PEDOT:PSS conductive polymers have received tremendous attention over the last two decades owing to their high conductivity,ease of processing,and biocompatibility.As a flexible versatile material,PEDOT:PSS can be dev...PEDOT:PSS conductive polymers have received tremendous attention over the last two decades owing to their high conductivity,ease of processing,and biocompatibility.As a flexible versatile material,PEDOT:PSS can be developed into various forms and has had a significant impact on emerging sensing applications.This review covers the development of PEDOT:PSS from material to physical sensors.We focus on the morphology of PEDOT:PSS in the forms of aqueous dispersions,solid films,and hydrogels.Manufacturing processes are summarized,including coating,printing,and lithography,and there is particular emphasis on nanoimprinting lithography that enables the production of PEDOT:PSS nanowires with superior sensing performance.Applications to various physical sensors,for humidity,temperature,pressure,and strain,are demonstrated.Finally,we discuss the challenges and propose new directions for the development of PEDOT:PSS.展开更多
Because poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)(PEDOT:PSS)is water processable,thermally stable,and highly conductive,PEDOT:PSS and its composites have been considered to be one of the most promising f...Because poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)(PEDOT:PSS)is water processable,thermally stable,and highly conductive,PEDOT:PSS and its composites have been considered to be one of the most promising flexible thermoelectric materials.However,the PEDOT:PSS film prepared from its commercial aqueous dispersion usually has very low conductivity,thus cannot be directly utilized for TE applications.Here,a simple environmental friendly strategy via femtosecond laser irradiation without any chemical dopants and treatments was demonstrated.Under optimal conditions,the electrical conductivity of the treated film is increased to 803.1 S cm^(-1)from 1.2 S cm^(-1)around three order of magnitude higher,and the power factor is improved to 19.0μW m^(-1)K^(-2),which is enhanced more than 200 times.The mechanism for such remarkable enhancement was attributed to the transition of the PEDOT chains from a coil to a linear or expanded coil conformation,reduction of the interplanar stacking distance,and the removal of insulating PSS with increasing the oxidation level of PEDOT,facilitating the charge transportation.This work presents an effective route for fabricating high-performance flexible conductive polymer films and wearable thermoelectric devices.展开更多
Recently, a high-performance and low-priced transparent conductive film has been expected to be developed because flexible devices produced using organic materials have been actively studied. An indium tin oxide (ITO)...Recently, a high-performance and low-priced transparent conductive film has been expected to be developed because flexible devices produced using organic materials have been actively studied. An indium tin oxide (ITO) thin film, which has been generally used as a material for a transparent conductive film, has problems, such as fragility to bending stress and depletion of the resource. The present study used poly(3, 4-ethylenedioxythiophene)/poly(styrenesulfonate) (PEDOT:PSS), an organic electroconductive material, and examined the improvement in the resistance value and visible light transmittance of a transparent conductive film produced using the ink-jet method. In previous studies, we reported that, to improve the resistance value and visible light transmittance of a thin film, it was effective to clean the film substrate with ultraviolet/ozone (UV/O<sub>3</sub>) treatment, anneal the film after it was deposited on the substance, and dip the annealed film into a polar solvent. Focusing on the thin film processing between printing operations, the present study improved resistance value and visible light transmittance by examining both the application methods of a polar solvent and the annealing time between printing operations. As a result, the resistance value and visible light transmittance of a PEDOT:PSS thin film were 390.4 Ω and 86.6%, respectively. This film was obtained by applying a polar solvent and performing annealing for 30 min between printing operations. The printing was performed three times.展开更多
We compare the electrical, optical, and surface properties of the PEDOT：PSS/Cu nanowires （Cu NWs）/PEDOT： PSS （PCP） multilayer for organic solar cells. It is demonstrated that the electrical and optical propertie...We compare the electrical, optical, and surface properties of the PEDOT：PSS/Cu nanowires （Cu NWs）/PEDOT： PSS （PCP） multilayer for organic solar cells. It is demonstrated that the electrical and optical properties of the PEDOT could be improved by the insertion of a Cu NW layer due to its very low resistivity and surface morphology. The organic bulk heterojunction solar cell fabricated on the multil^yer exhibits a higher power conversion ef^ciency than devices based on the PEDOT：PSS or PEDOT：PSS/Cu NWs layer. Moreover, the PCP multilayer can improve cell-performances such as a fill factor and the internal resistance in the device due to horizontally well-aligned Cu NWs. The results suggest that the PCP multilayer is a promising low-cost and low-temperature processing buffer layer candidate for low-cost organic photovoltaics.展开更多
