A novel, fluorescent probe was synthesized from 2,4-dihydroxybenzaldehyde and 8-hydroxyquinoline for sensing Cu2+ by the naked eye. The structure was confirmed by 1R, MS, 1H NMR, 13C NMR and the spectral properties o...A novel, fluorescent probe was synthesized from 2,4-dihydroxybenzaldehyde and 8-hydroxyquinoline for sensing Cu2+ by the naked eye. The structure was confirmed by 1R, MS, 1H NMR, 13C NMR and the spectral properties of the probe were investigated. It exhibited strong fluorescence responses toward Cu2+ and high selectivity over other metal ions. The binding constant between the probe and Cu2+ was calculated using Benesi-Hildebrand equation.展开更多
基金supported by the National Natural Scientific Foundation of China(Nos.21072158 and 20802056)the Natural Science Foundation of Shaanxi Province(No.2012JM8022)+2 种基金the Special Foundation of the Education Committee of Shaanxi Province(No.12JK0580)the French Chinese Foundation for Science and Applications(FFSCA)the China Scholars Council(CSC)
文摘A novel, fluorescent probe was synthesized from 2,4-dihydroxybenzaldehyde and 8-hydroxyquinoline for sensing Cu2+ by the naked eye. The structure was confirmed by 1R, MS, 1H NMR, 13C NMR and the spectral properties of the probe were investigated. It exhibited strong fluorescence responses toward Cu2+ and high selectivity over other metal ions. The binding constant between the probe and Cu2+ was calculated using Benesi-Hildebrand equation.