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Highly Thermoconductive,Strong Graphene‑Based Composite Films by Eliminating Nanosheets Wrinkles 被引量:2
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作者 Guang Xiao Hao Li +2 位作者 Zhizhou Yu Haoting Niu Yagang Yao 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第1期328-340,共13页
Graphene-based thermally conductive composites have been proposed as effective thermal management materials for cooling high-power electronic devices.However,when flexible graphene nanosheets are assembled into macros... Graphene-based thermally conductive composites have been proposed as effective thermal management materials for cooling high-power electronic devices.However,when flexible graphene nanosheets are assembled into macroscopic thermally conductive composites,capillary forces induce shrinkage of graphene nanosheets to form wrinkles during solution-based spontaneous drying,which greatly reduces the thermal conductivity of the composites.Herein,graphene nanosheets/aramid nanofiber(GNS/ANF)composite films with high thermal conductivity were prepared by in-plane stretching of GNS/ANF composite hydrogel networks with hydrogen bonds andπ-πinteractions.The in-plane mechanical stretching eliminates graphene nanosheets wrinkles by suppressing inward shrinkage due to capillary forces during drying and achieves a high in-plane orientation of graphene nanosheets,thereby creating a fast in-plane heat transfer channel.The composite films(GNS/ANF-60 wt%)with eliminated graphene nanosheets wrinkles showed a significant increase in thermal conductivity(146 W m^(−1)K^(−1))and tensile strength(207 MPa).The combination of these excellent properties enables the GNS/ANF composite films to be effectively used for cooling flexible LED chips and smartphones,showing promising applications in the thermal management of high-power electronic devices. 展开更多
关键词 GRAPHENE Aramid nanofiber Wrinkles elimination In-plane stretching Thermal conductivity
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Unraveling the Fundamental Mechanism of Interface Conductive Network Influence on the Fast‑Charging Performance of SiO‑Based Anode for Lithium‑Ion Batteries 被引量:1
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作者 Ruirui Zhang Zhexi Xiao +6 位作者 Zhenkang Lin Xinghao Yan Ziying He Hairong Jiang Zhou Yang Xilai Jia Fei Wei 《Nano-Micro Letters》 SCIE EI CSCD 2024年第3期53-68,共16页
Progress in the fast charging of high-capacity silicon monoxide(SiO)-based anode is currently hindered by insufficient conductivity and notable volume expansion.The construction of an interface conductive network effe... Progress in the fast charging of high-capacity silicon monoxide(SiO)-based anode is currently hindered by insufficient conductivity and notable volume expansion.The construction of an interface conductive network effectively addresses the aforementioned problems;however,the impact of its quality on lithium-ion transfer and structure durability is yet to be explored.Herein,the influence of an interface conductive network on ionic transport and mechanical stability under fast charging is explored for the first time.2D modeling simulation and Cryo-transmission electron microscopy precisely reveal the mitigation of interface polarization owing to a higher fraction of conductive inorganic species formation in bilayer solid electrolyte interphase is mainly responsible for a linear decrease in ionic diffusion energy barrier.Furthermore,atomic force microscopy and Raman shift exhibit substantial stress dissipation generated by a complete conductive network,which is critical to the linear reduction of electrode residual stress.This study provides insights into the rational design of optimized interface SiO-based anodes with reinforced fast-charging performance. 展开更多
关键词 Fast charging SiO anode Interface conductive network Ionic transport Mechanical stability
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Flexible, Transparent and Conductive Metal Mesh Films with Ultra‑High FoM for Stretchable Heating and Electromagnetic Interference Shielding 被引量:1
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作者 Zibo Chen Shaodian Yang +9 位作者 Junhua Huang Yifan Gu Weibo Huang Shaoyong Liu Zhiqiang Lin Zhiping Zeng Yougen Hu Zimin Chen Boru Yang Xuchun Gui 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第5期201-213,共13页
Despite the growing demand for transparent conductive films in smart and wearable electronics for electromagnetic interference(EMI)shielding,achieving a flexible EMI shielding film,while maintaining a high transmittan... Despite the growing demand for transparent conductive films in smart and wearable electronics for electromagnetic interference(EMI)shielding,achieving a flexible EMI shielding film,while maintaining a high transmittance remains a significant challenge.Herein,a flexible,transparent,and conductive copper(Cu)metal mesh film for EMI shielding is fabricated by self-forming crackle template method and electroplating technique.The Cu mesh film shows an ultra-low sheet resistance(0.18Ω□^(-1)),high transmittance(85.8%@550 nm),and ultra-high figure of merit(>13,000).It also has satisfactory stretchability and mechanical stability,with a resistance increases of only 1.3%after 1,000 bending cycles.As a stretchable heater(ε>30%),the saturation temperature of the film can reach over 110°C within 60 s at 1.00 V applied voltage.Moreover,the metal mesh film exhibits outstanding average EMI shielding effectiveness of 40.4 dB in the X-band at the thickness of 2.5μm.As a demonstration,it is used as a transparent window for shielding the wireless communication electromagnetic waves.Therefore,the flexible and transparent conductive Cu mesh film proposed in this work provides a promising candidate for the next-generation EMI shielding applications. 展开更多
