In classical quantum theory, the Rydberg constant is a fundamental physical constant that plays an important role. It comes into play as an indispensable physical constant in basic formulas for describing natural phen...In classical quantum theory, the Rydberg constant is a fundamental physical constant that plays an important role. It comes into play as an indispensable physical constant in basic formulas for describing natural phenomena. However, relativity is not taken into account in this Rydberg formula for wavelength. If the special theory of relativity is taken into account, R<sub>∞</sub> can no longer be regarded as a physical constant. That is, we have continued to conduct experiments to this day in an attempt to determine the value of a physical constant, the Rydberg constant, which does not exist in the natural world.展开更多
Based on two-dimensional topological structures, a novel molecular electronegativity interaction vector with hybridization （MEHIV） was developed to describe atomic hybridization state in different molecular environm...Based on two-dimensional topological structures, a novel molecular electronegativity interaction vector with hybridization （MEHIV） was developed to describe atomic hybridization state in different molecular environments. Five quantitative models by MEHIV characterization and multiple linear regression modeling were successfully established to predict reduced ion mobility constants （Ko） of alkanes, aromatic hydrocarbons, fatty alcohols, fatty aldehydes and ketones and carboxylic esters. The correlation coefficients Roy by leave-one-out cross-validation are 0.792, 0.787, 0,949, 0.972 and 0.981, respectively, and the standard deviations SDcv are 0.067, 0.086, 0.064, 0.043 and 0.042, respectively. These results suggested that MEHIV is an excellent topological index descriptor with many advantages such as straightforward physicochemical meaning, high characterization competence, convenient expansibility and easy manipulation.展开更多
In many areas of physics and chemistry, the Rydberg constant is a fundamental physical constant that plays an important role. It comes into play as an indispensable physical constant in basic equations for describing ...In many areas of physics and chemistry, the Rydberg constant is a fundamental physical constant that plays an important role. It comes into play as an indispensable physical constant in basic equations for describing natural phenomena. The Rydberg constant appears in the formula for calculating the wavelengths in the line spectrum emitted from the hydrogen atom. However, this Rydberg wavelength formula is a nonrelativistic formula derived at the level of classical quantum theory. In this paper, the Rydberg formula is rewritten as a wavelength formula taking into account the theory of relativity. When this is done, we come to an unexpected conclusion. What we try to determine by measuring spectra wavelengths is not actually the value of the Rydberg constant <em>R</em><sub>∞</sub> but the value <em>R</em><sub><em>n</em>,<em>m</em></sub> of Formula (18). <em>R</em><sub>∞</sub> came into common use in the world of nonrelativistic classical quantum theory. If the theory of relativity is taken into account, <em>R</em><sub>∞</sub> can no longer be regarded as a physical constant. That is, we have continued to conduct experiments to this day in an attempt to determine the value of a physical constant, the Rydberg constant, which does not exist in the natural world.展开更多
文摘In classical quantum theory, the Rydberg constant is a fundamental physical constant that plays an important role. It comes into play as an indispensable physical constant in basic formulas for describing natural phenomena. However, relativity is not taken into account in this Rydberg formula for wavelength. If the special theory of relativity is taken into account, R<sub>∞</sub> can no longer be regarded as a physical constant. That is, we have continued to conduct experiments to this day in an attempt to determine the value of a physical constant, the Rydberg constant, which does not exist in the natural world.
基金the State Key Laboratory of Chemo/Biosensing and Chemometrics Foundation(No.05-12-1)
文摘Based on two-dimensional topological structures, a novel molecular electronegativity interaction vector with hybridization （MEHIV） was developed to describe atomic hybridization state in different molecular environments. Five quantitative models by MEHIV characterization and multiple linear regression modeling were successfully established to predict reduced ion mobility constants （Ko） of alkanes, aromatic hydrocarbons, fatty alcohols, fatty aldehydes and ketones and carboxylic esters. The correlation coefficients Roy by leave-one-out cross-validation are 0.792, 0.787, 0,949, 0.972 and 0.981, respectively, and the standard deviations SDcv are 0.067, 0.086, 0.064, 0.043 and 0.042, respectively. These results suggested that MEHIV is an excellent topological index descriptor with many advantages such as straightforward physicochemical meaning, high characterization competence, convenient expansibility and easy manipulation.
文摘In many areas of physics and chemistry, the Rydberg constant is a fundamental physical constant that plays an important role. It comes into play as an indispensable physical constant in basic equations for describing natural phenomena. The Rydberg constant appears in the formula for calculating the wavelengths in the line spectrum emitted from the hydrogen atom. However, this Rydberg wavelength formula is a nonrelativistic formula derived at the level of classical quantum theory. In this paper, the Rydberg formula is rewritten as a wavelength formula taking into account the theory of relativity. When this is done, we come to an unexpected conclusion. What we try to determine by measuring spectra wavelengths is not actually the value of the Rydberg constant <em>R</em><sub>∞</sub> but the value <em>R</em><sub><em>n</em>,<em>m</em></sub> of Formula (18). <em>R</em><sub>∞</sub> came into common use in the world of nonrelativistic classical quantum theory. If the theory of relativity is taken into account, <em>R</em><sub>∞</sub> can no longer be regarded as a physical constant. That is, we have continued to conduct experiments to this day in an attempt to determine the value of a physical constant, the Rydberg constant, which does not exist in the natural world.
