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Critical radius and dipole polarizability for a confined system 被引量:1
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作者 许田 曹庄琪 +2 位作者 欧永成 沈启舜 视国龙 《Chinese Physics B》 SCIE EI CAS CSCD 2006年第6期1172-1176,共5页
The analytical transfer matrix method (ATMM) is applied to calculating the critical radius τc and the dipole polarizability αd in two confined systems: the hydrogen atom and the Hulthēén potential. We find ... The analytical transfer matrix method (ATMM) is applied to calculating the critical radius τc and the dipole polarizability αd in two confined systems: the hydrogen atom and the Hulthēén potential. We find that there exists a linear relation between τe^1/2 and the quantum number nτ for a fixed angular quantum number l, moreover, the three bounds of αd(αd^K,αd^B,αd^U) satisfy an inequality:αd^K≤αd^B≤αd^U,A comparison betwen the ATMM,the exact numerical analysis, and the variational wavefunctions shows that our method works very well in the systems. 展开更多
关键词 ATMM confined system critical radius dipole polarizability
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70 Gbps PAM-4850-nm oxide-confined VCSEL without equalization and pre-emphasis 被引量:1
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作者 Anjin Liu Bao Tang +1 位作者 Zhiyong Li Wanhua Zheng 《Journal of Semiconductors》 EI CAS CSCD 2024年第5期5-7,共3页
Directly modulated 850-nm vertical-cavity surface-emitting lasers(VCSELs)with the advantages of low cost,high modulation speed,good reliability,and low power consumption,are the key sources in the optical interconnect... Directly modulated 850-nm vertical-cavity surface-emitting lasers(VCSELs)with the advantages of low cost,high modulation speed,good reliability,and low power consumption,are the key sources in the optical interconnects with multimode fibers for the supercomputers,data centers,and machine learning applications[1−3].Typically,non-return-tozero(NRZ)modulation format is used. 展开更多
关键词 RETURN confined fibers
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Effects of asymmetric coupling and boundary on the dynamic behaviors of a random nearest neighbor coupled system
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作者 徐玲 姜磊 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第6期309-322,共14页
This study investigates the dynamical behaviors of nearest neighbor asymmetric coupled systems in a confined space.First, the study derivative analytical stability and synchronization conditions for the asymmetrically... This study investigates the dynamical behaviors of nearest neighbor asymmetric coupled systems in a confined space.First, the study derivative analytical stability and synchronization conditions for the asymmetrically coupled system in an unconfined space, which are then validated through numerical simulations. Simulation results show that asymmetric coupling has a significant impact on synchronization conditions. Moreover, it is observed that irrespective of whether the system is confined, an increase in coupling asymmetry leads to a hastened synchronization pace. Additionally, the study examines the effects of boundaries on the system's collective behaviors via numerical experiments. The presence of boundaries ensures the system's stability and synchronization, and reducing these boundaries can expedite the synchronization process and amplify its effects. Finally, the study reveals that the system's output amplitude exhibits stochastic resonance as the confined boundary size increases. 展开更多
关键词 asymmetric coupled confined space SYNCHRONIZATION stochastic resonance stability
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Influence of confined water on the limit support pressure of tunnel face in weakly water-rich strata
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作者 LI Yun-fa WU Guo-jun +2 位作者 CHEN Wei-zhong YUAN Jing-qiang HUO Meng-zhe 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第8期2844-2859,共16页
In the process of shield tunneling through soft soil layers,the presence of confined water ahead poses a significant threat to the stability of the tunnel face.Therefore,it is crucial to consider the impact of confine... In the process of shield tunneling through soft soil layers,the presence of confined water ahead poses a significant threat to the stability of the tunnel face.Therefore,it is crucial to consider the impact of confined water on the limit support pressure of the tunnel face.This study employed the finite element method(FEM)to analyze the limit support pressure of shield tunnel face instability within a pressurized water-containing layer.Subsequently,a multiple linear regression approach was applied to derive a concise solution formula for the limit support pressure,incorporating various influencing factors.The analysis yields the following conclusions:1)The influence of confined water on the instability mode of the tunnel face in soft soil layers makes the displacement response of the strata not significant when the face is unstable;2)The limit support pressure increases approximately linearly with the pressure head,shield tunnel diameter,and tunnel burial depth.And inversely proportional to the thickness of the impermeable layer,soil cohesion and internal friction angle;3)Through an engineering case study analysis,the results align well with those obtained from traditional theoretical methods,thereby validating the rationality of the equations proposed in this paper.Furthermore,the proposed equations overcome the limitation of traditional theoretical approaches considering the influence of changes in impermeable layer thickness.It can accurately depict the dynamic variation in the required limit support pressure to maintain the stability of the tunnel face during shield tunneling,thus better reflecting engineering reality. 展开更多
