A new reaction-controlled phase-transfer catalyst system was designed and synthesized. In this system, heteropolytungstate [C7H7N(CH3)3]9PW9O34 was used for catalytic epoxidation of cyclohexene with H2O2 as the oxida...A new reaction-controlled phase-transfer catalyst system was designed and synthesized. In this system, heteropolytungstate [C7H7N(CH3)3]9PW9O34 was used for catalytic epoxidation of cyclohexene with H2O2 as the oxidant. The conversion of H2O2 was 100% and the yield of cyclohexene oxide was 87.1% based on cyclohexene. Infrared spectra showed that both fresh catalyst and the recovered catalyst do have completely same absorption peak, indicating the structure of catalyst is very stability and can be recycled.展开更多
As emerging artificial biomimetic membranes, smart or intelligent membranes that are able to respond to environmental stimuli are attracting ever-increasing interests from various fields. Their permeation properties i...As emerging artificial biomimetic membranes, smart or intelligent membranes that are able to respond to environmental stimuli are attracting ever-increasing interests from various fields. Their permeation properties including hydraulic permeability and diffusional permeability can be dramatically controlled or adjusted self-regulatively in response to small chemical and/or physical stimuli in their environments. Such environmental stimuli-responsive smart membranes could find myriad applications in numerous fields ranging from controlled release to separations. Here the trans-membrane mass-transfer and membrane separation is introduced as the beginning to initiate the requirement of smart membranes, and then bio-inspired design of environmental stimuli-responsive smart membranes and four essential elements for smart membranes are introduced and discussed. Next, smart membrane types and their applications as smart tools for controllable mass-transfer in controlled release and separations are reviewed. The research topics in the near future are also suggested.展开更多
To realize stable rotating spray transfer in the region of high constant current is the key of realizing high deposition rate MAG welding process without helium in shielding gas and extending the welding current rang...To realize stable rotating spray transfer in the region of high constant current is the key of realizing high deposition rate MAG welding process without helium in shielding gas and extending the welding current range of traditional MAG welding process. In this paper, the magnetic control mechanism of the rotating spray transfer is stated and mathematical model is given. Theoretic basis is established, which implements high deposition rate MAG welding process with magnetic control instead of helium in shielding gas.展开更多
A new kind of simple and flexible CO2 welding system was developed to carry out waveform control. The system consisted of IGBT inverter, PWM circuit and microprocessor unit ( MPU) , in which the output current of co...A new kind of simple and flexible CO2 welding system was developed to carry out waveform control. The system consisted of IGBT inverter, PWM circuit and microprocessor unit ( MPU) , in which the output current of constant current (CC) power supply could be changed according to transient physical state, and the variable down slope rate control could be used to ensure a stable welding process. The welding experiment results proved the effectiveness of this control approach.展开更多
A novel repetitive control strategy for the output waveform of single-phase CVCF inverters is presented. In this scheme, the inverse transfer function of inverter is used as a compensator to obtain stable and satisfy ...A novel repetitive control strategy for the output waveform of single-phase CVCF inverters is presented. In this scheme, the inverse transfer function of inverter is used as a compensator to obtain stable and satisfy harmonic rejection. Besides, PD controller is adopted to improve transient performance. Simulation and experimental results, which are gotten from a DSP-based 400Hz, 5.5KW inverter, indicate that the proposed control scheme can achieve not only low THD during steady-state operation but also fast transient response during load step change.展开更多
Based on the suitably defined multivariable version of Kranc operators and the extended input and output vectors, the multirate sampling plant is transformed to a equivalent time invariant single rate one, then the t...Based on the suitably defined multivariable version of Kranc operators and the extended input and output vectors, the multirate sampling plant is transformed to a equivalent time invariant single rate one, then the transfer function model of the multivariable multirate sampling plant is obtained. By combining this plant model with the time invariant description of the multirate controller in terms of extended vectors, the closed loop transfer function model of the multirate feedback control system can be determinated. This transfer function model has a very simple structure, and can be used as a basis for the analysis and synthesis of the multirate sampling feedback control systems in the frequency domain.展开更多
A new catalytic process for the synthesis of aldehyde from alcohol by oxidation with H202 with high selectivity, was studied. In this system, heteropolymolybdate [C7H7N(CH3)3]3 {PO4[MoO(O2)2]4} was utilized as the...A new catalytic process for the synthesis of aldehyde from alcohol by oxidation with H202 with high selectivity, was studied. In this system, heteropolymolybdate [C7H7N(CH3)3]3 {PO4[MoO(O2)2]4} was utilized as the reaction-controlled phase-transfer catalyst to catalyze oxidation of benzyl and aliphatic alcohols. The molar ratio of H2O2 and alcohol was 0.75, no other by-products were detected by gas chromatography, the results of oxidation reaction indicated that the catalyst has high activity and stability.展开更多
