A new one-dimensional Mg（Ⅱ） coordination polymer, [Mg（L）（phen）（H2O）]（1）, has been hydrothermally synthesized by using 3,5-dinitro-salicylic acid（H2L） and 1,10-phenanthroline（phen）. It crystallizes in mo...A new one-dimensional Mg（Ⅱ） coordination polymer, [Mg（L）（phen）（H2O）]（1）, has been hydrothermally synthesized by using 3,5-dinitro-salicylic acid（H2L） and 1,10-phenanthroline（phen）. It crystallizes in monoclinic, space group C2/c with a = 33.038（7）, b = 6.6481（13）, c = 22.750（5） A, β = 126.99（3）°, V = 3991.1（14） A3, Z = 8, C19H12 MgN4O8, Mr = 448.64, Dc = 1.493 g/cm3, F（000） = 1840, μ（Mo Ka） = 0.146 mm-1, R = 0.0559 and w R = 0.0975. In 1, each L anion bridges two Mg（Ⅱ） atoms to give one-dimensional zigzag chains with the Mg…Mg separation of 5.34 ？, which are extended by π-π stacking interactions between 1,10-phenanthroline ligands into a two-dimensional supramolecular layer. Moreover, the O–H…O hydrogen-bonding interactions further stabilize the layer structure of 1. The luminescent property was also studied for 1 in solid state at room temperature. In addition, natural bond orbital（NBO） analysis was performed by the B3LYP/LANL2 DZ method in Gaussian 09 Program. The calculation results show obvious covalent interaction between the coordinated atoms and Mg（Ⅱ） ion.展开更多
We propose a novel binary image representation algorithm using the non-symmetry and anti-packing model and the coordinate encoding procedure （NAMCEP）. By tak- ing some idiomatic standard binary images in the field o...We propose a novel binary image representation algorithm using the non-symmetry and anti-packing model and the coordinate encoding procedure （NAMCEP）. By tak- ing some idiomatic standard binary images in the field of image processing as typical test objects, and by comparing our proposed NAMCEP representation with linear quadtree （LQT）, binary tree （Bintree）, non-symmetry and anti-packing model （NAM） with K-lines （NAMK）, and NAM representa- tions, we show that NAMCEP can not only reduce the aver- age node, but also simultaneously improve the average com- pression. We also present a novel NAMCEP-based algorithm for area calculation and show experimentally that our algo- rithm offers significant improvements.展开更多
基金Supported by the Science and Technology Development Projects of Jilin Province(No.20150101007JC)
文摘A new one-dimensional Mg（Ⅱ） coordination polymer, [Mg（L）（phen）（H2O）]（1）, has been hydrothermally synthesized by using 3,5-dinitro-salicylic acid（H2L） and 1,10-phenanthroline（phen）. It crystallizes in monoclinic, space group C2/c with a = 33.038（7）, b = 6.6481（13）, c = 22.750（5） A, β = 126.99（3）°, V = 3991.1（14） A3, Z = 8, C19H12 MgN4O8, Mr = 448.64, Dc = 1.493 g/cm3, F（000） = 1840, μ（Mo Ka） = 0.146 mm-1, R = 0.0559 and w R = 0.0975. In 1, each L anion bridges two Mg（Ⅱ） atoms to give one-dimensional zigzag chains with the Mg…Mg separation of 5.34 ？, which are extended by π-π stacking interactions between 1,10-phenanthroline ligands into a two-dimensional supramolecular layer. Moreover, the O–H…O hydrogen-bonding interactions further stabilize the layer structure of 1. The luminescent property was also studied for 1 in solid state at room temperature. In addition, natural bond orbital（NBO） analysis was performed by the B3LYP/LANL2 DZ method in Gaussian 09 Program. The calculation results show obvious covalent interaction between the coordinated atoms and Mg（Ⅱ） ion.
基金We thank the anonymous reviewers and editors for their valuable comments on improving this paper. This work was supported by the National Natural Science Foundation of China （Grant No. 61300134）, the Research Fund for the Doctoral Program of Higher Education of China （20120172120036）, the Natural Science Foundation of Guangdong Province of China （S2011040005815 and S2013010012515）, the Foundation for Dis- tinguished Young Talents in Higher Education of Guangdong of China （LYM11015）, and the Fundamental Research Funds for the Central Universities of China （2011ZM0074 and 2013ZZ0050）.
文摘We propose a novel binary image representation algorithm using the non-symmetry and anti-packing model and the coordinate encoding procedure （NAMCEP）. By tak- ing some idiomatic standard binary images in the field of image processing as typical test objects, and by comparing our proposed NAMCEP representation with linear quadtree （LQT）, binary tree （Bintree）, non-symmetry and anti-packing model （NAM） with K-lines （NAMK）, and NAM representa- tions, we show that NAMCEP can not only reduce the aver- age node, but also simultaneously improve the average com- pression. We also present a novel NAMCEP-based algorithm for area calculation and show experimentally that our algo- rithm offers significant improvements.