关键词 weakly water-rich strata confined aquifer limit support pressure finite element method multiple linear regression
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Summary of the 11th Conference on Magnetic Confined Fusion Theory and Simulation
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作者 Guangzhou HAO Jianqiang XU +2 位作者 Youwen SUN Zhibin GUO Organizing Committee of the 11th Conference on Magnetic Confined Fusion Theory and Simulation 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第10期1-7,共7页
This conference report summarizes recent progress in plasma theory and simulation that was presented in contributed papers and discussions at the 11th Conference on Magnetic Confined Fusion Theory and Simulation(CMCFT... This conference report summarizes recent progress in plasma theory and simulation that was presented in contributed papers and discussions at the 11th Conference on Magnetic Confined Fusion Theory and Simulation(CMCFTS)held in Chengdu,China,27–30 October,2023.Progress in various fields has been achieved.For example,results on zonal flow generation by mode coupling,simulations of the key physics of divertor detachment,energetic particle effects on magnetohydrodynamic(MHD)modes in addition to ion-and electron-scale turbulence,physics of edge coherent modes and edge-localized modes,and the optimization of ion heating schemes as well as confinement scenarios using advanced integrated modeling are presented at the conference.In this conference,the scientific research groups were organized into six categories:(a)edge and divertor physics;(b)impurity,heating,and current drive;(c)energetic particle physics;(d)turbulent transport;(e)MHD instability;and(f)integrated modeling and code development.A summary of the highlighted progress in these working groups is presented. 展开更多
关键词 magnetic confined fusion(MCF) theory and simulation modeling TOKAMAK
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Strong shock propagation for the finite-source circular blast in a confined domain
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作者 Qihang MA Kaileong CHONG +1 位作者 Bofu WANG Quan ZHOU 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第6期1071-1084,共14页
The circular explosion wave produced by the abrupt discharge of gas from a high-temperature heat source serves as a crucial model for addressing explosion phenomena in compressible flow.The reflection of the primary s... The circular explosion wave produced by the abrupt discharge of gas from a high-temperature heat source serves as a crucial model for addressing explosion phenomena in compressible flow.The reflection of the primary shock and its propagation within a confined domain are studied both theoretically and numerically in this research.Under the assumption of strong shock,the scaling law governing propagation of the main shock is proposed.The dimensionless frequency of reflected shock propagation is associated with the confined distance.The numerical simulation for the circular explosion problem in a confined domain is performed for validation.Under the influence of confinement,the principal shock wave systematically undergoes reflection within the domain until it weakens,leading to the non-monotonic attenuation of kinetic energy in the explosion fireball and periodic oscillations of the fireball volume with a certain frequency.The simulation results indicate that the frequency of kinetic energy attenuation and the volume oscillation of the explosive fireball align consistently with the scaling law. 展开更多
关键词 explosion CONFINEMENT main shock frequency
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Nondestructive and active interrogation system for special nuclear material:proof of principle and initial results
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作者 Mahmoud Bakr Kai Masuda +3 位作者 Yoshiyuki Takahashi Tsuyoshi Misawa Norio Yamakawa Tomas Scott 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第5期216-225,共10页