Multi-level pressure source system is a novel hydraulic system with distinct advantage of energy saving. In order to balance each pressure level of the multi-level pressure source system, a pump motor energy transfer ...Multi-level pressure source system is a novel hydraulic system with distinct advantage of energy saving. In order to balance each pressure level of the multi-level pressure source system, a pump motor energy transfer unit is usually equipped. However, the pump motor energy transfer has the characteristics of poor starting and low response, which cause long time of pressure adjustment and large pressure jitter when the transformer is switched to system suddenly and the motor-side pressure has pressure impact when rail of the pump-side is switched. To address these problems, this paper proposes a compound control strategy of feedforward compensation control with Fuzzy-PID to improve the controllability of the multi-level pressure source system. A test rig of the pump motor energy transfer unit is built and the controllability of compound controller and PID controller are compared. The experiment results show that, compared with the traditional PID, the adjustment time and the pressure impact are reduced by 20% and 25% with the proposed compound control strategy. Therefore, the presented compound control strategy can be used to improve starting performance and robustness of the pump motor energy transfer unit control system.展开更多
On the basis of the relationship between the Hamiltonian of spin 1/2 quantum system under control and the energy level structure and transitions, a radio frequency pulse sequence is designed using intuitive and half c...On the basis of the relationship between the Hamiltonian of spin 1/2 quantum system under control and the energy level structure and transitions, a radio frequency pulse sequence is designed using intuitive and half counter-intuitive sequences of pulse to transfer the population of the 3-qubit system coherently. The effectiveness of the designed control sequence is verified through the system simulation experiment of the evolution of state. In principle, the design method of the control pulse sequence proposed can be generalized to use in the quantum systems of higher dimension.展开更多
In this paper the definitions of generalized transfer functios of control system and itscontinuity are presented.Using generalized transfer function as a tool,a set of theorems fordeciding movement stability have been...In this paper the definitions of generalized transfer functios of control system and itscontinuity are presented.Using generalized transfer function as a tool,a set of theorems fordeciding movement stability have been constructed.Thus basing understanding of thecharacteristics of a control dynamics system on its measured procedure will simplify thedecision method of movement stability problems.展开更多
INTRODUCTION Group transfer polymerization (GTP) is a method for controlling the structure of acrylic polymers in which reactive chain ends are covalentiy bound to a trimethylsilyl group. In the presence of a catalyst...INTRODUCTION Group transfer polymerization (GTP) is a method for controlling the structure of acrylic polymers in which reactive chain ends are covalentiy bound to a trimethylsilyl group. In the presence of a catalyst, monomer inserts into these chain ends between the silyl group and the last monomer unit. The process is illustrated by equation (1) for methyl methacrylate. GTP is a living polymerization, i. e., there is little or no chain termination and no chain transfer. A significant advantage of GTP is that it展开更多
As different power has its own receivers,this paper analyzes and designs a multiple-receiver wireless power transfer(WPT)system systematically.The equivalent circuit model of the system is established to analyze the k...As different power has its own receivers,this paper analyzes and designs a multiple-receiver wireless power transfer(WPT)system systematically.The equivalent circuit model of the system is established to analyze the key parameters including transmitter power,receiver power,transmission efficiency,and each receiver power allocation.A control circuit is proposed to achieve the maximum transmission efficiency and transmitter power control and arbitrary receiver power allocation ratios for different receivers.Through the proposed control circuit,receivers with different loads can allocate appropriate power according to its power demand,the transmitter power and system efficiency do not vary with the change of the number of receivers.Finally,this control circuit is validated using a 130-kHz WPT system with three receivers whose power received is 3:10:12,and the overall system efficiency can reach as high as 55.5%.展开更多
A simulation system used in the arc welding short circuit transfer process and current waveform control process was developed in this paper. The simulation results are basically consistent with welding technical exper...A simulation system used in the arc welding short circuit transfer process and current waveform control process was developed in this paper. The simulation results are basically consistent with welding technical experiments. The simulation system can be used to simulate and test the current waveform control parameters with welding variables. By this simulation system, the influence regularities of the current waveform control parameters in the CO 2 arc welding droplet short circuit transfer process can be got. Moreover, the basic mode of real time current waveform control can be also established by the simulation testing.展开更多
