The aim of this study was to simulate the solidification process of beam blank continuous casting, and then find the reasons for the typical defects of the beam blank. A two-dimensional transient coupled finite elemen...The aim of this study was to simulate the solidification process of beam blank continuous casting, and then find the reasons for the typical defects of the beam blank. A two-dimensional transient coupled finite element model has been developed to compute the temperature and stress profile in beam blank continuous casting. The enthalpy method was used in the heat conduction equation. The thermo-mechanical property in the mushy zone was taken into consideration in this calculation. It is shown that at the mold exit the thickness of the shell had its maximum value at the flange tip and its minimum value at the fillet. The temperature had a great fluctuation on the surface of the beam blank in the secondary cooling zone. At the unbending point, the surface temperature of the web was in the brittleness temperature range under the present condition. To ensure the quality, it is necessary to weaken the intensity of secondary cooling. At the mold exit the equivalent stress and strain have higher values at the flange tip and at the web. From the spray 1 to the unbending point, the maximum values of stress and strain gradually moved to the internal section of the flange tip and the web. However, whenever, there were bigger stress and strain values near the flange tip and the web than in the other parts, it must be very easy to generate cracks at those positions. Now, online verification of this simulation has been developed, which has proved to be very useful and efficient to instruct the practical production of beam blank continuous casting.展开更多
The degradation of formaldehyde gas was studied using UV/TiO2/O3 process under the condition of continuous flow mode. The effects of humidity, initial formaldehyde concentration, residence time and ozone adding amount...The degradation of formaldehyde gas was studied using UV/TiO2/O3 process under the condition of continuous flow mode. The effects of humidity, initial formaldehyde concentration, residence time and ozone adding amount on degradation of formaldehyde gas were investigated. The experimental results indicated that the combination of ozonation with photocatalytic oxidation on the degradation of formaldehyde showed a synergetic action, e.g,, it could considerably increase decomposing of formaldehyde. The degradation efficiency of formaldehyde was between 73.6% and 79.4% while the initial concentration in the range of 1.84--24 mg/m^3 by O3/TiO2flJV process. The optimal humidity was about 50% in UV/TiO2/O3 processs and degradation of formaldehyde increases from 39.0% to 94.1% when the ozone content increased from 0 to 141 mg/m^3. Furthermore, the kinetics of formaldehyde degradation reaction could be described by Langmuir-Hinshelwood model. The rate constant k of 46.72 mg/(m^3.min) and Langmuir adsorption coefficient K of 0.0268 m^3/mg were obtained.展开更多
In this paper, a novel near-net-shape forming process, continuous semisolid extrusion process (CSEP) of AZ31 alloy was proposed, and the dynamical solidification behaviors and metal flow during the process were firs...In this paper, a novel near-net-shape forming process, continuous semisolid extrusion process (CSEP) of AZ31 alloy was proposed, and the dynamical solidification behaviors and metal flow during the process were firstly investigated. During casting AZ31 alloy by this process, non-uniform microstructure distributions and non- equilibrium solidification region near the roll surface were found in the roll-shoe gap. Microstructural evolution from dendrite to rosette and spherical grains was observed during the casting by CSEP. Casting temperature, roll-shoe gap width and cooling ability have great effect on casting process and metal flow, so these factors should be carefully controlled, a proper casting temperature of 710-750℃ is suggested. The white α phases were strongly stretched during the processing, and the remnant liquids are correspondingly distributes along the solid phase boundaries and also show stripped lines.展开更多
An iterative learning model predictive control (ILMPC) technique is applied to a class of continuous/batch processes. Such processes are characterized by the operations of batch processes generating periodic strong ...An iterative learning model predictive control (ILMPC) technique is applied to a class of continuous/batch processes. Such processes are characterized by the operations of batch processes generating periodic strong disturbances to the continuous processes and traditional regulatory controllers are unable to eliminate these periodic disturbances. ILMPC integrates the feature of iterative learning control (ILC) handling repetitive signal and the flexibility of model predictive control (MPC). By on-line monitoring the operation status of batch processes, an event-driven iterative learning algorithm for batch repetitive disturbances is initiated and the soft constraints are adjusted timely as the feasible region is away from the desired operating zone. The results of an industrial application show that the proposed ILMPC method is effective for a class of continuous/batch processes.展开更多
Continuous thermo-mechanical processing (CTMP) of 6201 aluminum alloy was simulated on Gleeble-1500. The deformed specimens were analyzed by the observation of TEM and the measurement of hardness. It was shown that r...Continuous thermo-mechanical processing (CTMP) of 6201 aluminum alloy was simulated on Gleeble-1500. The deformed specimens were analyzed by the observation of TEM and the measurement of hardness. It was shown that rapid solid solution and aging treatment can be effectively combined in one procedure by the strain induced during CTMP. The deformation temperature is ranging from 540* C to 300* C, the hardness increases directly before the 6th pass followed by a slight drop, the amount of precipitates increases with the holding time after deformation. Uniformly distributed and stabilized Mg2Si precipitates, as well as dislocation substructure can be observed on deformed specimens which have been subsequently held at 300℃ for 60 seconds.展开更多
