The separation of halogens and recovery of heavy metals from secondary copper smelting(SCS)dust using a sulfating roasting−water leaching process were investigated.The thermodynamic analysis results confirm the feasib...The separation of halogens and recovery of heavy metals from secondary copper smelting(SCS)dust using a sulfating roasting−water leaching process were investigated.The thermodynamic analysis results confirm the feasibility of the phase transformation to metal sulfates and to gaseous HF and HCl.Under the sulfating roasting conditions of the roasting temperature of 250°C and the sulfuric acid excess coefficient of 1.8,over 74 wt.%of F and 98 wt.%of Cl were volatilized into flue gas.Approximately 98.6 wt.%of Zn and 96.5 wt.%of Cu in the roasting product were dissolved into the leaching solution after the water leaching process,while the leaching efficiencies of Pb and Sn were only 0.12%and 0.22%,respectively.The mechanism studies indicate the pivotal effect of roasting temperature on the sulphation reactions from various metal species to metal sulfates and the salting out reactions from various metal halides to gaseous hydrogen halides.展开更多
We constructed a 1:10 cold water experimental model by geometrically scaling down an Isa smelting furnace. The mixing processes at different liquid heights, lance diameters, lance submersion depths, and gas flow rate...We constructed a 1:10 cold water experimental model by geometrically scaling down an Isa smelting furnace. The mixing processes at different liquid heights, lance diameters, lance submersion depths, and gas flow rates were subsequently measured using the conductivity method. A new criterion was proposed to determine the mixing time. On this basis, the quasi-equations of the mixing time as a function of different parameters were established. The parameters of the top-blown smelting process were optimized using high-speed photography. An excessively high gas flow rate or excessively low liquid height would enhance the fluctuation and splashing of liquid in the bath, which is unfavorable for material mixing. Simultaneously increasing the lance diameter and the lance submersion depth would promote the mixing in the bath, thereby improving the smelting efficiency.展开更多
A mathematical model has been presented to study the combustion of a single copper concentrate particle with high moisture content. By using the presented model, the effect of particle moisture content on particle tem...A mathematical model has been presented to study the combustion of a single copper concentrate particle with high moisture content. By using the presented model, the effect of particle moisture content on particle temperature, sulfur oxidation, and combustion heat generation has been evaluated. The mineralogical composition of the commonly used concentrate at Khatoonabad flash smelting furnace has been used in this study. It was found that the particle moisture content is removed in the sub-second time range and thus the moisture has marginal impact on the variation of particle temperature and on the reaction rate when the gas temperature is assumed to be constant in the reaction shaft. When a concentrate with high moisture content is charged, the particle size enlargement due to the agglomeration of concentrate particles causes an abrupt fall in the particle reaction rate.展开更多
In the morning of August 20,Heilongjiang Zijin Copper Project formally signed agreement at Fularji District in Qiqihar City.This also signals that the copper smelting project with a total investment of 4 billion yuan,...In the morning of August 20,Heilongjiang Zijin Copper Project formally signed agreement at Fularji District in Qiqihar City.This also signals that the copper smelting project with a total investment of 4 billion yuan,a project under planning since 2011,has formally landed in Qiqihar City.展开更多
The copper flash smelting process neural network model(CFSPNNM)was developed,its input layer includes eight nodes:oxygen grade(OG),oxygen volume per ton of concentrate(OVPTC),flux rate(FR)and quantifies of Cu,S,Fe,SiO...The copper flash smelting process neural network model(CFSPNNM)was developed,its input layer includes eight nodes:oxygen grade(OG),oxygen volume per ton of concentrate(OVPTC),flux rate(FR)and quantifies of Cu,S,Fe,SiO_2 and MgO in copper concentrate;output layer includes three nodes:matte grade,matte temperature and Fe/SiO_2 in slag,and net structure was 8-13-10-3.Then,the internal relationship between the technological parameters and the objective parameters was built after the CFSPNNM was trained by us...展开更多
