Creep prediction model for nickel-based single-crystal superalloys considering precipitation of TCP phase

The microstructure of nickel-based single-crystal(SC) superalloys has a pivotal influence on their creep properties. The addition of the Re element not only enhances the long-term creep properties of nickel-based SC superalloys, but also results in the formation of a topologically close-packed(TCP) phase which is a harmful and brittle hard phase. Here, high-temperature creep interruption tests of a nickel-based SC superalloy that contains4.8 wt% Re were performed under various temperatures and stress conditions, and the evolution of microstructure during creep was observed by scanning electron microscopy(SEM). The volume fraction of the TCP phase was also extracted to explore the mechanism that controls the impacts of the TCP phase on the creep properties.According to the microstructure evolution mechanism, the influence of the TCP phase was attributed to the initial damage and critical shear stress of the material. A creep performance prediction model for nickel-based SC superalloys considering the precipitation of the TCP phase that is based on the crystal plasticity theory and a modified creep damage model was established. The simulation curves fit well with the experimental results and the errors between prediction creep life with test results are within 5%.

Highly Improved Creep Resistance in Polypropylene Through Thermally Reduced Graphene Oxide and Its Creep Lifetime Prediction

Polypropylene(PP) exhibits suboptimal creep resistance due to the presence of methyl groups on its main chain, leading to irregular chain segment distribution, diminished inter-chain interaction, and crystallinity. This structural feature causes chain slippage in PP under stress,significantly constraining its service lifetime. In this study, thermally reduced graphene oxide(TrGO) nanosheets were incorporated into the PP matrix, yielding a nanocomposite with exceptional creep resistance performance. Results demonstrated that at a stress of 25 MPa, a 2.0 wt% TrGO content could enhance the creep failure lifetime of PP by 21.5 times compared to neat PP. Rheology, transmission electron microscopy(TEM),and scanning electron microscopy(SEM) characterization techniques were employed to analyze the mechanism of TrGO's influence on PP's creep behavior. It was observed that when TrGO content exceeded 1.0 wt%, an effective particle network structure formed within the PP matrix. This homogeneously dispersed TrGO-formed particle network structure restricted the migration and rearrangement of PP molecular chains, enabling prolonged stress resistance without structural failure. By combining the time-strain superposition method with the critical failure strain as a criterion, generalized creep compliance curves for PP and its composites were established, facilitating the prediction of material creep failure lifetimes, with a strong agreement between experimental and predicted lifetime values. This research proposes a novel strategy aimed at developing polypropylene materials and products with enhanced long-term stability and durability, thus extending service life, reducing failure risk, and broadening their potential across various application domains.

Experimental and simulated characterization of creep behavior of P92 steel with prior cyclic loading damage

The effect of prior cyclic loading on creep behavior of P92 steel was investigated. Creep tests on prior cyclic loading exposure specimens were performed at 650？C and 130 MPa. In order to clarify the influence of prior cyclic loading on creep behavior, optical microscope, scanning electron microscope and transmission electron microscope were used. Experimental results indicate that the prior cyclic loading degrades the creep strength significantly. However, the degradation tends to be saturated with further increase in prior cyclic loading. From the view of microstructural evolution, the recovery of martensite laths takes place during prior cyclic loading exposure. This facilitates the dislocation movement during the following creep process. Therefore, premature rupture of creep test occurs. Additionally, saturated behavior of degradation can be attributed to the near completed recovery of martensite laths. Based on the effect of prior cyclic loading, a newly modified Hayhurst creep damage model was proposed to consider the prior cyclic loading damage. The main advantage of the proposed model lies in its ability to directly predict creep behavior with different levels of prior cyclic loading damage. Comparison of the predicted and experimental results shows that the proposed model can give a reasonable prediction for creep behavior of P92 steel with different level of prior cyclic loading damage.

EBSD parameter assessment and constitutive models of crept HR3C austenitic steel

Creep damage and evolution of HR3C steel at 650℃ were investigated using electron backscatter diffraction(EBSD),and EBSD-based parameter assessments were conducted.EBSD analyses show that the grain size is almost unchanged and no obvious texture formed after creep at different creep rates.The lowest proportion of low Σ coincidence site lattice grain boundaries under 150 MPa implies that the primary twin structures are preserved under the low stress level,while some twin structures evolved into general grain boundaries at the high creep level.Two main damage features of microcracks and cavities can be seen along the grain boundaries:the former emerged at higher stress levels,while the latter appeared at the lower stress level,and both were shown under medium stress.Band contrast shows that the most severe creep damage is present at 170 MPa.It implies that the creep mechanism differs distinctly under different stress levels,and the transition point is around 170 MPa.Kernel average misorientation is better to describe the local plastic deformation related to the strain distribution while grain reference orientation deviation describes the inhomogeneous strain distribution.Creep lifetime prediction models including the isothermal method,Larson-Miller parameter method and Monkman–Grant relation were evaluated by the experimental data and literature data,and they are valid for predicting creep behavior.