference(emi)shielding electrical conductivity
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Electromagnetic interference assessment of a train-network-pipeline coupling system based on a harmonic transmission model
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作者 Minwu Chen Jinyu Zhao +2 位作者 Zongyou Liang Xin Gong Yu Cao 《Railway Engineering Science》 2023年第4期396-410,共15页
The harmonics and resonance of traction power supply systems(TPSSs)aggravate the electromagnetic interference(EMI)to adjacent metallic pipelines(MPs),which has aroused widespread concern.In this paper,an evaluation me... The harmonics and resonance of traction power supply systems(TPSSs)aggravate the electromagnetic interference(EMI)to adjacent metallic pipelines(MPs),which has aroused widespread concern.In this paper,an evaluation method on pipeline interference voltage under harmonic induction is presented.The results show that the Carson integral formula is more accurate in calculating the mutual impedance at higher frequencies.Then,an integrated train-network-pipeline model is established to estimate the influences of harmonic distortion and resonance on an MP.It is revealed that the higher the harmonic cur-rent distortion rate of the traction load,the larger the interference voltage on an MP.Particularly,the interference voltage is amplified up to 7 times when the TPSS resonates,which is worthy of attention.In addition,the parameters that affect the variation and sensitivity of the interference voltage are studied,namely,the pipeline coating material,locomotive position,and soil resistivity,indicating that soil resistivity and 3PE(3-layer polyethylene)anticorrosive coating are more sensitive to harmonic induction.Field test results show that the harmonic distortion can make the interference voltage more serious,and the protective measures are optimized. 展开更多
关键词 Induced voltage Inductive coupling conductive coupling Harmonic resonance electromagnetic interference
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Direct Ink Writing of Highly Conductive MXene Frames for Tunable Electromagnetic Interference Shielding and Electromagnetic Wave-Induced Thermochromism 被引量:12
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作者 Xinyu Wu Tingxiang Tu +6 位作者 Yang Dai Pingping Tang Yu Zhang Zhiming Deng Lulu Li Hao-Bin Zhang Zhong-Zhen Yu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2021年第10期14-28,共15页
The highly integrated and miniaturized next-generation electronic products call for high-performance electromagnetic interference(EMI)shielding materials to assure the normal operation of their closely assembled compo... The highly integrated and miniaturized next-generation electronic products call for high-performance electromagnetic interference(EMI)shielding materials to assure the normal operation of their closely assembled components.However,the most current techniques are not adequate for the fabrication of shielding materials with programmable structure and controllable shielding efficiency.Herein,we demonstrate the direct ink writing of robust and highly conductive Ti3C2Tx MXene frames with customizable structures by using MXene/AlOOH inks for tunable EMI shielding and electromagnetic wave-induced thermochromism applications.The as-printed frames are reinforced by immersing in AlCl_(3)/HCl solution to remove the electrically insulating AlOOH nanoparticles,as well as cross-link the MXene sheets and fuse the filament interfaces with aluminum ions.After freeze-drying,the resultant robust and porous MXene frames exhibit tunable EMI shielding efficiencies in the range of 25-80 dB with the highest electrical conductivity of 5323 S m−1.Furthermore,an electromagnetic wave-induced thermochromic MXene pattern is assembled by coating and curing with thermochromic polydimethylsiloxane on a printed MXene pattern,and its color can be changed from blue to red under the high-intensity electromagnetic irradiation.This work demonstrates a direct ink printing of customizable EMI frames and patterns for tuning EMI shielding efficiency and visualizing electromagnetic waves. 展开更多
关键词 MXene electromagnetic interference shielding Direct ink writing Electrical conductivity THERMOCHROMISM
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Printable Aligned Single-Walled Carbon Nanotube Film with Outstanding Thermal Conductivity and Electromagnetic Interference Shielding Performance 被引量:9
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作者 Zhihui Zeng Gang Wang +8 位作者 Brendan F.Wolan Na Wu Changxian Wang Shanyu Zhao Shengying Yue Bin Li Weidong He Jiurong Liu Joseph W.Lyding 《Nano-Micro Letters》 SCIE EI CAS CSCD 2022年第11期143-156,共14页
