Correlation between the absolute configuration and the CD spectra of organic peroxides was studied by ab initio method with a mo- d el moleeule CH_3-O-O-CH_3.For P form when 0°≤θ(twist angle of C-O-O-C) <90&...Correlation between the absolute configuration and the CD spectra of organic peroxides was studied by ab initio method with a mo- d el moleeule CH_3-O-O-CH_3.For P form when 0°≤θ(twist angle of C-O-O-C) <90°, there is positive Cotton effect;when 90°<θ≤180°, there is nega- tive Cotton effect;the curve is bisignate at θ=90°.展开更多
Most current computations of trubulent flows with second-moment closure adopt the diffusion mo- dels which neglect the effect of pressure-velocity correlation.ln the present paper the importance of this correlation ef...Most current computations of trubulent flows with second-moment closure adopt the diffusion mo- dels which neglect the effect of pressure-velocity correlation.ln the present paper the importance of this correlation effect is elucidated the neglect of this effect accounts for some major defects in the wide application of the se- cond-moment closures.Through the relation between and ,established by Lumley,we propose here a new turbulence diffusion model which takes into consideration the pressure effect.Applications of this new model in the computation of shearless turbulence mixing layer and plane-and round-jet flows show that the spreading rate of these flows can be satisfactorily captured.展开更多
文摘Correlation between the absolute configuration and the CD spectra of organic peroxides was studied by ab initio method with a mo- d el moleeule CH_3-O-O-CH_3.For P form when 0°≤θ(twist angle of C-O-O-C) <90°, there is positive Cotton effect;when 90°<θ≤180°, there is nega- tive Cotton effect;the curve is bisignate at θ=90°.
文摘Most current computations of trubulent flows with second-moment closure adopt the diffusion mo- dels which neglect the effect of pressure-velocity correlation.ln the present paper the importance of this correlation effect is elucidated the neglect of this effect accounts for some major defects in the wide application of the se- cond-moment closures.Through the relation between and ,established by Lumley,we propose here a new turbulence diffusion model which takes into consideration the pressure effect.Applications of this new model in the computation of shearless turbulence mixing layer and plane-and round-jet flows show that the spreading rate of these flows can be satisfactorily captured.
