Nd-Hf Isotopic Decoupling of the Silurian–Devonian Granitoids in the Chinese Altai: A Consequence of Crustal Recycling of the Ordovician Accretionary Wedge?

Voluminous Silurian–Devonian granitoids intruded a greywacke-dominated Ordovician accretionary wedge in the Chinese Altai. These granitoids are characterized by significant Nd-Hf isotopic decoupling, the underlying mechanism of which, so far, has been poorly understood. This issue is addressed in this study by the integration of our new and regional published geological and geochemical data. Geological studies indicated a close spatial relationship between the regional anatexis of the Ordovician wedge and the formation of the granitoids, which is characterized by a gradual textural evolution from the partial molten Ordovician wedge sedimentary rocks(the Habahe Group) to the granitoid bodies. Compositionally, these granitoids and the Ordovician Habahe Group rocks displayed close geochemical similarities, in the form of arclike trace elemental signatures as well as comparable Nd isotopic characteristics. Combined with regional available data, we suggest that the Silurian–Devonian granitoids originated from the immature and chemically primitive Habahe Group rocks. Since Nd and Hf isotopic data for the Habahe Group rocks show significant Nd-Hf isotopic decoupling, we propose that the Silurian–Devonian granitoids inherited the Nd and Hf isotopic signatures from their sources, i.e., the Habahe Group rocks. In other words, the Nd-Hf decoupling in the Habahe Group rocks is the primary causative factor leading to the prevailing Nd-Hf isotopic decoupling of the Silurian–Devonian granitoids in the Chinese Altai.

Molybdenum isotope composition of the upper mantle and its origin:insight from mid-ocean ridge basalt

The molybdenum(Mo)isotope system is pivotal in reconstructing marine redox changes throughout Earth’s history and has emerged as a promising tracer for igneous and metamorphic processes.Understanding its composition and variation across major geochemical reservoirs is essential for its application in investigating high-temperature processes.However,there is debate regarding theδ^(98/95)Mo value of the Earth’s mantle,with estimates ranging from sub-chondritic to super-chondritic values.Recent analyses of global mid-ocean ridge basalt(MORB)glasses revealed significantδ^(98/95)Mo variations attributed to mantle heterogeneity,proposing a two-component mixing model to explain the observed variation.Complementary studies confirmed the sub-chondriticδ^(98/95)Mo of the depleted upper mantle,suggesting remixing of subduction-modified oceanic crust as a plausible mechanism.These findings underscore the role of Mo isotopes as effective tracers for understanding dynamic processes associated with mantle-crustal recycling.

Ophiolites as Archives of Recycled Crustal Material Residing in the Deep Mantle

Deeply subducted lithospheric slabs may reach to the mantle transition zone(MTZ,410-660 km depth)or even to the core–mantle boundary(CMB)at depths of^2900km.Our knowledge of the fate of subducted surface material at the MTZ or near the CMB is poor and based mainly on the tomography data and laboratory experiments through indirect methods.Limited data come from the samples of deep mantle diamonds and their mineral inclusions obtained from kimberlites and associated rock assemblages in old cratons.We report in this presentation new data and observations from diamonds and other UHP minerals recovered from ophiolites that we consider as a new window into the life cycle of deeply subducted oceanic and continental crust.Ophiolites are fragments of ancient oceanic lithosphere tectonically accreted into continental margins,and many contain significant podiform chromitites.Our research team has investigated over the last 10 years ultrahigh-pressure and super-reducing mineral groups discovered in peridotites and/or chromitites of ophiolites around the world,including the Luobusa(Tibet),Ray-Iz(Polar Urals-Russia),and 12 other ophiolites from 8orogenic belts in 5 different countries(Albania,China,Myanmar,Russia,and Turkey).High-pressure minerals include diamond,coesite,pseudomorphic stishovite,qingsongite(BN)and Ca-Si perovskite,and the most important native and highly reduced minerals recovered to date include moissanite(Si C),Ni-Mn-Co alloys,Fe-Si and Fe-C phases.These mineral groups collectively confirm extremely high?pressures(300 km to≥660 km)and super-reducing conditions in their environment of formation in the mantle.All of the analyzed diamonds have unusually light carbon isotope compositions(δ13C=-28.7 to-18.3‰)and variable trace element contents that*d i stinguish them from most kimberlitic and UHPmetamorphic varieties.The presence of exsolution lamellae of diopside and coesite in some chromite grains suggests chromite crystallization depths around>380 km,near the mantle transition zone.The carbon isotopes and other features of the high-pressure and super-reduced mineral groups point to previously subducted surface material as their source of origin.Recycling of subducted crust in the deep mantle may proceed in three stages:Stage 1–Carbon-bearing fluids and melts may have been formed in the MTZ,in the lower mantle or even near the CMB.Stage 2–Fluids or melts may rise along with deep plumes through the lower mantle and reach the MTZ.Some minerals,such as diamond,stishovite,qingsongite and Ca-silicate perovskite can precipitate from these fluids or melts in the lower mantle during their ascent.Material transported to the MTZ would be mixed with highly reduced and UHP phases,presumably derived from zones with extremely low f O2,as required for the formation of moissanite and other native elements.Stage 3–Continued ascent above the transition of peridotites containing chromite and ultrahigh-pressure minerals transports them to shallow mantle depths,where they participate in decompressional partial melting and oceanic lithosphere formation.The widespread occurrence of ophiolite-hosted diamonds and associated UHP mineral groups suggests that they may be a common feature of in-situ oceanic mantle.Because mid-ocean ridge spreading environments are plate boundaries widely distributed around the globe,and because the magmatic accretion of oceanic plates occurs mainly along these ridges,the on-land remnants of ancient oceanic lithosphere produced at former mid-ocean ridges provide an important window into the Earth’s recycling system and a great opportunity to probe the nature of deeply recycled crustal material residing in the deep mantle

