Investigation of extraction fraction in confined impinging jet reactors for tri-butyl-phosphate extracting butyric acid process

The extraction fraction E and overall volumetric mass transfer coefficient kka of TBP extracting butyric acid pro- cess in confined impinging jet reactors （CIJR） with two jets were investigated. The main variables tested were the concentration of tri-butyl-phosphate （TBP） and butyric acid, the impinging velocity V, the impinging velocityratio of two phases Vorg/Vaq, the nozzle inner diameter di and the distance L between the jet axes and the top wall of the impinging chamber. The results showed that E and kLa increase with an increase of the impinging velocity V, the concentration ofTBP Corg, and the impinging velocity ratio Vor/Vaq. However, E and kta decrease with an increase of the inner diameter d1 from 1 to 2 mm, the concentration of butyric acid Caq from 0.5% （v/v） to 2% （v/v）. The factor L ranging from 3 to 11 mm has a negligible effect on E and kLa. A correlation on these variables and kLa was proposed based on the experimental data. These results indicated good mass transfer oerformance of CIJR in the extraction operation.

Numerical investigation of confined swirling gas-solid two phase jet

This paper presents a \%k\|ε\|k\-p\% multi\|fluid model for simulating confined swirling gas\|solid two phase jet comprised of particle\|laden flow from a center tube and a swirling air stream entering the test section from the coaxial annular. A series of numerical simulations of the two\|phase flow of 30 μm, 45 μm, 60 μm diameter particles respectively yielded results fitting well with published experimental data.

Jet dispersion and deposition of charged particles in confined chambers

Dispersion and surface deposition of charged particles by gas-solids jets in confined chambers are constantly encountered in many industrial applications such as in electrostatic precipitation and dry powder coating processes. Understanding and control of flow patterns and trajectories of charged particles are important to the optimal design and operation of such devices. In this study, modeling of flow fields and particle trajectories of dilute gas-solid two-phase flows with charged particles in confined chambers is performed. The dilute gas-solid two-phase flows are simulated by use of a hybrid Eulerian-Lagrangian approach with the one-way coupling between the gaseous phase and particle phase. The space charge distribution is included as a source term in equations of motion or Lagrangian equation of charged particles, which in turn depends on the particle trajectories that determine the space charge distribution. Our modeling predictions suggested that the electrostatic charge plays a significant role in particle radial dispersion. Effect of voltage has limited influence on particle trajectories however it can have a big impact on the residence time. Cone angle has a significant effect on the structure of flow field. For cone with a larger cone angle （typically over 15°）, there will be a flow separation along the side wall near the flow entrance region. By comparing with the conical chamber, the cylindrical chamber has a big vortex and three smaller vortexes in the lower part of the chamber, which would complicate the particle dispersion with or without the coupling of charging.

Three-dimensional Numerical Study of Laminar Confined Slot Jet Impingement Cooling using Slurry of Nano—encapsulated Phase Change Material

This Article presents a three dimensional numerical model investigating thermal performance and hydrodynamics features of the confined slot jet impingement using slurry of Nano Encapsulated Phase Change Material(NEPCM)as a coolant.The slurry is composed of water as a base fluid and n-octadecane NEPCM particles with mean diameter of 100 nm suspended in it.A single phase fluid approach is employed to model the NEPCM slurry.The thermo physical properties of the NEPCM slurry are computed using modern approaches being proposed recently and governing equations are solved with a commercial Finite Volume based code.The effects of jet Reynolds number varying from 100 to 600 and particle volume fraction ranging from 0% to 28% are considered.The computed results are validated by comparing Nusselt number values at stagnation point with the previously published results with water as working fluid.It was found that adding NEPCM to the base fluid results with considerable amount of heat transfer enhancement.The highest values of heat transfer coefficients are observed at H/W=4 and C_m=0.28.However,due to the higher viscosity of slurry compared with the base fluid,the slurry can produce drastic increase in pressure drop of the system that increases with NEPCM particle loading and jet Reynolds number.

Facile pathway to generate agrochemical nanosuspensions integrating super-high load, eco-friendly excipients, intensified preparation process, and enhanced potency

An aqueous nanosuspension of agrochemicals unlike pharmaceutics has to achieve massive production in an effective way,capable to ensure sufficient profits in commercialization.This work implements the flash nanoprecipitation(FNP)technique to effectively generate agrochemical nanosuspension,anticipatedly overcoming such an obstacle.Azoxystrobin,a broad spectrum fungicide,in either acetone or ethanol is used herein as a mode agrochemical.To ensure a green and practical utilization,three kinds of commercially available and eco-friendly surfactants,i.e.,poly(ethylene glycol)-block-poly(lactic-co-glycolic acid)(PEG-b-PLGA),Tween 80 and alkyl polyglucosides(APGs),are employed for stabilizing the nanoparticles.The results show that the polymeric stabilizer,PEG-b-PLGA,has the best stabilization efficiency,and can maintain the particles below 100 nm for at least three weeks.The azoxystrobin load of the nanoparticles reaches as high as 77 wt.%,beneficial to enhancing the biological potency.Moreover,the FNP brings the particles a much smaller size,narrower size distribution,better size stability,and higher biological efficacy than the ones made via a traditional method of the drop and stir(DS).The nanosuspensions present superior fungicidal performances over a prevailing counterpart from Syngenta.This study proves an enhanced biological potency and reduced dosage of agrochemical nanosuspension made via the FNP,indicating a remarkable advantage of the FNP over the conventional preparation.The integration of a super-high load,eco-friendly excipients,intensified preparation process,enhanced potency,and reduced dosage creates a promising pathway to generate a green aqueous nanosuspension of agrochemicals.