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静电组装低感度CL-20@GO核壳复合材料的制备及性能研究 被引量:1
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作者 黄业明 汪鑫 +1 位作者 张竞轩 王敦举 《火炸药学报》 EI CAS CSCD 北大核心 2024年第1期44-50,共7页
为降低六硝基六氮杂异伍兹烷(CL-20)的机械感度,提高其综合性能,以3-氨丙基三乙氧基硅烷(APS)为改性剂对CL-20改性,以氧化石墨烯(GO)为包覆材料,利用静电自组装方法对改性CL-20炸药进行表面包覆,制备得到CL-20@GO核壳复合材料;采用水接... 为降低六硝基六氮杂异伍兹烷(CL-20)的机械感度,提高其综合性能,以3-氨丙基三乙氧基硅烷(APS)为改性剂对CL-20改性,以氧化石墨烯(GO)为包覆材料,利用静电自组装方法对改性CL-20炸药进行表面包覆,制备得到CL-20@GO核壳复合材料;采用水接触角测试、扫描电子显微镜(SEM)和X射线光电子能谱(XPS)等对样品进行形貌表征;利用差示扫描量热仪(DSC)测试其热性能,并测试了其机械感度。结果表明,经质量分数5%的APS溶液改性的CL-20成功引入氨基基团,亲水性效果最佳;GO层包覆改性CL-20完整,致密性强;与原料CL-20相比,CL-20@GO核壳复合材料的活化能提高了63.0kJ/mol,撞击感度(H 50)由13.0cm提升至23.5cm,摩擦感度由100%降至24%,表明采用静电自组装的GO涂层可以明显降低CL-20的感度。 展开更多
关键词 材料科学 cl-20@GO 表面改性 静电自组装 氧化石墨烯 GO 复合炸药
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太赫兹光谱学研究CL-20/MTNP共晶振动特性
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作者 刘泉澄 杨富 +3 位作者 张祺 段勇威 邓琥 尚丽平 《物理学报》 SCIE EI CAS CSCD 北大核心 2024年第19期212-218,共7页
共晶是一种分子层次调控材料物化性质的高效方法,然而目前共晶复杂体系结构与宏观性质间关系一直难以得到深入理解.本文依据太赫兹光谱可激发晶体内弱作用的优势,以CL-20/MTNP共晶为对象开展了太赫兹振动光谱研究.首先,测量CL-20、MTNP... 共晶是一种分子层次调控材料物化性质的高效方法,然而目前共晶复杂体系结构与宏观性质间关系一直难以得到深入理解.本文依据太赫兹光谱可激发晶体内弱作用的优势,以CL-20/MTNP共晶为对象开展了太赫兹振动光谱研究.首先,测量CL-20、MTNP和共晶CL-20/MTNP的太赫兹吸收光谱.其次,分析了基于密度泛函理论的振动计算方法,获得了3种物质太赫兹频段振动特性,对吸收光谱进行振动匹配.最后,采用振动分解方法将晶体分子的整体振动分解为分子间和分子内振动.在此基础上,分析了共晶前后振动变化规律.结果表明:共晶后新形成的弱相互作用由CL-20分子主导,同时MTNP分子主要通过3个硝基与CL-20分子交互作用.本文的研究结论为共晶热性质提供了微观解析. 展开更多
关键词 太赫兹光谱 密度泛函理论 振动分解 cl-20共晶
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喷墨打印CA/CL-20点火起爆序列及其性能研究
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作者 杨宏伟 熊庭隆 +3 位作者 陶培培 易镇鑫 朱顺官 张琳 《火工品》 CAS CSCD 北大核心 2024年第4期86-91,共6页
为了实现CA/CL-20点火起爆序列的微型化制备,基于喷墨打印技术,以叠氮化钠墨水、铜盐墨水、CL-20墨水为前驱体,采用分层打印的方式在SCB上原位制备了叠氮化铜(CA)和CL-20炸药,制成SCB+CA+CL-20微型化点火起爆序列,并通过发火性能试验及... 为了实现CA/CL-20点火起爆序列的微型化制备,基于喷墨打印技术,以叠氮化钠墨水、铜盐墨水、CL-20墨水为前驱体,采用分层打印的方式在SCB上原位制备了叠氮化铜(CA)和CL-20炸药,制成SCB+CA+CL-20微型化点火起爆序列,并通过发火性能试验及RDX雷管-铅板起爆试验对其性能进行了研究。结果表明:原位制备的CA在作用过程中发生了爆燃转爆轰,且能够点燃CL-20;SCB+CA+CL-20样品的点火持续时间超过6ms,而SCB裸桥和SCB+CA样品均小于2ms,表明打印的CL-20未发生爆轰,而是以燃烧为主;SCB+CA+CL-20点火起爆序列能够可靠起爆RDX雷管,并将铅板炸穿。 展开更多
关键词 喷墨打印 叠氮化铜(CA) cl-20 点火 起爆
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氟橡胶包覆对CL-20机械感度及爆轰特性的影响研究
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作者 过光飞 吴三震 +3 位作者 徐飞扬 马腾 徐森 刘大斌 《爆破器材》 CAS CSCD 北大核心 2024年第2期1-6,共6页
为研究CL-20晶体表面钝化对安全及爆轰性能的影响,采用氟橡胶F2311作为黏结剂,基于水悬浮法对比研究了CL-20包覆前、后的机械感度及爆轰性能变化规律。实验结果表明:F2311包覆可以显著改善CL-20材料的表面缺陷;在-20、0、20、40°C... 为研究CL-20晶体表面钝化对安全及爆轰性能的影响,采用氟橡胶F2311作为黏结剂,基于水悬浮法对比研究了CL-20包覆前、后的机械感度及爆轰性能变化规律。实验结果表明:F2311包覆可以显著改善CL-20材料的表面缺陷;在-20、0、20、40°C与80°C条件下,F2311包覆可明显提高CL-20的临界撞击能与临界摩擦载荷;在-40℃环境下,包覆对CL-20临界撞击能与临界摩擦载荷无影响,原因可能与包覆材料的玻璃化转变温度有关;包覆后样品的实测爆热与爆速可达到5612.03 kJ/kg和8975.81m/s,与CL-20相比分别减小了8.70%和2.39%。研究结论对CL-20的安全储存、使用和高效能量输出具有一定的参考价值。 展开更多
关键词 cl-20 包覆 机械感度 爆轰性能
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含CL-20的微孔发射药的设计及性能研究
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作者 郏杭生 崔立宝 +3 位作者 丁亚军 李成龙 顾晗 王晓倩 《爆破器材》 CAS CSCD 北大核心 2024年第4期37-44,共8页