Ultrathin,lightweight,and flexible aligned single-walled carbon nanotube(SWCNT)films are fabricated by a facile,environmentally friendly,and scalable printing methodology.The aligned pattern and outstanding intrinsic ... Ultrathin,lightweight,and flexible aligned single-walled carbon nanotube(SWCNT)films are fabricated by a facile,environmentally friendly,and scalable printing methodology.The aligned pattern and outstanding intrinsic properties render“metal-like”thermal conductivity of the SWCNT films,as well as excellent mechanical strength,flexibility,and hydrophobicity.Further,the aligned cellular microstructure promotes the electromagnetic interference(EMI)shielding ability of the SWCNTs,leading to excellent shielding effectiveness(SE)of~39 to 90 dB despite a density of only~0.6 g cm^(−3) at thicknesses of merely 1.5-24μm,respectively.An ultrahigh thickness-specific SE of 25693 dB mm^(−1) and an unprecedented normalized specific SE of 428222 dB cm^(2)g^(−1) are accomplished by the freestanding SWCNT films,significantly surpassing previously reported shielding materials.In addition to an EMI SE greater than 54 dB in an ultra-broadband frequency range of around 400 GHz,the films demonstrate excellent EMI shielding stability and reliability when subjected to mechanical deformation,chemical(acid/alkali/organic solvent)corrosion,and high-/low-temperature environments.The novel printed SWCNT films offer significant potential for practical applications in the aerospace,defense,precision components,and smart wearable electronics industries. 展开更多
关键词 Aligned film Single-walled carbon nanotube LIGHTWEIGHT FLEXIBLE Thermal conductivity electromagnetic interference shielding
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Directional Electromagnetic Interference Shielding Based on Step-Wise Asymmetric Conductive Networks 被引量:5
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作者 Bai Xue Yi Li +4 位作者 Ziling Cheng Shengdu Yang Lan Xie Shuhao Qin Qiang Zheng 《Nano-Micro Letters》 SCIE EI CAS CSCD 2022年第1期262-277,共16页
Some precision electronics such as signal transmitters need to not only emit effective signal but also be protected from the external electromagnetic(EM)waves.Thus,directional electromagnetic interference(EMI)shieldin... Some precision electronics such as signal transmitters need to not only emit effective signal but also be protected from the external electromagnetic(EM)waves.Thus,directional electromagnetic interference(EMI)shielding materials(i.e.,when the EM wave is incident from different sides of the sample,the EMI shielding effectiveness(SE)is rather different)are strongly required;unfortunately,no comprehensive literature report is available on this research field.Herein,Nicoated melamine foams(Ni@MF)were obtained by a facile electroless plating process,and multiwalled carbon nanotube(CNT)papers were prepared via a simple vacuum-assisted self-assembly approach.Then,step-wise asymmetric poly(butylene adipate-co-terephthalate)(PBAT)composites consisting of loose Ni@MF layer and compact CNT layer were successfully fabricated via a facile solution encapsulation approach.The step-wise asymmetric structures and electrical conductivity endow the Ni@MF/CNT/PBAT composites with unprecedented directional EMI shielding performances.When the EM wave is incident from Ni@MF layer or CNT layer,Ni@MF-5/CNT-75/PBAT exhibits the total EMI SE(SET)of 38.3 and 29.5 dB,respectively,which illustrates theΔSET of 8.8 dB.This work opens a new research window for directional EMI shielding composites with step-wise asymmetric structures,which has promising applications in portable electronics and next-generation communication technologies. 展开更多
关键词 Solution encapsulation Step-wise asymmetry Directional electromagnetic interference shielding Electrical conductivity Vacuum-assisted self-assembly
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Adding effects of Ni and Mn on electromagnetic interference(EMI) shield of Sn-based architectural materials
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作者 洪飞硕 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第9期2633-2637,共5页
It has been proved by the World Health Organization (WHO) that electromagnetic waves would bring threats to public health in the tourism environment. However, most of the recent research about the relationship betwe... It has been proved by the World Health Organization (WHO) that electromagnetic waves would bring threats to public health in the tourism environment. However, most of the recent research about the relationship between building materials and electromagnetic waves was mainly focused on the electromagnetic products. It has also been claimed that the related research can rarely been found. Generally, ecotourism more tends to emphasize on a development of a new product and uni-environment study. However, these studies did not concern much on the application for conformity of healthcare-living materials, particularly to those block high-transparency materials. Hence, this research approaches to conform the application of architectural technique for producing tin-based powder with the add-on of Ni and Mg, in order to discuss the fully anti-electromagnetic wave property of healthcare material. With a low-cost advantage, the application field of architecture defines the ternary powder system, namely Sn-Al-Ni (SAN) and Sn-Al-Mn (SAM). Additionally, the surface coating method can be implemented to review the influence of particle size, content ratio of Ni and Mn, stack effect, porosity and thickness to electromagnetic interference (EMI) mechanism. 展开更多