关键词 Metal mesh Transparent conductive film Stretchable heater Electromagnetic interference shielding
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Development and characterization of 3D-printed electroconductive pHEMA-co-MAA NP-laden hydrogels for tissue engineering 被引量:1
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作者 Sara De Nitto Aleksandra Serafin +3 位作者 Alexandra Karadimou Achim Schmalenberger John J.EMulvihill Maurice N.Collins 《Bio-Design and Manufacturing》 SCIE EI CAS CSCD 2024年第3期262-276,共15页
Tissue engineering(TE)continues to be widely explored as a potential solution to meet critical clinical needs for diseased tissue replacement and tissue regeneration.In this study,we developed a poly(2-hydroxyethyl me... Tissue engineering(TE)continues to be widely explored as a potential solution to meet critical clinical needs for diseased tissue replacement and tissue regeneration.In this study,we developed a poly(2-hydroxyethyl methacrylate-co-methacrylic acid)(pHEMA-co-MAA)based hydrogel loaded with newly synthesized conductive poly(3,4-ethylene-dioxythiophene)(PEDOT)and polypyrrole(PPy)nanoparticles(NPs),and subsequently processed these hydrogels into tissue engineered constructs via three-dimensional(3D)printing.The presence of the NPs was critical as they altered the rheological properties during printing.However,all samples exhibited suitable shear thinning properties,allowing for the development of an optimized processing window for 3D printing.Samples were 3D printed into pre-determined disk-shaped configurations of 2 and 10 mm in height and diameter,respectively.We observed that the NPs disrupted the gel crosslinking efficiencies,leading to shorter degradation times and compressive mechanical properties ranging between 450 and 550 kPa.The conductivity of the printed hydrogels increased along with the NP concentration to(5.10±0.37)×10^(−7)S/cm.In vitro studies with cortical astrocyte cell cultures demonstrated that exposure to the pHEMA-co-MAA NP hydrogels yielded high cellular viability and proliferation rates.Finally,hydrogel antimicrobial studies with staphylococcus epidermidis bacteria revealed that the developed hydrogels affected bacterial growth.Taken together,these materials show promise for various TE strategies. 展开更多
关键词 conductive nanoparticles Hydroxyethyl methacrylate(HEMA) Ultraviolet(UV)polymerization 3D printing
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High energy density in ultra-thick and flexible electrodes enabled by designed conductive agent/binder composite
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作者 Xiaoyu Shen Hailong Yu +6 位作者 Liubin Ben Wenwu Zhao Qiyu Wang Guanjun Cen Ronghan Qiao Yida Wu Xuejie Huang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第3期133-143,I0005,共12页
Thick electrodes can increase incorporation of active electrode materials by diminishing the proportion of inactive constituents,improving the overall energy density of batteries.However,thick electrodes fabricated us... Thick electrodes can increase incorporation of active electrode materials by diminishing the proportion of inactive constituents,improving the overall energy density of batteries.However,thick electrodes fabricated using the conventional slurry casting approach frequently exhibit an exacerbated accumulation of carbon additives and binders on their surfaces,invariably leading to compromised electrochemical properties.In this study,we introduce a designed conductive agent/binder composite synthesized from carbon nanotube and polytetrafluoroethylene.This agent/binder composite facilitates production of dry-process-prepared ultra-thick electrodes endowed with a three-dimensional and uniformly distributed percolative architecture,ensuring superior electronic conductivity and remarkable mechanical resilience.Using this approach,ultra-thick LiCoO_(2)(LCO) electrodes demonstrated superior cycling performance and rate capabilities,registering an impressive loading capacity of up to 101.4 mg/cm^(2),signifying a 242% increase in battery energy density.In another analytical endeavor,time-of-flight secondary ion mass spectroscopy was used to clarify the distribution of cathode electrolyte interphase(CEI) in cycled LCO electrodes.The results provide unprecedented evidence explaining the intricate correlation between CEI generation and carbon distribution,highlighting the intrinsic advantages of the proposed dry-process approach in fine-tu ning the CEI,with excellent cycling performance in batteries equipped with ultra-thick electrodes. 展开更多