Conjecture with water and rheological control for subducting slab in the mantle transition zone

Seismic observations have shown structural variation near the base of the mantle transition zone （MTZ） where subducted cold slabs, as visualized with high seismic speed anomalies （HSSAs）, flatten to form stagnant slabs or sink further into the lower mantle. The different slab behaviors were also accompanied by variation of the ＂660 kin＂ discontinuity depths and low viscosity layers （LVLs） beneath the MTZ that are suggested by geoid inversion studies. We address that deep water transport by subducted slabs and dehydration from hydrous slabs could affect the physical properties of mantle minerals and govern slab dynamics. A systematic series of three-dimensional numerical simulation has been conducted to examine the effects of viscosity reduction or contrast between slab materials on slab behaviors near the base of the MTZ. We found that the viscosity reduction of subducted crustal material leads to a sepa- ration of crustal material from the slab main body and its transient stagnation in the MTZ. The once trapped crustal materials in the MTZ eventually sink into the lower mantle within 20 30 My from the start of the plate subduction. The results suggest crustal material recycle in the whole mantle that is consistent with evidence from mantle geochemistry as opposed to a two-layer mantle convection model. Because of the smaller capacity of water content in lower mantle minerals than in MTZ minerals, dehydration should occur at the phase transformation depth, ~660 kin. The variation of the disconti- nuity depths and highly localized low seismic speed anomaly （LSSA） zones observed from seismic P waveforms in a relatively high frequency band （~ 1 Hz） support the hypothesis of dehydration from hydrous slabs at the phase boundary. The LSSAs which correspond to dehydration induced fluids are likely to be very local, given very small hydrogen （H＋） diffusivity associated with subducted slabs. The image of such local LSSA zones embedded in HSSAs may not be necessarily captured in tomography studies. The high electrical conductivity in the MTZ beneath the northwestern Pacific subduction zone does not necessarily require a broad range of high water content homogeneously.

Mantle geochemistry: Insights from ocean island basalts

The geochemical study of the Earth's mantle provides important constraints on our understanding of the formation and evolution of Earth, its internal structure, and the mantle dynamics. The bulk Earth composition is inferred by comparing terrestrial mantle rocks with chondrites, which leads to the chondritic Earth model. That is, Earth has the same relative proportions of refractory elements as that in chondrites, but it is depleted in volatiles. Ocean island basalts(OIB) may be produced by mantle plumes with possible deep origins; consequently, they provide unique opportunity to study the deep Earth. Isotopic variations within OIB can be described using a limited number of mantle endmembers, such as EM1, EM2 and HIMU, and they have been used to decipher important mantle processes. Introduction of crustal material into the deep mantle via subduction and delamination is important in generating mantle heterogeneity; however, there is active debate on how they were sampled by mantle melting, i.e.,the role of olivine-poor lithologies in the OIB petrogenesis. The origin and location of high 3He/4He mantle remain controversial,ranging from unprocessed(or less processed) primitive material in the lower mantle to highly processed materials with shallow origins, including ancient melting residues, mafic cumulates under arcs, and recycled hydrous minerals. Possible core-mantle interaction was hypothesized to introduce distinctive geochemical signatures such as radiogenic 186 Os and Fe and Ni enrichment in the OIB. Small but important variations in some short-lived nuclides, including 142 Nd, 182 W and several Xe isotopes, have been reported in ancient and modern terrestrial rocks, implying that the Earth's mantle must have been differentiated within the first 100 Myr of its formation, and the mantle is not efficiently homogenized by mantle convection.