This paper investigates an approach to improve the engagement quality of controlled transfer clutch mode in 4 wheel drive(WD) car from three considerations of reducing friction,smoothening responsiveness and alleviati...This paper investigates an approach to improve the engagement quality of controlled transfer clutch mode in 4 wheel drive(WD) car from three considerations of reducing friction,smoothening responsiveness and alleviating jerk.The method utilizes an improved sliding mode control with genetic algorithm instead of simplified mode to determine appropriate values of parameters in control close- loop.The simulation results show that the method is effective for improving the engagement quality of coupling satisfying different design needs for 4WD car,as well as robustness even if input torque is changed at a certain range.展开更多
A simulation model is introduced about the non-linearity process of short-circuiting transfer in CO2 arc welding for displaying the interaction between the inverter power source and welding arc under waveform control....A simulation model is introduced about the non-linearity process of short-circuiting transfer in CO2 arc welding for displaying the interaction between the inverter power source and welding arc under waveform control. In the simulation model, the feedback signals of current and voltage are taken respectively at the different phase in a short circuit periodic time and applied to the PWM (pulse width modulation) module in a model of inverter power source to control the output of power source. The simulation operation about the dynamic process of CO2 short-circuiting transfer welding is implemented on the founded simulation model with a peak arc current of 400 A and a peak voltage of 35 V, producing the dynamic arc waveforms which can embody the effect of inverter harmonic wave. The simulating waveforms are close to that of welding experiments.展开更多
In ACM'CCS 2009,Camenisch,et al.proposed the Oblivious Transfer with Access Control(AC-OT) in which each item is associated with an attribute set and can only be available,on request,to the users who have all the ...In ACM'CCS 2009,Camenisch,et al.proposed the Oblivious Transfer with Access Control(AC-OT) in which each item is associated with an attribute set and can only be available,on request,to the users who have all the attributes in the associated set.Namely,AC-OT achieves access control policy for conjunction of attributes.Essentially,the functionality of AC-OT is equivalent to the sim-plified version that we call AC-OT-SV:for each item,one attribute is associated with it,and it is requested that only the users who possess the associated attribute can obtain the item by queries.On one hand,AC-OT-SV is a special case of AC-OT when there is just one associated attribute with each item.On the other hand,any AC-OT can be realized by an AC-OT-SV.In this paper,we first present a concrete AC-OT-SV protocol which is proved to be secure in the model defined by Camenisch,et al..Then from the protocol,interestingly,a concrete Identity-Based Encryption(IBE) with Anonymous Key Issuing(AKI) is given which is just a direct application to AC-OT-SV.By comparison,we show that the AKI protocol we present is more efficient in communications than that proposed by Chow.展开更多
基金Supported by National Natural Science Foundation of P. R. China (60574083), Key Laboratory of Process Industry Automation, State Education Ministry of China (PAL200514)
文摘A new reaction-controlled phase-transfer catalyst system was designed and synthesized. In this system, heteropolytungstate [C7H7N(CH3)3]9PW9O34 was used for catalytic epoxidation of cyclohexene with H2O2 as the oxidant. The conversion of H2O2 was 100% and the yield of cyclohexene oxide was 87.1% based on cyclohexene. Infrared spectra showed that both fresh catalyst and the recovered catalyst do have completely same absorption peak, indicating the structure of catalyst is very stability and can be recycled.
基金Supported by the National Basic Research Program of China (2009CB623407), and the National Natural Science Foundation of China (20825622, 20806049, 20906064, 20990220, 21036002, 21076127, 21136006).
文摘As emerging artificial biomimetic membranes, smart or intelligent membranes that are able to respond to environmental stimuli are attracting ever-increasing interests from various fields. Their permeation properties including hydraulic permeability and diffusional permeability can be dramatically controlled or adjusted self-regulatively in response to small chemical and/or physical stimuli in their environments. Such environmental stimuli-responsive smart membranes could find myriad applications in numerous fields ranging from controlled release to separations. Here the trans-membrane mass-transfer and membrane separation is introduced as the beginning to initiate the requirement of smart membranes, and then bio-inspired design of environmental stimuli-responsive smart membranes and four essential elements for smart membranes are introduced and discussed. Next, smart membrane types and their applications as smart tools for controllable mass-transfer in controlled release and separations are reviewed. The research topics in the near future are also suggested.
