A method of estimating the safe storage life （τ）, self-accelerating decomposition temperature （TsADT） and critical temperature of thermal explosion （Tb） of double-base propellant using isothermal and non-isothe...A method of estimating the safe storage life （τ）, self-accelerating decomposition temperature （TsADT） and critical temperature of thermal explosion （Tb） of double-base propellant using isothermal and non-isothermal decomposition behaviours is presented. For double-base propellant composed of 56±1wt% of nitrocellulose （NC）, 27±0.5wt% of nitroglycerine （NG）, 8.15±0.15wt% of dinitrotoluene （DNT）, 2.5±0.1wt% of methyl centralite, 5.0±0.15wt% of catalyst and 1.0±0.1wt% of other, the values of r of 49.4 years at 40℃, of TSAOT of 151.35℃ and of Tb of 163.01℃ were obtained.展开更多
A method of estimating the critical rate of temperature rise for the thermal explosion of first order autocatalytic decomposition reaction systems by using non-isothermal DSC is presented. The information was obtained...A method of estimating the critical rate of temperature rise for the thermal explosion of first order autocatalytic decomposition reaction systems by using non-isothermal DSC is presented. The information was obtained on the increasing rate of temperature for the first order autocatalytic decomposition of nitrocellulose containing 13.86% nitrogen converting into the thermal explosion.展开更多
Two general expressions and their six derived formulae for estimating the critical temperature（Tb） of thermal explosion for energetic materials（EMs） were derived from the Semenov＇s thermal explosion theory and ei...Two general expressions and their six derived formulae for estimating the critical temperature（Tb） of thermal explosion for energetic materials（EMs） were derived from the Semenov＇s thermal explosion theory and eight non-isothermal kinetic equations via reasonable hypothesis. We can easily obtain the values of the initial temperature（T0i） at which DSC curve deviates from the baseline of the non-isothermal DSC curve of EMs, the onset temperature（Tei）, the exothermic decomposition reaction kinetic parameters and the values of Too and Te0 from the equation Toiorei=Tooore0＋α1β1＋α2β2＋...＋αL-2βi^L-2, i=1, 2, …, L and then calculate the values of Tb by means of the six derived formulae. The results obtained with the six derived calculating methods for six trinitromethyl explosives： bis（2,2,2- trinitroethyl-N-nitro） ethylene diamine（BTNEDA）, 2,2,2-trinitroethyl-4,4,4-trinitrobutyrate（TNETB）, bis（2,2,2- trinitroethyl） formal（BNTF）, bis（2,2,2-trinitroethyl-nitramine）（BTNNA）, 2,2,2-trinitroethyl-2,2,2-trinitroethyl-N- nitroamino acetate（TNTNNA） and tetrakis [2,2,2-trinitroethyl] orthoester（TTNOE） agree well with each other.展开更多
In this study,the approximate and exact solutions for the stationary-state of the solids model with neglecting reactant consumption for both non-uniform and uniform temperature systems were applied on gas ignition und...In this study,the approximate and exact solutions for the stationary-state of the solids model with neglecting reactant consumption for both non-uniform and uniform temperature systems were applied on gas ignition under a constant pressure condition.The criticality conditions for a slab,an infinite cylinder,and a sphere are determined and discussed using dimensionless temperatures under constant ambient and surface temperatures for a non-uniform temperature system.Exact solution for a Semenov model with convection heat loss was also presented.The solution of the Semenov problem for constant volume or density as a solid and constant pressure were compared.The critical parameterδis calculated and compared with those of Frank-Kamenetskii solution values.The validation of the calculated ignition temperatures with other exact solution and experimental results were offered.The relation between critical parameters form Semenov and F.K.models solution was introduced.展开更多
