In this paper,we propose an improved torque sensorless speed control method for electric assisted bicycle,this method considers the coordinate conversion.A low-pass filter is designed in disturbance observer to estima...In this paper,we propose an improved torque sensorless speed control method for electric assisted bicycle,this method considers the coordinate conversion.A low-pass filter is designed in disturbance observer to estimate and compensate the variable disturbance during cycling.A DC motor provides assisted power driving,the assistance method is based on the realtime wheel angular velocity and coordinate system transformation.The effect of observer is proved,and the proposed method guarantees stability under disturbances.It is also compared to the existing methods and their performances are illustrated through simulations.The proposed method improves the performance both in rapidity and stability.展开更多
A method for precise conversion between virtual world and real world is put forward in this paper. The method aims to precisely establish the connection between the virtual coordinates and the real coordinates with Op...A method for precise conversion between virtual world and real world is put forward in this paper. The method aims to precisely establish the connection between the virtual coordinates and the real coordinates with OpenGL. In the virtual world, two virtual cameras are set to capture the left and right perspective planar images, and coordinates of the planar images can be calculated by the perspective projection model. With coordinates of planar images, coordinates of the stereo- scopic image synthesized in the real world can be calculated by the binocular observation model. Therefore, the corresponding connection between the two systems is established. Experimental re- suits match data from this method well. Therefore, this method can precisely realize the conversion and the interactivity, laying a solid foundation for further study.展开更多
Lithium-sulfur batteries(LSBs)are widely regarded as promising next-generation batteries due to their high theoretical specific capacity and low material cost.However,the practical applications of LSBs are limited by ...Lithium-sulfur batteries(LSBs)are widely regarded as promising next-generation batteries due to their high theoretical specific capacity and low material cost.However,the practical applications of LSBs are limited by the shuttle effect of lithium polysulfides(LiPSs),electronic insulation of charge and discharge products,and slow LiPSs conversion reaction kinetics.Accordingly,the introduction of catalysts into LSBs is one of the effective strategy to solve the issues of the sluggished LiPS conversion.Because of their nearly 100%atom utilization and high electrocatalytic activity,single-atom catalysts(SACs)have been widely used as reaction mediators for LSBs’reactions.Excitingly,the SACs with asymmetric coordination structures have exhibited intriguing electronic structures and superior catalytic activities when compared to the traditional M-N_(4)active sites.In this review,we systematically describe the recent advancements in the installation of asymmetrically coordinated single-atom structure as reactions catalysts in LSBs,including asymmetrically nitrogen coordinated SACs,heteroatom coordinated SACs,support effective asymmetrically coordinated SACs,and bimetallic coordinated SACs.Particularly noteworthy is the discussion of the catalytic conversion mechanism of LiPSs spanning asymmetrically coordinated SACs.Finally,a perspective on the future developments of asymmetrically coordinated SACs in LSB applications is provided.展开更多
The targeted construction of donor-acceptor(D-A)materials featuring efficient photothermal(PT)conversion properties has been an attractive but challenging goal.Herein,a new series of coordination polymers(CPs)featurin...The targeted construction of donor-acceptor(D-A)materials featuring efficient photothermal(PT)conversion properties has been an attractive but challenging goal.Herein,a new series of coordination polymers(CPs)featuring different PT performances were constructed with flexible linker 1,1′-Ferrocenedicarboxylic acid(FCA)and 2,4,6-tri(pyridin-4-yl)-1,3,5-triazine(TPT)as acceptor and donor molecules including coronene and tetrathiafulvalene(TTF).Based on the flexible configurations of FCA ligand and the directing of donor dependent D-A interactions,the structures of TF-1 to TF-3 featuring distinctive dimension were obtained based on Cd(Ⅱ)ions for investigating the PT property in configurational perspectives.A systematic investigation of the PT properties of the CPs was performed.Notably,TF-3 exhibits the finest PT conversion effect under the irradiation of560 nm laser,while TF-2 shows optimal PT conversion under 808 nm laser irradiation required for biological PT therapy,illustrating the correlation between the structural and component features of the CPs and their PT performances.Furthermore,Zn(Ⅱ)as bio-friendly ion was utilized to construct hypotoxic TF-4 that reveals similar structure to that of TF-2 for potential application.Polydimethylsiloxane(PDMS)patches doped with TF-4 exhibits considerable NIR PT conversion effect under808 nm,represented by the nearly 80℃temperature increased in 120 s for TF-4@PDMS patch(1.2 wt%)under 0.9 W cm^(-2)irradiation,the results of which herein indicate the potential of D-A CPs as versatile platform for the modulation of PT materials.展开更多
In this paper,we propose an efficient computational method for converting local coordinates to world coordinates using specially structured coordinate data.The problem in question is the computation of world coordinat...In this paper,we propose an efficient computational method for converting local coordinates to world coordinates using specially structured coordinate data.The problem in question is the computation of world coordinates of an object throughout a motion,assuming that we only know the changing coordinates of some fixed surrounding reference points in the local coordinate system of the object.The proposed method is based on barycentric coordinates;by taking the aforementioned static positions as the vertices of a polyhedron,we can specify the coordinates of the object in each step with the help of barycentric coordinates.This approach can significantly help us to achieve more accurate results than by using other possible methods.In the paper,we describe the problem and barycentric coordinate-based solution in detail.We then compare the barycentric method with a technique based on transformation matrices,which we also tested for solving our problem.We also present various diagrams that demonstrate the efficiency of our proposed approach in terms of precision and performance.展开更多
