The coupling model of major influence factors such state affecting the chloride diffusion process in concrete is as environmental relative humidity, load-induced crack and stress discussed. The probability distributio...The coupling model of major influence factors such state affecting the chloride diffusion process in concrete is as environmental relative humidity, load-induced crack and stress discussed. The probability distributions of the critical chloride concentration Cc, the chloride diffusion coefficient D, and the surface chloride concentration Cs were determined based on the collected natural exposure data. And the estimation of probability of corrosion initiation considering the coupling effects of influence factors is presented. It is found that the relative humidity and curing time are the most effective factors affecting the probability of corrosion initiation before and after 10 years of exposure time. At the same exposure time, the influence of load-induced crack and stress state on the probability of corrosion initiation is obvious, in which the effect of crack is the most one展开更多
The polarization curves of theα-PHASE aluminium bronze measured in 5%NaCl electrochemically show that the corrosion process of the alloy is controlled by the diffusion of oxygen.The corrosion surface of theα-PHASE A...The polarization curves of theα-PHASE aluminium bronze measured in 5%NaCl electrochemically show that the corrosion process of the alloy is controlled by the diffusion of oxygen.The corrosion surface of theα-PHASE A1 bronze in NaCl solution for a short time was analysed by X-ray Photoelectron Spectroscopy(XPS).The results indicate that the initial corrosion product of the A1 bronze consists of a simple Cu20 phase.A1 and Ni are incorporated in Cu20 lattice structure in the form of ions,and none of the aluminium compound can be detected.The authors propose that the initial corrosion mechanism ofα-PHASE A1 bronzes in NaCl solution should include oxidation,reduction and diffusion.展开更多
The crack initiation mechanism of a Z3CN20.09M duplex stainless steel （DSS） during corrosion fatigue （CF） in water and air at 290 ℃ was investigated by using a CF cracking machine and a scanning electron microsco...The crack initiation mechanism of a Z3CN20.09M duplex stainless steel （DSS） during corrosion fatigue （CF） in water and air at 290 ℃ was investigated by using a CF cracking machine and a scanning electron microscopy （SEM）. The cracks were initiated successively at the persistent stip bands （PSBs）, phase boundaries （PBs） and pitting corrosion points （PCPs） of the specimens when they were tested in water at 290 ℃, while in airat 290 ℃ the cracks were only initiated at the PSBs and PBs. And the cracks were found mainly to initiate at the PSBs and PBs when the specimens were tested in water and air at 290 ℃, respectively. The results also reveal that the cracks were likely to be initiated at the first 20% of fatigue life of the specimens tested in water at 290 ℃. However, the cracks were not found until 50% of fatigue life when tested in air at 290 ℃. Moreover, the crack numbers of the specimens tested in water at 290 ℃ were much more than those tested in air at 290 ℃.展开更多
基金Project(50925829) supported by the National Science Fund for Distinguished Young Scholars of ChinaProject(50908148) supported by the National Natural Science Foundation of ChinaProjects(2009-K4-23,2010-11-33) supported by the Research of Ministry of Housing and Urban Rural Development of China
文摘The coupling model of major influence factors such state affecting the chloride diffusion process in concrete is as environmental relative humidity, load-induced crack and stress discussed. The probability distributions of the critical chloride concentration Cc, the chloride diffusion coefficient D, and the surface chloride concentration Cs were determined based on the collected natural exposure data. And the estimation of probability of corrosion initiation considering the coupling effects of influence factors is presented. It is found that the relative humidity and curing time are the most effective factors affecting the probability of corrosion initiation before and after 10 years of exposure time. At the same exposure time, the influence of load-induced crack and stress state on the probability of corrosion initiation is obvious, in which the effect of crack is the most one
文摘The polarization curves of theα-PHASE aluminium bronze measured in 5%NaCl electrochemically show that the corrosion process of the alloy is controlled by the diffusion of oxygen.The corrosion surface of theα-PHASE A1 bronze in NaCl solution for a short time was analysed by X-ray Photoelectron Spectroscopy(XPS).The results indicate that the initial corrosion product of the A1 bronze consists of a simple Cu20 phase.A1 and Ni are incorporated in Cu20 lattice structure in the form of ions,and none of the aluminium compound can be detected.The authors propose that the initial corrosion mechanism ofα-PHASE A1 bronzes in NaCl solution should include oxidation,reduction and diffusion.
基金financial support from the"863"Program of China under Nos.2008AA031702 and 2012AA03A507
文摘The crack initiation mechanism of a Z3CN20.09M duplex stainless steel （DSS） during corrosion fatigue （CF） in water and air at 290 ℃ was investigated by using a CF cracking machine and a scanning electron microscopy （SEM）. The cracks were initiated successively at the persistent stip bands （PSBs）, phase boundaries （PBs） and pitting corrosion points （PCPs） of the specimens when they were tested in water at 290 ℃, while in airat 290 ℃ the cracks were only initiated at the PSBs and PBs. And the cracks were found mainly to initiate at the PSBs and PBs when the specimens were tested in water and air at 290 ℃, respectively. The results also reveal that the cracks were likely to be initiated at the first 20% of fatigue life of the specimens tested in water at 290 ℃. However, the cracks were not found until 50% of fatigue life when tested in air at 290 ℃. Moreover, the crack numbers of the specimens tested in water at 290 ℃ were much more than those tested in air at 290 ℃.