文摘To realize stable rotating spray transfer in the region of high constant current is the key of realizing high deposition rate MAG welding process without helium in shielding gas and extending the welding current range of traditional MAG welding process. In this paper, the magnetic control mechanism of the rotating spray transfer is stated and mathematical model is given. Theoretic basis is established, which implements high deposition rate MAG welding process with magnetic control instead of helium in shielding gas.
基金Supported by Research Project of Henan Science and Technology Foundation(0124110209,0211061900).
文摘A new kind of simple and flexible CO2 welding system was developed to carry out waveform control. The system consisted of IGBT inverter, PWM circuit and microprocessor unit ( MPU) , in which the output current of constant current (CC) power supply could be changed according to transient physical state, and the variable down slope rate control could be used to ensure a stable welding process. The welding experiment results proved the effectiveness of this control approach.
基金This work was supported by the National Natural Science Foundation of China (No. 50007004)
文摘A novel repetitive control strategy for the output waveform of single-phase CVCF inverters is presented. In this scheme, the inverse transfer function of inverter is used as a compensator to obtain stable and satisfy harmonic rejection. Besides, PD controller is adopted to improve transient performance. Simulation and experimental results, which are gotten from a DSP-based 400Hz, 5.5KW inverter, indicate that the proposed control scheme can achieve not only low THD during steady-state operation but also fast transient response during load step change.
文摘Based on the suitably defined multivariable version of Kranc operators and the extended input and output vectors, the multirate sampling plant is transformed to a equivalent time invariant single rate one, then the transfer function model of the multivariable multirate sampling plant is obtained. By combining this plant model with the time invariant description of the multirate controller in terms of extended vectors, the closed loop transfer function model of the multirate feedback control system can be determinated. This transfer function model has a very simple structure, and can be used as a basis for the analysis and synthesis of the multirate sampling feedback control systems in the frequency domain.
文摘A new catalytic process for the synthesis of aldehyde from alcohol by oxidation with H202 with high selectivity, was studied. In this system, heteropolymolybdate [C7H7N(CH3)3]3 {PO4[MoO(O2)2]4} was utilized as the reaction-controlled phase-transfer catalyst to catalyze oxidation of benzyl and aliphatic alcohols. The molar ratio of H2O2 and alcohol was 0.75, no other by-products were detected by gas chromatography, the results of oxidation reaction indicated that the catalyst has high activity and stability.
基金Supported by the National Natural Science Foundation of China(No.51575471)the Key Project of Science and Technology Plan of Higher Education of Hebei Education Department(No.ZD2017077)
文摘Multi-level pressure source system is a novel hydraulic system with distinct advantage of energy saving. In order to balance each pressure level of the multi-level pressure source system, a pump motor energy transfer unit is usually equipped. However, the pump motor energy transfer has the characteristics of poor starting and low response, which cause long time of pressure adjustment and large pressure jitter when the transformer is switched to system suddenly and the motor-side pressure has pressure impact when rail of the pump-side is switched. To address these problems, this paper proposes a compound control strategy of feedforward compensation control with Fuzzy-PID to improve the controllability of the multi-level pressure source system. A test rig of the pump motor energy transfer unit is built and the controllability of compound controller and PID controller are compared. The experiment results show that, compared with the traditional PID, the adjustment time and the pressure impact are reduced by 20% and 25% with the proposed compound control strategy. Therefore, the presented compound control strategy can be used to improve starting performance and robustness of the pump motor energy transfer unit control system.
基金supported by the National Natural Science Foundation of China (60774098)the National Key Basic Research Program (2006922004)
文摘On the basis of the relationship between the Hamiltonian of spin 1/2 quantum system under control and the energy level structure and transitions, a radio frequency pulse sequence is designed using intuitive and half counter-intuitive sequences of pulse to transfer the population of the 3-qubit system coherently. The effectiveness of the designed control sequence is verified through the system simulation experiment of the evolution of state. In principle, the design method of the control pulse sequence proposed can be generalized to use in the quantum systems of higher dimension.