The system mathematical model of flexible 3D measuring system is built by theoretical analysis, and the theoretical formula for measuring space point coordinate is also derived. Frog-jumping based coordinate transform...The system mathematical model of flexible 3D measuring system is built by theoretical analysis, and the theoretical formula for measuring space point coordinate is also derived. Frog-jumping based coordinate transform method is put forward in order to solve measuring problem for large size parts. The frog-jumping method is discussed, and the coordinate transform mathematical model is method of the space point coordinate compared to original value, and an advanced method is provided, Form the space point coordinate transform formula can derive the calculation measuring method for measuring large size parts.展开更多
Organic radicals feature versatile unpaired electrons key for photoelectronic and biomedical applications but remain difficult to access in stable concentrated forms.We disclose easy generation of stable,concentrated ...Organic radicals feature versatile unpaired electrons key for photoelectronic and biomedical applications but remain difficult to access in stable concentrated forms.We disclose easy generation of stable,concentrated radicals from various alkynyl phenyl motifs,including 1)sulfur-functionalized alkyne-rich organic linkers in crystalline frameworks;2)the powders of these molecules alone;3)simple diethynylbenzenes.For Zr-based framework,the generation of radical-rich crystalline framework was achieved by thermal annealing in the range of 300-450℃.For terminal alkynes,electron paramagnetic resonance signals(EPR,indicative of free radicals)arise after air exposure or mild heating(e.g,70℃).Further heating(e.g.,150℃for 3 h)raises the radical concentrations up to 3.30 mol kg^(-1).For more stable internal alkynes,transformations into porous radical solids can also be triggered,albeit at higher temperatures(e.g.,250-500℃).The resulted radical-containing solids are porous,stable to air as well as heat(up to 300-450℃)and exhibit photothermal conversion and solar-driven water evaporation capacity.The formation of radicals can be ascribed to extensive alkyne cycliza-tions,forming defects,dangling bonds and the associated radicals stabilized by polycyclicπ-systems.展开更多
The Conversion of Farmland to Forests Project (CFF) is one of the six great forest ecological Projects inChina and one of the ten great forest ecological Projects in the world, ranking the third in overall scale and t...The Conversion of Farmland to Forests Project (CFF) is one of the six great forest ecological Projects inChina and one of the ten great forest ecological Projects in the world, ranking the third in overall scale and the first ininvestment. CFF was officially initiated in 2002, covering 1897 counties (county-level cities and districts) in 25provinces (autonomous regions or municipalities) of China. The whole investment is more than 40 billion US$ duringabout 20 years (from 1999 to 2017), aiming to form better ecology system in fragile ecology regions and effectivelycontrol the soil and water erosion of the Yangtze and the Yellow River and sandstorm of the Three-north Regions inChina. The experimental Project of CFF began in 1999, including Sichuan, Shanxi and Gansu province, and the scopeof CFF was widened later. About 1.16 million ha of farmlands were converted to forestlands, and one million ha ofplantation in mountains and wasted lands were completed in 3 years, involving 20 provinces (autonomous regions andmunicipalities), 400 counties, 27 thousand villages, 5.7 thousand towns, 4.1 million farm families and 16 millionfarmers.展开更多
Application of participatory approaches in governmental forestry projects is a bran-new forestry design method. The purpose is to plan the utilization of land correctly, and to determine planting sites, planting speci...Application of participatory approaches in governmental forestry projects is a bran-new forestry design method. The purpose is to plan the utilization of land correctly, and to determine planting sites, planting species, participating households and management models, based on the projects' requirements and the farmers' demands. Participatory approaches are now practiced in some of the counties in Land Conversion Project. The paper presents the significance and necessity of practicing community mechanis...展开更多
With the entrance into WTO, the Chinese supervision enterprises face the serious challenge never existed before. Comparing with other type enterprises Chinese supervision enterprises nature of China are the same as pr...With the entrance into WTO, the Chinese supervision enterprises face the serious challenge never existed before. Comparing with other type enterprises Chinese supervision enterprises nature of China are the same as project management companies in connotation and service scope in nature. They have much superiority in development of the project management work. Through comparing and analyzing the special feature between Chinese supervision enterprise and international project management enterprise, this paper points out the gap between them, and table the proposal of they transforming to the project management enterprises.展开更多
基金supported by the National Natural Science Foundation of China(51775325)Hong Kong Scholars Program of China(XJ2013015)。
文摘In this paper,we propose an improved torque sensorless speed control method for electric assisted bicycle,this method considers the coordinate conversion.A low-pass filter is designed in disturbance observer to estimate and compensate the variable disturbance during cycling.A DC motor provides assisted power driving,the assistance method is based on the realtime wheel angular velocity and coordinate system transformation.The effect of observer is proved,and the proposed method guarantees stability under disturbances.It is also compared to the existing methods and their performances are illustrated through simulations.The proposed method improves the performance both in rapidity and stability.