关键词 conductive agent/binder composite Dry process Ultra-thick electrodes High energy density CEI reconstruction ToF-SIMS
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Highly Thermally Conductive and Structurally Ultra‑Stable Graphitic Films with Seamless Heterointerfaces for Extreme Thermal Management
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作者 Peijuan Zhang Yuanyuan Hao +17 位作者 Hang Shi Jiahao Lu Yingjun Liu Xin Ming Ya Wang Wenzhang Fang Yuxing Xia Yance Chen Peng Li Ziqiu Wang Qingyun Su Weidong Lv Ji Zhou Ying Zhang Haiwen Lai Weiwei Gao Zhen Xu Chao Gao 《Nano-Micro Letters》 SCIE EI CSCD 2024年第3期383-397,共15页
Highly thermally conductive graphitic film(GF)materials have become a competitive solution for the thermal management of high-power electronic devices.However,their catastrophic structural failure under extreme altern... Highly thermally conductive graphitic film(GF)materials have become a competitive solution for the thermal management of high-power electronic devices.However,their catastrophic structural failure under extreme alternating thermal/cold shock poses a significant challenge to reliability and safety.Here,we present the first investigation into the structural failure mechanism of GF during cyclic liquid nitrogen shocks(LNS),which reveals a bubbling process characterized by“permeation-diffusion-deformation”phenomenon.To overcome this long-standing structural weakness,a novel metal-nanoarmor strategy is proposed to construct a Cu-modified graphitic film(GF@Cu)with seamless heterointerface.This well-designed interface ensures superior structural stability for GF@Cu after hundreds of LNS cycles from 77 to 300 K.Moreover,GF@Cu maintains high thermal conductivity up to 1088 W m^(−1)K^(−1)with degradation of less than 5%even after 150 LNS cycles,superior to that of pure GF(50%degradation).Our work not only offers an opportunity to improve the robustness of graphitic films by the rational structural design but also facilitates the applications of thermally conductive carbon-based materials for future extreme thermal management in complex aerospace electronics. 展开更多
关键词 Highly thermally conductive Structurally ultra-stable Graphitic film Extreme thermal management Liquid nitrogen bubbling
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Effects of conductive agent type on lithium extraction from salt lake brine with LiFePO_(4) electrodes
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作者 Zhen Zhang Pan Luo +7 位作者 Yan Zhang Yuhan Wang Li Liao Bo Yu Mingshan Wang Junchen Chen Bingshu Guo Xing Li 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第4期678-687,共10页
Electrochemical lithium extraction from salt lakes is an effective strategy for obtaining lithium at a low cost.Nevertheless,the elevated Mg:Li ratio and the presence of numerous coexisting ions in salt lake brines gi... Electrochemical lithium extraction from salt lakes is an effective strategy for obtaining lithium at a low cost.Nevertheless,the elevated Mg:Li ratio and the presence of numerous coexisting ions in salt lake brines give rise to challenges,such as prolonged lithium extraction periods,diminished lithium extraction efficiency,and considerable environmental pollution.In this work,Li FePO4(LFP)served as the electrode material for electrochemical lithium extraction.The conductive network in the LFP electrode was optimized by adjusting the type of conductive agent.This approach resulted in high lithium extraction efficiency and extended cycle life.When the single conductive agent of acetylene black(AB)or multiwalled carbon nanotubes(MWCNTs)was replaced with the mixed conductive agent of AB/MWCNTs,the average diffusion coefficient of Li+in the electrode increased from 2.35×10^(-9)or 1.77×10^(-9)to 4.21×10^(-9)cm^(2)·s^(-1).At the current density of 20 mA·g^(-1),the average lithium extraction capacity per gram of LFP electrode increased from 30.36 mg with the single conductive agent(AB)to 35.62 mg with the mixed conductive agent(AB/MWCNTs).When the mixed conductive agent was used,the capacity retention of the electrode after 30 cycles reached 82.9%,which was considerably higher than the capacity retention of 65.8%obtained when the single AB was utilized.Meanwhile,the electrode with mixed conductive agent of AB/MWCNTs provided good cycling performance.When the conductive agent content decreased or the loading capacity increased,the electrode containing the mixed conductive agent continued to show excellent electrochemical performance.Furthermore,a self-designed,highly efficient,continuous lithium extraction device was constructed.The electrode utilizing the AB/MWCNT mixed conductive agent maintained excellent adsorption capacity and cycling performance in this device.This work provides a new perspective for the electrochemical extraction of lithium using LFP electrodes. 展开更多
关键词 salt lake brine lithium extraction electrochemical lithium extraction conductive agent extraction efficiency adsorption capacity
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Incorporation of Ionic Conductive Polymers into Sulfide Electrolyte-Based Solid-State Batteries to Enhance Electrochemical Stability and Cycle Life