为了研究六硝基六氮杂异伍兹烷(CL-20)含量及微孔结构对发射药性能的影响,采用超临界发泡工艺设计并制备了含CL-20的微孔发射药。利用扫描电子显微镜(SEM)观察了发射药的形貌结构,通过密闭爆发器实验、简支梁冲击仪和摩擦感度仪等研究... 为了研究六硝基六氮杂异伍兹烷(CL-20)含量及微孔结构对发射药性能的影响,采用超临界发泡工艺设计并制备了含CL-20的微孔发射药。利用扫描电子显微镜(SEM)观察了发射药的形貌结构,通过密闭爆发器实验、简支梁冲击仪和摩擦感度仪等研究了发射药的燃烧性能、力学性能和感度。结果表明:CL-20颗粒均匀地分散在样品表面及内部,样品内部形成了大量尺寸为0.08~2.00μm的泡孔;CL-20颗粒的加入降低了样品的力学性能,CL-20含量越高,样品的抗冲击强度与拉伸强度降低得越明显;随着CL-20含量的增加,样品的摩擦感度和静电感度会随之升高,燃速也会得到一定程度的提高;经发泡改性后的样品的力学性能弱于未经发泡改性的样品;发泡工艺能够抑制因CL-20含量上升而导致的感度上升;经过发泡后的样品,燃烧性能得到了显著提升,样品的L-B(相对动态活度-相对压力)曲线在B为0~0.10范围内即出现急速上升趋势,L在B为0.14~0.18范围内达到最大,CL-20质量分数为15%和20%时,L_(max)分别为14.39 MPa^(-1)·s^(-1)和9.70 MPa^(-1)·s^(-1)。 展开更多
关键词 微孔发泡 超临界流体 发射药 cl-20 燃烧 感度 力学性能
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子弹撞击下CL-20基PBX装药响应研究
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作者 焦纲领 陈鹏万 +2 位作者 刘睿 王志浩 张雪丽 《南京理工大学学报》 CAS CSCD 北大核心 2024年第2期127-133,共7页
为了提高战斗部安全性,指导CL-20基PBX炸药在战斗部装药中的应用和设计,开展了基于子弹撞击试验的典型战斗部撞击响应特性研究。进行了子弹撞击试验,通过分析战斗部响应后的超压数据、验证板穿孔、试验影像和试验样品回收等,评估了子弹... 为了提高战斗部安全性,指导CL-20基PBX炸药在战斗部装药中的应用和设计,开展了基于子弹撞击试验的典型战斗部撞击响应特性研究。进行了子弹撞击试验,通过分析战斗部响应后的超压数据、验证板穿孔、试验影像和试验样品回收等,评估了子弹撞击战斗部的反应等级。结果表明,子弹撞击试验中,子弹速度为836 m/s,战斗部在子弹撞击下发生了爆轰等级的反应。此外,开展了不同撞击条件下战斗部安全性数值模拟,研究了不同撞击速度下战斗部的反应过程。结果表明,子弹以850 m/s和750 m/s撞击时,战斗部分别发生爆轰和燃烧等级的反应。该研究为典型战斗部的撞击响应预测及反应等级评价提供了数据支撑。 展开更多
关键词 战斗部 子弹撞击 试验评估 数值模拟 反应等级 cl-20基PBX装药 点火增长模型 冲击波超压
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Pickering乳液自组装CL-20/n-Al/F2605复合空心微球的制备与性能
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作者 孙鹏瞻 杨敏 +4 位作者 尢淇 高登钊 李聪颖 张行泉 郭长平 《爆破器材》 CAS CSCD 北大核心 2024年第4期9-16,共8页
高能量、高爆热的六硝基六氮杂异伍兹烷(CL-20)/Al复合物由于自身的高感度而限制了在炸药领域的广泛应用。为制备高能量和高安全性的CL-20/Al含能复合材料,采用Pickering乳液法制备了空心球形CL-20/n-Al/F2605(氟橡胶)复合物,并对Picker... 高能量、高爆热的六硝基六氮杂异伍兹烷(CL-20)/Al复合物由于自身的高感度而限制了在炸药领域的广泛应用。为制备高能量和高安全性的CL-20/Al含能复合材料,采用Pickering乳液法制备了空心球形CL-20/n-Al/F2605(氟橡胶)复合物,并对Pickering乳液稳定性、复合物表面结构、热分解、燃烧及安全性能进行了分析。结果显示:当2 mL乙酸乙酯中溶解的CL-20固体质量为0.10~0.14 g、油水质量比在1:5~1:7之间、超声时间小于30 min、静置时间小于120 min时,形成的乳液稳定性好。该复合物表面结构粗糙,中位径d_(50)为73.17μm,各组分复合均匀。复合物的热分解峰温和活化能分别为236.7℃、164.6 kJ/mol,n-Al和F2605降低了CL-20分解过程中21.2%的活化能。复合物平均线性燃速为7.14 cm/s;特性落高H_(50)为39.5 cm,和原料CL-20相比提升了26.5 cm,安全性能得到提高。 展开更多
关键词 六硝基六氮杂异伍兹烷(cl-20) 纳米铝粉(n-Al) 微球 Pickering乳液
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Mechanical properties and acoustic emission characteristics of soft rock with different water contents under dynamic disturbance 被引量:1
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作者 Yujing Jiang Lugen Chen +4 位作者 Dong Wang Hengjie Luan Guangchao Zhang Ling Dong Bin Liang 《International Journal of Coal Science & Technology》 EI CAS CSCD 2024年第3期135-148,共14页
Uniaxial compression tests and cyclic loading acoustic emission tests were conducted on 20%,40%,60%,80%,dry and saturated muddy sandstone by using a creep impact loading system to investigate the mechanical properties... Uniaxial compression tests and cyclic loading acoustic emission tests were conducted on 20%,40%,60%,80%,dry and saturated muddy sandstone by using a creep impact loading system to investigate the mechanical properties and acoustic emission characteristics of soft rocks with different water contents under dynamic disturbance.The mechanical properties and acoustic emission characteristics of muddy sandstones at different