Energy conversion in micro/nano-systems is a subject of current research,among which the electrokinetic energy conversion has attracted extensive attention.However,there exist two different definitions on the electrok...Energy conversion in micro/nano-systems is a subject of current research,among which the electrokinetic energy conversion has attracted extensive attention.However,there exist two different definitions on the electrokinetic energy conversion efficiency in literature.A few researchers defined the efficiency using the pure pressure-driven flow rate,while other groups defined the efficiency based on the flow rate with the inclusion of the effect of the streaming potential field.In this work,both definitions are investigated for different fluid types under the periodic electrokinetic flow condition.For Newtonian fluids,the two definitions give similar results.However,for viscoelastic fluids,these two definitions lead to significant difference.The efficiency defined by the pure pressure-driven flow rate even exceeds 100%in a certain range of the parameters.The result shows that in the case of viscoelastic flow,it is incorrect to define the energy conversion efficiency by pure pressure-driven flow rate.At the same time,the reason for this problem is clarified through comprehensive analysis.展开更多
Nowadays, urban transit system has become one of the major forces underlying urban pace transformation via changing accessibility of related land parcels, which leads to the changes of land value and land use structur...Nowadays, urban transit system has become one of the major forces underlying urban pace transformation via changing accessibility of related land parcels, which leads to the changes of land value and land use structure. This paper studied the interaction between land use changes and related transport routes, particular about how different transport routes and road nodes influence the conversion of industrial lands to residential and commercial uses respectively. Taking Changchun, an old industrial city in the rust belt of China as a case of study, we explored and compared the influences of different transport routes and road nodes on industrial land conversion. We found that surrounding the studied transport routes, more industrial lands were replaced by residential lands than by commercial lands. Also, apparent differences exist in the corridor effects of different transport routes(i.e., light rail, expressway and trunk road) and road nodes(i.e., expressway nodes and trunk road nodes) while the industrial lands convert to residential and commercial uses. Our research findings help us to illuminate the interactive relationships between transportation and industrial land conversion in old industrial cities which are undergoing social, economic and the related urban transition in Northeast China.展开更多
Nanostructured TiO2 with differentiate morphologies has attracted tremendous attention due to its wide band-gap nature as well as outstanding optical and electric properties for solar-driven light-toelectricity conver...Nanostructured TiO2 with differentiate morphologies has attracted tremendous attention due to its wide band-gap nature as well as outstanding optical and electric properties for solar-driven light-toelectricity conversion application. Layered-stacking TiO2 film such as double-layer, tri-layer, quadrupleor quintuplicate-layer, is highly desirable to the design of high-performance semiconductor material photoanodes and the development of advanced photovoltaic devices. In this minireview, we will summarize the recent progress and achievements on proof-of-concept of layered-stacking TiO2 films（LTFs） for solar cells with emphasis on the tailored properties and synergistic functionalization of LTFs, such as optimized sensitizer adsorption, broadened light confinement as well as facilitated electron transport characteristics.Various demonstrations of LTFs photovoltaic systems provide lots of possibilities and flexibilities for more efficient solar energy utilization that a wide variety of TiO2 with distinguished morphologies can be integrated into differently structured photoanodes with synergistic and complementary advantages. This key structure engineering technology will also pave the way for the development of next generation state-ofthe-art electronics and optoelectronics. Finally, from our point of view, we conclude the future research interest and efforts for constructing more efficient LTFs as photoelectrode, which will be highly warranted to advance the solar energy conversion process.展开更多
