Preparative isolation and purification of 12,13-dihydroxyeuparin from Radix Eupatorii Chinensis by high-speed counter-current chromatography

An efficient method for the isolation and purification of 12,13-dihydroxyeuparin from Radix Eupatorii Chinensis by high speed counter-current chromatography (HSCCC) was established in this paper. The ether extracts of Radix Eupatorii Chinensis were purified by HSCCC with a solvent system of hexyl hydride-ethyl acetate-methanol-water (1:2:1:2, v/v/v/v). The upper phase was used as the stationary phase and the lower phase as the mobile phase. About 8.4 mg of 12, 13-dihydroxyeuparin was obtained from 200 mg of ether extracts from Radix Eupatorii Chinensis in one-step HSCCC separation, with the purity of 96.71%, as determined by HPLC. After methanol- water recrystallization, the purity of 12,13-dihydroxyeuparin reached 99.83%. Such a simple and effective method was fairly useful to prepare pure compound as reference substances for related study on Radix Eupatorii Chinensis.

Effect of welding current and speed on occurrence of humping bead in high-speed GMAW

The developed mathematical model of humping formation mechanism in high-speed gas metal arc welding （GMAW） is used to analyze the effects of welding current and welding speed on the occurrence of humping bead. It considers both the momentum and heat content of backward flowing molten jet inside weld pool. Three-dimensional geometry of weld pool, the spacing between two adjacent humps and hump height along humping weld bead are calculated under different levels of welding current and welding speed. It shows that wire feeding rate, power intensity and the moment of backward flowing molten jet are the major factors on humping bead formation.

Effects of current waveform parameters during droplet transfer on spatter in high speed waveform controlled Short-circuiting GMAW

Aim at improving the stability of the Short-circuiting Gas Metal Arc Welding （GMAW-S） process for the enhanced speed usage, effects of current waveform parameters during short-term on the welding stability have been investigated by experimental method. The welding power source used for the research is an inverter with a special current waveform control. It is shown that the spatter decreases at first then increases with each increase of the low current period, current increase rate and the maximum current limit. The test results are provided for welding of 1 mm and 3 mm mild steel at speed of 1.2 m/min. The stable GMA W-S process under high speed welding condition has been achieved by optimizing the parameters.

An Economical Method for Preparative Purification of Five Alkaloids from Coptis Chinensis Franch by High-Speed Counter-Current Chromatography Using Singled Prepared Solvent System by GC

Coptis chinensis Franch, a widely used Traditional Chinese Medicine, shows various kinds of bioactivity. The major active components of the herb are considered to be alkaloids. Thus, preparative separation of these alkaloids is critical important for further pharmacology and mechanism studies. In the paper, five alkaloids from C. chinensis were purified by HSCCC using the solvent system composed of chloro-form-metha- nol-water (2:1:1, v/v/v) single prepared. The content of each solvent in solvent system were determined by gas chromatography (GC), then according the ratios of solvents in each phase to prepare the mobile and stationary phase respectively. And a comparative study was carried out between together preparation and single preparation of the solvent system. The purities and recoveries of all the products were over 98.5% and 92%. However, 134 mL chloroform, 336 mL methanol and 452 mL water were saved when the two phase were singled by GC. Our research showed an economical method for separating alkaloids from C. chinensis by HSCCC using the solvent system single prepared by GC.

Preface: Current research progress on mechanics of high speed rail

The construction and operation of high-speed rail（HSR）grid within the past two decades in China,in terms of the scale,may be possibly comparable to any national-wide construction in the history of China,even the Great Wall.By counting railways with commercial train service at the speed of200 km/h,China has the world’s longest HSR network with over 19 369.8 km of track in service today and this number

Separation and Purification of Acetophenones from Cynanchum bengei Decne Root Bark by Combination of Silica Gel and High-speed Counter-current Chromatography

[Objectives] To develop a method for separation and purification of acetophenones from Cynanchum bengei Decne root bark by combination of silica gel and high-speed counter-current chromatography( HSCCC). [Methods]The crude extract of Cynanchum bengei Decne root bark was separated by silica gel column chromatography,and parts A and B containing acetophenones were obtained. Then,parts A and B were separated by HSCCC with a two-phase solvent system composed of petroleum ether-ethyl acetate-methanol-water( 4∶ 6∶ 4. 5∶ 5. 5 and4∶ 6 ∶ 3 ∶ 7, V/V), respectively. [Results] From 260 mg of part A, four compounds with p-dihydroxybenzene 3. 9 mg(Ⅰ),4-hydroxyacetophenone 17. 1 mg( Ⅱ),2,5-di-hydroxyacetophenone 13. 3 mg(Ⅲ) and 2,4-dihydroxyaceto-phenone 21. 0 mg(Ⅳ) were obtained. And from 300 mg of part B,136 mg of Radix Cynanchi Bungei benzophenone(Ⅴ) was obtained. The purity of compounds determined by HPLC was 97. 0%,96. 6%,99. 2%,99. 7%,99. 5%,respectively. [Conclusions] The established method is simple and efficient. It can be used for separation of acetophenones from Cynanchum bengei Decne root bark and has better practical value,which could provide a reference basis for development and utilization of Cynanchum bengei Decne root bark.

