In this paper the self-regeneration process of the mixed resins consisting of cationand anion ion exchangers in the electrolialyser of the packed bed is analyzed and anelectric regeneration method is put forward to su...In this paper the self-regeneration process of the mixed resins consisting of cationand anion ion exchangers in the electrolialyser of the packed bed is analyzed and anelectric regeneration method is put forward to supply the desalinated water by mixedbed The electric regeneration technology is a new one used for regeneration of theexhausted ion exchangers in the mixed bed instead of the traditional regeneratingprocess by using acid and abc liquor Electric energy is consumed to regenerat theion exchangers loaded by salts from water treatment without any chemicals- acid alkali. The advantage of the electric regeneration process edibited convenientoperation, no discharge any waste, and therefore no Polluted to the recehang waterbode and the environmental展开更多
The study of copper adsorption onto ion exchange resins of anionic type is part of the gold recovery from ammonia-thiosulfate solutions, where copper is the main impurity of the system because it acts as a catalyst of...The study of copper adsorption onto ion exchange resins of anionic type is part of the gold recovery from ammonia-thiosulfate solutions, where copper is the main impurity of the system because it acts as a catalyst of gold dissolution reaction. A study is made of the adsorption and desorption of copper in the form of the complex in an ammonia-thiosulfate media on an ion exchange resin, DOWEX 550A, classified as a strong base, which in its inner structure has a quaternary amine functional group. In the studied pH range copper adsorption increased with increasing pH, while the presence of thiosulfate decreased it, the same as the ammonia content, due to the greater presence of cuprotetramine, . Elution of the copper complexes from the resin was more efficient with sulfite than with perchlorate.展开更多
SP-C was applied for the removal of Cu2 + from simulated cobalt sulfate electrolyte containing Co 2+50 g/L and Cu 2+ 0.5-2.0 g/L.Experimental conditions included pH of 2-4,temperature of 20-60°C and contact time ...SP-C was applied for the removal of Cu2 + from simulated cobalt sulfate electrolyte containing Co 2+50 g/L and Cu 2+ 0.5-2.0 g/L.Experimental conditions included pH of 2-4,temperature of 20-60°C and contact time of 10-40 min.The investigation demonstrated that SP-C had recommendable efficiency in adsorbing Cu2 + from the electrolyte with 25-to 100-fold of Co2 +.The optimal adsorption conditions of SP-C were pH of 4,contact time of 30 min and ambient temperature.The study also showed that the loaded resin could be effectively eluted with 2.0 mol/L H2SO4 solution at a contact time of 40 min;the peak concentration of Cu2 + in the eluate was about 35 g/L.The sorption characteristics of Cu 2+ by SP-C could be described by Langmuir isotherm and the pseudo second-order kinetic equation.Infrared spectra showed that nitrogen atoms in the functional group coordinated with Cu2 + to form coordination bands.展开更多
Acid mine drainage is wastewater from a mine having a low pH and an elevated level of dissolved heavy metals. These metals are harmful to aquatic, animal and human life. This paper looks at the removal of copper from ...Acid mine drainage is wastewater from a mine having a low pH and an elevated level of dissolved heavy metals. These metals are harmful to aquatic, animal and human life. This paper looks at the removal of copper from acid mine drainage using ion exchange to less than 1 mg/l. A weak acidic cation resin was used. Spectrophotometric determination of copper with sodium diethyldithiocarbamate was used to determine the copper concentrations in the treated water. Using regression analysis, the experimental results gave a correlation coefficient of 0.977 and a coefficient of determination of 99.5%. Results indicated that the higher the flows rate the shorter the period after which the copper concentration in the treated water reaches 1 mg/l. At pH 3.85 and 5.09, the resin performed better and at pH above 6.62 and between pH 3.0 and below the resin’s does not perform well. The higher the resin height the greater is the resin exchange capacity and the longer it takes for the copper concentration to reach 1 mg/l in the treated water. The higher the wastewater copper concentration the shorter the time it takes the resin to reach 1 mg/l. The results for this experiment indicated that acid mine drainage can be treated well by ion exchange resins, but it is also very important to establish suitable operating conditions.展开更多
文摘In this paper the self-regeneration process of the mixed resins consisting of cationand anion ion exchangers in the electrolialyser of the packed bed is analyzed and anelectric regeneration method is put forward to supply the desalinated water by mixedbed The electric regeneration technology is a new one used for regeneration of theexhausted ion exchangers in the mixed bed instead of the traditional regeneratingprocess by using acid and abc liquor Electric energy is consumed to regenerat theion exchangers loaded by salts from water treatment without any chemicals- acid alkali. The advantage of the electric regeneration process edibited convenientoperation, no discharge any waste, and therefore no Polluted to the recehang waterbode and the environmental
文摘The study of copper adsorption onto ion exchange resins of anionic type is part of the gold recovery from ammonia-thiosulfate solutions, where copper is the main impurity of the system because it acts as a catalyst of gold dissolution reaction. A study is made of the adsorption and desorption of copper in the form of the complex in an ammonia-thiosulfate media on an ion exchange resin, DOWEX 550A, classified as a strong base, which in its inner structure has a quaternary amine functional group. In the studied pH range copper adsorption increased with increasing pH, while the presence of thiosulfate decreased it, the same as the ammonia content, due to the greater presence of cuprotetramine, . Elution of the copper complexes from the resin was more efficient with sulfite than with perchlorate.
文摘SP-C was applied for the removal of Cu2 + from simulated cobalt sulfate electrolyte containing Co 2+50 g/L and Cu 2+ 0.5-2.0 g/L.Experimental conditions included pH of 2-4,temperature of 20-60°C and contact time of 10-40 min.The investigation demonstrated that SP-C had recommendable efficiency in adsorbing Cu2 + from the electrolyte with 25-to 100-fold of Co2 +.The optimal adsorption conditions of SP-C were pH of 4,contact time of 30 min and ambient temperature.The study also showed that the loaded resin could be effectively eluted with 2.0 mol/L H2SO4 solution at a contact time of 40 min;the peak concentration of Cu2 + in the eluate was about 35 g/L.The sorption characteristics of Cu 2+ by SP-C could be described by Langmuir isotherm and the pseudo second-order kinetic equation.Infrared spectra showed that nitrogen atoms in the functional group coordinated with Cu2 + to form coordination bands.
文摘Acid mine drainage is wastewater from a mine having a low pH and an elevated level of dissolved heavy metals. These metals are harmful to aquatic, animal and human life. This paper looks at the removal of copper from acid mine drainage using ion exchange to less than 1 mg/l. A weak acidic cation resin was used. Spectrophotometric determination of copper with sodium diethyldithiocarbamate was used to determine the copper concentrations in the treated water. Using regression analysis, the experimental results gave a correlation coefficient of 0.977 and a coefficient of determination of 99.5%. Results indicated that the higher the flows rate the shorter the period after which the copper concentration in the treated water reaches 1 mg/l. At pH 3.85 and 5.09, the resin performed better and at pH above 6.62 and between pH 3.0 and below the resin’s does not perform well. The higher the resin height the greater is the resin exchange capacity and the longer it takes for the copper concentration to reach 1 mg/l in the treated water. The higher the wastewater copper concentration the shorter the time it takes the resin to reach 1 mg/l. The results for this experiment indicated that acid mine drainage can be treated well by ion exchange resins, but it is also very important to establish suitable operating conditions.