Combined with the technological characteristics of thin slab continuous rolling process (TSCR), dynamic recrystallization of an extremely coarse austenite of low carbon steel is studied by Thermecmaster-Z hot simula...Combined with the technological characteristics of thin slab continuous rolling process (TSCR), dynamic recrystallization of an extremely coarse austenite of low carbon steel is studied by Thermecmaster-Z hot simulator. By the analysis of true stress-strain curves and the observation of microstructures at different deformation stages, the critical stress and critical strain are determined under different deformation conditions. The effect of Z parameter on dynamic recrystallization of coarse austenite is studied. The microstructure evolution in real production is also discussed.展开更多
The methanolysis of amides,which is widely employed in the synthetic organic chemistry,hardly occurs under mild conditions.To safely and controllably intensify the methanolysis reaction with hightemperature and high-p...The methanolysis of amides,which is widely employed in the synthetic organic chemistry,hardly occurs under mild conditions.To safely and controllably intensify the methanolysis reaction with hightemperature and high-pressure environment,a continuous tubular reaction technology is developed,whose space-time yield is over twice of that of the conventional batch reaction.The methanolysis of acetanilide is selected as the representative reaction,and the influences of temperature,pressure,reactant and catalyst concentration,and residence time on the reaction performances are systematically investigated.Taking the advantages of precise temperature and reaction time control by the tubular reactor,the kinetics of acetanilide methanolysis are determined and compared to the kinetics of acetanilide hydrolysis reaction.The tubular reaction method is also employed to test a variety of other amides to show the effects of substituents,steric hindrance,and alkalinity on the reaction rate of methanolysis.展开更多
The approaches to discrete approximation of Pareto front using multi-objective evolutionary algorithms have the problems of heavy computation burden, long running time and missing Pareto optimal points. In order to ov...The approaches to discrete approximation of Pareto front using multi-objective evolutionary algorithms have the problems of heavy computation burden, long running time and missing Pareto optimal points. In order to overcome these problems, an approach to continuous approximation of Pareto front using geometric support vector regression is presented. The regression model of the small size approximate discrete Pareto front is constructed by geometric support vector regression modeling and is described as the approximate continuous Pareto front. In the process of geometric support vector regression modeling, considering the distribution characteristic of Pareto optimal points, the separable augmented training sample sets are constructed by shifting original training sample points along multiple coordinated axes. Besides, an interactive decision-making(DM)procedure, in which the continuous approximation of Pareto front and decision-making is performed interactively, is designed for improving the accuracy of the preferred Pareto optimal point. The correctness of the continuous approximation of Pareto front is demonstrated with a typical multi-objective optimization problem. In addition,combined with the interactive decision-making procedure, the continuous approximation of Pareto front is applied in the multi-objective optimization for an industrial fed-batch yeast fermentation process. The experimental results show that the generated approximate continuous Pareto front has good accuracy and completeness. Compared with the multi-objective evolutionary algorithm with large size population, a more accurate preferred Pareto optimal point can be obtained from the approximate continuous Pareto front with less computation and shorter running time. The operation strategy corresponding to the final preferred Pareto optimal point generated by the interactive DM procedure can improve the production indexes of the fermentation process effectively.展开更多
The quantitative evaluation of multi-process collaborative operation is of great significance for the improvement of production planning and scheduling in steelmaking–continuous casting sections(SCCSs). However, this...The quantitative evaluation of multi-process collaborative operation is of great significance for the improvement of production planning and scheduling in steelmaking–continuous casting sections(SCCSs). However, this evaluation is difficult since it relies on an in-depth understanding of the operating mechanism of SCCSs, and few existing methods can be used to conduct the evaluation, due to the lack of full-scale consideration of the multiple factors related to the production operation. In this study, three quantitative models were developed, and the multiprocess collaborative operation level was evaluated through the laminar-flow operation degree, the process matching degree, and the scheduling strategy availability degree. Based on the evaluation models for the laminar-flow operation and process matching levels, this study investigated the production status of two steelmaking plants, plants A and B, based on actual production data. The average laminar-flow operation(process matching) degrees of SCCSs were obtained as 0.638(0.610) and 1.000(0.759) for plants A and B, respectively, for the period of April to July 2019. Then, a scheduling strategy based on the optimization of the furnace-caster coordinating mode was suggested for plant A. Simulation experiments showed higher availability than the greedy-based and manual strategies. After the proposed scheduling strategy was applied,the average process matching degree of the SCCS of plant A increased by 4.6% for the period of September to November 2019. The multi-process collaborative operation level was improved with fewer adjustments and interruptions in casting.展开更多