基于EMD-PSO-BP模型的短期潮流流速预测

针对潮流流速的随机性和波动性,本研究基于经验模态分解(Empirical mode decomposition,EMD)和粒子群优化(Particle swarm optimization,PSO)算法,改进了反向传播(Back propagation,BP)神经网络的短期潮流流速预测模型。该模型首先对原始流速序列进行EMD分解,得到多个本征模函数(Intrinsic mode function,IMF)和残差。然后,利用PSO改进BP神经网络,对分解所得的IMF和残差分别进行预测。最后,将各个预测结果相结合,得出流速的最终预测结果,从而提高潮流流速的预测精度。本文以江苏省潮流流速为例,分别建立BP、PSO-BP、EMD-BP以及EMD-PSO-BP四类预测模型,以对潮流流速进行预测和对比分析。结果表明,相较于其他模型,EMD-PSO-BP预测模型在潮流流速的预测方面具有更高的精度,为潮流能开发提供重要的数据支撑。

Current Search: Performance Evaluation and Application to DC Motor Speed Control System Design

This paper proposes the current search (CS) metaheuristics conceptualized from the electric current flowing through electric networks for optimization problems with continuous design variables. The CS algorithm possesses two powerful strategies, exploration and exploitation, for searching the global optimum. Based on the stochastic process, the derivatives of the objective function is unnecessary for the proposed CS. To evaluate its performance, the CS is tested against several unconstrained optimization problems. The results obtained are compared to those obtained by the popular search techniques, i.e., the genetic algorithm (GA), the particle swarm optimization (PSO), and the adaptive tabu search (ATS). As results, the CS outperforms other algorithms and provides superior results. The CS is also applied to a constrained design of the optimum PID controller for the dc motor speed control system. From experimental results, the CS has been successfully applied to the speed control of the dc motor.

直流快速开断技术研究进展和展望

由于直流电流无自然过零点且短路电流上升率高,直流电流快速开断与系统故障切除成为制约直流电力系统发展的一大瓶颈。该综述首先介绍了直流快速开断技术要求与难点。其次,详细分析了直流快速开断过程涉及的关键技术,包括电流转移技术、固态式直流开断技术、介质恢复技术和高速机械开关技术等,综述了各种技术的当前发展现状及其应用情况,对比了不同技术方案的特点及适应性。最后,对直流快速开断技术未来发展方向进行了讨论和总结,为小型化、高性能、低成本、高可靠快速直流断路器的研发及推广应用提供了新的技术思路。

面向海流反演的多普勒散射计天线转速优化方法

本文针对多普勒散射计天线转速过快或者过慢导致海流反演精度较低甚至无法进行海流反演的问题,提出了一种面向海流反演的天线转速优化方法。该方法以研究区域内被天线波束覆盖3次或者4次的目标海面数量为目标函数,以顺轨与交轨方向的波束足印连续性、空间分辨率要求作为约束条件,结合天线转速与天线扫描损耗的关系,建立了非线性约束下的多普勒散射计天线转速优化模型,利用优化得到的天线转速计算得到每个目标海面的观测方位向组合。利用海洋表面流实时分析数据,采用基于观测方位向优选的矢量流合成方法进行了海流反演实验。结果表明,在天线转速为20 r·min^(-1)时,不同研究区域内被雷达内、外波束足印覆盖到3次或者4次的目标海面数量占总目标海面数量的80%以上,反演得到的流速、流向标准差小于0.1 m·s^(-1)、20°,满足海洋工程应用对海流观测的精度需求。

永磁同步电机新型趋近律滑模控制器设计

针对传统指数趋近律因函数不连续性引起抖振、趋近速度与抖振抑制之间无法同时满足高性能控制系统要求的问题,提出基于系统状态变量的新型滑模趋近律,并应用于永磁同步电机速度、电流控制器中。趋近律引入系统状态变量幂次项和状态变量的双曲正弦值,使系统状态变量以等速和指数2种速率趋向切换面,可以加快系统到达切换面的速度,当系统接近切换面时,指数项接近于0,等速项开始起关键作用,对系统的抖振进行抑制。同时采用双曲正切开关函数替代符号函数,以去除因函数的不连续性所引起的抖振问题。既能提高系统到达滑模面的速度,又能有效抑制固有抖振,提升系统的动态性能。仿真和实验结果表明,新型趋近律相比于传统指数趋近律能够有效降低永磁同步电机启动时转速超调,提高系统的响应速度,抑制系统的抖振。