Herein,we employ the threshold energy neutron analysis(TENA)technique to introduce the world's first active interrogation system to detect special nuclear materials(SNMs),including U-235 and Pu-239.The system util... Herein,we employ the threshold energy neutron analysis(TENA)technique to introduce the world's first active interrogation system to detect special nuclear materials(SNMs),including U-235 and Pu-239.The system utilizes a DD neutron generator based on inertial electrostatic confinement(IEC)to interrogate suspicious objects.To detect secondary neutrons produced during fission reactions induced in SNMs,a tensioned metastable fluid detector(TMFD)is employed.The current status of the system's development is reported in this paper,accompanied by the results from experiments conducted to detect 10 g of highly enriched uranium(HEU).Notably,the experimental findings demonstrate a distinct difference in the count rates of measurements with and without HEU.This difference in count rates surpasses two times the standard deviation,indicating a confidence level of more than 96% for identifying the presence of HEU.The paper presents and extensively discusses the proof-of-principle experimental results,along with the system's planned trajectory. 展开更多
关键词 Special nuclear materials Uranium detection Inertial electrostatic confinement fusion TENA HEU CTMFD
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Investigation of system parameters towards safer impact based shock-to-detonation transition in a novel laser driven flyer plate prototype
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作者 Gonca Saglam Ozkasapoglu Selis Onel 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第9期103-113,共11页
Laser driven flyer plate technology offers improved safety and reliability for detonation of explosives in industrial applications ranging from mining and stone quarrying to the aerospace and defense industries.This s... Laser driven flyer plate technology offers improved safety and reliability for detonation of explosives in industrial applications ranging from mining and stone quarrying to the aerospace and defense industries.This study is based on developing a safer laser driven flyer plate prototype comprised of a laser initiator and a flyer plate subsystem that can be used with secondary explosives.System parameters were optimized to initiate the shock-to-detonation transition(SDT)of a secondary explosive based on the impact created by the flyer plate on the explosive surface.Rupture of the flyer was investigated at the mechanically weakened region located on the interface of these subsystems,where the product gases from the deflagration of the explosive provide the required energy.A bilayer energetic material was used,where the first layer consisted of a pyrotechnic component,zirconium potassium perchlorate(ZPP),for sustaining the ignition by the laser beam and the second layer consisted of an insensitive explosive,cyclotetramethylene-tetranitramine(HMX),for deflagration.A plexiglass interface was used to enfold the energetic material.The focal length of the laser beam from the diode was optimized to provide a homogeneous beam profile with maximum power at the surface of the ZPP.Closed bomb experiments were conducted in an internal volume of 10 cm^(3) for evaluation of performance.Dependency of the laser driven flyer plate system output on confinement,explosive density,and laser beam power were analyzed.Measurements using a high-speed camera resulted in a flyer velocity of 670±20 m/s that renders the prototype suitable as a laser detonator in applications,where controlled employment of explosives is critical. 展开更多
关键词 Laser driven flyer plate Shock to detonation transition DETONATION Secondary explosives Pyrotechnic materials CONFINEMENT
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Influence of Confined Concrete Models on the Seismic Response of RC Frames
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作者 Hüseyin Bilgin Bredli Plaku 《Structural Durability & Health Monitoring》 EI 2024年第3期197-222,共26页
In this study, the influence of confined concrete models on the response of reinforced concrete structures is investigatedat member and global system levels. The commonly encountered concrete models such as Modified K... In this study, the influence of confined concrete models on the response of reinforced concrete structures is investigatedat member and global system levels. The commonly encountered concrete models such as Modified Kent-Park, Saatçioğlu-Razvi, and Mander are considered. Two moment-resisting frames designed according to thepre-modern code are taken into consideration to reflect the example of an RC moment-resisting frame in thecurrent building stock. The building is in an earthquake-prone zone located on Z3 Soil Type. The inelasticresponse of the building frame is modelled by considering the plastic hinges formed on each beam and columnelement for different concrete classes and stirrups spacings. The models are subjected to non-linear static analyses.The differences between confined concrete models are comparatively investigated at both reinforced concretemember and system levels. Based on the results of the comparative analysis, it is revealed that the column behaviouris mostly influenced by the choice of model, due to axial loads and confinement effects, while the beams areless affected, and also it is observed that the differences exhibited in the moment-curvature response of columncross-sections do not significantly affect the overall behaviour of the global system. This highlights the critical roleof model selection relative to the concrete strength and stirrup spacing of the member. 展开更多