In nuclear collisions at RHIC energies, an excess of Ω hyperons over ■ is observed, indicating that Ω has a net baryon number despite s and s quarks being produced in pairs. The baryon number in Ω may have been tr...In nuclear collisions at RHIC energies, an excess of Ω hyperons over ■ is observed, indicating that Ω has a net baryon number despite s and s quarks being produced in pairs. The baryon number in Ω may have been transported from the incident nuclei and/or produced in the baryon-pair production of Ω with other types of anti-hyperons such as Ξ. To investigate these two scenarios, we propose to measure the correlations between Ω and K and between Ω and anti-hyperons. We use two versions, the default and string-melting, of a multiphase transport(AMPT) model to illustrate the method for measuring the correlation and to demonstrate the general shape of the correlation. We present the Ω-hadron correlations from simulated Au+Au collisions at ■ =7.7 and 14.6 Ge V and discuss the dependence on the collision energy and on the hadronization scheme in these two AMPT versions. These correlations can be used to explore the mechanism of baryon number transport and the effects of baryon number and strangeness conservation on nuclear collisions.展开更多
Self-assembled monolayers(SAMs)have recently emerged as excellent hole transport materials in inverted perovskite solar cells(PSCs)owing to their ability to minimize parasitic absorption,regulate energy level alignmen...Self-assembled monolayers(SAMs)have recently emerged as excellent hole transport materials in inverted perovskite solar cells(PSCs)owing to their ability to minimize parasitic absorption,regulate energy level alignment,and passivate perovskite defects.Herein,we design and synthesize a novel dimethyl acridinebased SAM,[2-(9,10-dihydro-9,9-dimethylacridine-10-yl)ethyl]phosphonic acid(2PADmA),and employ it as a hole-transporting layer in inverted PSCs.Experimental results show that the 2PADmA SAM can modulate perovskite crystallization,facilitate carrier transport,passivate perovskite defects,and reduce nonradiative recombination.Consequently,the 2PADmA-based device achieves an enhanced power conversion efficiency(PCE)of 24.01%and an improved fill factor(FF)of 83.92%compared to the commonly reported[2-(9H-carbazol-9-yl)ethyl]phosphonic acid(2PACz)-based control device with a PCE of 22.32%and FF of 78.42%,while both devices exhibit comparable open-circuit voltage and short-circuit current density.In addition,2PADmA-based devices exhibit outstanding dark storage and thermal stabilities,retaining approximately~98%and 87%of their initial PCEs after 1080 h of dark storage and 400 h of heating at 85°C,respectively,both considerably superior to the control device.展开更多
Recent advancements in perovskites’ application as a solar energy harvester have been astonishing. The power conversion efficiency(PCE) of perovskite solar cells(PSCs) is currently reaching parity(>25 percent), an...Recent advancements in perovskites’ application as a solar energy harvester have been astonishing. The power conversion efficiency(PCE) of perovskite solar cells(PSCs) is currently reaching parity(>25 percent), an accomplishment attained over past decades. PSCs are seen as perovskites sandwiched between an electron transporting material(ETM) and a hole transporting material(HTM). As a primary component of PSCs, HTM has been shown to have a considerable effect on solar energy harvesting, carrier extraction and transport, crystallization of perovskite, stability, and price. In PSCs, it is still necessary to use a HTM.While perovskites are capable of conducting holes, they are present in trace amounts, necessitating the use of an HTM layer for efficient charge extraction. In this review, we provide an understanding of the significant forms of HTM accessible(inorganic, polymeric and small molecule-based HTMs), to motivate further research and development of such materials. The identification of additional criteria suggests a significant challenge to high stability and affordability in PSC.展开更多
In the electrochemical conversion of carbon dioxide, high currents need to be employed to obtain large production rates, thus implying that mass transport of reactants and products is of crucial importance.This aspect...In the electrochemical conversion of carbon dioxide, high currents need to be employed to obtain large production rates, thus implying that mass transport of reactants and products is of crucial importance.This aspect can be investigated by employing a model that depicts the local environment for the reduction reactions. Simultaneously, electrochemical impedance spectroscopy, despite being a versatile technique, has rarely been adopted for studying the mass transport features during the carbon dioxide(CO_(2))electroreduction. In this work, this aspect is deeply analyzed by correlating the results of impedance spectroscopy characterization with those obtained by a bubble-induced mass transport modeling under controlled diffusion conditions on a gold rotating disk electrode. The effects of potential and rotation rate on the local environment are also clarified. In particular, it has been found that CO_(2) depletion occurs at high kinetics when the rotation is absent, giving rise to an increment of the competing hydrogen evolution reaction. This feature reflects in an enlargement of the diffusion resistance, which overcomes the charge transport one.展开更多
