Effect of carbon on high temperature compressive and creep properties of β-stabilized TiA l alloy

Carbon is an important alloying element in improving high temperature mechanical properties of various metallic materials.The effects of carbon on high temperature mechanical properties of aβ-stabilized Ti?45Al?3Fe?2Mo(molar fraction,%)alloy were studied through compressive and creep tests.The results show that the carbon addition(0.5%,molar fraction)obviously enhances the high temperature compressive strength and creep resistance of theβ-stabilized Ti?45Al?3Fe?2Mo alloy.A lot of nano-scaled Ti3AlC carbides precipitate in theβ-stabilized alloy and these carbides pin the dislocations,and greatly increase the high temperature properties.At the same time,the carbon addition decreases the amount of?phase,refines the lamellar spacing,and causes solution strengthening,which also contribute to the improvement of the high temperature properties.

A multi-scale algorithm for dislocation creep at elevated temperatures

Dislocation creep at elevated temperatures plays an important role for plastic deformation in crystalline metals.When using traditional discrete dislocation dynamics(DDD)to capture this process,we often need to update the forces on N dislocations involving~N 2 interactions.In this letter,we introduce a multi-scale algorithm to speed up the calculations by dividing a sample of interest into sub-domain grids:dislocations within a characteristic area interact following the conventional way,but their interaction with dislocations in other grids are simplified by lumping all dislocations in another grid as a super one.Such a multi-scale algorithm lowers the computational load to~N 1.5.We employed this algorithm to model dislocation creep in Al-Mg alloy.The simulation leads to a power-law creep rate in consistent with experimental observations.The stress exponent of the power-law creep is a resultant of dislocations climb for~5 and viscous dislocations glide for~3.

Creep performance of PVC aged at temperature relatively close to glass transition temperature

In order to predict the mechanical performance of the polyvinyl chloride （PVC） at a high operating temperature, a series of short-term tensile creep tests （one- tenth of the physical aging time） of the PVC are carried out at 63 ℃ with a small constant stress by a dynamic mechanical analyzer （DMA）. The Struik-Kohlrausch （SK） formula and Struik shifting methods are used to describe these creep data for various physical aging time. A new phenomenological model based on the multiple relaxation mechanisms of an amorphous polymer is developed to quantitatively characterize the SK parameters （the initial creep compliance, the characteristic retardation time, and the shape factor） determined by the aging time. It is shown that the momentary creep compliance curve of the PVC at 63℃ can be very well fitted by the SK formula for each aging time. However, the SK parameters for the creep curves are not constant during the aging process at the elevated temperatures, and the evolution of these parameters and the creep rate versus aging time curves at the double logarithmic coordinafes have shown a nonlinear phenomenon. Moreover, the creep master curves obtained by the superposition with the Struik shifting methods are unsatisfactory in such a case. Finally, the predicted results calculated from the present model incorporating with the SK formula are in excellent agreement with the creep experimental data for the PVC isothermally aged at the temperature relatively close to the glass transition temperature.

High Temperature Creep behaviour of a Si_3N_4 Whisker Reinforced Al-Fe-V-Si Composite

The creep behaviour of β-Si3N4 whisker reinforced Al-8.5Fe-1.3V-1.7Si composite has been investigated at the temperature 773 and 823 K. The results are characterized by high stress exponent and high apparent creep activation energy The creep data can be interpreted based on the incorporation of a threshold Stress and a load transfer coefficient into the power-law creep equation. A good correlation between the normalized creep rate and normalized effective stress is available which demonstrates that the creep behaviour of both the alloy and the composite is controlled by the matrix lattice self-diffusion in AI. EXamination on microstructure shows that edge dislocations exist at the interfaces between two adjacent whiskers and the intedeces emit edge dislocations in parallel paired-columns.

“Low Creep Ultra-high Temperature Corundum Mullite Kiln Furnature” Developed by Sinosteel LIRR Rewarded as “National New Product”

Recently, ＂ Low Creep Ultra-high Temperature Corundum Mullite Kiln Fumature＂ developed by Sinosteel L1RR was listed in The National New Product Program in 2012 of The Ministry of Science and Technology of China.