关键词 Non-linear static analysis moment-curvature relationships plastic hinges concrete confinement models seismic action
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Induction System for a Fusion Reactor: Quantum Mechanics Chained up
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作者 Friedrich Björn Grimm 《Journal of High Energy Physics, Gravitation and Cosmology》 CAS 2024年第1期158-166,共9页
In the quest for a sustainable and abundant energy source, nuclear fusion technology stands as a beacon of hope. This study introduces a groundbreaking quantum mechanically effective induction system designed for magn... In the quest for a sustainable and abundant energy source, nuclear fusion technology stands as a beacon of hope. This study introduces a groundbreaking quantum mechanically effective induction system designed for magnetic plasma confinement within fusion reactors. The pursuit of clean energy, essential to combat climate change, hinges on the ability to harness nuclear fusion efficiently. Traditional approaches have faced challenges in plasma stability and energy efficiency. The novel induction system presented here not only addresses these issues but also transforms fusion reactors into integrated construction systems. This innovation promises compact fusion reactors, marking a significant step toward a clean and limitless energy future, free from the constraints of traditional power sources. This revolutionary quantum induction system redefines plasma confinement in fusion reactors, unlocking clean, compact, and efficient energy production. 展开更多
关键词 Fusion Reactor Plasma Confinement Quantum Mechanics Clean Energy
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Mechanical behaviour analysis and support system field experiment of confined concrete arches 被引量:5
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作者 WANG Qi LUAN Ying-cheng +2 位作者 JIANG Bei LI Shu-cai YU Heng-chang 《Journal of Central South University》 SCIE EI CAS CSCD 2019年第4期970-983,共14页
Soft rock control is a big challenge in underground engineering.As for this problem,a high-strength support technique of confined concrete(CC)arches is proposed and studied in this paper.Based on full-scale mechanical... Soft rock control is a big challenge in underground engineering.As for this problem,a high-strength support technique of confined concrete(CC)arches is proposed and studied in this paper.Based on full-scale mechanical test system of arch,research is made on the failure mechanism and mechanical properties of CC arch.Then,a mechanical calculation model of circular section is established for the arches with arbitrary section and unequal rigidity;a calculation formula is deduced for the internal force of the arch;an analysis is made on the influence of different factors on the internal force of the arch;and a calculation formula is got for the bearing capacity of CC arch through the strength criterion of bearing capacity.With numerical calculation and laboratory experiment,the ultimate bearing capacity and internal force distribution is analyzed for CC arches.The research results show that:1)CC arch is 2.31 times higher in strength than the U-shaped steel arch and has better stability;2)The key damage position of the arch is the two sides;3)Theoretical analysis,numerical calculation and laboratory experiment have good consistency in the internal force distribution,bearing capacity,and deformation and failure modes of the arch.All of that verifies the correctness of the theoretical calculation.Based on the above results,a field experiment is carried out in Liangjia Mine.Compared with the U-shaped steel arch support,CC arch support is more effective in surrounding rock deformation control.The research results can provide a basis for the design of CC arch support in underground engineering. 展开更多
关键词 confined concrete arch full-scale laboratory experiment theoretical analysis numerical experiment field application
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Boundary Element Analysis (Laplace Transform Solution) of Groundwater Unsteady Flow to a Multiple Well System in a Confined Aquifer 被引量:1
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作者 Zhu Xueyu Xie Chunhong Zou Zeyuan Nanjing University, Nanjing, Jiangsu 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 1990年第1期93-99,共7页
The calculations of unsteady flow to a multiple well system with the application of boundary elementmethod (BEM) are discussed. The mathematical model of unsteady well flow is a boundary value problem ofparabolic diff... The calculations of unsteady flow to a multiple well system with the application of boundary elementmethod (BEM) are discussed. The mathematical model of unsteady well flow is a boundary value problem ofparabolic differential equation. It is changed into an elliptic one by Laplace transform to eliminate time varia-ble. The image function of water head H can be solved by BEM. We derived the boundary integral equation ofthe transformed variable H and the discretization form of it, so that there is no need to discretize the bounda-ries of well walls and it becomes easier to solve the groundwater head H by numerical inversion. 展开更多