A novel technology of continuous semisolid extrusion Process(CSEP) was adopted to produce AZ31 alloy structural materials.Effects of technological conditions on the microstructures of AZ31 alloy during CSEP were studi...A novel technology of continuous semisolid extrusion Process(CSEP) was adopted to produce AZ31 alloy structural materials.Effects of technological conditions on the microstructures of AZ31 alloy during CSEP were studied.During the casting process,the non-uniform distribution of microstructures was found in the roll-shoe gap.Microstructure evolution from dendrite to rosette or spherical grains was observed during the casting process by CSEP.The results show that high casting temperature and large cooling intensity can cause non-equilibrium solidification region near the roll surface,large roll-shoe gap width and high cooling intensity can lead to the formation of discontinuous solidification microstructure and slip plane near the shoe surface,which will finally cause the failure of the casting process.The proper casting temperature range of 730-750 °C,the roll cooling intensity of 0.4 L/s and the roll-shoe gap width of less than 10 mm are suggested.Under the suggested conditions,the product with diameter of 10 mm of AZ31 alloy with smooth surface and homogeneous striped microstructure is obtained.The average strength of the product after heat treatment reaches 270 MPa,and the elongation is 16%.展开更多
Semisolid continuous casting (SSCC) is a new technology to produce billets for semisolid metal forming (SSMF). The effect of process factors, such as pouring temperature, stirring rate, preheating temperature and ther...Semisolid continuous casting (SSCC) is a new technology to produce billets for semisolid metal forming (SSMF). The effect of process factors, such as pouring temperature, stirring rate, preheating temperature and thermal conductivity of stirring chamber, on the microstructure of SSCC billets was studied by means of the factorial experimental method. The results show that the microstructure of SSCC billets can be controlled by the above-mentioned four process factors. In order to obtain fine and rounded granular grains in an SSCC billet, the pouring temperature, preheating temperature and stirring rate should be kept in a moderate range, and the thermal conductivity of stirring chamber should be high. The regression equations with the process factors connecting the microstructure was also set up based on experimental data.展开更多
The relationships between the surface quality of a single crystal copper ingot and the process parameters of heated mould continuous casting method were studied experimentally using our own design of horizontal heated...The relationships between the surface quality of a single crystal copper ingot and the process parameters of heated mould continuous casting method were studied experimentally using our own design of horizontal heated mould continuous casting apparatus, and the mechanism by which process parameters affect the surface quality of a single crystal copper ingot is analyzed in the present paper. The results show that the process parameters affect the surface quality of a pure copper ingot by affecting the position of the liquid-solid interface in the mould. The position of the liquid-solid interface in the mould must be controlled carefully within an appropriate range, which is determined through a series of experiments, in order to gain a single crystal copper ingot with good surface quality.展开更多
Semantic processing is a high level cognition function of the human brain. It has been argued intensively whether this process could be accomplished in the absence of awareness. Continuous flash suppression (CFS) is a...Semantic processing is a high level cognition function of the human brain. It has been argued intensively whether this process could be accomplished in the absence of awareness. Continuous flash suppression (CFS) is a powerful approach to create stable unconscious state. In this study, subjects were required to observe a series of paired Chinese words and judge the correlation between them in CFS paradigm. A negative component of event related potential, N400, and a Brain symmetry index were used to measure whether the meaning of the paired stimulus was registered in subliminal semantic processing. Analysis didn’t detect a significant difference in N400 response and EEG signal symmetry between correlated and uncorrelated pairs under unconscious condition. These results support the view that semantic information of Chinese character processing is absent without consciousness created by CFS.展开更多
[Objective] The research aimed to analyze a rare low temperature and rainy weather process which happened in Anhui Province from July 22 to August 14,2009.[Method] Based on the data of conventional observation,NCEP an...[Objective] The research aimed to analyze a rare low temperature and rainy weather process which happened in Anhui Province from July 22 to August 14,2009.[Method] Based on the data of conventional observation,NCEP analysis field and automatic station,a rare low temperature and rainy weather process which occurred in Anhui Province from July 22 to August 14,2009 was analyzed.The formation reason of continuous rainy process in midsummer was discussed.The circulation characteristics and influence systems of continuous rainy process were revealed.On the base,the influences of configuration of circulation fields and difference of physical quantity fields at high and low layers on range and intensity of precipitation were analyzed.[Result] According to the circulation situation and influence system,the continuous rainy process could be divided into four stages:July 22-24,from July 27 to August 1,August 4-8 and August 9-14.Moreover,it was respectively affected by northeast low vortex,cold and warm air,high-level low trough,typhoon and periphery of subtropical high at four stages.The maintenance of big specific humidity zone provided sufficient water vapor condition for the continuous rainy weather.The rainstorm appeared in dense zone of specific humidity line,where the specific humidity >13 g/kg in the humidity front zone.A temperature trough maintained at 850 hPa.The cold air which continued to diffuse and go south was main reason of the abnormally low temperature during the continuous rainy period.Moreover,it provided ascending motion condition for precipitation maintenance.[Conclusion] The research provided references for actual forecast of continuous rainy weather.展开更多