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作者 Juhyoung Kim Woonghee Choi +1 位作者 Seong-Ju Hwang Dong Wook Kim 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第6期4-12,共9页
Sulfide-based inorganic solid electrolytes are promising materials for high-performance safe solid-state batteries.The high ion conductivity,mechanical characteristics,and good processability of sulfide-based inorgani... Sulfide-based inorganic solid electrolytes are promising materials for high-performance safe solid-state batteries.The high ion conductivity,mechanical characteristics,and good processability of sulfide-based inorganic solid electrolytes are desirable properties for realizing high-performance safe solid-state batteries by replacing conventional liquid electrolytes.However,the low chemical and electrochemical stability of sulfide-based inorganic solid electrolytes hinder the commercialization of sulfide-based safe solid-state batteries.Particularly,the instability of sulfide-based inorganic solid electrolytes is intensified in the cathode,comprising various materials.In this study,carbonate-based ionic conductive polymers are introduced to the cathode to protect cathode materials and suppress the reactivity of sulfide electrolytes.Several instruments,including electrochemical spectroscopy,X-ray photoelectron spectroscopy,and scanning electron microscopy,confirm the chemical and electrochemical stability of the polymer electrolytes in contact with sulfide-based inorganic solid electrolytes.Sulfide-based solid-state cells show stable electrochemical performance over 100 cycles when the ionic conductive polymers were applied to the cathode. 展开更多
关键词 composite cathode electrochemical stability ionic conductive polymer solid-state battery sulfide solid electrolyte
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Ignition processes and characteristics of charring conductive polymers with a cavity geometry in precombustion chamber for applications in micro/nano satellite hybrid rocket motors
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作者 Zhiyuan Zhang Hanyu Deng +2 位作者 Wenhe Liao Bin Yu Zai Yu 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第2期55-66,共12页
The arc ignition system based on charring polymers has advantages of simple structure,low ignition power consumption and multiple ignitions,which bringing it broadly application prospect in hybrid propulsion system of... The arc ignition system based on charring polymers has advantages of simple structure,low ignition power consumption and multiple ignitions,which bringing it broadly application prospect in hybrid propulsion system of micro/nano satellite.However,charring polymers alone need a relatively high input voltage to achieve pyrolysis and ignition,which increases the burden and cost of the power system of micro/nano satellite in practical application.Adding conductive substance into charring polymers can effectively decrease the conducting voltage which can realize low voltage and low power consumption repeated ignition of arc ignition system.In this paper,a charring conductive polymer ignition grain with a cavity geometry in precombustion chamber,which is composed of PLA and multiwall carbon nanotubes(MWCNT)was proposed.The detailed ignition processes were analyzed and two different ignition mechanisms in the cavity of charring conductive polymers were revealed.The ignition characteristics of charring conductive polymers were also investigated at different input voltages,ignition grain structures,ignition locations and injection schemes in a visual ignition combustor.The results demonstrated that the ignition delay and external energy required for ignition were inversely correlated with the voltages applied to ignition grain.Moreover,the incremental depth of cavity shortened the ignition delay and external energy required for ignition while accelerated the propagation of flame.As the depth of cavity increased from 2 to 6 mm(at 50 V),the time of flame propagating out of ignition grain changed from 235.6 to 108 ms,and values of mean ignition delay time and mean external energy required for ignition decreased from 462.8 to 320 ms and 16.2 to 10.75 J,respectively.The rear side of the cavity was the ideal ignition position which had a shorter ignition delay and a faster flame propagation speed in comparison to other ignition positions.Compared to direct injection scheme,swirling injection provided a more favorable flow field environment in the cavity,which was beneficial to ignition and initial flame propagation,but the ignition position needed to be away from the outlet of swirling injector.At last,the repeated ignition characteristic of charring conductive polymers was also investigated.The ignition delay time and external energy required for ignition decreased with repeated ignition times but the variation was decreasing gradually. 展开更多
关键词 Micro/nano satellite hybrid propulsion Arc ignition Charring conductive polymer Ignition mechanism Ignition characteristic Repeated ignition
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Porous Indium Nanocrystals on Conductive Carbon Nanotube Networks for High-Performance CO_(2)-to-Formate Electrocatalytic Conversion