关键词 of Groundwater Unsteady Flow to a Multiple Well system in a confined Aquifer Laplace Transform Solution Boundary Element Analysis FLOW
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Mechanical properties and influence mechanism of confined concrete arches in high-stress tunnels 被引量:10
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作者 Bei Jiang Zhongxin Xin +4 位作者 Xiufeng Zhang Yusong Deng Mingzi Wang Shidong Li Wentao Ren 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2023年第7期829-841,共13页
Deep underground projects(e.g., coal mines), are often faced with complex conditions such as high stress and extremely soft rock. The strength and rigidity of the traditional support system are often insufficient,whic... Deep underground projects(e.g., coal mines), are often faced with complex conditions such as high stress and extremely soft rock. The strength and rigidity of the traditional support system are often insufficient,which makes it difficult to meet the requirements of ground control under complex conditions. As a new support form with high strength and rigidity, the confined concrete arch plays an important role in controlling the rock deformation under complex conditions. The section shape of the tunnel has an important impact on the mechanical properties and design of the support system. However, studies on the mechanical properties and influence mechanism of the new confined concrete arch are rarely reported. To this end, the mechanical properties of traditional U-shaped steel and new confined concrete arches are compared and comparative tests on arches of circular and straight-leg semicircular shapes in deep tunnels are conducted. A large mechanical testing system for underground engineering support structure is developed. The mechanical properties and influence mechanism of confined concrete arches with different section shapes under different loading modes and cross-section parameters are systematically studied. Test results show that the bearing capacity of the confined concrete arch is 2.10 times that of the U-shaped steel arch, and the bearing capacity of the circular confined concrete arch is 2.27 times that of the straight-leg semicircular arch. Among the various influencing factors and their engineering parameters,the lateral stress coefficient has the greatest impact on the bearing capacity of the confined concrete arch,followed by the steel pipe wall thickness, steel strength, and core concrete strength. Subsequently, the economic index of bearing capacity and cost is established, and the optimization design method for the confined concrete arch is proposed. Finally, this design method is applied to a high-stress tunnel under complex conditions, and the deformation of the surrounding rock is effectively controlled. 展开更多
关键词 High-stress tunnel confined concrete arch Section shape Mechanical properties Design method
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Summary of the 10th Conference on Magnetically Confined Fusion Theory and Simulation(CMCFTS)
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作者 王志斌 仇志勇 +1 位作者 王璐 陈伟 《Plasma Science and Technology》 SCIE EI CAS CSCD 2023年第8期1-11,共11页
This paper gives a summary of the organization and the presentations delivered at the 10th Conference on Magnetically Confined Fusion Theory and Simulation(CMCFTS)held in Zhuhai,China,from 28th to 31st October 2022.Th... This paper gives a summary of the organization and the presentations delivered at the 10th Conference on Magnetically Confined Fusion Theory and Simulation(CMCFTS)held in Zhuhai,China,from 28th to 31st October 2022.The conference focused on the latest progress in the research of the magnetic confined fusion plasma theory and simulations,as well as the largescale numerical simulation techniques developed in recent years.This conference is held both online and offline,with about 110 domestic participants from 18 institutes participating in the live conference,and the statistical data from the live broadcast platform indicated that the online conference attracted over 20000 views per day.A summary of the conference is given,and the history of the CMCFTS is presented.A brief introduction to the poster section is also included in this paper. 展开更多
关键词 CMCFTS magnetically confined fusion THEORY simulation conference report
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Liquid–liquid phase transition in confined liquid titanium
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作者 张迪 段云瑞 +6 位作者 郑培儒 马英杰 钱俊平 李志超 黄建 蒋妍彦 李辉 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第2期391-398,共8页
We report the layering and liquid–liquid phase transition of liquid titanium confined between two parallel panel walls.Abnormal changes in the volume and the potential energy confirm the existence of the liquid–liqu... We report the layering and liquid–liquid phase transition of liquid titanium confined between two parallel panel walls.Abnormal changes in the volume and the potential energy confirm the existence of the liquid–liquid phase transition of the liquid titanium. The typical feature of the liquid–liquid phase transition is layering, which is induced by the slit size,pressure and temperature. We highlight the fact that the slit size and pressure will determine the number of layers. In addition, with the change in the slit size, the density of the confined liquid expresses a fluctuating law. The phase diagram of the layering transition is drawn to clearly understand the layering. This study provides insights into the liquid–liquid phase transition of liquid metal in a confined space. 展开更多
