In our paper we demonstrate that the filtration equation used by Gorban’ et al. for determining the maximum efficiency of plane propellers of about 30 percent for free fluids plays no role in describing the flows in ...In our paper we demonstrate that the filtration equation used by Gorban’ et al. for determining the maximum efficiency of plane propellers of about 30 percent for free fluids plays no role in describing the flows in the atmospheric boundary layer (ABL) because the ABL is mainly governed by turbulent motions. We also demonstrate that the stream tube model customarily applied to derive the Rankine-Froude theorem must be corrected in the sense of Glauert to provide an appropriate value for the axial velocity at the rotor area. Including this correction leads to the Betz-Joukowsky limit, the maximum efficiency of 59.3 percent. Thus, Gorban’ et al.’s 30% value may be valid in water, but it has to be discarded for the atmosphere. We also show that Joukowsky’s constant circulation model leads to values of the maximum efficiency which are higher than the Betz-Jow-kowsky limit if the tip speed ratio is very low. Some of these values, however, have to be rejected for physical reasons. Based on Glauert’s optimum actuator disk, and the results of the blade-element analysis by Okulov and Sørensen we also illustrate that the maximum efficiency of propeller-type wind turbines depends on tip-speed ratio and the number of blades.展开更多
The extraction kinetics of Ce（Ⅳ） and Ce（Ⅳ）-F^- mixture systems from sulfuric solutions to n-heptane solution containing Bif-ILE[A336][P204]（[trialkylmethylammonium][di-2-ethylhewanxylphosphinate]） with a const...The extraction kinetics of Ce（Ⅳ） and Ce（Ⅳ）-F^- mixture systems from sulfuric solutions to n-heptane solution containing Bif-ILE[A336][P204]（[trialkylmethylammonium][di-2-ethylhewanxylphosphinate]） with a constant interfacial area cell with laminar flow were studied,just to elucidate the extraction mechanism and the mass transfer models.The data were analyzed in terms of pseudo-first-order constants.The effects of stirring speed,specific interfacial area and temperature on the extraction rate in both systems were discussed,suggesting that the extractions were mixed bulk phases-interfacial control process.Supported by the experimental data,the corresponding rate equations for Ce（Ⅳ） extraction system and Ce（Ⅳ）-F^- mixture extraction system were obtained.The experimental results indicated the rate-controlling step.The kinetics model was deduced from the rate-controlling step and consistent with the rate equation.展开更多
In this work,we studied the adsorption of modified cellulose nanocrystals onto solid surfaces by quartz crystal microbalance with dissipation monitoring(QCM-D).Cellulose nanocrystals obtained from tunicate(CNC)were mo...In this work,we studied the adsorption of modified cellulose nanocrystals onto solid surfaces by quartz crystal microbalance with dissipation monitoring(QCM-D).Cellulose nanocrystals obtained from tunicate(CNC)were modified at reducing end by amidation reactions.Two different functionalities were investigated:a polyamine dendrimer(CNC-NH_(2)),which interacts with gold surface by the amine groups;and a biotin moiety(CNC-Biot),which has a strong affinity for the protein streptavidin(SAV).QCM-D results revealed different adsorption behaviors between modified and unmodified CNCs.Hence,unmodified CNCs covered almost all the surface forming a rigid and flat layer whereas reducing end modified CNCs remained rather upright forming a hydrated and viscoelastic layer with lower surface coverage.The analysis of adsorption kinetics allowed the calculation of an apparent collision rate factor,which resulted 10-fold higher for unmodified CNCs compared to reducing end modified CNCs,therefore,demonstrating the different adsorption behavior.展开更多
文摘In our paper we demonstrate that the filtration equation used by Gorban’ et al. for determining the maximum efficiency of plane propellers of about 30 percent for free fluids plays no role in describing the flows in the atmospheric boundary layer (ABL) because the ABL is mainly governed by turbulent motions. We also demonstrate that the stream tube model customarily applied to derive the Rankine-Froude theorem must be corrected in the sense of Glauert to provide an appropriate value for the axial velocity at the rotor area. Including this correction leads to the Betz-Joukowsky limit, the maximum efficiency of 59.3 percent. Thus, Gorban’ et al.’s 30% value may be valid in water, but it has to be discarded for the atmosphere. We also show that Joukowsky’s constant circulation model leads to values of the maximum efficiency which are higher than the Betz-Jow-kowsky limit if the tip speed ratio is very low. Some of these values, however, have to be rejected for physical reasons. Based on Glauert’s optimum actuator disk, and the results of the blade-element analysis by Okulov and Sørensen we also illustrate that the maximum efficiency of propeller-type wind turbines depends on tip-speed ratio and the number of blades.
基金Project (2012CBA01202) supported by the National Basic Research Program of ChinaProject (51174184) supported by the National Natural Science Foundation of China+2 种基金Project (KGZD-EW-201-1) supported by the Key Research Program of the Chinese Academy of SciencesProject (BK2013030) supported by Science and Technology Plan of Nantong City,ChinaProject (RERU2014016) supported by Open Subject of Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,China
文摘The extraction kinetics of Ce（Ⅳ） and Ce（Ⅳ）-F^- mixture systems from sulfuric solutions to n-heptane solution containing Bif-ILE[A336][P204]（[trialkylmethylammonium][di-2-ethylhewanxylphosphinate]） with a constant interfacial area cell with laminar flow were studied,just to elucidate the extraction mechanism and the mass transfer models.The data were analyzed in terms of pseudo-first-order constants.The effects of stirring speed,specific interfacial area and temperature on the extraction rate in both systems were discussed,suggesting that the extractions were mixed bulk phases-interfacial control process.Supported by the experimental data,the corresponding rate equations for Ce（Ⅳ） extraction system and Ce（Ⅳ）-F^- mixture extraction system were obtained.The experimental results indicated the rate-controlling step.The kinetics model was deduced from the rate-controlling step and consistent with the rate equation.
基金French National Research Agency(Project Cellmach,ANR-17-CE07-0010-01)Region Pays de la Loire(Project Nanomach,Etoiles Montantes 2017-10691).
文摘In this work,we studied the adsorption of modified cellulose nanocrystals onto solid surfaces by quartz crystal microbalance with dissipation monitoring(QCM-D).Cellulose nanocrystals obtained from tunicate(CNC)were modified at reducing end by amidation reactions.Two different functionalities were investigated:a polyamine dendrimer(CNC-NH_(2)),which interacts with gold surface by the amine groups;and a biotin moiety(CNC-Biot),which has a strong affinity for the protein streptavidin(SAV).QCM-D results revealed different adsorption behaviors between modified and unmodified CNCs.Hence,unmodified CNCs covered almost all the surface forming a rigid and flat layer whereas reducing end modified CNCs remained rather upright forming a hydrated and viscoelastic layer with lower surface coverage.The analysis of adsorption kinetics allowed the calculation of an apparent collision rate factor,which resulted 10-fold higher for unmodified CNCs compared to reducing end modified CNCs,therefore,demonstrating the different adsorption behavior.