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作者 Liangping Xiao Rusen Zhou +4 位作者 Tianqi Zhang Xiaoxiang Wang Renwu Zhou Patrick J.Cullen Kostya(Ken)Ostrikov 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第4期413-421,共9页
Ever-increasing emissions of anthropogenic carbon dioxide(CO_(2))cause global environmental and climate challenges.Inspired by biological photosynthesis,developing effective strategies NeuNlto up-cycle CO_(2)into high... Ever-increasing emissions of anthropogenic carbon dioxide(CO_(2))cause global environmental and climate challenges.Inspired by biological photosynthesis,developing effective strategies NeuNlto up-cycle CO_(2)into high-value organics is crucial.Electrochemical CO_(2)reduction reaction(CO_(2)RR)is highly promising to convert CO_(2)into economically viable carbon-based chemicals or fuels under mild process conditions.Herein,mesoporous indium supported on multi-walled carbon nanotubes(mp-In@MWCNTs)is synthesized via a facile wet chemical method.The mp-In@MWCNTs electrocatalysts exhibit high CO_(2)RR performance in reducing CO_(2)into formate.An outstanding activity(current density-78.5 mA cm^(-2)),high conversion efficiency(Faradaic efficiency of formate over 90%),and persistent stability(∼30 h)for selective CO_(2)-to-formate conversion are observed.The outstanding CO_(2)RR process performance is attributed to the unique structures with mesoporous surfaces and a conductive network,which promote the adsorption and desorption of reactants and intermediates while improving electron transfer.These findings provide guiding principles for synthesizing conductive metal-based electrocatalysts for high-performance CO_(2)conversion. 展开更多
关键词 CO_(2)RR conductive network ELECTROCATALYSTS FORMATE
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Preparation and Characterization of lonic Conductive Eutectogels Based on Polyacrylamide Copolymers with Long Hydrophobic Chain
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作者 Minhao Zhang Qiang Zhou +3 位作者 Jiaqing He Yongjun Xie Haiyang Yang Weidong He 《Chinese Journal of Chemical Physics》 SCIE EI CAS CSCD 2024年第5期685-695,I0101,共12页
With the blooming development of electronic technology,the use of electron conductive gel or ionic conductive gel in preparing flexible electronic devices is drawing more and more attention.Deep eutectic solvents are ... With the blooming development of electronic technology,the use of electron conductive gel or ionic conductive gel in preparing flexible electronic devices is drawing more and more attention.Deep eutectic solvents are excellent substitutes for ionic liquids because of their good biocompatibility,low cost,and easy preparation,except for good conductivity.In this work,we synthesized a reactive quaternary ammonium monomer(3-acrylamidopropyl)octadecyldimethyl ammonium bromide with a hydrophobic chain of 18 carbons via the quaternization of 1-bromooctadecane and N-dimethylaminopropyl acrylamide at first,then we mixed quaternary ammonium with choline chloride,acrylic acid and glycerol to obtain a hydrophobic deep eutectic solvent,and initialized polymerization in UV light of 365 nm to obtain the ionic conductive eutectogel based on polyacrylamide copolymer with long hydrophobic chain.The obtained eutectogel exibits good stretchability(1200%),Young's modulus(0.185 MPa),toughness(4.2 MJ/m^(3)),conductivity(0.315 S/m).The eutectogel also shows desireable moisture resistance with the maximum water absorption of 11.7 wt%after one week at 25℃and 60%humidity,while the water absorption of eutectogel without hydrophobic long chains is 24.0 wt%.The introduction of long-chain hydrophobic groups not only improves the mechanical strength of the gels,but also significantly improves moisture resistance of the eutectogel.This work provides a simpler and more effective method for the preparation of ionic conductive eutectogels,which can further provide a reference for the applications of ionic conductive eutectogels in the field of flexible electronic devices. 展开更多
关键词 Hydrophobic long-chain copolymer Deep eutectic solvent Ionic conductive eutectogel Moisture resistance
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Interfacial Modulation of Polydopamine-Reduced Graphene Oxide for Achieving Highly Conductive and Strong Graphene/Cotton Composite Yarn Toward Smart Wearable Devices
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作者 Yujin Zhang Guowen Zhang +3 位作者 Yuqi Dong Yongcai Wu Liqian Yu Yongxiao Bai 《Advanced Fiber Materials》 SCIE EI CAS 2024年第6期1798-1812,共15页