Peirce-Smith copper converting involves complex multiphase flow and mixing.In this work,the flow zone distribution and mixing time in a Peirce-Smith copper converter were investigated in a 1:5 scaled cold model.Flow f...Peirce-Smith copper converting involves complex multiphase flow and mixing.In this work,the flow zone distribution and mixing time in a Peirce-Smith copper converter were investigated in a 1:5 scaled cold model.Flow field distribution,including dead,splashing,and strong-loop zones,were measured,and a dimensionless equation was established to determine the correlation of the effects of stirring and mixing energy with an error of<5%.Four positions in the bath,namely,injection,splashing,strong-loop,and dead zones,were selected to add a hollow salt powder tracer and measure the mixing time.Injecting a quartz flux through tuyeres or into the backflow point of the splashing wave through a chute was recommended instead of adding it through a crane hopper from the top of the furnace to improve the slag-making reaction.展开更多
Heavy metal pollution is hazardous for the environment and human health.However,there are few studies of heavy metal pollution caused by historic metallurgical activity.The Laoniupo site in the Bahe River valley,Guanz...Heavy metal pollution is hazardous for the environment and human health.However,there are few studies of heavy metal pollution caused by historic metallurgical activity.The Laoniupo site in the Bahe River valley,Guanzhong Basin,China,was an important settlement of the Shang Culture(1600-1046 BCE).We studied two stratigraphic profiles at the Laoniupo site,which were used for measurements of magnetic susceptibility,heavy metal concentrations,and AMS 14C ages to provide evidence of copper smelting activity at the site during the Shang Dynasty.The Nemerow Pollution Index and Geoaccumulation Index were calculated to assess the heavy metals record(Cu,Zn,Ni,Pb,Cr,and As)in the topsoil on the loess tableland.According to the Single Pollution Index,the topsoil was slightly polluted by As and unpolluted by Cu,Zn,Ni,Pb and Cr;according to the Nemerow Composite Pollution Index the topsoil was mildly polluted;and according to the Geoaccumulation Index,the topsoil was moderately polluted by As,slightly polluted by Cu,and unpolluted by Zn,Ni,Pb and Cr_The main cause of the heavy metal pollution in the topsoil is the presence of copper slag in the cultural layers that was disturbed by modern farming activity.展开更多
基金the National Key Research and Development Program of China(No.2019YFC1908400)the National Natural Science Foundation of China(Nos.52174334,52374413)+3 种基金the Jiangxi Provincial Cultivation Program for Academic and Technical Leaders of Major Subjects,China(Nos.20212BCJ23007,20212BCJL23052)the Jiangxi Provincial Natural Science Foundation,China(Nos.20224ACB214009,20224BAB214040)the Double Thousand Plan of Jiangxi Province,China(No.S2021GDQN2970)the Distinguished Professor Program of Jinggang Scholars in Institutions of Higher Learning of Jiangxi Province,China.
文摘The separation of halogens and recovery of heavy metals from secondary copper smelting(SCS)dust using a sulfating roasting−water leaching process were investigated.The thermodynamic analysis results confirm the feasibility of the phase transformation to metal sulfates and to gaseous HF and HCl.Under the sulfating roasting conditions of the roasting temperature of 250°C and the sulfuric acid excess coefficient of 1.8,over 74 wt.%of F and 98 wt.%of Cl were volatilized into flue gas.Approximately 98.6 wt.%of Zn and 96.5 wt.%of Cu in the roasting product were dissolved into the leaching solution after the water leaching process,while the leaching efficiencies of Pb and Sn were only 0.12%and 0.22%,respectively.The mechanism studies indicate the pivotal effect of roasting temperature on the sulphation reactions from various metal species to metal sulfates and the salting out reactions from various metal halides to gaseous hydrogen halides.
基金financially supported by the National Natural Science Foundation of China(No.51504018)the China Postdoctoral Science Foundation(No.2015M580986)the Fundamental Research Funds for the Central Universities(No.FRF-TP-15-069A1)
文摘We constructed a 1:10 cold water experimental model by geometrically scaling down an Isa smelting furnace. The mixing processes at different liquid heights, lance diameters, lance submersion depths, and gas flow rates were subsequently measured using the conductivity method. A new criterion was proposed to determine the mixing time. On this basis, the quasi-equations of the mixing time as a function of different parameters were established. The parameters of the top-blown smelting process were optimized using high-speed photography. An excessively high gas flow rate or excessively low liquid height would enhance the fluctuation and splashing of liquid in the bath, which is unfavorable for material mixing. Simultaneously increasing the lance diameter and the lance submersion depth would promote the mixing in the bath, thereby improving the smelting efficiency.