Continuous material processing operations like printing and textiles manufacturing are conducted under highly variable conditions due to changes in the environment and/or in the materials being processed.As such,the p...Continuous material processing operations like printing and textiles manufacturing are conducted under highly variable conditions due to changes in the environment and/or in the materials being processed.As such,the processing parameters require robust real-time adjustment appropriate to the conditions of a nonlinear system.This paper addresses this issue by presenting a hybrid feedforward-feedback nonlinear model predictive controller for continuous material processing operations.The adaptive feedback control strategy of the controller augments the standard feedforward control to ensure improved robustness and compensation for environmental disturbances and/or parameter uncertainties.Thus,the controller can reduce the need for manual adjustments.The controller applies nonlinear generalized predictive control to generate an adaptive control signal for attaining robust performance.A wavelet-based neural network model is adopted as the prediction model with high prediction precision and time-frequency localization characteristics.Online training is utilized to predict uncertain system dynamics by tuning the wavelet neural network parameters and the controller parameters adaptively.The performance of the controller algorithm is verified by both simulation,and in a real-time practical application involving a single-input single-output double-zone sliver drafting system used in textiles manufacturing.Both the simulation and practical results demonstrate an excellent control performance in terms of the mean thickness and coefficient of variation of output slivers,which verifies the effectiveness of this approach in improving the long-term uniformity of slivers.展开更多
We study the Nadaraya-Watson estimators for the drift function of two-sided reflected stochastic differential equations.The estimates,based on either the continuously observed process or the discretely observed proces...We study the Nadaraya-Watson estimators for the drift function of two-sided reflected stochastic differential equations.The estimates,based on either the continuously observed process or the discretely observed process,are considered.Under certain conditions,we prove the strong consistency and the asymptotic normality of the two estimators.Our method is also suitable for one-sided reflected stochastic differential equations.Simulation results demonstrate that the performance of our estimator is superior to that of the estimator proposed by Cholaquidis et al.(Stat Sin,2021,31:29-51).Several real data sets of the currency exchange rate are used to illustrate our proposed methodology.展开更多
This paper reviews recent developments in the contin- uous processing of steels in Japan.The following items are discussed:continuous casting-direct rolling(CC-DR) process of hot-rolled strip:thermomechanical control ...This paper reviews recent developments in the contin- uous processing of steels in Japan.The following items are discussed:continuous casting-direct rolling(CC-DR) process of hot-rolled strip:thermomechanical control process(TMCP)of heavy plates:in—line heat treating pro- cess of rails:direct lead patenting(DLP)process of wire rods;and fully integrated processing line(FIPL)of cold-rolled strip.展开更多
For continuous-state branching processes in Lévy random environments, the recursion of n-moments and the equivalent condition for the existence of general f-moments are established, where f is a positive continuo...For continuous-state branching processes in Lévy random environments, the recursion of n-moments and the equivalent condition for the existence of general f-moments are established, where f is a positive continuous function satisfying some standard conditions.展开更多
A plate's internal quality is very critical, especially for boilers and high-pressure vessels. The ultrasonic test (UT) is the main type of non-destructive flaw detection for heavy plates, which is important becaus...A plate's internal quality is very critical, especially for boilers and high-pressure vessels. The ultrasonic test (UT) is the main type of non-destructive flaw detection for heavy plates, which is important because one of the main reasons for plate defects is ultrasonic flaws. This study, based on Baosteel' s practical experience in the manufacture of heavy plates, elucidates the cause of defect formation by analyzing ultrasonic flaw testing maps and using special equipment, such as the scanning electron microscope, electron probe and the optical microscope. The author puts forward the following improvement measures: ① Ultrasonic flaws are caused by central porosity and segregation,[H] bubbles and inclusion in slabs.②Ultrasonic flaws are more likely to occur in the bottom and top of slabs rather than the other positions in the casting sequence. It is clear that one-quarter of the inner camber' s thickness is accumulated inclusion.③It is clear that overheating in the tundish and the flow of the casting mould have an effect on ultrasonic flaws caused by inclusions.④Soft reduction improves central porosity and segregation,which decreases the number of ultrasonic flaws in the plate.展开更多
In this paper,it presents the results of calculation of solidification process of copper continuous cast bar by cross section size 120 mm × 70 mm with application of Pro Cast 2010 software. The estimation of moul...In this paper,it presents the results of calculation of solidification process of copper continuous cast bar by cross section size 120 mm × 70 mm with application of Pro Cast 2010 software. The estimation of mould design effect on solidification process of continuos copper cast bar is completed at various speeds of casting.Profiles of liquid metal cavities and temperature allocations in the cast bar at various casting speeds are defined.The analysis of received liquid metal cavity profiles shows that a new mold construction allows significantly decrease of the length of the liquid metal cavity during continuous copper casting at HAZELETTcasting machine and the increase of maximum casting speed from 10 to 11 m / min. Adequacy of the results of copper continuous cast bar solidification process calculation is confirmed by the experimental data.展开更多
基金supported by the Hebei Provincial Natural Science Foundation of China(No.E2007000591).