A Langmuir-Blodgett （LB） inducing method was firstly used to prepare single layer and multilayer conducting composite PEDOT-PSS film. The film-forming ability of ionization ODA and ODA-SA monolayer spread on PEDOT-P...A Langmuir-Blodgett （LB） inducing method was firstly used to prepare single layer and multilayer conducting composite PEDOT-PSS film. The film-forming ability of ionization ODA and ODA-SA monolayer spread on PEDOT-PSS nanoparticle sub-phase and the behavior of ODA/PEDOT-PSS assembly particles on pure water were firstly investigated. The results indicated that nanoparticles in the suphase are packed in the ionization monolayer and stable complex Langmuir film is formed at the air/water interface. It has been found that the best film-forming conditions for composite film are as follows：distinct interface was formed between ODA and PEDOT-PSS layer and single layer thickness of PEDOT-PSS was about 23 nm,well accordant to the size of PEDOT-PSS nanoparticles. Different structures were designed to test the conductive ability of these composite films and a variable range hopping （VRH） model was used to explain the film conductive mechanism. The results indicated that a 3D-VRH model explained well the transferring of charge carrier in the multilayer film.展开更多
Flexible devices manufactured using printed electronics have attracted the attention of many researchers. A high-performance transparent conductive film exhibiting high flexibility and elasticity is expected to be dev...Flexible devices manufactured using printed electronics have attracted the attention of many researchers. A high-performance transparent conductive film exhibiting high flexibility and elasticity is expected to be developed because of its need for the creation of flexible devices. An indium tin oxide (ITO) thin film, which has generally been used, has weaknesses such as fragility to bending stress and depletion of the resource. This study focused on poly (3, 4-ethy-lenedioxythiophene)/poly (styrenesulfonate) (PEDOT:PSS), a conductive polymer material, and examined improvement in the resistivity and transmittance of the transparent conductive film produced using an inkjet method. The present study improved the electrical and optical characteristics of the thin film by examining the annealing temperature between printing operations and the application method of a polar solvent. As a result, the resistivity and transmittance of a PEDOT:PSS thin film were 1.49 × 10-3 Ω·cm and 89.2%, respectively. This film was obtained by annealing at 90°C for 30 min and applying a polar solvent, using an inkjet printer, between printing operations. The printing was performed three times.展开更多
PEDOT:PSS buffer layers have been processed with the standard annealing step used for organic solar cells device applications. The d.c. conductivity σ as a function of temperature for two heating rates under He and a...PEDOT:PSS buffer layers have been processed with the standard annealing step used for organic solar cells device applications. The d.c. conductivity σ as a function of temperature for two heating rates under He and atmospheric air was studied. Moreover, the stability of the conductivity was investigated at different temperatures and environments vs time. The main results can be summarized in the following: the increase of σ due to the thermal activation of the carriers and the improvement of the crystallinity compete with the decrease of σ resulting from the irreversible structural degradation of the polymer chains promoted by the oxygen and moisture of the atmospheric air. The heat treatment time and the temperature at which the two competing mechanisms result in a maximum of the electrical conductivity have been determined and results are discussed relevant to organic optoelectronic devices containing PEDOT: PSS buffer layers.展开更多
Flexible devices produced using organic materials have attracted the attention of many researchers. Important components of these flexible devices include transparent electrodes, which transmit visible light and posse...Flexible devices produced using organic materials have attracted the attention of many researchers. Important components of these flexible devices include transparent electrodes, which transmit visible light and possess conductivity. The present study improved the characteristics of a transparent conductive film that was made of poly(3, 4 ethylenedioxythiophene):poly(styrenesul-fonate) (PEDOT:PSS), an organic conductive material, and that had been prepared using ink-jet printing. To improve the resistance value and visible light transmittance of the film, the film substrate was first cleaned with ultraviolet/ozone treatment, and then the film was annealed after it was deposited on the substrate and dipped into a polar solvent. Consequently, the resistance value of the thin film decreased. However, the surface state of the film changed according to the treatment method and affected its visible light transmittance. Thus, the surface state of the film substrate, the annealing temperature after film deposition, and the dipping treatment with a polar solvent influenced the characteristics of a thin film.展开更多
基金This work was supported by the National Natural Science Foundation of China(Grant Nos.62001325,91743110,52075384,and 21861132001)the National Key R&D Program of China(Grant No.2018YFE0118700)+2 种基金Tianjin Applied Basic Research and Advanced Technology(Grant No.17JCJQJC43600)the Foundation for Talent Scientists of Nanchang Institute for Microtechnology of Tianjin Universitythe“111”Project(Grant No.B07014).