A method for estimating the critical temperature of thermal explosion for energetic materials using differential scanning calorimetry (DSC) measurement is derived from the Semenov's thermal explosion theory and th...A method for estimating the critical temperature of thermal explosion for energetic materials using differential scanning calorimetry (DSC) measurement is derived from the Semenov's thermal explosion theory and the non-isothermal kinetic equation based on Harcourt-Esson's kinetic equation.The result obtained from this method coincides completely with that of the Hu-Yang-Liang-Wu method.展开更多
The thermal decomposition behavior of composite modified double-base（CMDB） propellant containing cyclotrimethylene trinitramine（RDX） was studied via a Calvet microcalorimeter at five different heating rates. The a...The thermal decomposition behavior of composite modified double-base（CMDB） propellant containing cyclotrimethylene trinitramine（RDX） was studied via a Calvet microcalorimeter at five different heating rates. The activation energy（E） and the pre-exponential factor（A） of two obvious exothermic processes were obtained by Kissinger＇s method and Ozawa＇s method. The entropy of activation（△S^≠）, the enthalpy of activation（△H^≠）, and the free energy of activation（△G^≠） of the first stage were calculated. To evaluate the thermal hazard of the RDX-CMDB propellant, the critical temperature of thermal explosion（Tb）, the self acceleration decomposition temperature（Tsgox）, the adiabatic decomposition temperature increment（ATad） and the time-to-explosion of adiabatic system（t） were presented as 145.3 ℃, 138.15 ℃, 1634 K and 583.71 s（n=0） and 586.28 s（n=1）, respectively.展开更多
为了防止RDX在生产过程中发生爆炸事故,采用自行设计的临界爆温测试装置测试了RDX溶液的临界爆温.结果表明,0.4 g RDX在较高温度下加热时只发生分解反应而不会发生爆炸;RDX质量分数为4％～8％时,RDX溶液在193.0℃左右迅速分解并发生爆炸...为了防止RDX在生产过程中发生爆炸事故,采用自行设计的临界爆温测试装置测试了RDX溶液的临界爆温.结果表明,0.4 g RDX在较高温度下加热时只发生分解反应而不会发生爆炸;RDX质量分数为4％～8％时,RDX溶液在193.0℃左右迅速分解并发生爆炸,从而得出丙酮对RDX溶液热分解有一定的催化作用.在RDX溶液质量分数为4％～8％时,浓度变化对RDX溶液的临界爆温影响较小;当RDX溶液质量分数低于4％时,RDX溶液不发生爆炸.展开更多
基金We are grateful to the National Natural Science Foundation of China （No. 20573098）
文摘A method of estimating the safe storage life （τ）, self-accelerating decomposition temperature （TsADT） and critical temperature of thermal explosion （Tb） of double-base propellant using isothermal and non-isothermal decomposition behaviours is presented. For double-base propellant composed of 56±1wt% of nitrocellulose （NC）, 27±0.5wt% of nitroglycerine （NG）, 8.15±0.15wt% of dinitrotoluene （DNT）, 2.5±0.1wt% of methyl centralite, 5.0±0.15wt% of catalyst and 1.0±0.1wt% of other, the values of r of 49.4 years at 40℃, of TSAOT of 151.35℃ and of Tb of 163.01℃ were obtained.
基金Supported by the Science and Technology Foundation of Shaanxi Key L aboratory of Physico- Inorganic Chemistry(No.2 9- 3,2 0 0 1) and the Science and Technology Foundation of Propellant and Explosive Combustion of China(No.5 14 5 5 0 10 1)
文摘A method of estimating the critical rate of temperature rise for the thermal explosion of first order autocatalytic decomposition reaction systems by using non-isothermal DSC is presented. The information was obtained on the increasing rate of temperature for the first order autocatalytic decomposition of nitrocellulose containing 13.86% nitrogen converting into the thermal explosion.