文摘A mathematical model has been presented to study the combustion of a single copper concentrate particle with high moisture content. By using the presented model, the effect of particle moisture content on particle temperature, sulfur oxidation, and combustion heat generation has been evaluated. The mineralogical composition of the commonly used concentrate at Khatoonabad flash smelting furnace has been used in this study. It was found that the particle moisture content is removed in the sub-second time range and thus the moisture has marginal impact on the variation of particle temperature and on the reaction rate when the gas temperature is assumed to be constant in the reaction shaft. When a concentrate with high moisture content is charged, the particle size enlargement due to the agglomeration of concentrate particles causes an abrupt fall in the particle reaction rate.
文摘In the morning of August 20,Heilongjiang Zijin Copper Project formally signed agreement at Fularji District in Qiqihar City.This also signals that the copper smelting project with a total investment of 4 billion yuan,a project under planning since 2011,has formally landed in Qiqihar City.
基金Key Industrial Technology Development Project of China (No.20051255)National Natural Science Foundation of China (No.50364004)+1 种基金Scientific and Technological Project of Jiangxi Province (No.20061B0101100)Natural Science Foundation of Jiangxi Province (No.2007GZC0713)
文摘The copper flash smelting process neural network model(CFSPNNM)was developed,its input layer includes eight nodes:oxygen grade(OG),oxygen volume per ton of concentrate(OVPTC),flux rate(FR)and quantifies of Cu,S,Fe,SiO_2 and MgO in copper concentrate;output layer includes three nodes:matte grade,matte temperature and Fe/SiO_2 in slag,and net structure was 8-13-10-3.Then,the internal relationship between the technological parameters and the objective parameters was built after the CFSPNNM was trained by us...
基金This work was financially supported by the National Nat-ural Science Foundation of China(No.51974018)the Guangxi Innovation-Driven Development Project(No.AA18242042-1)the Fundamental Research Funds for the Central Universities(No.FRF-TP-19-016A3).
文摘Peirce-Smith copper converting involves complex multiphase flow and mixing.In this work,the flow zone distribution and mixing time in a Peirce-Smith copper converter were investigated in a 1:5 scaled cold model.Flow field distribution,including dead,splashing,and strong-loop zones,were measured,and a dimensionless equation was established to determine the correlation of the effects of stirring and mixing energy with an error of<5%.Four positions in the bath,namely,injection,splashing,strong-loop,and dead zones,were selected to add a hollow salt powder tracer and measure the mixing time.Injecting a quartz flux through tuyeres or into the backflow point of the splashing wave through a chute was recommended instead of adding it through a crane hopper from the top of the furnace to improve the slag-making reaction.
基金Project(52022111)supported by the National Natural Science Fundation for Distinguished Young Scholars of ChinaProject(51974379)supported by the National Natural Science Foundation of China+1 种基金Project(2020SK2006)supported by the High-tech Industry Science and Technology Innovation Leading Plan of Hunan Provice,ChinaProject(2020RC3012)supported by the Huxiang Youth Talent Support Program,China。
基金National Natural Science Foundation of China,No.41801060The Strategic Priority Research Program of the Chinese Academy of Sciences,No.XDA20060201The Open Foundation of the Key Laboratory of Cultural Heritage Research and Conservation of the Education Ministry in Northwest University of China,No.GXYDFA2018XBD003,No.WYSYS2019。
文摘Heavy metal pollution is hazardous for the environment and human health.However,there are few studies of heavy metal pollution caused by historic metallurgical activity.The Laoniupo site in the Bahe River valley,Guanzhong Basin,China,was an important settlement of the Shang Culture(1600-1046 BCE).We studied two stratigraphic profiles at the Laoniupo site,which were used for measurements of magnetic susceptibility,heavy metal concentrations,and AMS 14C ages to provide evidence of copper smelting activity at the site during the Shang Dynasty.The Nemerow Pollution Index and Geoaccumulation Index were calculated to assess the heavy metals record(Cu,Zn,Ni,Pb,Cr,and As)in the topsoil on the loess tableland.According to the Single Pollution Index,the topsoil was slightly polluted by As and unpolluted by Cu,Zn,Ni,Pb and Cr;according to the Nemerow Composite Pollution Index the topsoil was mildly polluted;and according to the Geoaccumulation Index,the topsoil was moderately polluted by As,slightly polluted by Cu,and unpolluted by Zn,Ni,Pb and Cr_The main cause of the heavy metal pollution in the topsoil is the presence of copper slag in the cultural layers that was disturbed by modern farming activity.