关键词 NI MN electromagnetic interference (emi shield
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Preparation and electromagnetic shielding properties of PET/rGO/SWCNT composite fabric
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作者 ZHANG Xu LIU Xuejiao YAN Yehai 《合成纤维工业》 CAS 2024年第5期58-62,68,共6页
Graphene oxide(GO)with excellent dispersion ability can assist the dispersion of single-walled carbon nanotube(SWCNT)and promote the formation of uniform and stable GO/SWCNT coating liquid.The highly conductive polyet... Graphene oxide(GO)with excellent dispersion ability can assist the dispersion of single-walled carbon nanotube(SWCNT)and promote the formation of uniform and stable GO/SWCNT coating liquid.The highly conductive polyethylene terephthalate/reduced graphene oxide/SWCNT(PET/rGO/SWCNT)electromagnetic shielding composite fabric was successfully prepared by anchoring rGO/SWCNT on PET fabric via dip-coating piror to low-temperature thermal reduction.The results showed that the carboxyl groups and hydroxyl groups formed of hydrophilic-treated PET were conducive to the formation of hydrogen bonds with that of GO,which enhanced the interaction between PET fabric and GO/SWCNT coating;the loading of GO/SWCNT increased with the number of dip-coating,the unit area loading of rGO/SWCNT in the final composite fabric was 2.7 mg/cm^(2) after 10 dip-coating cycles and thermal reduction;the PET/rGO/SWCNT composite fabric had a continuous and dense conductive network,with a conductivity of up to 41.6 S/m and the average electromagnetic interference shielding effectiveness in X-band was 22 dB;the flexible PET/rGO/SWCNT composite fabric was not only easy to process,but also exhibited excellent conductivity and shielding efficiency,showing great potential in the application of electromagnetic shielding fabrics. 展开更多
关键词 electromagnetic interference shielding graphene oxide single-walled carbon nanotubes conductive fabric thermal reduction
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A Perspective for Developing Polymer-Based Electromagnetic Interference Shielding Composites 被引量:25
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作者 Yali Zhang Junwei Gu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2022年第6期39-47,共9页
The rapid development of aerospace weapons and equipment,wireless base stations and 5G communication technologies has put forward newer and higher requirements for the comprehensive performances of polymer-based elect... The rapid development of aerospace weapons and equipment,wireless base stations and 5G communication technologies has put forward newer and higher requirements for the comprehensive performances of polymer-based electromagnetic interference(EMI)shielding composites.However,most of currently prepared polymer-based EMI shielding composites are still difficult to combine high performance and multi-functionality.In response to this,based on the research works of relevant researchers as well as our research group,three possible directions to break through the above bottlenecks are proposed,including construction of efficient conductive networks,optimization of multi-interfaces for lightweight and multifunction compatibility design.The future development trends in three directions are prospected,and it is hoped to provide certain theoretical basis and technical guidance for the preparation,research and development of polymer-based EMI shielding composites. 展开更多
关键词 Polymer composites electromagnetic interference shielding conductive network LIGHTWEIGHT
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Environmentally Tough and Stretchable MXene Organohydrogel with Exceptionally Enhanced Electromagnetic Interference Shielding Performances 被引量:17
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作者 Yuanhang Yu Peng Yi +5 位作者 Wenbin Xu Xin Sun Gao Deng Xiaofang Liu Jianglan Shui Ronghai Yu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2022年第5期77-91,共15页