基金Supported by the National Natural Science Foundation of China(Nos.20573098, 50846021 and 69075036)
文摘Two general expressions and their six derived formulae for estimating the critical temperature（Tb） of thermal explosion for energetic materials（EMs） were derived from the Semenov＇s thermal explosion theory and eight non-isothermal kinetic equations via reasonable hypothesis. We can easily obtain the values of the initial temperature（T0i） at which DSC curve deviates from the baseline of the non-isothermal DSC curve of EMs, the onset temperature（Tei）, the exothermic decomposition reaction kinetic parameters and the values of Too and Te0 from the equation Toiorei=Tooore0＋α1β1＋α2β2＋...＋αL-2βi^L-2, i=1, 2, …, L and then calculate the values of Tb by means of the six derived formulae. The results obtained with the six derived calculating methods for six trinitromethyl explosives： bis（2,2,2- trinitroethyl-N-nitro） ethylene diamine（BTNEDA）, 2,2,2-trinitroethyl-4,4,4-trinitrobutyrate（TNETB）, bis（2,2,2- trinitroethyl） formal（BNTF）, bis（2,2,2-trinitroethyl-nitramine）（BTNNA）, 2,2,2-trinitroethyl-2,2,2-trinitroethyl-N- nitroamino acetate（TNTNNA） and tetrakis [2,2,2-trinitroethyl] orthoester（TTNOE） agree well with each other.
文摘In this study,the approximate and exact solutions for the stationary-state of the solids model with neglecting reactant consumption for both non-uniform and uniform temperature systems were applied on gas ignition under a constant pressure condition.The criticality conditions for a slab,an infinite cylinder,and a sphere are determined and discussed using dimensionless temperatures under constant ambient and surface temperatures for a non-uniform temperature system.Exact solution for a Semenov model with convection heat loss was also presented.The solution of the Semenov problem for constant volume or density as a solid and constant pressure were compared.The critical parameterδis calculated and compared with those of Frank-Kamenetskii solution values.The validation of the calculated ignition temperatures with other exact solution and experimental results were offered.The relation between critical parameters form Semenov and F.K.models solution was introduced.
基金the National Natural Science Foundation of China (60975036)
文摘A method for estimating the critical temperature of thermal explosion for energetic materials using differential scanning calorimetry (DSC) measurement is derived from the Semenov's thermal explosion theory and the non-isothermal kinetic equation based on Harcourt-Esson's kinetic equation.The result obtained from this method coincides completely with that of the Hu-Yang-Liang-Wu method.
基金Supported by the National Natural Science Foundation of China(No.20573098)the Science and Technology Foundation of the National Defense Key Laboratory of Propellant and Explosive Combustion in China(No.9140C3501020901)
文摘The thermal decomposition behavior of composite modified double-base（CMDB） propellant containing cyclotrimethylene trinitramine（RDX） was studied via a Calvet microcalorimeter at five different heating rates. The activation energy（E） and the pre-exponential factor（A） of two obvious exothermic processes were obtained by Kissinger＇s method and Ozawa＇s method. The entropy of activation（△S^≠）, the enthalpy of activation（△H^≠）, and the free energy of activation（△G^≠） of the first stage were calculated. To evaluate the thermal hazard of the RDX-CMDB propellant, the critical temperature of thermal explosion（Tb）, the self acceleration decomposition temperature（Tsgox）, the adiabatic decomposition temperature increment（ATad） and the time-to-explosion of adiabatic system（t） were presented as 145.3 ℃, 138.15 ℃, 1634 K and 583.71 s（n=0） and 586.28 s（n=1）, respectively.
文摘为了防止RDX在生产过程中发生爆炸事故,采用自行设计的临界爆温测试装置测试了RDX溶液的临界爆温.结果表明,0.4 g RDX在较高温度下加热时只发生分解反应而不会发生爆炸;RDX质量分数为4％～8％时,RDX溶液在193.0℃左右迅速分解并发生爆炸,从而得出丙酮对RDX溶液热分解有一定的催化作用.在RDX溶液质量分数为4％～8％时,浓度变化对RDX溶液的临界爆温影响较小;当RDX溶液质量分数低于4％时,RDX溶液不发生爆炸.