文摘In this paper the definitions of generalized transfer functios of control system and itscontinuity are presented.Using generalized transfer function as a tool,a set of theorems fordeciding movement stability have been constructed.Thus basing understanding of thecharacteristics of a control dynamics system on its measured procedure will simplify thedecision method of movement stability problems.
文摘INTRODUCTION Group transfer polymerization (GTP) is a method for controlling the structure of acrylic polymers in which reactive chain ends are covalentiy bound to a trimethylsilyl group. In the presence of a catalyst, monomer inserts into these chain ends between the silyl group and the last monomer unit. The process is illustrated by equation (1) for methyl methacrylate. GTP is a living polymerization, i. e., there is little or no chain termination and no chain transfer. A significant advantage of GTP is that it
基金supported by the National Natural Science Foundation of China under Grant No.51574198Nanchong City 2018 Special Fund for City-School Cooperation under Grant No.18SXHZ0021
文摘As different power has its own receivers,this paper analyzes and designs a multiple-receiver wireless power transfer(WPT)system systematically.The equivalent circuit model of the system is established to analyze the key parameters including transmitter power,receiver power,transmission efficiency,and each receiver power allocation.A control circuit is proposed to achieve the maximum transmission efficiency and transmitter power control and arbitrary receiver power allocation ratios for different receivers.Through the proposed control circuit,receivers with different loads can allocate appropriate power according to its power demand,the transmitter power and system efficiency do not vary with the change of the number of receivers.Finally,this control circuit is validated using a 130-kHz WPT system with three receivers whose power received is 3:10:12,and the overall system efficiency can reach as high as 55.5%.
文摘A simulation system used in the arc welding short circuit transfer process and current waveform control process was developed in this paper. The simulation results are basically consistent with welding technical experiments. The simulation system can be used to simulate and test the current waveform control parameters with welding variables. By this simulation system, the influence regularities of the current waveform control parameters in the CO 2 arc welding droplet short circuit transfer process can be got. Moreover, the basic mode of real time current waveform control can be also established by the simulation testing.
文摘This paper investigates an approach to improve the engagement quality of controlled transfer clutch mode in 4 wheel drive(WD) car from three considerations of reducing friction,smoothening responsiveness and alleviating jerk.The method utilizes an improved sliding mode control with genetic algorithm instead of simplified mode to determine appropriate values of parameters in control close- loop.The simulation results show that the method is effective for improving the engagement quality of coupling satisfying different design needs for 4WD car,as well as robustness even if input torque is changed at a certain range.
基金Supported by National Natural Science Foundation of China ( No59975068)Natural Science Foundation of Tianjin ( No993602911)
文摘A simulation model is introduced about the non-linearity process of short-circuiting transfer in CO2 arc welding for displaying the interaction between the inverter power source and welding arc under waveform control. In the simulation model, the feedback signals of current and voltage are taken respectively at the different phase in a short circuit periodic time and applied to the PWM (pulse width modulation) module in a model of inverter power source to control the output of power source. The simulation operation about the dynamic process of CO2 short-circuiting transfer welding is implemented on the founded simulation model with a peak arc current of 400 A and a peak voltage of 35 V, producing the dynamic arc waveforms which can embody the effect of inverter harmonic wave. The simulating waveforms are close to that of welding experiments.
文摘In ACM'CCS 2009,Camenisch,et al.proposed the Oblivious Transfer with Access Control(AC-OT) in which each item is associated with an attribute set and can only be available,on request,to the users who have all the attributes in the associated set.Namely,AC-OT achieves access control policy for conjunction of attributes.Essentially,the functionality of AC-OT is equivalent to the sim-plified version that we call AC-OT-SV:for each item,one attribute is associated with it,and it is requested that only the users who possess the associated attribute can obtain the item by queries.On one hand,AC-OT-SV is a special case of AC-OT when there is just one associated attribute with each item.On the other hand,any AC-OT can be realized by an AC-OT-SV.In this paper,we first present a concrete AC-OT-SV protocol which is proved to be secure in the model defined by Camenisch,et al..Then from the protocol,interestingly,a concrete Identity-Based Encryption(IBE) with Anonymous Key Issuing(AKI) is given which is just a direct application to AC-OT-SV.By comparison,we show that the AKI protocol we present is more efficient in communications than that proposed by Chow.