Conductive hydrogels have potential applications in shielding electromagnetic(EM)radiation interference in deformable and wearable electronic devices,but usually suffer from poor environmental stability and stretching... Conductive hydrogels have potential applications in shielding electromagnetic(EM)radiation interference in deformable and wearable electronic devices,but usually suffer from poor environmental stability and stretching-induced shielding performance degradation.Although organohydrogels can improve the environmental stability of materials,their development is at the expense of reducing electrical conductivity and thus weakening EM interference shielding ability.Here,a MXene organohydrogel is prepared which is composed of MXene network for electron conduction,binary solvent channels for ion conduction,and abundant solvent-polymer-MXene interfaces for EM wave scattering.This organohydrogel possesses excellent anti-drying ability,low-temperature tolerance,stretchability,shape adaptability,adhesion and rapid self-healing ability.Two effective strategies have been proposed to solve the problems of current organohydrogel shielding materials.By reasonably controlling the MXene content and the glycerol-water ratio in the gel,MXene organohydrogel can exhibit exceptionally enhanced EM interference shielding performances compared to MXene hydrogel due to the increased physical cross-linking density of the gel.Moreover,MXene organohydrogel shows attractive stretching-enhanced interference effectiveness,caused by the connection and parallel arrangement of MXene nanosheets.This well-designed MXene organohydrogel has potential applications in shielding EM interference in deformable and wearable electronic devices. 展开更多
关键词 electromagnetic interference shielding MXene organohydrogel Stretchable conductive film Anti-drying ability Lowtemperature tolerance
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Significantly Enhanced Electromagnetic Interference Shielding Performances of Epoxy Nanocomposites with Long-Range Aligned Lamellar Structures 被引量:9
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作者 Lei Wang Zhonglei Ma +3 位作者 Hua Qiu Yali Zhang Ze Yu Junwei Gu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2022年第12期617-629,共13页
High-efficiency electromagnetic interference(EMI)shielding materials are of great importance for electronic equipment reliability,information security and human health.In this work,bidirectional aligned Ti_(3)C_(2)T_(... High-efficiency electromagnetic interference(EMI)shielding materials are of great importance for electronic equipment reliability,information security and human health.In this work,bidirectional aligned Ti_(3)C_(2)T_(x)@Fe_(3)O_(4)/CNF aerogels(BTFCA)were firstly assembled by bidirectional freezing and freeze-drying technique,and the BTFCA/epoxy nanocomposites with long-range aligned lamellar structures were then prepared by vacuum-assisted impregnation of epoxy resins.Benefitting from the successful construction of bidirectional aligned three-dimensional conductive networks and electromagnetic synergistic effect,when the mass fraction of Ti_(3)C_(2)T_(x) and Fe_(3)O_(4) are 2.96 and 1.48 wt%,BTFCA/epoxy nanocomposites show outstanding EMI shield-ing effectiveness of 79 dB,about 10 times of that of blended Ti_(3)C_(2)T_(x)@Fe_(3)O_(4)/epoxy(8 dB)nanocomposites with the same loadings of Ti_(3)C_(2)T_(x) and Fe_(3)O_(4).Meantime,the corresponding BTFCA/epoxy nanocomposites also present excellent thermal stability(T_(heat-resistance index) of 198.7℃)and mechanical properties(storage modulus of 9902.1 MPa,Young’s modulus of 4.51 GPa and hardness of 0.34 GPa).Our fabricated BTFCA/epoxy nanocomposites would greatly expand the applications of MXene and epoxy resins in the fields of information security,aerospace and weapon manufacturing,etc. 展开更多
关键词 electromagnetic interference shielding Epoxy nanocomposites Ti_(3)C_(2)Tx Fe_(3)O_(4) Bidirectional aligned three-dimensional conductive networks
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Near‑Instantaneously Self‑Healing Coating toward Stable and Durable Electromagnetic Interference Shielding 被引量:3
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作者 Lihua Zou Chuntao Lan +6 位作者 Songlin Zhang Xianhong Zheng Zhenzhen Xu Changlong Li Li Yang Fangtao Ruan Swee Ching Tan 《Nano-Micro Letters》 SCIE EI CAS CSCD 2021年第11期452-467,共16页