water contents were analysed.Results of experimental studies show that water is a key factor in the mechanical properties of rocks,softening them,increasing their porosity,reducing their brittleness and increasing their plasticity.Under uniaxial compression,the macroscopic damage characteristics of the muddy sandstone change from mono-bevel shear damage and‘X’type conjugate bevel shear damage to a roadway bottom-drum type damage as the water content increases.Dynamic perturbation has a strengthening effect on the mechanical properties of samples with 60%and less water content,and a weakening effect on samples with 80%and more water content,but the weakening effect is not obvious.Macroscopic damage characteristics of dry samples remain unchanged,water samples from shear damage and tensile–shear composite damage gradually transformed into cleavage damage,until saturation transformation monoclinic shear damage.The evolution of acoustic emission energy and event number is mainly divided into four stages:loading stage(Ⅰ),dynamic loading stage(Ⅱ),yield failure stage(Ⅲ),and post-peak stage(Ⅳ),the acoustic emission characteristics of the stages were different for different water contents.The characteristic value of acoustic emission key point frequency gradually decreases,and the damage degree of the specimen increases,corresponding to low water content—high main frequency—low damage and high water content—low main frequency—high damage. 展开更多
关键词 Dynamic disturbance Soft rock Cyclic loading Acoustic emission Water content
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微流控制备微纳米LLM-105/CL-20复合含能材料
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作者 李营 刘美祺 +3 位作者 刘子君 詹乐武 侯静 李斌栋 《火炸药学报》 EI CAS CSCD 北大核心 2024年第6期521-527,I0003,共8页
为了增加含能材料在生产、使用中的安全性能,利用微流控技术,以改良型氟橡胶作为黏结剂,采用LLM-105和CL-20为原料,成功实现了高能钝感LLM-105/CL-20复合材料的连续且安全的制备;采用场发射扫描电镜(SEM)观察了样品的微观形貌,采用傅里... 为了增加含能材料在生产、使用中的安全性能,利用微流控技术,以改良型氟橡胶作为黏结剂,采用LLM-105和CL-20为原料,成功实现了高能钝感LLM-105/CL-20复合材料的连续且安全的制备;采用场发射扫描电镜(SEM)观察了样品的微观形貌,采用傅里叶红外光谱(FT-IR)和X射线衍射(XRD)分析了样品的结构和晶型;采用DSC分析了样品的热分解性能;测试了原料CL-20及复合粒子的机械感度。结果表明,在优化条件下,即溶剂与非溶剂流速比为1∶6,黏结剂质量分数为6%,总流速为80mL/min时,LLM-105能够有效地包覆在CL-20表面,粒径分布范围为0.19~3.92μm;通过FT-IR和XRD表征,进一步证明LLM-105成功包覆在CL-20表面;复合粒子的撞击感度从10cm提升至55cm(落锤质量为2kg),显著增强了其安全性能。表明微通道内制备LLM-105/CL-20复合粒子的方法具有降感效果显著的优点,且该方法易于操作,适合连续安全生产。 展开更多
关键词 物理化学 微流控 LLM-105/cl-20复合粒子 安全性能
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活性可反应亚微米壳包覆CL-20及其性能表征
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作者 成雅芝 任慧 常世隆 《火炸药学报》 EI CAS CSCD 北大核心 2024年第5期422-429,I0004,共9页
为了获得高能低感的CL-20颗粒,采用喷雾干燥工艺改善CL-20原料的形貌,采用顺丁橡胶BR、微晶蜡和胶体石墨对CL-20/微纳复合铝粉进行钝感包覆,构建具有可反应活性、能量补强的包覆外壳,同时提升CL-20使用安全性。采用扫描电子显微镜(SEM)... 为了获得高能低感的CL-20颗粒,采用喷雾干燥工艺改善CL-20原料的形貌,采用顺丁橡胶BR、微晶蜡和胶体石墨对CL-20/微纳复合铝粉进行钝感包覆,构建具有可反应活性、能量补强的包覆外壳,同时提升CL-20使用安全性。采用扫描电子显微镜(SEM)观察了包覆颗粒的表观形貌,编写MATLAB程序代码对SEM图像颗粒的长宽比和圆度值进行识别计算,表征其球形度,采用有机元素分析(EA)和电感耦合等离子体原子发射光谱(ICP-AES)分析测试包覆颗粒中CL-20和铝粉的实际含量,采用X射线衍射(XRD)对包覆颗粒进行晶型结构分析,采用GJB方法对包覆颗粒的感度和爆热进行测试,并与CL-20原料进行了对比,采用差式扫描-热重-红外-质谱联用(DSC-TG-FTIR-MS)对包覆颗粒及其分解产物进行热分析。结果表明,制备得到的包覆颗粒粒径在10μm左右,球形度较高,长宽比为1.03,圆度值为0.91;包覆颗粒中CL-20和铝粉的实际含量分别为88.17%和7.76%;包覆颗粒的晶型为β-CL-20,摩擦感度为36%,撞击感度爆炸概率为38%,撞击感度特性落高为13.4 cm,降感效果明显;爆热值为5946 J/g,是CL-20原料(6073 J/g)的97.91%,能量损失不超过3%。 展开更多