文摘The aim of this study was to simulate the solidification process of beam blank continuous casting, and then find the reasons for the typical defects of the beam blank. A two-dimensional transient coupled finite element model has been developed to compute the temperature and stress profile in beam blank continuous casting. The enthalpy method was used in the heat conduction equation. The thermo-mechanical property in the mushy zone was taken into consideration in this calculation. It is shown that at the mold exit the thickness of the shell had its maximum value at the flange tip and its minimum value at the fillet. The temperature had a great fluctuation on the surface of the beam blank in the secondary cooling zone. At the unbending point, the surface temperature of the web was in the brittleness temperature range under the present condition. To ensure the quality, it is necessary to weaken the intensity of secondary cooling. At the mold exit the equivalent stress and strain have higher values at the flange tip and at the web. From the spray 1 to the unbending point, the maximum values of stress and strain gradually moved to the internal section of the flange tip and the web. However, whenever, there were bigger stress and strain values near the flange tip and the web than in the other parts, it must be very easy to generate cracks at those positions. Now, online verification of this simulation has been developed, which has proved to be very useful and efficient to instruct the practical production of beam blank continuous casting.
基金Project supported by the Science Project of Harbin City(No. H2001-12)the Youth Foundation of School of Municipal and Environmental Engineering in Harbin Institute of Technology(No. 01306914).
文摘The degradation of formaldehyde gas was studied using UV/TiO2/O3 process under the condition of continuous flow mode. The effects of humidity, initial formaldehyde concentration, residence time and ozone adding amount on degradation of formaldehyde gas were investigated. The experimental results indicated that the combination of ozonation with photocatalytic oxidation on the degradation of formaldehyde showed a synergetic action, e.g,, it could considerably increase decomposing of formaldehyde. The degradation efficiency of formaldehyde was between 73.6% and 79.4% while the initial concentration in the range of 1.84--24 mg/m^3 by O3/TiO2flJV process. The optimal humidity was about 50% in UV/TiO2/O3 processs and degradation of formaldehyde increases from 39.0% to 94.1% when the ozone content increased from 0 to 141 mg/m^3. Furthermore, the kinetics of formaldehyde degradation reaction could be described by Langmuir-Hinshelwood model. The rate constant k of 46.72 mg/(m^3.min) and Langmuir adsorption coefficient K of 0.0268 m^3/mg were obtained.
基金supports from National High-Tech R&D Program of China (GrantNo. 2007AA03Z111)Natural Science Foundation of China (Grant No. 50604007)the Program for New Century Excellent Talents in University (Grant No.NCET-06-0285 and NCET-08-0097)
文摘In this paper, a novel near-net-shape forming process, continuous semisolid extrusion process (CSEP) of AZ31 alloy was proposed, and the dynamical solidification behaviors and metal flow during the process were firstly investigated. During casting AZ31 alloy by this process, non-uniform microstructure distributions and non- equilibrium solidification region near the roll surface were found in the roll-shoe gap. Microstructural evolution from dendrite to rosette and spherical grains was observed during the casting by CSEP. Casting temperature, roll-shoe gap width and cooling ability have great effect on casting process and metal flow, so these factors should be carefully controlled, a proper casting temperature of 710-750℃ is suggested. The white α phases were strongly stretched during the processing, and the remnant liquids are correspondingly distributes along the solid phase boundaries and also show stripped lines.
基金Supported by the National Creative Research Groups Science Foundation of China (60721062) and the National High Technology Research and Development Program of China (2007AA04Z162).
