The effect of cooling rate on the crystallization of perovskite in high Ti-bearing blast furnace（BF） slag was studied using confocal scanning laser microscopy（CSLM）. Results showed that perovskite was the primary ...The effect of cooling rate on the crystallization of perovskite in high Ti-bearing blast furnace（BF） slag was studied using confocal scanning laser microscopy（CSLM）. Results showed that perovskite was the primary phase formed during the cooling of slag. On the slag surface, the growth of perovskite proceeded via the successive production of quasi-particles along straight lines, which further extended in certain directions. The morphology and structure of perovskite was found to vary as a function of cooling rate. At cooling rates of 10 and 30 K/min, the dendritic arms of perovskite crossed obliquely, while they were orthogonal at a cooling rate of 20 K/min and hexagonal at cooling rates of 40 and 50 K/min. These three crystal morphologies thus obtained at different cooling rates respectively corresponded to the orthorhombic, cubic and hexagonal crystal structures of perovskite. The observed change in the structure of perovskite could probably be attributed to the deficiency of O^2-, when Ti2O3 was involved in the formation of perovskite.展开更多
The temperature field in MgO single crystal furnace is crucial to grow high-purity MgO single crystals with large sizes. In order to build proper temperature gradient, firstly finite element method （FEM） was used to...The temperature field in MgO single crystal furnace is crucial to grow high-purity MgO single crystals with large sizes. In order to build proper temperature gradient, firstly finite element method （FEM） was used to study the temperature field distributions, and then a temperature controller with adaptive neuro- fuzzy inference system （ANFIS） was developed based on the result of FEM and practical experiences. When the temperature in MgO single crystal furnace was changed, the controller would regulate the positions of three- phase electrodes and the voltage of the power simultaneously. The experimental results indicate that using the adaptive neuro-fuzzy control system can improve the quality and the quantity of the MgO single crystal production.展开更多
基金financially supported by the National Natural Science Foundation of China(No.51090383)the Fundamental Research Funds for the Central Universities of China(No.CDJZR12130049)
文摘The effect of cooling rate on the crystallization of perovskite in high Ti-bearing blast furnace（BF） slag was studied using confocal scanning laser microscopy（CSLM）. Results showed that perovskite was the primary phase formed during the cooling of slag. On the slag surface, the growth of perovskite proceeded via the successive production of quasi-particles along straight lines, which further extended in certain directions. The morphology and structure of perovskite was found to vary as a function of cooling rate. At cooling rates of 10 and 30 K/min, the dendritic arms of perovskite crossed obliquely, while they were orthogonal at a cooling rate of 20 K/min and hexagonal at cooling rates of 40 and 50 K/min. These three crystal morphologies thus obtained at different cooling rates respectively corresponded to the orthorhombic, cubic and hexagonal crystal structures of perovskite. The observed change in the structure of perovskite could probably be attributed to the deficiency of O^2-, when Ti2O3 was involved in the formation of perovskite.
基金Funded by the National High-Tech R&D Program(Nos.2008AA03A325, 2011AA06103)
文摘The temperature field in MgO single crystal furnace is crucial to grow high-purity MgO single crystals with large sizes. In order to build proper temperature gradient, firstly finite element method （FEM） was used to study the temperature field distributions, and then a temperature controller with adaptive neuro- fuzzy inference system （ANFIS） was developed based on the result of FEM and practical experiences. When the temperature in MgO single crystal furnace was changed, the controller would regulate the positions of three- phase electrodes and the voltage of the power simultaneously. The experimental results indicate that using the adaptive neuro-fuzzy control system can improve the quality and the quantity of the MgO single crystal production.