Titanylphthalocyanine （TiOPc） as hole transporting material （HTM） was successfully synthesized by a simple process with low cost. Perovskite solar cells using the TiOPc as HTM were fabricated and characterized. Ti...Titanylphthalocyanine （TiOPc） as hole transporting material （HTM） was successfully synthesized by a simple process with low cost. Perovskite solar cells using the TiOPc as HTM were fabricated and characterized. TiOPc as HTM plays an important role in increasing the power conversion efficiency （PCE） by minimizing recombi- nation losses at the perovskite/Au interface because TiOPc as HTM can extract photogenerated holes from the perovskite and then transport quickly these charges to the back metal electrode. In the research, the β-TiOPc gives a higher PCE than α-TiOPc for the devices due to sufficient transfer dynamics, The β-TiOPc was applied in perovskite solar cells without clopping to afford an impressive PCE of 5.05% under AM 1.5G illumination at the thickness of 40 nm which is competitive with spiro-OMeTAD at the same condition. The present work suggests a guideline for optimizing the photovoltaic properties ofperovskite solar cells using the TiOPc as the HTM.展开更多
Osmotic energy from the ocean,also called blue energy,serves as a clean,renewable,and vast energy source for the energy demands of the world.Reverse electrodialysis-based blue energy harvesting via ion-selective membr...Osmotic energy from the ocean,also called blue energy,serves as a clean,renewable,and vast energy source for the energy demands of the world.Reverse electrodialysis-based blue energy harvesting via ion-selective membranes,by the regulation and manipulation of directional ion transport,has been greatly developed recently.In particular,light has been employed to enhance directional ion transport for energy conversion through an increase in photo-induced surface charge.Here,the authors demonstrate a novel nanofluidic regulation strategy based on the phenomenon of light-induced heat-driven active ion transport through the lamellar MXene membrane.Due to the great light-induced heat effect,a temperature gradient appears as soon as illumination is applied to an off-center position,inducing an actively temperature gradient-driven ionic species transport.By employing this phenomenon,the authors conducted light-induced heat-enhanced osmotic energy conversion and doubled the osmotic energy conversion power density.This study has extended the scope of light-enhanced osmotic energy conversion and could further bring other photothermal materials into this field.Furthermore,the proposed system provides a new avenue of light-controlled ionic transport for ion gathering,desalination,and energy conversion applications.展开更多
基金Project supported by the National Natural Science Foundation of China(Nos.11902165,11772162,and 11862018)the Natural Science Foundation of Inner Mongolia Autonomous Region of China(Nos.2019BS01004 and 2021MS01007)the Inner Mongolia Grassland Talent(No.12000-12102013)。
文摘Energy conversion in micro/nano-systems is a subject of current research,among which the electrokinetic energy conversion has attracted extensive attention.However,there exist two different definitions on the electrokinetic energy conversion efficiency in literature.A few researchers defined the efficiency using the pure pressure-driven flow rate,while other groups defined the efficiency based on the flow rate with the inclusion of the effect of the streaming potential field.In this work,both definitions are investigated for different fluid types under the periodic electrokinetic flow condition.For Newtonian fluids,the two definitions give similar results.However,for viscoelastic fluids,these two definitions lead to significant difference.The efficiency defined by the pure pressure-driven flow rate even exceeds 100%in a certain range of the parameters.The result shows that in the case of viscoelastic flow,it is incorrect to define the energy conversion efficiency by pure pressure-driven flow rate.At the same time,the reason for this problem is clarified through comprehensive analysis.
基金Under the auspices of National Natural Science Foundation of China(No.41871158)。
文摘Nowadays, urban transit system has become one of the major forces underlying urban pace transformation via changing accessibility of related land parcels, which leads to the changes of land value and land use structure. This paper studied the interaction between land use changes and related transport routes, particular about how different transport routes and road nodes influence the conversion of industrial lands to residential and commercial uses respectively. Taking Changchun, an old industrial city in the rust belt of China as a case of study, we explored and compared the influences of different transport routes and road nodes on industrial land conversion. We found that surrounding the studied transport routes, more industrial lands were replaced by residential lands than by commercial lands. Also, apparent differences exist in the corridor effects of different transport routes(i.e., light rail, expressway and trunk road) and road nodes(i.e., expressway nodes and trunk road nodes) while the industrial lands convert to residential and commercial uses. Our research findings help us to illuminate the interactive relationships between transportation and industrial land conversion in old industrial cities which are undergoing social, economic and the related urban transition in Northeast China.