Graphene composite yarns have demonstrated significant potential in the development of multifunctional wearable elec-tronics,showcasing exceptional conductivity,mechanical properties,flexibility,and lightweight design... Graphene composite yarns have demonstrated significant potential in the development of multifunctional wearable elec-tronics,showcasing exceptional conductivity,mechanical properties,flexibility,and lightweight design.However,their performance is limited by the weak interfacial interaction between the fibers and graphene.Herein,a polydopamine-reduced graphene oxide(PDA-RGO)interfacial modulation strategy is proposed to prepare graphene-coated cotton yarns with high electrical conductivity and strength.PDA-RGO serves as an interfacial bonding molecule that interacts with the cotton yarn(CY)substrate to establish a hydrogen interface,while interconnecting with highly conductive graphene throughπ-πinterac-tions.The developed interface-designed graphene-coated yarn demonstrates an impressive average electrical conductivity of(856.27±7.02)S/m(i.e.,average resistance of(57.57±5.35)Ω).Simultaneously,the obtained conductive yarn demonstrates an exceptional average tensile strength of(172.03±8.03)MPa,surpassing that of primitive CY by approximately 1.59 times.The conductive yarns can be further used as low-voltage flexible wearable heaters and high-sensitivity pressure sensors,thus showcasing their remarkable potential for high-performance and multifunctional wearable devices in real-world applications. 展开更多
关键词 GRAPHENE Interface modulation conductive yarn Flexible wearable device
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Constructing Anisotropic Conductive Networks inside Hollow Elastic Fiber with High Sensitivity and Wide‑Range Linearity by Cryo‑spun Drying Strategy
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作者 Along Zheng Kening Wan +6 位作者 Yuwen Huang Yanyan Ma Tao Ding Yong Zheng Ziyin Chen Qichun Feng Zhaofang Du 《Advanced Fiber Materials》 SCIE EI CAS 2024年第6期1898-1909,共12页
Stretchable conductive fibers composed of conductive materials and elastic substrates have advantages such as braiding abil-ity,electrical conductivity,and high resilience,making them ideal materials for fibrous weara... Stretchable conductive fibers composed of conductive materials and elastic substrates have advantages such as braiding abil-ity,electrical conductivity,and high resilience,making them ideal materials for fibrous wearable strain sensors.However,the weak interface between the conductive materials and elastic substrates restricts fibers flexibility under strain,leading to challenges in achieving both linearity and sensitivity of the as-prepared fibrous strain sensor.Herein,cryo-spun drying strategy is proposed to fabricate the thermoplastic polyurethane(TPU)fiber with anisotropic conductive networks(ACN@TPU fiber).Benefiting from the excellent mechanical properties of TPU,and the excellent interface among TPU,silver nanoparticles(AgNPs)and polyvinyl alcohol(PVA),the prepared ACN@TPU fiber exhibits an outstanding mechanical performance.The anisotropic conductive networks enable the ACN@TPU fiber to achieve high sensitivity(gauge factor,GF=4.68)and excellent linearity within a wide working range(100%strain).Furthermore,mathematical model based on AgNPs is established and the resistance calculation equation is derived,with a highly matched fitting and experimental results(R2=0.998).As a conceptual demonstration,the ACN@TPU fiber sensor is worn on a mannequin to accurately and instantly detect movements.Therefore,the successful construction of ACN@TPU fiber with anisotropic conductive networks through the cryo-spun drying strategy provides a feasible approach for the design and preparation of fibrous strain sensing materials with high linearity and high sensitivity. 展开更多
关键词 Cryo-spun drying Anisotropic conductive networks High sensitivity Wide-range linearity Fibrous wearable strain sensor
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Unlocking Intrinsic Conductive Dynamics of Ionogel Microneedle Arrays as Wearable Electronics for Intelligent Fire Safety
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作者 Yapeng Zheng Haodong Liu +3 位作者 Jingwen Wang Tianyang Cui Jixin Zhu Zhou Gui 《Advanced Fiber Materials》 SCIE EI CAS 2024年第1期195-213,共19页
Ionogels have enabled flexible electronic devices for wide-ranging innovative applications in wearable electronics,soft robotics,and intelligent systems.Ionogels for flexible electronics need to essentially tolerate s... Ionogels have enabled flexible electronic devices for wide-ranging innovative applications in wearable electronics,soft robotics,and intelligent systems.Ionogels for flexible electronics need to essentially tolerate stress,temperature,humidity,and solvents that may cause their electrical conductivity,structural stability,processing compatibility and sensibility failure.Herein,we developed a novel in-situ photopolymerization protocol to fabricate intrinsically conductive,self-gated ionogels via ion-restriction dual effects.Highly sensitive and intelligent safety sensors with tunable stretchability,robust chemical stability,favorable printability,and complete recyclability,are programmed from defined microneedle arrays printed by the intrinsically conductive ionogel.Ultrahigh elasticity(~794%elongation),high compression tolerance(~90%deformation),improved mechanical strength(tensile and compressive strength of~2.0 MPa and~16.3 MPa,respectively)and remark-able transparency(>91.1%transmittance),as well as high-temperature sensitivity(-2.07%℃^(-1))and a wide working range(-40 to200℃)can be achieved.In particular,the intrinsic sensing mechanisms of ion-restriction dual effects are unlocked based on DFT calculations and MD simulations,and operando temperature-dependent FTIR,and Raman technolo-gies.Moreover,the real-time intelligent monitoring systems toward physical signals and precise temperature based on the microneedle array-structures sensors are also presented and demonstrate great potential applications for extreme environ-ments,e.g.,fire,deep-sea or aerospace. 展开更多
