Construction and the Second-order Nonlinear Optics of a New Chiral Coordination Network Based on Two Types of Homo-chiral Helices

A new 2D chiral cadmium coordination network [Cd（TCBA）2]？2EtOH （1） was prepared by the reaction of achiral angular asymmetric bridging ligand 2-（（3,5-dimethyl- 4H-1,2,4-triazol-4-yl）-carbamoyl）-benzoic acid （TCBA） with cadmium acetate, which was structurally characterized by IR, elemental analysis, thermogravimetric analysis and single-crystal X-ray diffraction. Complex 1 crystallizes in the chiral space group P21 and features a 2D chiral network consisting of two types of homo-chiral helices, which are further extended into a 3D chiral framework along the a-axis via hydrogen bonds. Moreover, powder second-order nonlinear optical （NLO） measurements reveal complex 1 has a modest second-harmonic-generation （SHG） efficiency at room temperature.

Key technologies and the implementation of wind,PV and storage co-generation monitoring system

The coordinated control of multiple-sources including wind,photovoltaic(PV)and storage brings new challenges to traditional dispatch and control technologies.This paper firstly introduces a framework of wind,PV and storage co-generation monitoring system.Then,key technologies of co-generation monitoring system including day-ahead optimal dispatching,active power coordinated control and reactive power and voltage control are proposed.The framework and the techniques described in this paper have been applied in the National Wind,Photovoltaic,Storage and Transmission Demonstration Project of China,and their validity have been tested and verified.

Multi-period Two-stage Robust Optimization of Radial Distribution System with Cables Considering Time-of-use Price

In the existing multi-period robust optimization methods for the optimal power flow in radial distribution systems,the capability of distributed generators(DGs)to regulate the reactive power,the operation costs of the regulation equipment,and the current of the shunt capacitor of the cables are not considered.In this paper,a multi-period two-stage robust scheduling strategy that aims to minimize the total cost of the power supply is developed.This strategy considers the time-ofuse price,the capability of the DGs to regulate the active and reactive power,the action costs of the regulation equipment,and the current of the shunt capacitors of the cables in a radial distribution system.Furthermore,the numbers of variables and constraints in the first-stage model remain constant during the iteration to enhance the computation efficiency.To solve the second-stage model,only the model of each period needs to be solved.Then,their objective values are accumulated,revealing that the computation rate using the proposed method is much higher than that of existing methods.The effectiveness of the proposed method is validated by actual 4-bus,IEEE 33-bus,and PG 69-bus distribution systems.

Optimal Active Power Dispatching of Microgrid and Distribution Network Based on Model Predictive Control

First, a three-tier coordinated scheduling system consisting of a distribution network dispatch layer, a microgrid centralized control layer, and local control layer in the energy internet is proposed. The multi-time scale optimal scheduling of the microgrid based on Model Predictive Control（MPC） is then studied, and the optimized genetic algorithm and the microgrid multi-time rolling optimization strategy are used to optimize the datahead scheduling phase and the intra-day optimization phase. Next, based on the three-tier coordinated scheduling architecture, the operation loss model of the distribution network is solved using the improved branch current forward-generation method and the genetic algorithm. The optimal scheduling of the distribution network layer is then completed. Finally, the simulation examples are used to compare and verify the validity of the method.

A new power coordination method for islanded micro-grid basing on multi-agent system

Multi-agent system (MAS) can provide flexible and intelligent control for micro-grid (MG). In this paper, a new power coordination method of MAS is presented for MG. New way for dispatching controllable generations (CGs) and direct cooperation between storages and CGs are designed. Real-time emulations of the coordination, including the usage of both CGs and storages, have been carried out in islanded situation basing on this method, and much higher performance than conventional method is found.

Pd-catalyzed ortho-olefination of aromatic acetyl esters

A Pd（Ⅱ）-catalyzed ortho-olefination of aromatic acetic esters is described which features with an excellent funcitional group tolerance, good yields, mild reaction conditions, good scalability as well as high chemo-and regio-selectivity.