基金the financial supports from the NSFC(51472274)the GDUPS(2016)+2 种基金the program of Guangzhou Science and Technology Project(201504010031)the NSF of Guangdong Province(S2013030013474)the Fundamental Research Funds for the Central Universities
文摘Nanostructured TiO2 with differentiate morphologies has attracted tremendous attention due to its wide band-gap nature as well as outstanding optical and electric properties for solar-driven light-toelectricity conversion application. Layered-stacking TiO2 film such as double-layer, tri-layer, quadrupleor quintuplicate-layer, is highly desirable to the design of high-performance semiconductor material photoanodes and the development of advanced photovoltaic devices. In this minireview, we will summarize the recent progress and achievements on proof-of-concept of layered-stacking TiO2 films（LTFs） for solar cells with emphasis on the tailored properties and synergistic functionalization of LTFs, such as optimized sensitizer adsorption, broadened light confinement as well as facilitated electron transport characteristics.Various demonstrations of LTFs photovoltaic systems provide lots of possibilities and flexibilities for more efficient solar energy utilization that a wide variety of TiO2 with distinguished morphologies can be integrated into differently structured photoanodes with synergistic and complementary advantages. This key structure engineering technology will also pave the way for the development of next generation state-ofthe-art electronics and optoelectronics. Finally, from our point of view, we conclude the future research interest and efforts for constructing more efficient LTFs as photoelectrode, which will be highly warranted to advance the solar energy conversion process.
文摘In nuclear collisions at RHIC energies, an excess of Ω hyperons over ■ is observed, indicating that Ω has a net baryon number despite s and s quarks being produced in pairs. The baryon number in Ω may have been transported from the incident nuclei and/or produced in the baryon-pair production of Ω with other types of anti-hyperons such as Ξ. To investigate these two scenarios, we propose to measure the correlations between Ω and K and between Ω and anti-hyperons. We use two versions, the default and string-melting, of a multiphase transport(AMPT) model to illustrate the method for measuring the correlation and to demonstrate the general shape of the correlation. We present the Ω-hadron correlations from simulated Au+Au collisions at ■ =7.7 and 14.6 Ge V and discuss the dependence on the collision energy and on the hadronization scheme in these two AMPT versions. These correlations can be used to explore the mechanism of baryon number transport and the effects of baryon number and strangeness conservation on nuclear collisions.
基金National Natural Science Foundation of China(Grant Nos.51925206,52302052)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB0450301)+1 种基金Yunnan Provincial Science and Technology Project at Southwest United Graduate School(Grant No.202302AO370013)Huacai Solar Co.,Ltd.
文摘Self-assembled monolayers(SAMs)have recently emerged as excellent hole transport materials in inverted perovskite solar cells(PSCs)owing to their ability to minimize parasitic absorption,regulate energy level alignment,and passivate perovskite defects.Herein,we design and synthesize a novel dimethyl acridinebased SAM,[2-(9,10-dihydro-9,9-dimethylacridine-10-yl)ethyl]phosphonic acid(2PADmA),and employ it as a hole-transporting layer in inverted PSCs.Experimental results show that the 2PADmA SAM can modulate perovskite crystallization,facilitate carrier transport,passivate perovskite defects,and reduce nonradiative recombination.Consequently,the 2PADmA-based device achieves an enhanced power conversion efficiency(PCE)of 24.01%and an improved fill factor(FF)of 83.92%compared to the commonly reported[2-(9H-carbazol-9-yl)ethyl]phosphonic acid(2PACz)-based control device with a PCE of 22.32%and FF of 78.42%,while both devices exhibit comparable open-circuit voltage and short-circuit current density.In addition,2PADmA-based devices exhibit outstanding dark storage and thermal stabilities,retaining approximately~98%and 87%of their initial PCEs after 1080 h of dark storage and 400 h of heating at 85°C,respectively,both considerably superior to the control device.