关键词 Multifunctional ionogel Intrinsic conductive dynamics Bionic microneedle array Intelligent safety system
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Preparation and Analysis of Carbon Fiber-Silicon Carbide Thermally Conductive Asphalt Concrete
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作者 Zhiyong Yang Enjie Hu +3 位作者 Lei Xi Zhi Chen Feng Xiong Chuanhai Zhan 《Fluid Dynamics & Materials Processing》 EI 2024年第4期705-723,共19页
An experimental investigation into the thermal conductivity of CF-SiC two-phase composite asphalt concrete is presented.The main objective of this study was to verify the possibility of using SiC powder instead of min... An experimental investigation into the thermal conductivity of CF-SiC two-phase composite asphalt concrete is presented.The main objective of this study was to verify the possibility of using SiC powder instead of mineral powder as the thermal conductive filler to prepare a new type of asphalt concrete and improve the efficiency of electrothermal snow and ice melting systems accordingly.The thermal conductivity of asphalt concrete prepared with different thermally conductive fillers was tested by a transient plane source method,and the related performances were measured.Then the temperature rise rate and surface temperature were studied through field heating tests.Finally,the actual ice melting efficiency of the thermally conductive asphalt concrete was evaluated using an effective electrothermal system.As shown by the experimental results,the composite made of SiC powder and carbon fiber has a high thermal conductivity.When SiC replaces mineral powder,the thermal conductivity of the asphalt mixture increases first and then decreases with the increase of carbon fiber content.In the present study,in particular,the thermal conductivity attained a peak when the carbon fiber content was 0.2%of the aggregate mass. 展开更多
关键词 Carbon fiber silicon carbide thermally conductive asphalt concrete road performance electrothermal snow melting
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Enhancing the Tribological Performance of Conductive Grease Through the Modification of Polypyrrole with Ionic Liquids
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作者 Xia Yanqiu Chen Wenhao +1 位作者 Jiang Zhirong Yang Kuo 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS CSCD 2024年第3期158-172,共15页
This study prepared four types of ionic liquid-modified polypyrrole(IL-modified PPy)as conductive additives and investigated their tribological performance and conductivity in polytetrafluoroethylene lubricating greas... This study prepared four types of ionic liquid-modified polypyrrole(IL-modified PPy)as conductive additives and investigated their tribological performance and conductivity in polytetrafluoroethylene lubricating grease.The results indicated that IL-modified PPy effectively enhanced the anti-wear performance and conductivity of the base grease.Among the additives,1-octyl-3-methylimidazolium tetrafluoroborate([OMIm][BF4])modified PPy showed superior performance compared to the other three additives,with the best effect observed at a mass fraction of 0.5%.X-ray photoelectron spectroscopy analysis revealed that IL-modified PPy forms a stable friction chemical film during the friction process,effectively enhancing the lubrication performance and conductivity of the base grease.This indicates broad potential applications in the field of conductive lubrication. 展开更多
关键词 conductive lubricating grease ILs modified PPy anti-friction and anti-wear additive
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Design,progress and challenges of 3D carbon-based thermally conductive networks
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作者 JING Yuan LIU Han-qing +2 位作者 ZHOU Feng DAI Fang-na WU Zhong-shuai 《新型炭材料(中英文)》 SCIE EI CAS CSCD 北大核心 2024年第5期844-871,共28页
The advent of the 5G era has stimulated the rapid development of high power electronics with dense integration.Three-dimensional(3D)thermally conductive networks,possessing high thermal and electrical conductivities a... The advent of the 5G era has stimulated the rapid development of high power electronics with dense integration.Three-dimensional(3D)thermally conductive networks,possessing high thermal and electrical conductivities and many different structures,are regarded as key materials to improve the performance of electronic devices.We provide a critical overview of carbonbased 3D thermally conductive networks,emphasizing their preparation-structure-property relationships and their applications in different scenarios.A detailed discussion of the microscopic principles of thermal conductivity is provided,which is crucial for increasing it.This is followed by an in-depth account of the construction of 3D networks using different carbon materials,such as graphene,carbon foam,and carbon nanotubes.Techniques for the assembly of two-dimensional graphene into 3D networks and their effects on thermal conductivity are emphasized.Finally,the existing challenges and future prospects for 3D carbon-based thermally conductive networks are discussed. 展开更多