Hydrogen Release and Room Temperature Creep for Vanadium Alloys Containing Hydrogen

Vanadium alloy has been taken as one of the candidate structural materials for fusion reactors because of its excellent high-temperature mecha nical performances, high thermal stress factor and low radioactivity. It is a kind of potential materials for hydrogen storage as well. Because operated in an environment conta!ning hydrogen and its isotopes or the neutron irradiation resulting transmutation product of H, the problem that H induced degradation of mechanical properties and hydrogen embrittlement has been being one of the key issues for the application for vanadium alloys.

Elevated temperature creep model of parallel wire strands

T Parallel wire strands(PWSs),which are widely used in prestressed steel structures,are typically in highstress states.Under fire conditions,significant creep effects occur,reducing the prestress and influencing the mechanical behavior of PWSs.As there is no existing approach to analyze their creep behavior,this study experimentally investigated the elevated temperature creep model of PWSs.A charge-coupled camera system was incorporated to accurately obtain the deformation of the specimen during the elevated temperature creep test.It was concluded that the temperature level had a more significant effect on the creep strain than the stress level,and 450℃ was the key segment point where the creep rate varied significantly.By comparing the elevated temperature creep test results for PWSs and steel strands,it was found that the creep strain of PWSs was lower than that of steel strands at the same temperature and stress levels.The parameters in the general empirical formula,the Bailey–Norton model,and the composite timehardening model were fitted based on the experimental results.By evaluating the accuracy and form of the models,the composite time-hardening model,which can simultaneously consider temperature,stress,and time,is recommended for use in the fire-resistance design of pre-tensioned structures with PWSs.

SiCp/Al复合材料高温蠕变行为

研究了蠕变温度与蠕变应力载荷对SiCp/Al复合材料高温蠕变行为的影响,分析了该复合材料的蠕变断裂机制,并计算得出了材料的应力指数与激活能。结果表明:蠕变速率随蠕变应力荷载的增大和蠕变温度的升高而增大,应力指数与变形激活能分别为n=9.8和Q=182 k J/mol。该复合材料的蠕变断裂机制为韧性断裂。通过对比得出,SiCp/Al复合材料的抗高温蠕变性能明显优于基体材料。

Influences of Shrinkage,Creep,and Temperature on the Load Distributions in Reinforced Concrete Buildings During Construction

Site measurements have shown that slab loads re-distribute, between the slabs during the concrete curing, while the external Ioadings and structural geometry remain the same. Some have assumed that this is caused by concrete shrinkage and creep, but there have been no studies on how these factors exactly influence the load distributions and to what degree these influences exist. This paper analyzes the influences of concrete shrinkage, creep, and temperature on the load re-distributions among slabs. Although these factors may all lead to load re-distribution, the results show that the influence of concrete shrinkage can be neglected. Simulations indicate that shrinkage only reduces slab loads by a maximum of 1.1%. Creep, however, may reduce the maximum slab load by from 3% to 16% for common construction schemes. More importantly, temperature variations between day and night can cause load fluctuation as large as 31.6%. This analysis can, therefore, assist site engineers to more accurately estimate slab loads for construction planning.

Microscopic damage mechanism of SA508 Gr3 steel in ultra-high temperature creep

The lower head of reactor pressure vessel （RPV） will endure a great temperature gradient above the phase transition temperature, and the creep and fracture will be the primary failure mode for the RPV material in such a situation. The interrupted creep tests were performed on a typical RPV material, SA508 Gr3 steel, at 800 ℃. The microstructure of different creep stages was examined by scanning electron microscopy and transmission electron microscopy. The results showed that the microscopic damage is mainly induced by creep cavities and coarse second-phase particles. Furthermore, the volume fractions of creep cavities and coarse second-phase particles show a linear relationship with the extended creep time. The second-phase particles are determined to be MoC in the second creep stage and Mo2C in the third creep stage, according to the results of selected-area electron diffraction pattern. Combined with energy-dispersive spectrum analysis, the segregation of precipitates caused by the migration of atoms is finally unveiled, which leads to the coarsening of the particles.