文摘Recent advancements in perovskites’ application as a solar energy harvester have been astonishing. The power conversion efficiency(PCE) of perovskite solar cells(PSCs) is currently reaching parity(>25 percent), an accomplishment attained over past decades. PSCs are seen as perovskites sandwiched between an electron transporting material(ETM) and a hole transporting material(HTM). As a primary component of PSCs, HTM has been shown to have a considerable effect on solar energy harvesting, carrier extraction and transport, crystallization of perovskite, stability, and price. In PSCs, it is still necessary to use a HTM.While perovskites are capable of conducting holes, they are present in trace amounts, necessitating the use of an HTM layer for efficient charge extraction. In this review, we provide an understanding of the significant forms of HTM accessible(inorganic, polymeric and small molecule-based HTMs), to motivate further research and development of such materials. The identification of additional criteria suggests a significant challenge to high stability and affordability in PSC.
文摘In the electrochemical conversion of carbon dioxide, high currents need to be employed to obtain large production rates, thus implying that mass transport of reactants and products is of crucial importance.This aspect can be investigated by employing a model that depicts the local environment for the reduction reactions. Simultaneously, electrochemical impedance spectroscopy, despite being a versatile technique, has rarely been adopted for studying the mass transport features during the carbon dioxide(CO_(2))electroreduction. In this work, this aspect is deeply analyzed by correlating the results of impedance spectroscopy characterization with those obtained by a bubble-induced mass transport modeling under controlled diffusion conditions on a gold rotating disk electrode. The effects of potential and rotation rate on the local environment are also clarified. In particular, it has been found that CO_(2) depletion occurs at high kinetics when the rotation is absent, giving rise to an increment of the competing hydrogen evolution reaction. This feature reflects in an enlargement of the diffusion resistance, which overcomes the charge transport one.
基金supported by the National Nature Science Foundation of China (NO.21206110)Tianjin Science and Technology Support Plan Key Projects (NO.13ZCZDGX00900)
文摘Titanylphthalocyanine （TiOPc） as hole transporting material （HTM） was successfully synthesized by a simple process with low cost. Perovskite solar cells using the TiOPc as HTM were fabricated and characterized. TiOPc as HTM plays an important role in increasing the power conversion efficiency （PCE） by minimizing recombi- nation losses at the perovskite/Au interface because TiOPc as HTM can extract photogenerated holes from the perovskite and then transport quickly these charges to the back metal electrode. In the research, the β-TiOPc gives a higher PCE than α-TiOPc for the devices due to sufficient transfer dynamics, The β-TiOPc was applied in perovskite solar cells without clopping to afford an impressive PCE of 5.05% under AM 1.5G illumination at the thickness of 40 nm which is competitive with spiro-OMeTAD at the same condition. The present work suggests a guideline for optimizing the photovoltaic properties ofperovskite solar cells using the TiOPc as the HTM.
基金This study was supported by the National Key R&D Program of China(nos.2017YFA0206904 and 2017YFA0206900)the National Natural Science Foundation of China(nos.21625303,21905287,51673206,and 21988102)+2 种基金the Beijing Natural Science Foundation(no.2194088)the Strategic Priority Research Program of the Chinese Academy of Science(no.XDA21010213)the Key Research Program of the Chinese Academy of Sciences(no.QYZDY-SSW-SLH014).
文摘Osmotic energy from the ocean,also called blue energy,serves as a clean,renewable,and vast energy source for the energy demands of the world.Reverse electrodialysis-based blue energy harvesting via ion-selective membranes,by the regulation and manipulation of directional ion transport,has been greatly developed recently.In particular,light has been employed to enhance directional ion transport for energy conversion through an increase in photo-induced surface charge.Here,the authors demonstrate a novel nanofluidic regulation strategy based on the phenomenon of light-induced heat-driven active ion transport through the lamellar MXene membrane.Due to the great light-induced heat effect,a temperature gradient appears as soon as illumination is applied to an off-center position,inducing an actively temperature gradient-driven ionic species transport.By employing this phenomenon,the authors conducted light-induced heat-enhanced osmotic energy conversion and doubled the osmotic energy conversion power density.This study has extended the scope of light-enhanced osmotic energy conversion and could further bring other photothermal materials into this field.Furthermore,the proposed system provides a new avenue of light-controlled ionic transport for ion gathering,desalination,and energy conversion applications.
