The geometry and the energy of conformers of PnHn+2(n=2-9) have been studied with PM3 method. It is concluded that gauche interaction between adjacent lone electron pairs and gauche interaction between P-H bond with a...The geometry and the energy of conformers of PnHn+2(n=2-9) have been studied with PM3 method. It is concluded that gauche interaction between adjacent lone electron pairs and gauche interaction between P-H bond with adjacent P-P bond are important for predicting the stable conformer of open-chain phosphoanes.展开更多
文摘The geometry and the energy of conformers of PnHn+2(n=2-9) have been studied with PM3 method. It is concluded that gauche interaction between adjacent lone electron pairs and gauche interaction between P-H bond with adjacent P-P bond are important for predicting the stable conformer of open-chain phosphoanes.