关键词 物理化学 cl-20 可反应高活性 喷雾干燥 钝感包覆
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基于新型Contention网络的滚动轴承早期故障诊断方法研究
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作者 赵俊豪 郑煜 +1 位作者 王英 王凯 《机械设计与制造工程》 2024年第3期87-91,共5页
针对滚动轴承早期故障诊断问题,为了同时建模振动信号中的高频和低频特征,实现高精度诊断,提出了一种新的模型Contention。它以一种互补的方式集成了空洞卷积和自注意力机制的优点,具有同时捕捉高频和低频信息的能力。为了验证其诊断能... 针对滚动轴承早期故障诊断问题,为了同时建模振动信号中的高频和低频特征,实现高精度诊断,提出了一种新的模型Contention。它以一种互补的方式集成了空洞卷积和自注意力机制的优点,具有同时捕捉高频和低频信息的能力。为了验证其诊断能力,首先,在完整信息原则下将振动信号连续构造成数据集;其次,搭建Contention网络并训练,其最终测试集准确度可达100%,t-SNE显示随网络层次的深入特征被明显聚类;最后,设置对照实验,将该模型与传统RNN、CNN、Transformer模型对比,证明该模型具备突出的诊断能力。 展开更多
关键词 contention网络 空洞卷积 自注意力机制 滚动轴承 早期故障诊断
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双发CL-20基含铝装药水下爆炸载荷特性
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作者 张竞元 李海龙 +2 位作者 冯海云 王龙侃 张之凡 《火炸药学报》 EI CAS CSCD 北大核心 2024年第8期747-757,I0005,共12页
基于水下爆炸理论,采用耦合欧拉-拉格朗日(CEL)方法,建立了CL-20基含铝炸药水下爆炸模型,分析了冲击波载荷和气泡动力学特性;在此基础上探究了双发CL-20基含铝装药水下爆炸冲击波时空分布规律及气泡融合特性,讨论了不完整刚性边界附近双... 基于水下爆炸理论,采用耦合欧拉-拉格朗日(CEL)方法,建立了CL-20基含铝炸药水下爆炸模型,分析了冲击波载荷和气泡动力学特性;在此基础上探究了双发CL-20基含铝装药水下爆炸冲击波时空分布规律及气泡融合特性,讨论了不完整刚性边界附近双发CL-20基含铝装药水下爆炸气泡动力学特性,得到了装药种类、破口尺寸和爆距3种关键因素对双发装药水下爆炸气泡载荷特性的影响。结果表明,与TNT装药相比,CL-20基含铝装药水下爆炸气泡半径和脉动周期更大,气泡最大半径增大了27%,脉动周期提高了65%,但气泡脉动压力小于TNT。双发CL-20基含铝装药在水平和垂直位置具有特征尖锐波峰-波谷载荷曲线和特征双峰曲线,冲击波峰值压力大于单发装药,最大增长率可达48.26%。不完整刚性边界破口尺寸、爆距增大会增加双发装药气泡射流宽度和持续时间,CL-20会加剧不完整边界对气泡动力学的影响。 展开更多
关键词 爆炸力学 cl-20基含铝炸药 水下爆炸 冲击波 气泡动力学 不完整边界 耦合欧拉-拉格朗日(CEL)方法
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CL-20-NBC/Al球形复合物的制备及性能表征
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作者 郭灏 罗连聪 +5 位作者 李聪颖 唐颖冰 周小露 王茜 张行泉 郭长平 《火炸药学报》 EI CAS CSCD 北大核心 2024年第9期797-804,I0002,共9页
针对六硝基六氮杂异伍兹烷(CL-20)安全性能差的问题,基于Pickering乳液法,将CL-20、Al两种高能组分进行复合,引入含能黏结剂硝化细菌纤维素(NBC)降低体系感度,制备了CL-20-NBC/Al球形复合物;研究了油水比、物料比、表面活性剂用量对乳... 针对六硝基六氮杂异伍兹烷(CL-20)安全性能差的问题,基于Pickering乳液法,将CL-20、Al两种高能组分进行复合,引入含能黏结剂硝化细菌纤维素(NBC)降低体系感度,制备了CL-20-NBC/Al球形复合物;研究了油水比、物料比、表面活性剂用量对乳液稳定性的影响;采用X-射线衍射(XRD)、扫描电镜(SEM)、差示扫描量热(DSC)对CL-20-NBC/Al复合物的结构、形貌、热性能等进行了表征。结果表明,Pickering乳液法制备的CL-20-NBC/Al复合物,控制油水体积比为4∶6、CL-20与NBC质量比为6∶4、表面活性剂用量为原料用量的10%时,能形成稳定的乳液体系;CL-20-NBC/Al复合物为规则的球形,表面光滑,粒径分布(D_(50))为27.4μm;与原料CL-20相比,CL-20-NBC/Al复合物的放热量提高了42%;特性落高由原料的13 cm升高到40 cm,摩擦感度爆炸概率由原料的100%降至88%,其机械安全性能得到较大幅度的提升。 展开更多
关键词 物理化学 球形含能材料 cl-20 纳米AL Pickering乳液 硝化细菌纤维素 NBC
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基于铝基含能配合物及CL-20含能微芯片的制备及表征
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作者 孟珂娟 马小霞 +1 位作者 李宇翔 张开黎 《火炸药学报》 EI CAS CSCD 北大核心 2024年第5期438-444,I0004,共8页
为提高含能微芯片的能量特性和燃烧特性,推进其在微推进器、微驱动器、微毁伤器等装置中的应用,通过在铜箔上原位生长含能配位聚合物(ECP)、电子束沉积n-Al及重结晶CL-20的方法制备了ECP@Al@CL-20的含能阵列,采用SEM、XRD、TG/DSC及高... 为提高含能微芯片的能量特性和燃烧特性,推进其在微推进器、微驱动器、微毁伤器等装置中的应用,通过在铜箔上原位生长含能配位聚合物(ECP)、电子束沉积n-Al及重结晶CL-20的方法制备了ECP@Al@CL-20的含能阵列,采用SEM、XRD、TG/DSC及高速摄影等表征方法对其微观形貌、物相组成、热分解特性、燃烧性能及贮存寿命进行了测试与分析。在此基础上,将其与微机电系统(MEMS)集成制得了功能性的ECP@Al@CL-20含能微芯片,并对含能微芯片进行了电容点火测试。结果表明,由于ECP的导热系数低,使ECP@Al@CL-20含能阵列从外到内的传热效率降低,导致放热峰温相比纯CL-20提高了8.5℃,从而提高了ECP@Al@CL-20的热稳定性;ECP@Al@CL-20含能阵列具有优异的燃烧性能,自持燃烧时间(340 ms)远大于ECP@Al的自持燃烧时间(120 ms),含能微芯片可在15 mJ的输入能量下激发。 展开更多