文摘An iterative learning model predictive control (ILMPC) technique is applied to a class of continuous/batch processes. Such processes are characterized by the operations of batch processes generating periodic strong disturbances to the continuous processes and traditional regulatory controllers are unable to eliminate these periodic disturbances. ILMPC integrates the feature of iterative learning control (ILC) handling repetitive signal and the flexibility of model predictive control (MPC). By on-line monitoring the operation status of batch processes, an event-driven iterative learning algorithm for batch repetitive disturbances is initiated and the soft constraints are adjusted timely as the feasible region is away from the desired operating zone. The results of an industrial application show that the proposed ILMPC method is effective for a class of continuous/batch processes.
文摘Continuous thermo-mechanical processing (CTMP) of 6201 aluminum alloy was simulated on Gleeble-1500. The deformed specimens were analyzed by the observation of TEM and the measurement of hardness. It was shown that rapid solid solution and aging treatment can be effectively combined in one procedure by the strain induced during CTMP. The deformation temperature is ranging from 540* C to 300* C, the hardness increases directly before the 6th pass followed by a slight drop, the amount of precipitates increases with the holding time after deformation. Uniformly distributed and stabilized Mg2Si precipitates, as well as dislocation substructure can be observed on deformed specimens which have been subsequently held at 300℃ for 60 seconds.
文摘Combined with the technological characteristics of thin slab continuous rolling process (TSCR), dynamic recrystallization of an extremely coarse austenite of low carbon steel is studied by Thermecmaster-Z hot simulator. By the analysis of true stress-strain curves and the observation of microstructures at different deformation stages, the critical stress and critical strain are determined under different deformation conditions. The effect of Z parameter on dynamic recrystallization of coarse austenite is studied. The microstructure evolution in real production is also discussed.
基金the financial support from the National Natural Science Foundation of China(21991104)the Shandong Province Major Science and Technology Innovation Project(2019JZZY020401)。
文摘The methanolysis of amides,which is widely employed in the synthetic organic chemistry,hardly occurs under mild conditions.To safely and controllably intensify the methanolysis reaction with hightemperature and high-pressure environment,a continuous tubular reaction technology is developed,whose space-time yield is over twice of that of the conventional batch reaction.The methanolysis of acetanilide is selected as the representative reaction,and the influences of temperature,pressure,reactant and catalyst concentration,and residence time on the reaction performances are systematically investigated.Taking the advantages of precise temperature and reaction time control by the tubular reactor,the kinetics of acetanilide methanolysis are determined and compared to the kinetics of acetanilide hydrolysis reaction.The tubular reaction method is also employed to test a variety of other amides to show the effects of substituents,steric hindrance,and alkalinity on the reaction rate of methanolysis.
基金Supported by the National Natural Science Foundation of China(20676013,61240047)
文摘The approaches to discrete approximation of Pareto front using multi-objective evolutionary algorithms have the problems of heavy computation burden, long running time and missing Pareto optimal points. In order to overcome these problems, an approach to continuous approximation of Pareto front using geometric support vector regression is presented. The regression model of the small size approximate discrete Pareto front is constructed by geometric support vector regression modeling and is described as the approximate continuous Pareto front. In the process of geometric support vector regression modeling, considering the distribution characteristic of Pareto optimal points, the separable augmented training sample sets are constructed by shifting original training sample points along multiple coordinated axes. Besides, an interactive decision-making(DM)procedure, in which the continuous approximation of Pareto front and decision-making is performed interactively, is designed for improving the accuracy of the preferred Pareto optimal point. The correctness of the continuous approximation of Pareto front is demonstrated with a typical multi-objective optimization problem. In addition,combined with the interactive decision-making procedure, the continuous approximation of Pareto front is applied in the multi-objective optimization for an industrial fed-batch yeast fermentation process. The experimental results show that the generated approximate continuous Pareto front has good accuracy and completeness. Compared with the multi-objective evolutionary algorithm with large size population, a more accurate preferred Pareto optimal point can be obtained from the approximate continuous Pareto front with less computation and shorter running time. The operation strategy corresponding to the final preferred Pareto optimal point generated by the interactive DM procedure can improve the production indexes of the fermentation process effectively.
基金financially supported by the National Natural Science Foundation of China (Nos.50874014 and 51974023)the Fundamental Research Funds for Central Universities (No.FRF-BR-17-029A)。
文摘The quantitative evaluation of multi-process collaborative operation is of great significance for the improvement of production planning and scheduling in steelmaking–continuous casting sections(SCCSs). However, this evaluation is difficult since it relies on an in-depth understanding of the operating mechanism of SCCSs, and few existing methods can be used to conduct the evaluation, due to the lack of full-scale consideration of the multiple factors related to the production operation. In this study, three quantitative models were developed, and the multiprocess collaborative operation level was evaluated through the laminar-flow operation degree, the process matching degree, and the scheduling strategy availability degree. Based on the evaluation models for the laminar-flow operation and process matching levels, this study investigated the production status of two steelmaking plants, plants A and B, based on actual production data. The average laminar-flow operation(process matching) degrees of SCCSs were obtained as 0.638(0.610) and 1.000(0.759) for plants A and B, respectively, for the period of April to July 2019. Then, a scheduling strategy based on the optimization of the furnace-caster coordinating mode was suggested for plant A. Simulation experiments showed higher availability than the greedy-based and manual strategies. After the proposed scheduling strategy was applied,the average process matching degree of the SCCS of plant A increased by 4.6% for the period of September to November 2019. The multi-process collaborative operation level was improved with fewer adjustments and interruptions in casting.