Durable electromagnetic interference(EMI)shielding is highly desired,as electromagnetic pollution is a great concern for electronics’stable performance and human health.Although a superhydrophobic surface can extend ... Durable electromagnetic interference(EMI)shielding is highly desired,as electromagnetic pollution is a great concern for electronics’stable performance and human health.Although a superhydrophobic surface can extend the service lifespan of EMI shielding materials,degradation of its protection capability and insufficient self-healing are troublesome issues due to unavoidable physical/chemical damages under long-term application conditions.Here,we report,for the first time,an instantaneously self-healing approach via microwave heating to achieve durable shielding performance.First,a hydrophobic 1H,1H,2H,2H-perfluorooctyltriethoxysilane(POTS)layer was coated on a polypyrrole(PPy)-modified fabric(PPy@POTS),enabling protection against the invasion of water,salt solution,and corrosive acidic and basic solutions.Moreover,after being damaged,the POTS layer can,for the first time,be instantaneously self-healed via microwave heating for a very short time,i.e.,4 s,benefiting from the intense thermal energy generated by PPy under electromagnetic wave radiation.This self-healing ability is also repeatable even after intentionally severe plasma etching,which highlights the great potential to achieve robust and durable EMI shielding applications.Significantly,this approach can be extended to other EMI shielding materials where heat is a triggering stimulus for healing thin protection layers.We envision that this work could provide insights into fabricating EMI shielding materials with durable performance for portable and wearable devices,as well as for human health care. 展开更多
关键词 electromagnetic interference shielding Superhydrophobic coating Multifunctional textiles SELF-HEALING conductive polymer
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Highly Flexible Fabrics/Epoxy Composites with Hybrid Carbon Nanofillers for Absorption-Dominated Electromagnetic Interference Shielding 被引量:3
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作者 Jong-Hoon Lee Yoon-Sub Kim +2 位作者 Hea-Jin Ru Seul-Yi Lee Soo-Jin Park 《Nano-Micro Letters》 SCIE EI CAS CSCD 2022年第11期307-323,共17页
Epoxy-based nano-composites can be ideal electromagnetic interference(EMI)-shielding materials owing to their lightness,chemical inertness,and mechanical durability.However,poor conductivity and brittleness of the epo... Epoxy-based nano-composites can be ideal electromagnetic interference(EMI)-shielding materials owing to their lightness,chemical inertness,and mechanical durability.However,poor conductivity and brittleness of the epoxy resin are challenges for fast-growing portable and flexible EMI-shielding applications,such as smart wristband,medical cloth,aerospace,and military equipment.In this study,we explored hybrid nanofillers of single-walled carbon nanotubes(SWCNT)/reduced graphene oxide(rGO)as conductive inks and polyester fabrics(PFs)as a substrate for flexible EMI-shielding composites.The highest electrical conductivity and fracture toughness of the SWCNT/rGO/PF/epoxy composites were 30.2 S m^(−1)and 38.5 MPa m^(1/2),which are~270 and 65%enhancement over those of the composites without SWCNTs,respectively.Excellent mechanical durability was demonstrated by stable electrical conductivity retention during 1000 cycles of bending test.An EMI-shielding effectiveness of~41 dB in the X-band frequency of 8.2-12.4 GHz with a thickness of 0.6 mm was obtained with an EM absorption-dominant behavior over a 0.7 absorption coefficient.These results are attributed to the hierarchical architecture of the macroscale PF skeleton and nanoscale SWCNT/rGO networks,leading to superior EMI-shielding performance.We believe that this approach provides highly flexible and robust EMI-shielding composites for next-generation wearable electronic devices. 展开更多
关键词 conductive polymer composites Fracture toughness Flexible composites Absorption-dominated electromagnetic interference shielding
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Annealing effects of Sn-Al and Sn-Cu nano thin films on mechanism of electromagnetic interference shielding 被引量:1
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作者 洪飞硕 洪飞义 +1 位作者 江哲铭 吕传盛 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2011年第9期2020-2025,共6页
The sputtered Sn-Al and Sn-Cu thin films were used to investigate the effects of the crystallization mechanism and film thickness on the electromagnetic interference (EMI) characteristics. In addition, the annealed ... The sputtered Sn-Al and Sn-Cu thin films were used to investigate the effects of the crystallization mechanism and film thickness on the electromagnetic interference (EMI) characteristics. In addition, the annealed microstructure, electrical conductivities and EMI characteristics of the Sn-xAl films and the Sn-xCu films were compared. The results show that the electromagnetic interference (EMI) shielding of Sn-Al film was increased after annealing. For the Sn-Cu films with higher Cu mole concentration, the low frequency EMI shielding could not be improved. After annealing, the Sn-Cu thin film with lower Cu mole concentration possesses excellent EMI shielding at lower frequencies, but has an inverse tendency at higher frequencies. 展开更多
关键词 electromagnetic interference (emi Sn-Al SN-CU thin film