文摘PEDOT:PSS conductive polymers have received tremendous attention over the last two decades owing to their high conductivity,ease of processing,and biocompatibility.As a flexible versatile material,PEDOT:PSS can be developed into various forms and has had a significant impact on emerging sensing applications.This review covers the development of PEDOT:PSS from material to physical sensors.We focus on the morphology of PEDOT:PSS in the forms of aqueous dispersions,solid films,and hydrogels.Manufacturing processes are summarized,including coating,printing,and lithography,and there is particular emphasis on nanoimprinting lithography that enables the production of PEDOT:PSS nanowires with superior sensing performance.Applications to various physical sensors,for humidity,temperature,pressure,and strain,are demonstrated.Finally,we discuss the challenges and propose new directions for the development of PEDOT:PSS.
基金supported by the National Key Research and Development Program of China(2020YFA0715000)the Guangdong Basic and Applied Basic Research Foundation(2020A1515110250,2021B1515120041)+1 种基金the Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory(XHT2020-005)the Fundamental Research Funds for the Central Universities(2020IVA068,2021lll007JC)
文摘Because poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)(PEDOT:PSS)is water processable,thermally stable,and highly conductive,PEDOT:PSS and its composites have been considered to be one of the most promising flexible thermoelectric materials.However,the PEDOT:PSS film prepared from its commercial aqueous dispersion usually has very low conductivity,thus cannot be directly utilized for TE applications.Here,a simple environmental friendly strategy via femtosecond laser irradiation without any chemical dopants and treatments was demonstrated.Under optimal conditions,the electrical conductivity of the treated film is increased to 803.1 S cm^(-1)from 1.2 S cm^(-1)around three order of magnitude higher,and the power factor is improved to 19.0μW m^(-1)K^(-2),which is enhanced more than 200 times.The mechanism for such remarkable enhancement was attributed to the transition of the PEDOT chains from a coil to a linear or expanded coil conformation,reduction of the interplanar stacking distance,and the removal of insulating PSS with increasing the oxidation level of PEDOT,facilitating the charge transportation.This work presents an effective route for fabricating high-performance flexible conductive polymer films and wearable thermoelectric devices.
文摘Recently, a high-performance and low-priced transparent conductive film has been expected to be developed because flexible devices produced using organic materials have been actively studied. An indium tin oxide (ITO) thin film, which has been generally used as a material for a transparent conductive film, has problems, such as fragility to bending stress and depletion of the resource. The present study used poly(3, 4-ethylenedioxythiophene)/poly(styrenesulfonate) (PEDOT:PSS), an organic electroconductive material, and examined the improvement in the resistance value and visible light transmittance of a transparent conductive film produced using the ink-jet method. In previous studies, we reported that, to improve the resistance value and visible light transmittance of a thin film, it was effective to clean the film substrate with ultraviolet/ozone (UV/O<sub>3</sub>) treatment, anneal the film after it was deposited on the substance, and dip the annealed film into a polar solvent. Focusing on the thin film processing between printing operations, the present study improved resistance value and visible light transmittance by examining both the application methods of a polar solvent and the annealing time between printing operations. As a result, the resistance value and visible light transmittance of a PEDOT:PSS thin film were 390.4 Ω and 86.6%, respectively. This film was obtained by applying a polar solvent and performing annealing for 30 min between printing operations. The printing was performed three times.
