With a concrete pavement slab prestressed, its load carrying capacity can be significantly increased; thus a thinner slab may be used for the same loading. Prestressing modify the structural behavior of the pavement ...With a concrete pavement slab prestressed, its load carrying capacity can be significantly increased; thus a thinner slab may be used for the same loading. Prestressing modify the structural behavior of the pavement slab and there is a greater resistance to impact, vibration and overloading. This paper discusses the major design considerations necessary in the successful construction of prestressed concrete pavements and presents a design procedure developed to predict the compressive stress due to prestressing in the pavements at early stage, during service and after cracking. Variation in the approach for repetitive and nonrepetitive loads is clearly distinguished. Check on the recovery after cracking for overloading in prestressed pavements is also needed. Finally, a design example is illustrated the application of the approach developed.展开更多
A process to recover rare earth（RE） metals from spent fluid catalytic cracking（FCC） catalysts by solvent extraction was studied, using saponified 2-ethylhexyl phosphoric acid-2-ethylhexyl ester（EHEHPA or P507）. ...A process to recover rare earth（RE） metals from spent fluid catalytic cracking（FCC） catalysts by solvent extraction was studied, using saponified 2-ethylhexyl phosphoric acid-2-ethylhexyl ester（EHEHPA or P507）. The recovery process involved three steps：（1） leaching REs（mainly lanthanum and cerium）;（2） solvent extraction by applying saponified P507-kerosene system;（3） stripping. Experiments to assure optimal operating conditions were conducted. Results indicated that RE metals could be recovered effectively from spent catalyst with saponified P507-kerosene-HCl system. At room temperature of 25 oC, 10 g spent catalyst with 110 m L of HCl（1 mol/L） could achieve a leaching efficiency of 85%. For extraction, initial pH value of 3.17, organic/aqueous ratio（O/A ratio） of 2：1 with an extractants＇ saponification rate of 20% could obtain 100% efficiency. In the stripping process, 1 mol/L HCl with O/A ratio of 1：1 led to a stripping efficiency of 96%. In the present study, RE metals from spent FCC catalysts were effectively recovered, which avoided wasting a large amount of RE resources. It provides a theoretical support for commercial recycling of RE resources.展开更多
文摘With a concrete pavement slab prestressed, its load carrying capacity can be significantly increased; thus a thinner slab may be used for the same loading. Prestressing modify the structural behavior of the pavement slab and there is a greater resistance to impact, vibration and overloading. This paper discusses the major design considerations necessary in the successful construction of prestressed concrete pavements and presents a design procedure developed to predict the compressive stress due to prestressing in the pavements at early stage, during service and after cracking. Variation in the approach for repetitive and nonrepetitive loads is clearly distinguished. Check on the recovery after cracking for overloading in prestressed pavements is also needed. Finally, a design example is illustrated the application of the approach developed.
基金Project supported by the National Key Basic Research Program of China(2012CBA01203)the Specialized Research Fund for Doctoral Programme of Higher Education of MOE of China(20130002110018)in the State Key Laboratory of Chemical Engineering of Tsinghua University
文摘A process to recover rare earth（RE） metals from spent fluid catalytic cracking（FCC） catalysts by solvent extraction was studied, using saponified 2-ethylhexyl phosphoric acid-2-ethylhexyl ester（EHEHPA or P507）. The recovery process involved three steps：（1） leaching REs（mainly lanthanum and cerium）;（2） solvent extraction by applying saponified P507-kerosene system;（3） stripping. Experiments to assure optimal operating conditions were conducted. Results indicated that RE metals could be recovered effectively from spent catalyst with saponified P507-kerosene-HCl system. At room temperature of 25 oC, 10 g spent catalyst with 110 m L of HCl（1 mol/L） could achieve a leaching efficiency of 85%. For extraction, initial pH value of 3.17, organic/aqueous ratio（O/A ratio） of 2：1 with an extractants＇ saponification rate of 20% could obtain 100% efficiency. In the stripping process, 1 mol/L HCl with O/A ratio of 1：1 led to a stripping efficiency of 96%. In the present study, RE metals from spent FCC catalysts were effectively recovered, which avoided wasting a large amount of RE resources. It provides a theoretical support for commercial recycling of RE resources.