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Synchronous deprotonation–protonation for mechanically robust chitin/aramid nanofibers conductive aerogel with excellent pressure sensing, thermal management, and electromagnetic interference shielding 被引量:1
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作者 Xinxin Zhang Kunpeng Qian +3 位作者 Jianhui Fang Sineenat Thaiboonrod Miao Miao Xin Feng 《Nano Research》 SCIE EI CSCD 2024年第3期2038-2049,共12页
Aerogels with regularly porous structure and uniformly distributed conductive networks have received extensive attention in wearable electronic sensors,electromagnetic shielding,and so on.However,the poor mechanical p... Aerogels with regularly porous structure and uniformly distributed conductive networks have received extensive attention in wearable electronic sensors,electromagnetic shielding,and so on.However,the poor mechanical properties of the emerging nanofibers-based aerogels are limited in practical applications.In this work,we developed a synchronous deprotonation–protonation method in the KOH/dimethyl sulfoxide(DMSO)system at room temperature for achieving chitin cross-linked aramid nanofibers(CANFs)rather than chitin nanofibers(ChNFs)and aramid nanofibers(ANFs)separately by using chitin and aramid pulp as raw materials.After freeze-drying process,the cross-linked chitin/aramid nanofibers(CA)aerogel exhibited the synergetic properties of ChNF and ANF by the dual-nanofiber compensation strategy.The mechanical stress of CA aerogel was 170 kPa at 80%compressive strain,increased by 750%compared with pure ChNF aerogel.Similarly,the compressibility of CA aerogel was somewhat improved compared to ANF aerogel.The enhancement verified that the crosslinking reaction between ANF and ChNF during the synchronous deprotonation process was formed.Afterwards,the conductive aerogels with uniform porous structure(CA-M)were successfully obtained by vacuum impregnating CA aerogels in Ti_(3)C_(2)T_(x) MXene solution,displaying low thermal conductivity(0.01 W/(m·K)),high electromagnetic interference(EMI)shielding effectiveness(SE)(75 dB),flame retardant,and heat insulation.Meanwhile,the as-obtained CA-M aerogels were also applied as a pressure sensor with excellent compression cycle stability and superior human motion monitoring capabilities.As a result,the dual-nanofiber based conductive aerogels have great potentials in flexible/wearable electronics,EMI shielding,flame retardant,and heat insulation. 展开更多
关键词 synchronous deprotonation–protonation electromagnetic interference(emi)shielding flame retardant heat insulation pressure sensing
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Flexible mille-feuille structure electromagnetic interference shielding film with excellent thermal conductivity and Joule heating
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作者 Dingwen Yin Huijuan Xiu +6 位作者 Simin Wang Yanfei Pan Na Li Rui Cheng Shaoyan Huang Sha Fan Jinbao Li 《Nano Research》 SCIE EI CSCD 2024年第5期4544-4554,共11页
The intelligent electronic devices have urgent demands for electromagnetic interference(EMI)shielding films with excellent heat dissipation capability.However,it is challenging to obtain excellent EMI shielding and th... The intelligent electronic devices have urgent demands for electromagnetic interference(EMI)shielding films with excellent heat dissipation capability.However,it is challenging to obtain excellent EMI shielding and thermal conductivity performances simultaneously.Herein,inspired by mille-feuille structure,the multifunctional EMI shielding films developed by a layer-by-layer self-assembly and hot-pressing strategy.The ingenious introduction of silver nanoparticles(AgNPs)with large specific surface area and highly conductive into the network formed by TEMPO-oxidized cellulose nanofibrils(TOCNFs)with large aspect ratio to form the TOCNFs/AgNPs.And the graphene nanoplates(GNPs)with high conductivity loss distributed alternately with TOCNFs/AgNPs to construct mille-feuille structure,which had highly efficient conductive network,complete thermally conduction pathway and rich heterogeneous interfaces.Consequently,the designed films presented high electrical conductivity of 8520 S/cm,superb EMI effectiveness(SE)of 98.05 dB,and excellent thermal conductivity of 18.82 W/(m·K).Furthermore,the films possessed outstanding Joule heating performances with low voltages,including high heating temperature(100℃),fast response time(<20 s),and impressive heating stability and reliability.Thus,such high-performance EMI shielding films with fascinating thermal conductivity and Joule heating performances have substantial application in flexible electronics,electromagnetic waves shielding and thermal management. 展开更多
关键词 TEMPO-oxidized cellulose nanofibrils/silver nanoparticles(TOCNFs/AgNPs) mille-feuille structure electromagnetic interference shielding thermal conductivity Joule heating
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