基金Projects(50974038,51034002) supported by the National Natural Science Foundation of ChinaProject (2007AA03Z111) supported by Natural High-tech Research and Development Program of ChinaProjects(N090502003) supported by the Basic Scientific Research Operation of Center University,China
文摘A novel technology of continuous semisolid extrusion Process(CSEP) was adopted to produce AZ31 alloy structural materials.Effects of technological conditions on the microstructures of AZ31 alloy during CSEP were studied.During the casting process,the non-uniform distribution of microstructures was found in the roll-shoe gap.Microstructure evolution from dendrite to rosette or spherical grains was observed during the casting process by CSEP.The results show that high casting temperature and large cooling intensity can cause non-equilibrium solidification region near the roll surface,large roll-shoe gap width and high cooling intensity can lead to the formation of discontinuous solidification microstructure and slip plane near the shoe surface,which will finally cause the failure of the casting process.The proper casting temperature range of 730-750 °C,the roll cooling intensity of 0.4 L/s and the roll-shoe gap width of less than 10 mm are suggested.Under the suggested conditions,the product with diameter of 10 mm of AZ31 alloy with smooth surface and homogeneous striped microstructure is obtained.The average strength of the product after heat treatment reaches 270 MPa,and the elongation is 16%.
基金This work was financed by the NatUral Science Research Fotmdation of Hebei Province, China and the NatUral Science Researc
文摘Semisolid continuous casting (SSCC) is a new technology to produce billets for semisolid metal forming (SSMF). The effect of process factors, such as pouring temperature, stirring rate, preheating temperature and thermal conductivity of stirring chamber, on the microstructure of SSCC billets was studied by means of the factorial experimental method. The results show that the microstructure of SSCC billets can be controlled by the above-mentioned four process factors. In order to obtain fine and rounded granular grains in an SSCC billet, the pouring temperature, preheating temperature and stirring rate should be kept in a moderate range, and the thermal conductivity of stirring chamber should be high. The regression equations with the process factors connecting the microstructure was also set up based on experimental data.
文摘The relationships between the surface quality of a single crystal copper ingot and the process parameters of heated mould continuous casting method were studied experimentally using our own design of horizontal heated mould continuous casting apparatus, and the mechanism by which process parameters affect the surface quality of a single crystal copper ingot is analyzed in the present paper. The results show that the process parameters affect the surface quality of a pure copper ingot by affecting the position of the liquid-solid interface in the mould. The position of the liquid-solid interface in the mould must be controlled carefully within an appropriate range, which is determined through a series of experiments, in order to gain a single crystal copper ingot with good surface quality.
文摘Semantic processing is a high level cognition function of the human brain. It has been argued intensively whether this process could be accomplished in the absence of awareness. Continuous flash suppression (CFS) is a powerful approach to create stable unconscious state. In this study, subjects were required to observe a series of paired Chinese words and judge the correlation between them in CFS paradigm. A negative component of event related potential, N400, and a Brain symmetry index were used to measure whether the meaning of the paired stimulus was registered in subliminal semantic processing. Analysis didn’t detect a significant difference in N400 response and EEG signal symmetry between correlated and uncorrelated pairs under unconscious condition. These results support the view that semantic information of Chinese character processing is absent without consciousness created by CFS.
文摘[Objective] The research aimed to analyze a rare low temperature and rainy weather process which happened in Anhui Province from July 22 to August 14,2009.[Method] Based on the data of conventional observation,NCEP analysis field and automatic station,a rare low temperature and rainy weather process which occurred in Anhui Province from July 22 to August 14,2009 was analyzed.The formation reason of continuous rainy process in midsummer was discussed.The circulation characteristics and influence systems of continuous rainy process were revealed.On the base,the influences of configuration of circulation fields and difference of physical quantity fields at high and low layers on range and intensity of precipitation were analyzed.[Result] According to the circulation situation and influence system,the continuous rainy process could be divided into four stages:July 22-24,from July 27 to August 1,August 4-8 and August 9-14.Moreover,it was respectively affected by northeast low vortex,cold and warm air,high-level low trough,typhoon and periphery of subtropical high at four stages.The maintenance of big specific humidity zone provided sufficient water vapor condition for the continuous rainy weather.The rainstorm appeared in dense zone of specific humidity line,where the specific humidity >13 g/kg in the humidity front zone.A temperature trough maintained at 850 hPa.The cold air which continued to diffuse and go south was main reason of the abnormally low temperature during the continuous rainy period.Moreover,it provided ascending motion condition for precipitation maintenance.[Conclusion] The research provided references for actual forecast of continuous rainy weather.
