The optical properties of coatings pigmented with different black colorants were systematically investigated and their surface temperatures and cooling energy savings were estimated. The black coatings pigmented with ...The optical properties of coatings pigmented with different black colorants were systematically investigated and their surface temperatures and cooling energy savings were estimated. The black coatings pigmented with chromite iron nickel black and manganese ferrite black spinel colorants are not cool enough to be energy efficient cool black coatings. The cool black coatings pigmented with NIR-transmitting perylene black and dioxazine purple colorants possess a green shade and a violet shade, respectively. The estimated surface temperature reduction values and annual cooling energy savings in Beijing range from 3.0°C and 1.21 kWhm-2yr-1 for the black coating pigmented with chromite iron nickel colorant to 13.8°C and 5.52 kWhm-2yr-1 for the black coating pigmented with dioxazine purple colorant, respectively.展开更多
Environment-friendly pigments based on AFeO_(3)(A=La,Pr,Nd,Sm,Gd,Tb,Y or Yb)with high nearinfrared(NIR)reflectance were synthesised by a coprecipitation method at 1200℃.The Rietveld refinement analysis showed single-...Environment-friendly pigments based on AFeO_(3)(A=La,Pr,Nd,Sm,Gd,Tb,Y or Yb)with high nearinfrared(NIR)reflectance were synthesised by a coprecipitation method at 1200℃.The Rietveld refinement analysis showed single-phase orthorhombic perovskite for all compositions.All pigments,which showed reddish hues,offered good colour stability after mixing these pigments in powder form with siloxane transparent paint and two different glazes.The powderepaint mixtures produced with GdFeO_(3),TbFeO_(3) and YFeO_(3) pigments have the highest NIR solar reflectance,reaching values of R=50%.The temperature shielding studies conducted using TbFeO_(3) pigmentepaint mixture for a roof coating yielded a reduction of 3.2℃ in comparison to a commercial pigment.Moreover,the glazes that were pigmented using GdFeO_(3),TbFeO_(3) and YFeO_(3) compositions also presented the most intense reddish colours.A study of the thermal and chemical stability of the pigment with the highest NIR solar reflectance showed good stability in both cases.The reddish pigments that were prepared can therefore be good candidates for use in different applications such as cool pigments or pigments for ceramic glazes at high temperatures.展开更多
文摘The optical properties of coatings pigmented with different black colorants were systematically investigated and their surface temperatures and cooling energy savings were estimated. The black coatings pigmented with chromite iron nickel black and manganese ferrite black spinel colorants are not cool enough to be energy efficient cool black coatings. The cool black coatings pigmented with NIR-transmitting perylene black and dioxazine purple colorants possess a green shade and a violet shade, respectively. The estimated surface temperature reduction values and annual cooling energy savings in Beijing range from 3.0°C and 1.21 kWhm-2yr-1 for the black coating pigmented with chromite iron nickel colorant to 13.8°C and 5.52 kWhm-2yr-1 for the black coating pigmented with dioxazine purple colorant, respectively.
基金Project(11204304)supported by the National Natural Science Foundation of ChinaProject(2013CB632600)supported by the National Basic Research Program of ChinaProject(2011AA060702)supported by the National High-tech Research and Development Program of China
基金Authors thanks the Universitat Jaume I[UJI-B2019-41]the Ministerio de Economía,Industria y Competitividad[MAT2016-80410-P]for financial support.
文摘Environment-friendly pigments based on AFeO_(3)(A=La,Pr,Nd,Sm,Gd,Tb,Y or Yb)with high nearinfrared(NIR)reflectance were synthesised by a coprecipitation method at 1200℃.The Rietveld refinement analysis showed single-phase orthorhombic perovskite for all compositions.All pigments,which showed reddish hues,offered good colour stability after mixing these pigments in powder form with siloxane transparent paint and two different glazes.The powderepaint mixtures produced with GdFeO_(3),TbFeO_(3) and YFeO_(3) pigments have the highest NIR solar reflectance,reaching values of R=50%.The temperature shielding studies conducted using TbFeO_(3) pigmentepaint mixture for a roof coating yielded a reduction of 3.2℃ in comparison to a commercial pigment.Moreover,the glazes that were pigmented using GdFeO_(3),TbFeO_(3) and YFeO_(3) compositions also presented the most intense reddish colours.A study of the thermal and chemical stability of the pigment with the highest NIR solar reflectance showed good stability in both cases.The reddish pigments that were prepared can therefore be good candidates for use in different applications such as cool pigments or pigments for ceramic glazes at high temperatures.