关键词 TITANIUM layering transition liquid–liquid phase transition confined space
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Numerical simulation of tritium behavior under a postulated accident condition for CFETR TEP system
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作者 Hai-Xia Wang Xue-Wei Fu +2 位作者 Wei-Ping Liu Tao-Sheng Li Jie Yu 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2023年第7期206-218,共13页
China Fusion Engineering Test Reactor(CFETR)is China's self-designed and ongoing next-generation fusion reactor project.Tritium confinement systems in CFETR guarantee that the radiation level remains below the saf... China Fusion Engineering Test Reactor(CFETR)is China's self-designed and ongoing next-generation fusion reactor project.Tritium confinement systems in CFETR guarantee that the radiation level remains below the safety limit during tritium handling and operation in the fuel cycle system.Our tritium technology team is responsible for studying tritium transport behavior in the CFETR tritium safety confinement systems of the National Key R&D Program of China launched in 2017,and we are conducting CFETR tritium plant safety analysis by using CFD software.In this paper,the tritium migration and removal behavior were studied under a postulated accident condition for the Tokamak Exhaust Processing system of CFETR.The quantitative results of the transport behavior of tritium in the process room and glove box during the whole accident sequence(e.g.,tritium release,alarm,isolation,and tritium removal)have been presented.The results support the detailed design and engineering demonstration-related research of CFETR tritium plant. 展开更多
关键词 China Fusion Engineering Test Reactor(CFETR) Tokamak Exhaust Processing(TEP)system Numerical simulation Tritium transport behavior Tritium confinement system Accident condition
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Propagation Characteristics of Ultrasonic Guided Waves in Grouted Rockbolt Systems with Bond Defects under Different Confining Conditions
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作者 Shuisheng Yu Jin Chen +2 位作者 Yawei Wang Honghao Yang Shucan Lu 《Journal of Modern Physics》 CAS 2023年第5期722-740,共19页
A rockbolt acting in the rock mass is subjected to the combined action of the pull-out load and confining pressure, and the bond quality of the rockbolt directly affects the stability of the roadway and cavern. Theref... A rockbolt acting in the rock mass is subjected to the combined action of the pull-out load and confining pressure, and the bond quality of the rockbolt directly affects the stability of the roadway and cavern. Therefore, in this study, confining pressure and pull-out load are applied to grouted rockbolt systems with bond defects by a numerical simulation method, and the rockbolt is detected by ultrasonic guided waves to study the propagation law of ultrasonic guided waves in defective rockbolt systems and the bond quality of rockbolts under the combined action of pull-out load and confining pressure. The numerical simulation results show that the length and location of bond defects can be detected by ultrasonic guided waves under the combined action of pull-out load and confining pressure. Under no pull-out load, with increasing confining pressure, the low-frequency part of the guided wave frequency in the rockbolt increases, the high-frequency part decreases, the weakening effect of the confining pressure on the guided wave propagation law increases, and the bond quality of the rockbolt increases. The existence of defects cannot change the strengthening effect of the confining pressure on the guided wave propagation law under the same pull-out load or the weakening effect of the pull-out load on the guided wave propagation law under the same confining pressure. 展开更多
关键词 Grouted Rockbolt systems Bond Defect Pull-Out Load Confining Pressure Ultrasonic Guided Wave
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Estimating shear strength of high-level pillars supported with cemented backfilling using the HoekeBrown strength criterion 被引量:3
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作者 Kaizong Xia Congxin Chen +3 位作者 Xiumin Liu Yue Wang Xuanting Liu Jiahao Yuan 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第2期454-469,共16页