关键词 Carbon material 3D network GRAPHENE Thermal conductivity Heat transfer
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A Modification of LiMn2O4 by Ionic Conductive Agent and Electronic Conductive Agent Coating
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作者 Xiaohui Sun Meng Wang +1 位作者 Tianming Yuan Jingkang Li 《Natural Science》 2024年第1期1-6,共6页
Carbon was used as electronic conductive agent, and metasilicic acid lithium (Li<sub>2</sub>SiO<sub>3</sub>) as ionic conductive agent, the two factors were investigated cooperatively. We evalu... Carbon was used as electronic conductive agent, and metasilicic acid lithium (Li<sub>2</sub>SiO<sub>3</sub>) as ionic conductive agent, the two factors were investigated cooperatively. We evaluated their effect by using spherical spinel LiMn<sub>2</sub>O<sub>4</sub> which prepared ourselves as cathode material. Then Li<sub>2</sub>SiO<sub><sub></sub>3</sub>/carbon surface coating on LiMn<sub><sub></sub>2</sub>O<sub>4</sub> (LMO/C/LSO) which Li<sub><sub></sub>2</sub>SiO<sub><sub></sub>3</sub> inside and carbon/Li<sub><sub></sub>2</sub>SiO<sub><sub></sub>3</sub> coated LiMn<sub><sub></sub>2</sub>O<sub><sub></sub>4</sub> (LMO/LSO/C) were prepared, All of materials were characterized by X-ray diffraction (XRD) and electrochemical test;spherical LiMn<sub></sub>2O<sub></sub>4 was characterized by scanning electron microscopy (SEM);and coated materials were characterized by transmission electron microscopy (TEM). While uncoated spinel LiMn<sub><sub></sub>2</sub>O<sub><sub></sub>4</sub> maintained 72% of capacity in 60 cycles by the rate of 0.2C, and LMO/LSO/C showed the best electrochemical performance, 89% of the initial capacity remained after 75 cycles at 0.2C. Furthermore, the rate performance of LMO/LSO/C also improved obviously, about 30 mAh·g<sup>-1</sup> of capacity attained at the rate of 5C, higher than LMO/C/LSO and bare LiMn<sub><sub></sub>2</sub>O<sub><sub></sub>4</sub>. 展开更多
关键词 Electronic Conduction Ionic Conduction LMO/LSO/C
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Application of face centred cubic TiB powder as conductive filler for electrically conductive adhesives 被引量:1
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作者 赵健闯 胡建东 +1 位作者 焦东宁 S.TOSTO 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第6期1773-1778,共6页
Face centred cubic(FCC) TiB ceramic powder synthesized by Ti-boronizing method was used as conductive filler to make ceramic electrically conductive adhesives(ECAs) with the polymer matrix.Electrically conductive ... Face centred cubic(FCC) TiB ceramic powder synthesized by Ti-boronizing method was used as conductive filler to make ceramic electrically conductive adhesives(ECAs) with the polymer matrix.Electrically conductive properties of the ceramic ECAs were studied.The bulk electrical resistivity varied with the powder content of the FCC-TiB in ECAs.The FCC-TiB filled ECAs also showed the percolation behavior that usually occurred for the metal-filled ECAs,the percolation threshold was located at the content of 60%FCC-TiB.A minimum value of 0.1 Ω·cm was obtained at a content of 75%FCC-TiB.In order to check the reliability of mechanical property,tensile test was done to measure the shear strength,and the shear strength dropped with increasing the content of FCC-TiB powders.It is about 12.26 MPa at the content of 70%TiB powders.The Cu filled ECAs were also prepared for comparison.The properties of the oxidation resistance of the two ECAs were evaluated.The results show that the ceramic ECAs have excellent oxidation resistance and better stability compared with the Cu filled ECAs. 展开更多
关键词 ceramic powder face centred cubic TIB electrically conductive adhesives bulk resistivity OXIDATION shear strength
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Exploring the novel role of oligodendrocyte precursor cells in phagocytosis:beyond myelinogenesis
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作者 Gen Hamanaka Ken Arai 《Neural Regeneration Research》 SCIE CAS 2025年第2期473-474,共2页
Roles of oligodendrocyte precursor cells in the central nervous system:Oligodendrocyte precursor cells(OPCs)have long been recognized for their critical role as precursors to oligodendrocytes,the primary myelin-produc... Roles of oligodendrocyte precursor cells in the central nervous system:Oligodendrocyte precursor cells(OPCs)have long been recognized for their critical role as precursors to oligodendrocytes,the primary myelin-producing cells.As precursors,OPCs mature and differentiate into oligodendrocytes,which contribute significantly to the formation of myelin sheaths around axons.This myelination,which is critical for the conduction of salutatory nerve impulses in the cerebral white matter,underscores the classical role of oligodendrocytes in central nervous system(CNS)functionality.Importantly,because oligodendrocytes are differentiated cells that cannot proliferate. 展开更多
关键词 CRITICAL system conduction
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