Precipitate Phases in an 11% Cr Ferritic/Martensitic Steel with Tempering and Creep Conditions

Precipitates in an 11% Cr ferritic/martensitic steel containing Nd with tempering and creep conditions were investigated using transmission electron microscope with energy-dispersive X-ray spectroscopy. The precipitates in the steel with a tempering condition were identified to be Cr-rich M23C6 carbide, Nb-rich/V-rich/Ta–Nb-rich MX carbides, Nbrich MX carbonitride, and Fe-rich M5C2 carbide. Nd-rich carbonitride, which is not known to have been reported previously in steels, was also detected in the steel after tempering. Most of the Nb-rich MX precipitates were dissolved, whereas the amount of Ta-rich MX precipitates was increased significantly in the steel after a creep test at 600 °C at an applied stress of180 MPa for 1,100 h. No Fe2 W Laves phase has been detected in the steel after tempering.（Fe, Cr）2W Laves phase with a relatively large size was observed in the steel after the creep test.

Influence of Ta/Al ratio on the microstructure and creep property of a Ru-containing Ni-based single-crystal superalloy

Two alloys with different Ta and Al contents were applied to study the influence of Ta/Al ratio on the microstructural evolution and creep deformation under high temperature.The increase of Ta/Al ratio made theγ/γ'lattice misfit more negative and enhanced the volume fraction ofγ'phase,which produced cubic and smallγ'phase in the initial microstructures.These initial tinyγ'phases impeded the dislocations movement and delayed the course of complete raftedγ'phase during the origination of creep deformation,which prolonged the time of the primary creep stage.Moreover,the increase of Ta/Al ratio and addition of Ru produced the denser and stable dislocation networks,the high APB energy and better solution strengthening,which hindered the climbing and sliding of dislocations,and restrained the formation of superdislocations in theγ'precipitate.The second creep stage was extended,and the minimum creep rate was reduced.Hence,the increase of whole creep life of the alloy containing high Ta/Al ratio was attributed to the prolongation of the primary and second creep stages,and the low minimum creep rate.The appearance of the topological inversion phenomenon during the tertiary creep stage was the primary cause for the sudden increase of the creep strain rate of the alloy containing low Ta/Al ratio.However,the high creep strain rate of the alloy containing high Ta/Al ratio during the tertiary creep stage was related to the occurrence and extending of the cracks near the voids.Both alloys would lose efficacy within 20 h-30 h.

Effect of rhenium on the microstructure and mechanical behavior of Fe–2.25Cr–1.6W–0.25V-0.1C bainitic steels

A new ferritic creep resistant steel has been developed by eliminating Nb and adding 1.5 mass % Re to a ferritic steel grade T/P23 with the aim of enhancing its mechanical properties at high temperature.Cast ingots of both steels, new grade and ASTM T/P 23, were hot rolled at 900℃ and then submitted to a thermal treatment consisting of solubilization at 1050℃ and tempering at 700℃. Tempered bainitic microstructures obtained contain second phases reinforcing carbide particles, mainly M_6C and M_（23）C_6 at the boundaries of both, prior austenite grains and bainitic ferrite laths, as well as MC within the grains. Mechanical properties at temperatures ranging from 540 to 600℃ were studied by strain-ratechange tests in compression at strain rates between 10^（-7） and 10^（-4）s^（-1）. These tests showed high stress exponents（n ≥ 20） and activation energies（Q ≈ 400 k J/mol） for both alloys, which were associated with a dislocation movement mechanism with a strong interaction between dislocations and precipitates. On the other hand, a creep exponent of 5 was derived for the stress dependence of minimum creep rate from conventional-type creep tests at 600℃. Although this stress exponent is usually related to a dislocation climb controlled creep mechanism, remarkable microstructural degradation observed with increasing creep time makes difficult to elucidate the true deformation mechanism controlling creep.