文摘Continuous material processing operations like printing and textiles manufacturing are conducted under highly variable conditions due to changes in the environment and/or in the materials being processed.As such,the processing parameters require robust real-time adjustment appropriate to the conditions of a nonlinear system.This paper addresses this issue by presenting a hybrid feedforward-feedback nonlinear model predictive controller for continuous material processing operations.The adaptive feedback control strategy of the controller augments the standard feedforward control to ensure improved robustness and compensation for environmental disturbances and/or parameter uncertainties.Thus,the controller can reduce the need for manual adjustments.The controller applies nonlinear generalized predictive control to generate an adaptive control signal for attaining robust performance.A wavelet-based neural network model is adopted as the prediction model with high prediction precision and time-frequency localization characteristics.Online training is utilized to predict uncertain system dynamics by tuning the wavelet neural network parameters and the controller parameters adaptively.The performance of the controller algorithm is verified by both simulation,and in a real-time practical application involving a single-input single-output double-zone sliver drafting system used in textiles manufacturing.Both the simulation and practical results demonstrate an excellent control performance in terms of the mean thickness and coefficient of variation of output slivers,which verifies the effectiveness of this approach in improving the long-term uniformity of slivers.
基金partially supported by the National Natural Science Foundation of China(11871244)the Fundamental Research Funds for the Central Universities,JLU。
文摘We study the Nadaraya-Watson estimators for the drift function of two-sided reflected stochastic differential equations.The estimates,based on either the continuously observed process or the discretely observed process,are considered.Under certain conditions,we prove the strong consistency and the asymptotic normality of the two estimators.Our method is also suitable for one-sided reflected stochastic differential equations.Simulation results demonstrate that the performance of our estimator is superior to that of the estimator proposed by Cholaquidis et al.(Stat Sin,2021,31:29-51).Several real data sets of the currency exchange rate are used to illustrate our proposed methodology.
文摘This paper reviews recent developments in the contin- uous processing of steels in Japan.The following items are discussed:continuous casting-direct rolling(CC-DR) process of hot-rolled strip:thermomechanical control process(TMCP)of heavy plates:in—line heat treating pro- cess of rails:direct lead patenting(DLP)process of wire rods;and fully integrated processing line(FIPL)of cold-rolled strip.
基金supported by the National Natural Science Foundation of China(11531001)
文摘For continuous-state branching processes in Lévy random environments, the recursion of n-moments and the equivalent condition for the existence of general f-moments are established, where f is a positive continuous function satisfying some standard conditions.
文摘A plate's internal quality is very critical, especially for boilers and high-pressure vessels. The ultrasonic test (UT) is the main type of non-destructive flaw detection for heavy plates, which is important because one of the main reasons for plate defects is ultrasonic flaws. This study, based on Baosteel' s practical experience in the manufacture of heavy plates, elucidates the cause of defect formation by analyzing ultrasonic flaw testing maps and using special equipment, such as the scanning electron microscope, electron probe and the optical microscope. The author puts forward the following improvement measures: ① Ultrasonic flaws are caused by central porosity and segregation,[H] bubbles and inclusion in slabs.②Ultrasonic flaws are more likely to occur in the bottom and top of slabs rather than the other positions in the casting sequence. It is clear that one-quarter of the inner camber' s thickness is accumulated inclusion.③It is clear that overheating in the tundish and the flow of the casting mould have an effect on ultrasonic flaws caused by inclusions.④Soft reduction improves central porosity and segregation,which decreases the number of ultrasonic flaws in the plate.
文摘In this paper,it presents the results of calculation of solidification process of copper continuous cast bar by cross section size 120 mm × 70 mm with application of Pro Cast 2010 software. The estimation of mould design effect on solidification process of continuos copper cast bar is completed at various speeds of casting.Profiles of liquid metal cavities and temperature allocations in the cast bar at various casting speeds are defined.The analysis of received liquid metal cavity profiles shows that a new mold construction allows significantly decrease of the length of the liquid metal cavity during continuous copper casting at HAZELETTcasting machine and the increase of maximum casting speed from 10 to 11 m / min. Adequacy of the results of copper continuous cast bar solidification process calculation is confirmed by the experimental data.