Deep metal mines are often mined using the high-level pillars with subsequent cementation backfilling(HLSCB)mining method.At the design stage,it is therefore important to have a reasonable method for determining the s... Deep metal mines are often mined using the high-level pillars with subsequent cementation backfilling(HLSCB)mining method.At the design stage,it is therefore important to have a reasonable method for determining the shear strength of the high-level pillars(i.e.cohesion and internal friction angle)when they are supported by cemented backfilling.In this study,a formula was derived for the upper limit of the confining pressure σ3max on a high-level pillar supported by cemented backfilling in a deep metal mine.A new method of estimating the shear strength of such pillars was then proposed based on the Hoek eBrown failure criterion.Our analysis indicates that the horizontal stress σhh acting on the cemented backfill pillar can be simplified by expressing it as a constant value.A reasonable and effective value for σ3max can then be determined.The value of s3max predicted using the proposed method is generally less than 3 MPa.Within this range,the shear strength of the high-level pillar is accurately calculated using the equivalent MohreCoulomb theory.The proposed method can effectively avoid the calculation of inaccurate shear strength values for the high-level pillars when the original HoekeBrown criterion is used in the presence of large confining pressures,i.e.the situation in which the cohesion value is too large and the friction angle is too small can effectively be avoided.The proposed method is applied to a deep metal mine in China that is being excavated using the HLSCB method.The shear strength parameters of the high-level pillars obtained using the proposed method were input in the numerical simulations.The numerical results show that the recommended level heights and sizes of the high-level pillars and rooms in the mine are rational. 展开更多
关键词 Deep metal mines High-level pillars HoekeBrown strength criterion Cemented backfilling Confining pressure Shear strength
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Single-atom Pt on carbon nanotubes for selective electrocatalysis 被引量:2
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作者 Samuel S.Hardisty Xiaoqian Lin +1 位作者 Anthony R.J.Kucernak David Zitoun 《Carbon Energy》 SCIE EI CAS CSCD 2024年第1期63-71,共9页
Utilizing supported single atoms as catalysts presents an opportunity to reduce the usage of critical raw materials such as platinum,which are essential for electrochemical reactions such as hydrogen oxidation reactio... Utilizing supported single atoms as catalysts presents an opportunity to reduce the usage of critical raw materials such as platinum,which are essential for electrochemical reactions such as hydrogen oxidation reaction(HOR).Herein,we describe the synthesis of a Pt single electrocatalyst inside single-walled carbon nanotubes(SWCNTs)via a redox reaction.Characterizations via electron microscopy,X-ray photoelectron microscopy,and X-ray absorption spectroscopy show the single-atom nature of the Pt.The electrochemical behavior of the sample to hydrogen and oxygen was investigated using the advanced floating electrode technique,which minimizes mass transport limitations and gives a thorough insight into the activity of the electrocatalyst.The single-atom samples showed higher HOR activity than state-of-the-art 30%Pt/C while almost no oxygen reduction reaction activity in the proton exchange membrane fuel cell operating range.The selective activity toward HOR arose as the main fingerprint of the catalyst confinement in the SWCNTs. 展开更多
关键词 CONFINEMENT ELECTROCATALYSIS hydrogen PLATINUM single atom catalysts
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Wetting sub-nanochannels via ionic hydration effect for improving charging dynamics 被引量:1
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作者 Yayun Shi Xiaoli Zhao +5 位作者 Qihang Liu Zhenghui Pan Congcong Liu Shanyi Zhu Zhijun Zuo Xiaowei Yang 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第3期473-480,共8页
The ionic transport in sub-nanochannels plays a key role in energy storage,yet suffers from a high energy barrier.Wetting sub-nanochannels is crucial to accelerate ionic transport,but the introduction of water is chal... The ionic transport in sub-nanochannels plays a key role in energy storage,yet suffers from a high energy barrier.Wetting sub-nanochannels is crucial to accelerate ionic transport,but the introduction of water is challenging because of the hydrophobic extreme confinement.We propose wetting the channels by the exothermic hydration process of pre-intercalated ions,the effect of which varies distinctly with different ionic hydration structures and energies.Compared to the failed pre-intercalation of SO_(4)^(2-),HSO_(4)^(-) with weak hydration energy results in a marginal effect on the HOMO(Highest Occupied Molecular Orbital)level of water to avoid water splitting during the electrochemical intercalation.Meanwhile,the ability of water introduction is reserved by the initial incomplete dissociation state of HSO_(4)^(-),so the consequent exothermic reionization and hydration processes of the intercalated HSO_(4)^(-) promote the water introduction into sub-nanochannels,finally forming the stable confined water through hydrogen bonding with functional groups.The wetted channels exhibit a significantly enhanced ionic diffusion coef-ficient by~9.4 times. 展开更多
关键词 Sub-nanochannels Ionic hydration Ionic transport SUPERCAPACITORS confined water
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