直线轨道涡流制动对高速列车制动动力学特性的影响

列车制动性能直接影响车辆运行安全性和平稳性、稳定性,本文研究了加装直线轨道涡流制动系统对不同动力分配方式的高速列车制动动力学特性的影响规律.首先建立了6M2T和4M4T两种编组方式的列车动力学仿真模型,并与线路实验数据进行对比,验证了模型的有效性.基于该模型,研究了不同时速下的列车在不同动力分配形式下的动力学特性.针对惰行工况、电空制动工况与加装直线轨道涡流制动系统的联合制动工况,分别研究了第1、5、8节车厢的Sperling指标、脱轨系数、轮重减载率、轮轨作用力的变化规律,研究结果表明,动力分配方式、制动特性对车辆动力学性能有显著影响,涉及的关键动力学性能指标均满足安全限值标准,研究结果将为高速列车加装直线轨道涡流制动系统提供理论参考.

金刚石微粉电镀镍品质影响因素研究

金刚石微粉在镀液中易漂浮导致电镀镍困难,为获得金刚石微粉电镀镍工艺,本文研究了镀瓶转速和电镀电流对金刚石微粉电镀镍品质的影响。通过对金刚石微粉颗粒在不同镀瓶转速时运动状态进行理论分析,得到了镀瓶转速调节方法,并通过实验确定了不同电镀电流时镀瓶转速的调节范围。采用单因素实验,研究了电镀电流对镀层增重率、形貌和密度的影响。结果表明:镀瓶转速在1~7 r/min范围内,从小到大逐步提高,同时电镀电流不超过3.0 A条件下,能够实现金刚石微粉电镀镍。电镀电流在0.5 A时镀层失重,出现明显退镀现象,在1.0 A时镀层有少部分漏镀现象,在1.5~2.5 A时镀层包裹完整,基本无漏镀;电镀电流在1.0~2.5 A范围时,随着电镀电流增大,镀层增重率逐渐增大,镀层密度逐渐减小。采用低转速低电流、逐步提高镀瓶转速的方法对金刚石微粉进行电镀镍,镀瓶转速在1~7 r/min,电镀电流在1.5~2.5 A时金刚石微粉电镀镍品质较好。

具有快响应速度和低暗电流的垂直MSM型CsPbBr_(3)薄膜光电探测器

卤化物钙钛矿具有优异的电学和光学性能,是光电子器件中理想的有源层候选材料,特别是在高性能光探测方面显示出更具竞争力的发展前景,其中全无机钙钛矿CsPbBr_(3)因其良好的环境稳定性而被广泛关注.本文报道了一种具有快响应速度和低暗电流的垂直MSM型CsPbBr_(3)薄膜光电探测器.由于采用垂直结构缩短了光生载流子的渡越距离,器件具有超快的响应速度63μs,比传统平面MSM型光电探测器提高了两个数量级.然后,通过在p型CsPbBr_(3)与Ag电极之间旋涂一层TiO_(2)薄膜,提升了界面光生载流子的分离效率,实现了钙钛矿薄膜与金属电极间的物理钝化,从而大大降低了器件的暗电流,在–1 V的偏压下暗电流只有–4.81×10^(-12) A.此外,该种垂直MSM型CsPbBr_(3)薄膜光电探测器还具有线性动态范围大(122 dB)、探测率高(1.16×10^(12) Jones)和光稳定性好等诸多优点.通过Sentaurus TCAD模拟发现,电荷传输层可以选择性的阻挡载流子传输,从而起到降低暗电流的作用,Sentaurus TCAD模拟结果与实验数据吻合,揭示了电荷传输层降低器件暗电流的内在物理机制.