关键词 含能配位聚合物 微机电系统 纳米铝 cl-20 微加热器 含能微芯片 ECP MEMS
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CL-20@PCHA复合粒子的制备及性能
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作者 文艺蒙 茆俊卿 +3 位作者 马宋雨辰 狄阳 刘涛 刘杰 《含能材料》 EI CAS CSCD 北大核心 2024年第10期1040-1048,共9页
多晶型六硝基六氮杂异伍兹烷(CL-20)在推进剂体系中因与添加剂接触或环境条件(温度或压力)改变,晶型易发生转变形成混合晶型,导致推进剂结构损伤,性能降低。为阻止溶剂与CL-20的接触,抑制CL-20晶型转变,研究将基于己二胺(HMDA)与邻苯二... 多晶型六硝基六氮杂异伍兹烷(CL-20)在推进剂体系中因与添加剂接触或环境条件(温度或压力)改变,晶型易发生转变形成混合晶型,导致推进剂结构损伤,性能降低。为阻止溶剂与CL-20的接触,抑制CL-20晶型转变,研究将基于己二胺(HMDA)与邻苯二酚(CCh)氧化自聚合反应生成聚酚胺(PCHA)薄膜,采用水悬浮法在温和的条件下对CL-20炸药晶体进行表面修饰,通过扫描电子显微镜(SEM)、傅里叶变换红外光谱仪(FT-IR)、拉曼光谱仪(RAMAN)、X射线衍射仪(XRD)、X射线光电子能谱仪(XPS)等对表面改性颗粒的形貌结构、包覆物含量、热稳定性及其在乙二醇溶液中的稳定性进行研究。结果表明,HMDA与CCh在温和条件下可对CL-20晶体表面进行修饰,并形成一层致密的PCHA包覆层;溶解称重法和高效液相色谱法(HPLC)测得PCHA包覆物含量约为1%;PCHA包覆将晶型转变温度和热分解温度分别提升了16℃和7℃,通过Kissinger法计算不同升温速率下的热分解活化能E_a发现CL-20@PCHA的活化能较CL-20提高了约8 kJ·mol^(-1),热稳定性得到较大提升;XRD测试结果表明PCHA薄膜可以有效阻隔溶剂与CL-20的接触,减缓CL-20在溶剂中的溶解速率,可有效抑制CL-20的晶型转变。 展开更多
关键词 聚酚胺(PCHA) 六硝基六氮杂异伍兹烷(cl-20) 晶型转变 热稳定性
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Incorporating empirical knowledge into data-driven variable selection for quantitative analysis of coal ash content by laser-induced breakdown spectroscopy 被引量:1
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作者 吕一涵 宋惟然 +1 位作者 侯宗余 王哲 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第7期148-156,共9页
Laser-induced breakdown spectroscopy(LIBS)has become a widely used atomic spectroscopic technique for rapid coal analysis.However,the vast amount of spectral information in LIBS contains signal uncertainty,which can a... Laser-induced breakdown spectroscopy(LIBS)has become a widely used atomic spectroscopic technique for rapid coal analysis.However,the vast amount of spectral information in LIBS contains signal uncertainty,which can affect its quantification performance.In this work,we propose a hybrid variable selection method to improve the performance of LIBS quantification.Important variables are first identified using Pearson's correlation coefficient,mutual information,least absolute shrinkage and selection operator(LASSO)and random forest,and then filtered and combined with empirical variables related to fingerprint elements of coal ash content.Subsequently,these variables are fed into a partial least squares regression(PLSR).Additionally,in some models,certain variables unrelated to ash content are removed manually to study the impact of variable deselection on model performance.The proposed hybrid strategy was tested on three LIBS datasets for quantitative analysis of coal ash content and compared with the corresponding data-driven baseline method.It is significantly better than the variable selection only method based on empirical knowledge and in most cases outperforms the baseline method.The results showed that on all three datasets the hybrid strategy for variable selection combining empirical knowledge and data-driven algorithms achieved the lowest root mean square error of prediction(RMSEP)values of 1.605,3.478 and 1.647,respectively,which were significantly lower than those obtained from multiple