基金Supported by the National Natural Science Foundation of China ( 60674052)
文摘A method for precise conversion between virtual world and real world is put forward in this paper. The method aims to precisely establish the connection between the virtual coordinates and the real coordinates with OpenGL. In the virtual world, two virtual cameras are set to capture the left and right perspective planar images, and coordinates of the planar images can be calculated by the perspective projection model. With coordinates of planar images, coordinates of the stereo- scopic image synthesized in the real world can be calculated by the binocular observation model. Therefore, the corresponding connection between the two systems is established. Experimental re- suits match data from this method well. Therefore, this method can precisely realize the conversion and the interactivity, laying a solid foundation for further study.
基金supported by the National Natural Science Foundation of China(Grant Nos.22108133,51972180)Science,Education and Industry Integration of Basic Research Projects of Qilu University of Technology(Grant No.2022PY062,2023PY034,2023PY022)
文摘Lithium-sulfur batteries(LSBs)are widely regarded as promising next-generation batteries due to their high theoretical specific capacity and low material cost.However,the practical applications of LSBs are limited by the shuttle effect of lithium polysulfides(LiPSs),electronic insulation of charge and discharge products,and slow LiPSs conversion reaction kinetics.Accordingly,the introduction of catalysts into LSBs is one of the effective strategy to solve the issues of the sluggished LiPS conversion.Because of their nearly 100%atom utilization and high electrocatalytic activity,single-atom catalysts(SACs)have been widely used as reaction mediators for LSBs’reactions.Excitingly,the SACs with asymmetric coordination structures have exhibited intriguing electronic structures and superior catalytic activities when compared to the traditional M-N_(4)active sites.In this review,we systematically describe the recent advancements in the installation of asymmetrically coordinated single-atom structure as reactions catalysts in LSBs,including asymmetrically nitrogen coordinated SACs,heteroatom coordinated SACs,support effective asymmetrically coordinated SACs,and bimetallic coordinated SACs.Particularly noteworthy is the discussion of the catalytic conversion mechanism of LiPSs spanning asymmetrically coordinated SACs.Finally,a perspective on the future developments of asymmetrically coordinated SACs in LSB applications is provided.
基金supported by the National Natural Science Foundation of China(22375104,22371134,and 22035003)the National Key R&D Program of China(2022YFA1503301)Haihe Laboratory of Sustainable Chemical Transformations(YYJC202101)。
文摘The targeted construction of donor-acceptor(D-A)materials featuring efficient photothermal(PT)conversion properties has been an attractive but challenging goal.Herein,a new series of coordination polymers(CPs)featuring different PT performances were constructed with flexible linker 1,1′-Ferrocenedicarboxylic acid(FCA)and 2,4,6-tri(pyridin-4-yl)-1,3,5-triazine(TPT)as acceptor and donor molecules including coronene and tetrathiafulvalene(TTF).Based on the flexible configurations of FCA ligand and the directing of donor dependent D-A interactions,the structures of TF-1 to TF-3 featuring distinctive dimension were obtained based on Cd(Ⅱ)ions for investigating the PT property in configurational perspectives.A systematic investigation of the PT properties of the CPs was performed.Notably,TF-3 exhibits the finest PT conversion effect under the irradiation of560 nm laser,while TF-2 shows optimal PT conversion under 808 nm laser irradiation required for biological PT therapy,illustrating the correlation between the structural and component features of the CPs and their PT performances.Furthermore,Zn(Ⅱ)as bio-friendly ion was utilized to construct hypotoxic TF-4 that reveals similar structure to that of TF-2 for potential application.Polydimethylsiloxane(PDMS)patches doped with TF-4 exhibits considerable NIR PT conversion effect under808 nm,represented by the nearly 80℃temperature increased in 120 s for TF-4@PDMS patch(1.2 wt%)under 0.9 W cm^(-2)irradiation,the results of which herein indicate the potential of D-A CPs as versatile platform for the modulation of PT materials.