工业循环冷却水腐蚀影响因素研究

通过模拟现场工业循环冷却水的运行条件,采用旋转挂片法、动电位极化曲线法,开展氯离子、流速、硫化物、氨氮等重要水质运行参数对碳钢、不锈钢、铜材质的腐蚀影响实验,分析超滤处理及在用药剂配方对中水回用的腐蚀性影响,并根据实验结果进一步优化循环水水质管控,降低循环冷却水的腐蚀性。

An ocean current inversion accuracy analysis based on a Doppler spectrum model

Microwave remote sensing is one of the most useful methods for observing the ocean parameters. The Doppler frequency or interferometric phase of the radar echoes can be used for an ocean surface current speed retrieval,which is widely used in spaceborne and airborne radars. While the effect of the ocean currents and waves is interactional. It is impossible to retrieve the ocean surface current speed from Doppler frequency shift directly. In order to study the relationship between the ocean surface current speed and the Doppler frequency shift, a numerical ocean surface Doppler spectrum model is established and validated with a reference. The input parameters of ocean Doppler spectrum include an ocean wave elevation model, a directional distribution function, and wind speed and direction. The suitable ocean wave elevation spectrum and the directional distribution function are selected by comparing the ocean Doppler spectrum in C band with an empirical geophysical model function（CDOP）. What is more, the error sensitivities of ocean surface current speed to the wind speed and direction are analyzed. All these simulations are in Ku band. The simulation results show that the ocean surface current speed error is sensitive to the wind speed and direction errors. With VV polarization, the ocean surface current speed error is about 0.15 m/s when the wind speed error is 2 m/s, and the ocean surface current speed error is smaller than 0.3 m/s when the wind direction error is within 20° in the cross wind direction.

核电半速汽轮发电机励磁绕组匝间短路时转子涡流损耗研究

为研究核电半速汽轮发电机励磁绕组匝间短路时转子涡流损耗特性,推导了核电半速汽轮发电机空载运行时励磁绕组匝间短路故障下,定子分数次谐波环流产生的合成磁动势表达式,分析合成磁动势相对于转子的转速,揭示了转子表面产生涡流的原因以及涡流的频率特性。结合涡流损耗计算方法,以一台核电半速汽轮发电机为例进行了仿真验证。在此基础上,对核电半速汽轮发电机励磁绕组不同位置发生相同程度匝间短路,以及励磁绕组发生不同程度匝间短路过程进行了仿真,计算了转子各阻尼条及槽楔中的涡流及涡流损耗,揭示了励磁绕组匝间短路时影响转子阻尼条及槽楔中涡流和涡流损耗的因素。为核电半速汽轮发电机励磁绕组匝间短路故障时,分析转子发热的影响因素提供了理论基础。

高速列车弓网受流系统放电实验平台设计

为掌握外环境下高速列车的运行特点,开展弓网电弧变化特性研究,该文设计并研制了高速列车弓网受流系统放电实验平台,其风洞系统由风洞结构、风扇转子系统、风洞控制系统、弓网电弧发生系统、观测系统组成。测试结果表明:低速直流风洞风速可达50 m/s,湍流度低于1%,速度不均匀性小于1%,流场稳定性不超过1%,气流偏角不超过0.5°,满足《低速风洞和高速风洞流场品质要求》(GJB 1179A—2012)中所规定的参数指标。该系统为探究强气流场环境下弓网电弧物理特性的变化规律提供了良好的实验环境,可为高速运行环境下列车弓网电弧研究提供参考数据。

基于频域分析的PMSM双闭环PI控制器整定方法

以永磁同步电机(PMSM)双闭环调速系统为对象,在对其数学模型进行合理简化的基础上,综合考虑了逆变器开关周期、电流和速度滤波等环节的影响,给出了一种在频域进行PI控制器参数设计的整定方法。通过建立双环的数学模型,得到关于开环频域特征量的解析式,根据电流环在中低频段的特性以及转速环中阻尼系数难以精确测定的问题,分析推导了电流环和转速环PI参数简化设计的方法。利用工程经验将闭环时域指标转化开环频域特征量,并结合各类约束条件合理界定其取值范围,由此得到的PI控制器可以兼顾快速性和稳态跟踪能力。仿真和实物实验验证了整定方法的可行性,该方法确立了双环控制器参数与其对应的开环截止频率和相位裕度的解析式,并明确了开环频域特征量与闭环时域指标的关系,具有较强的工程参考和应用价值。

高速永磁电机铁耗精确计算两项式模型

基于分段带补偿项的铁耗计算方法,本文提出了一种适用于高速永磁电机铁耗精确计算的两项式数学模型。通过结合高速电机运行特性对频率和磁密区间进行双重划分,在Jordan损耗分离模型的基础上引入涡流及磁滞损耗补偿项考虑磁饱和、局部磁滞回环及涡流趋肤效应等非线性因素对硅钢片单位损耗特性的影响。该模型新增参数均为随频率和磁密变化的分段常函数,通过L-M算法拟合求解,在减小计算量的同时明确反映铁磁材料非线性对铁耗计算的影响,实现铁耗精确计算。最后,以某高速电机用硅钢片35SWH1900为例,对比了本文所提模型与Jordan损耗分离模型在单位损耗上的计算误差,实验结果表明所提模型计算误差基本在15%以内,能够有效提升高速永磁电机铁耗的计算精度。