linear regression using only 12 empirical variables,which are 1.959,3.718 and 2.181,respectively.The LASSO-PLSR model with empirical support and 20 selected variables exhibited a significantly improved performance after variable deselection,with RMSEP values dropping from 1.635,3.962 and 1.647 to 1.483,3.086 and 1.567,respectively.Such results demonstrate that using empirical knowledge as a support for datadriven variable selection can be a viable approach to improve the accuracy and reliability of LIBS quantification. 展开更多
关键词 laser-induced breakdown spectroscopy(LIBS) coal ash content quantitative analysis variable selection empirical knowledge partial least squares regression(PLSR)
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Digital twin driven and intelligence enabled content delivery in end-edge-cloud collaborative 5G networks
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作者 Bo Yi Jianhui Lv +2 位作者 Xingwei Wang Lianbo Ma Min Huang 《Digital Communications and Networks》 SCIE CSCD 2024年第2期328-336,共9页
The rapid development of 5G/6G and AI enables an environment of Internet of Everything(IoE)which can support millions of connected mobile devices and applications to operate smoothly at high speed and low delay.Howeve... The rapid development of 5G/6G and AI enables an environment of Internet of Everything(IoE)which can support millions of connected mobile devices and applications to operate smoothly at high speed and low delay.However,these massive devices will lead to explosive traffic growth,which in turn cause great burden for the data transmission and content delivery.This challenge can be eased by sinking some critical content from cloud to edge.In this case,how to determine the critical content,where to sink and how to access the content correctly and efficiently become new challenges.This work focuses on establishing a highly efficient content delivery framework in the IoE environment.In particular,the IoE environment is re-constructed as an end-edge-cloud collaborative system,in which the concept of digital twin is applied to promote the collaboration.Based on the digital asset obtained by digital twin from end users,a content popularity prediction scheme is firstly proposed to decide the critical content by using the Temporal Pattern Attention(TPA)enabled Long Short-Term Memory(LSTM)model.Then,the prediction results are input for the proposed caching scheme to decide where to sink the critical content by using the Reinforce Learning(RL)technology.Finally,a collaborative routing scheme is proposed to determine the way to access the content with the objective of minimizing overhead.The experimental results indicate that the proposed schemes outperform the state-of-the-art benchmarks in terms of the caching hit rate,the average throughput,the successful content delivery rate and the average routing overhead. 展开更多
关键词 Digital twin IoE content delivery CACHING Routing
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Surface and Content Validity of the Mentoring Function Scale for Novice Nurses