基金supported by the construction EFOP-3.6.3-VEKOP-16-2017-00002supported by the European Union,co-financed by the European Social Fund.
文摘In this paper,we propose an efficient computational method for converting local coordinates to world coordinates using specially structured coordinate data.The problem in question is the computation of world coordinates of an object throughout a motion,assuming that we only know the changing coordinates of some fixed surrounding reference points in the local coordinate system of the object.The proposed method is based on barycentric coordinates;by taking the aforementioned static positions as the vertices of a polyhedron,we can specify the coordinates of the object in each step with the help of barycentric coordinates.This approach can significantly help us to achieve more accurate results than by using other possible methods.In the paper,we describe the problem and barycentric coordinate-based solution in detail.We then compare the barycentric method with a technique based on transformation matrices,which we also tested for solving our problem.We also present various diagrams that demonstrate the efficiency of our proposed approach in terms of precision and performance.
文摘The system mathematical model of flexible 3D measuring system is built by theoretical analysis, and the theoretical formula for measuring space point coordinate is also derived. Frog-jumping based coordinate transform method is put forward in order to solve measuring problem for large size parts. The frog-jumping method is discussed, and the coordinate transform mathematical model is method of the space point coordinate compared to original value, and an advanced method is provided, Form the space point coordinate transform formula can derive the calculation measuring method for measuring large size parts.
基金fundings by the National Natural Science Foundation of China(22371054,22301045)the Foundation of Basic and Applied Basic Research of Guangdong Province(2020B1515120024,2024A1515012801)+1 种基金Science and Technology Planning Project of Guangdong Province(2021A0505030066,2023A0505050164)Z.X.acknowledges a startup fund from A^(*)STAR(SC25/22-119116).
文摘Organic radicals feature versatile unpaired electrons key for photoelectronic and biomedical applications but remain difficult to access in stable concentrated forms.We disclose easy generation of stable,concentrated radicals from various alkynyl phenyl motifs,including 1)sulfur-functionalized alkyne-rich organic linkers in crystalline frameworks;2)the powders of these molecules alone;3)simple diethynylbenzenes.For Zr-based framework,the generation of radical-rich crystalline framework was achieved by thermal annealing in the range of 300-450℃.For terminal alkynes,electron paramagnetic resonance signals(EPR,indicative of free radicals)arise after air exposure or mild heating(e.g,70℃).Further heating(e.g.,150℃for 3 h)raises the radical concentrations up to 3.30 mol kg^(-1).For more stable internal alkynes,transformations into porous radical solids can also be triggered,albeit at higher temperatures(e.g.,250-500℃).The resulted radical-containing solids are porous,stable to air as well as heat(up to 300-450℃)and exhibit photothermal conversion and solar-driven water evaporation capacity.The formation of radicals can be ascribed to extensive alkyne cycliza-tions,forming defects,dangling bonds and the associated radicals stabilized by polycyclicπ-systems.
文摘The Conversion of Farmland to Forests Project (CFF) is one of the six great forest ecological Projects inChina and one of the ten great forest ecological Projects in the world, ranking the third in overall scale and the first ininvestment. CFF was officially initiated in 2002, covering 1897 counties (county-level cities and districts) in 25provinces (autonomous regions or municipalities) of China. The whole investment is more than 40 billion US$ duringabout 20 years (from 1999 to 2017), aiming to form better ecology system in fragile ecology regions and effectivelycontrol the soil and water erosion of the Yangtze and the Yellow River and sandstorm of the Three-north Regions inChina. The experimental Project of CFF began in 1999, including Sichuan, Shanxi and Gansu province, and the scopeof CFF was widened later. About 1.16 million ha of farmlands were converted to forestlands, and one million ha ofplantation in mountains and wasted lands were completed in 3 years, involving 20 provinces (autonomous regions andmunicipalities), 400 counties, 27 thousand villages, 5.7 thousand towns, 4.1 million farm families and 16 millionfarmers.
文摘Application of participatory approaches in governmental forestry projects is a bran-new forestry design method. The purpose is to plan the utilization of land correctly, and to determine planting sites, planting species, participating households and management models, based on the projects' requirements and the farmers' demands. Participatory approaches are now practiced in some of the counties in Land Conversion Project. The paper presents the significance and necessity of practicing community mechanis...
文摘With the entrance into WTO, the Chinese supervision enterprises face the serious challenge never existed before. Comparing with other type enterprises Chinese supervision enterprises nature of China are the same as project management companies in connotation and service scope in nature. They have much superiority in development of the project management work. Through comparing and analyzing the special feature between Chinese supervision enterprise and international project management enterprise, this paper points out the gap between them, and table the proposal of they transforming to the project management enterprises.