基金Supported by the Tianjin Natural Science Foundation under Grant Nos 13JCYBJC18900,12JCQNJC01300 and13JCZDJC26700the Ministry of Science and Technology of China under Grant No 2013AA014201the Tianjin Key Discipline of Material Physics and Chemistry
文摘We compare the electrical, optical, and surface properties of the PEDOT：PSS/Cu nanowires （Cu NWs）/PEDOT： PSS （PCP） multilayer for organic solar cells. It is demonstrated that the electrical and optical properties of the PEDOT could be improved by the insertion of a Cu NW layer due to its very low resistivity and surface morphology. The organic bulk heterojunction solar cell fabricated on the multil^yer exhibits a higher power conversion ef^ciency than devices based on the PEDOT：PSS or PEDOT：PSS/Cu NWs layer. Moreover, the PCP multilayer can improve cell-performances such as a fill factor and the internal resistance in the device due to horizontally well-aligned Cu NWs. The results suggest that the PCP multilayer is a promising low-cost and low-temperature processing buffer layer candidate for low-cost organic photovoltaics.
基金Supported by the National Natural Science Foundation of China (No. 60372002)
文摘A Langmuir-Blodgett （LB） inducing method was firstly used to prepare single layer and multilayer conducting composite PEDOT-PSS film. The film-forming ability of ionization ODA and ODA-SA monolayer spread on PEDOT-PSS nanoparticle sub-phase and the behavior of ODA/PEDOT-PSS assembly particles on pure water were firstly investigated. The results indicated that nanoparticles in the suphase are packed in the ionization monolayer and stable complex Langmuir film is formed at the air/water interface. It has been found that the best film-forming conditions for composite film are as follows：distinct interface was formed between ODA and PEDOT-PSS layer and single layer thickness of PEDOT-PSS was about 23 nm,well accordant to the size of PEDOT-PSS nanoparticles. Different structures were designed to test the conductive ability of these composite films and a variable range hopping （VRH） model was used to explain the film conductive mechanism. The results indicated that a 3D-VRH model explained well the transferring of charge carrier in the multilayer film.
文摘Flexible devices manufactured using printed electronics have attracted the attention of many researchers. A high-performance transparent conductive film exhibiting high flexibility and elasticity is expected to be developed because of its need for the creation of flexible devices. An indium tin oxide (ITO) thin film, which has generally been used, has weaknesses such as fragility to bending stress and depletion of the resource. This study focused on poly (3, 4-ethy-lenedioxythiophene)/poly (styrenesulfonate) (PEDOT:PSS), a conductive polymer material, and examined improvement in the resistivity and transmittance of the transparent conductive film produced using an inkjet method. The present study improved the electrical and optical characteristics of the thin film by examining the annealing temperature between printing operations and the application method of a polar solvent. As a result, the resistivity and transmittance of a PEDOT:PSS thin film were 1.49 × 10-3 Ω·cm and 89.2%, respectively. This film was obtained by annealing at 90°C for 30 min and applying a polar solvent, using an inkjet printer, between printing operations. The printing was performed three times.
文摘PEDOT:PSS buffer layers have been processed with the standard annealing step used for organic solar cells device applications. The d.c. conductivity σ as a function of temperature for two heating rates under He and atmospheric air was studied. Moreover, the stability of the conductivity was investigated at different temperatures and environments vs time. The main results can be summarized in the following: the increase of σ due to the thermal activation of the carriers and the improvement of the crystallinity compete with the decrease of σ resulting from the irreversible structural degradation of the polymer chains promoted by the oxygen and moisture of the atmospheric air. The heat treatment time and the temperature at which the two competing mechanisms result in a maximum of the electrical conductivity have been determined and results are discussed relevant to organic optoelectronic devices containing PEDOT: PSS buffer layers.
文摘Flexible devices produced using organic materials have attracted the attention of many researchers. Important components of these flexible devices include transparent electrodes, which transmit visible light and possess conductivity. The present study improved the characteristics of a transparent conductive film that was made of poly(3, 4 ethylenedioxythiophene):poly(styrenesul-fonate) (PEDOT:PSS), an organic conductive material, and that had been prepared using ink-jet printing. To improve the resistance value and visible light transmittance of the film, the film substrate was first cleaned with ultraviolet/ozone treatment, and then the film was annealed after it was deposited on the substrate and dipped into a polar solvent. Consequently, the resistance value of the thin film decreased. However, the surface state of the film changed according to the treatment method and affected its visible light transmittance. Thus, the surface state of the film substrate, the annealing temperature after film deposition, and the dipping treatment with a polar solvent influenced the characteristics of a thin film.