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作者 Aimi Furukawa Yasuko Hosoda 《Open Journal of Nursing》 2024年第8期401-411,共11页
This study aimed to examine the surface and content validity of the Mentoring Function Scale for Novice Nurses, used to assess the mentoring of entry-level nurses, and to refine the scale items. In Study 1, six nurse ... This study aimed to examine the surface and content validity of the Mentoring Function Scale for Novice Nurses, used to assess the mentoring of entry-level nurses, and to refine the scale items. In Study 1, six nurse education researchers, selected using convenience sampling, with five or more years of nursing experience and experience teaching novice nurses, were invited to an expert meeting in July 2015. A group interview was conducted that lasted approximately 120 minutes. Study 2 examined the content validity index. Between September and November 2015, we distributed a self-administered questionnaire survey to 11 participants selected by convenience sampling. The participants included five nurse education researchers with a minimum of five years of nursing experience and experience teaching novice nurses, as well as six clinical nurses with a master’s degree or higher. Finally, 81 questionnaire items were retained from the initial 125 items. The 81-item Mentoring Function Scale for Novice Nurses had higher content validity than the original scale. To further increase the scale’s applicability, future studies should assess its reliability, construct validity, and criterion-related validity. 展开更多
关键词 Novice Nurses Mentoring Function Surface and content Validity Item-Level content Validity Index
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A glutathione S-transferase IbGSTL2 interacts with IbcPGM to increase starch content and improve starch quality in sweetpotato
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作者 Yue Fan Tianyu Chen +6 位作者 Luyao Xue Huan Zhang Shaopei Gao Ning Zhao Shaozhen He Hong Zhai Qingchang Liu 《The Crop Journal》 SCIE CSCD 2024年第6期1666-1676,共11页
A glutathione S-transferase(GST)gene IbGSTL2 was cloned and characterized from sweetpotato.It harbored a variation associated with starch content in storage roots.Overexpression of IbGSTL2 increased starch content and... A glutathione S-transferase(GST)gene IbGSTL2 was cloned and characterized from sweetpotato.It harbored a variation associated with starch content in storage roots.Overexpression of IbGSTL2 increased starch content and amylopectin proportion,decreased gelatinization temperature,and improved degree of crystallinity in sweetpotato storage roots,while its RNA interference resulted in the opposite trends.IbGSTL2 physically interacted with IbcPGM,an enzyme of sucrose metabolism,and improve starch content and quality by regulating genes involved in starch biosynthesis. 展开更多
关键词 IbcPGM IbGSTL2 Starch content Starch quality SWEETPOTATO
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A Survey of Digital Content Required for STD Prevention Education Taught by School Nurses
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作者 Tomoko Nakamura 《Health》 2024年第4期350-370,共21页
