The deposition of high-quality diamond films and their adhesion on cemented carbides are strongly influenced by the catalytic effect of cobalt under typical deposition conditions. Decreasing Co content on the surface...The deposition of high-quality diamond films and their adhesion on cemented carbides are strongly influenced by the catalytic effect of cobalt under typical deposition conditions. Decreasing Co content on the surface of the cemented carbide is often used for the diamond film deposition. But the leaching of Co from the WC-Co substrate leading to a mechanical weak surface often causes a poor adhesion. In this paper we adopted an implant copper layer prepared by vaporization to improve the mechanical properties of the Co-leached substrate. The diamond films were grown by microwave plasma chemical vapor deposition from CH4:H2 gas mixture. The cross section and the morphology of the diamond film were characterized by scanning electron microscopy (SEM). The non-diamond content in the film was analyzed by Raman spectroscopy. The effects of pretreatment on the concentrations of Co and Cu near the interfacial region were examined by energy dispersive spectrum (EDS) equipped with SEM. The adhesion of the diamond on the substrate was evaluated with a Rockwell-type hardness tester. The results indicate that the diamond films prepared with implant copper layer have a good adhesion to the cemented carbide substrate due to the recovery of the mechanical properties of the Co-depleted substrate after the copper implantation and the formation of less amorphous carbon between the substrate and the diamond film.展开更多
In this work, the deposition process features of a copper coating on stainless steel substrate, using the pulse vacuum arc spraying method were researched. A continuous layer of copper was deposited on a stainless ste...In this work, the deposition process features of a copper coating on stainless steel substrate, using the pulse vacuum arc spraying method were researched. A continuous layer of copper was deposited on a stainless steel substrate, and a high degree of coating adhesion to the substrate was demonstrated. The thickness of coating using application time was calculated, and the surface unevenness was estimated. Inside the coating layer substrate material elements were observed, that could appear as a result of simultaneously plasma spraying on the surface of the substrate. The feature of this method was discovered, that surface plasma plays a significant role in the deposition process. Finally, it was shown that the device with a pulsed arc could effectively be used in industry, since it is possible to change the layer thickness in the range of hundreds of microns by varying the deposition time.展开更多
古遗址土壤形成物是研究古代人类活动的重要载体。通过对安徽蒙城尉迟寺遗址YC1剖面中Pb、Al等金属元素的分析,研究了Pb在5050cal a BP～4000cal a BP间剖面中的富集特征。结果表明,尉迟寺遗址文化层剖面中的铅富集系数变化范围为1...古遗址土壤形成物是研究古代人类活动的重要载体。通过对安徽蒙城尉迟寺遗址YC1剖面中Pb、Al等金属元素的分析,研究了Pb在5050cal a BP～4000cal a BP间剖面中的富集特征。结果表明,尉迟寺遗址文化层剖面中的铅富集系数变化范围为1·0～1·8左右,富集程度不是很高。但是随着时间的推移,从大汶口文化到龙山文化,Pb的富集系数有明显逐步上升的趋势,表明遗址剖面中的Pb很可能与原始社会中期发展起来的冶金活动有关。5050～4000cal a BP间,中国先后经历了石器时代、铜石并用时代,到最后进入青铜时代,这个过程中铜资源利用越来越多导致产生的大气粉尘铅越来越多,很可能是YC1剖面中Pb富集系数逐步增长的主要原因。此外,铅同位素结果表明,土壤206Pb/204Pb比值分布在18·3～19·8之间,平均为18·82;207Pb/204Pb比值分布在15·3～16·5之间,平均为15·76;208Pb/204Pb比值分布在38·0～41·0之间,平均为39·04。铅同位素示踪表明,土壤中的铅的来源自5050calaBP至4000calaBP有越来越广的趋势,并且很可能与出自中国南方地区的矿料有关,包括云南、四川、湖北、湖南或广东地区的矿料。展开更多
文摘The deposition of high-quality diamond films and their adhesion on cemented carbides are strongly influenced by the catalytic effect of cobalt under typical deposition conditions. Decreasing Co content on the surface of the cemented carbide is often used for the diamond film deposition. But the leaching of Co from the WC-Co substrate leading to a mechanical weak surface often causes a poor adhesion. In this paper we adopted an implant copper layer prepared by vaporization to improve the mechanical properties of the Co-leached substrate. The diamond films were grown by microwave plasma chemical vapor deposition from CH4:H2 gas mixture. The cross section and the morphology of the diamond film were characterized by scanning electron microscopy (SEM). The non-diamond content in the film was analyzed by Raman spectroscopy. The effects of pretreatment on the concentrations of Co and Cu near the interfacial region were examined by energy dispersive spectrum (EDS) equipped with SEM. The adhesion of the diamond on the substrate was evaluated with a Rockwell-type hardness tester. The results indicate that the diamond films prepared with implant copper layer have a good adhesion to the cemented carbide substrate due to the recovery of the mechanical properties of the Co-depleted substrate after the copper implantation and the formation of less amorphous carbon between the substrate and the diamond film.
文摘In this work, the deposition process features of a copper coating on stainless steel substrate, using the pulse vacuum arc spraying method were researched. A continuous layer of copper was deposited on a stainless steel substrate, and a high degree of coating adhesion to the substrate was demonstrated. The thickness of coating using application time was calculated, and the surface unevenness was estimated. Inside the coating layer substrate material elements were observed, that could appear as a result of simultaneously plasma spraying on the surface of the substrate. The feature of this method was discovered, that surface plasma plays a significant role in the deposition process. Finally, it was shown that the device with a pulsed arc could effectively be used in industry, since it is possible to change the layer thickness in the range of hundreds of microns by varying the deposition time.
文摘古遗址土壤形成物是研究古代人类活动的重要载体。通过对安徽蒙城尉迟寺遗址YC1剖面中Pb、Al等金属元素的分析,研究了Pb在5050cal a BP～4000cal a BP间剖面中的富集特征。结果表明,尉迟寺遗址文化层剖面中的铅富集系数变化范围为1·0～1·8左右,富集程度不是很高。但是随着时间的推移,从大汶口文化到龙山文化,Pb的富集系数有明显逐步上升的趋势,表明遗址剖面中的Pb很可能与原始社会中期发展起来的冶金活动有关。5050～4000cal a BP间,中国先后经历了石器时代、铜石并用时代,到最后进入青铜时代,这个过程中铜资源利用越来越多导致产生的大气粉尘铅越来越多,很可能是YC1剖面中Pb富集系数逐步增长的主要原因。此外,铅同位素结果表明,土壤206Pb/204Pb比值分布在18·3～19·8之间,平均为18·82;207Pb/204Pb比值分布在15·3～16·5之间,平均为15·76;208Pb/204Pb比值分布在38·0～41·0之间,平均为39·04。铅同位素示踪表明,土壤中的铅的来源自5050calaBP至4000calaBP有越来越广的趋势,并且很可能与出自中国南方地区的矿料有关,包括云南、四川、湖北、湖南或广东地区的矿料。