Purpose: In recent years, there has been concern in Japan about the increase in STDs among adolescents aged 15 - 19. In order to prevent STDs and guide adolescents toward desirable sexual behavior, this study’s goal ... Purpose: In recent years, there has been concern in Japan about the increase in STDs among adolescents aged 15 - 19. In order to prevent STDs and guide adolescents toward desirable sexual behavior, this study’s goal was to examine the actual state of STD prevention education taught by school nurses as part of the school curriculum, as well as the kinds of digital content they wish to have for teaching on the subject. Method: An anonymous, self-administered questionnaire was distributed by email and leaflet. Targeting the 100 valid responses received from the surveyed school nurses, descriptive statistics were made for each survey item and comparisons were made between the early- and mid-career groups based on years of experience. Results: 70.0% of respondents reported teaching about STDs in Health & Physical Education classes. School nurses in the early-career group used ready-made materials, while the mid-career group used both ready-made and self-made materials. 95% of respondents reported that they had little or no knowledge of STDs, while 84% reported that they were “good” or “fairly good” at teaching classes on sexuality. Both groups reported difficulty with the topics of “phimosis” and “nocturnal emissions” in the physiological category, “sexual behavior” in the “sex-adjacent” category, and “sexual and reproductive issues” in the psychosocial category. Respondents expressed a need for digital content covering the topics of “sexual violence”, “sexual abuse”, “sexually transmitted diseases”, and “how to turn down sex”. The mid-career group desired digital content for more items than the early-career group, with significant differences in the pathogens involved in sexually transmitted diseases and sex-adjacent items. 32.0% of respondents answered that they had done self-study for sex education classes in the past three years, and both groups desired self-study on “sexually transmitted diseases”, with the mid-career group significantly higher than the early-career group on “cervical cancer & HPV”, “emergency contraceptives”, and “media literacy”. Conclusion: Health & Physical Education is the main subject that covers STDs, and pre-existing materials are commonly used. It is expected that this is due to nurses’ busy schedules and the fact that only one school nurse is assigned to each school. The data collected suggested that nurse teachers want categorized digital content that can be used in the classes they are responsible for, rather than educational content on topics they are not comfortable with. In addition, given the changing environment surrounding sex, it was clear that they wish to understand the realities and needs of the high school students they teach, and desire self-study opportunities to improve their teaching methods. 展开更多
关键词 High School Students Sexually Transmitted Diseases Digital content School Nurses
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