Two cyano bridged dimeric 4f 3d complexes [Nd(DMF) 4(H 2O) 3Co(CN) 6]·H 2O (A) and [Sm(pyr) 4(H 2O) 3Cr(CN) 6]·2H 2O (B) (DMF=N,N dimethylformamide, pyr=2 pyrrolidone) were prepared and structu...Two cyano bridged dimeric 4f 3d complexes [Nd(DMF) 4(H 2O) 3Co(CN) 6]·H 2O (A) and [Sm(pyr) 4(H 2O) 3Cr(CN) 6]·2H 2O (B) (DMF=N,N dimethylformamide, pyr=2 pyrrolidone) were prepared and structurally characterized. Single crystal X ray diffraction analysis revealed that the complexes contain cyano bridged 3 and [Ln(L) 4(H 2O) 3] 3+ groups. The Ln 3+ is eight coordinate, and is coordinated by seven oxygen atoms of three water molecules and four organic ligands (DMF or pyr). Each terminal CN ligand of the 3- entity is hydrogen bonded to some oxygen atoms of the coordinated water molecules yielding a hydrogen bonded three dimensional network. Crystal data for A: monoclinic, space group P 2(1)/ n , a = 1.7525(4) nm, b =0.8879(2) nm, c =1.9876(4) nm, β =95.92(3)°, V =3.0763(12) nm 3, Z =4, D c= 1.563 mg·m -3 . Complex B crystallizes in the P 1 space group, with lattice parameters of a =1.22720(4) nm, b =1.45550(8) nm, c =0.91310(4) nm, α =92.5869(17)°, β = 90.9569(12)°, γ =89.822(3)°, V =1.62908(13) nm 3, Z =2, D c=1.608 mg·m -3 .展开更多
The title complex [La(DMSO)3(H2O)3Cr(CN)6]H2O was obtained by the reaction of LaCl37H2O, DMSO and K3[Cr(CN)6] in aqueous solution on a hot water bath. The crystal crystallizes in orthorhombic, space group P212121 with...The title complex [La(DMSO)3(H2O)3Cr(CN)6]H2O was obtained by the reaction of LaCl37H2O, DMSO and K3[Cr(CN)6] in aqueous solution on a hot water bath. The crystal crystallizes in orthorhombic, space group P212121 with a = 9.827(3), b = 15.037(4), c = 17.633(5) ? C12H26CrLaN6O7S3, Mr = 653.48, Z = 4, V = 2605.7(13) ?, Dc = 1.666 g/m3, (MoKa) = 2.314 mm-1, F(000) = 1300, R = 0.0205 and wR = 0.0481 for 5038 observed reflec- tions (I > 2s(I)). La3+ ion is eight-coordinated by three DMSO molecules, three H2O molecules and two [Cr(CN)6]3- units. The structure of the title complex possesses a cyano-bridged one- dimensional zigzag chain structure with alternating La(DMSO)3(H2O)3 and Cr(CN)6 moieties, which are linked by some hydrogen bonds to form a 3D network structure.展开更多
The cyano-bridged bimetallic complex K3(TMS)2(H2O)2Cr(CN)6 with three- dimensional microporous structure was synthesized and characterized. The title complex (C14H20CrK3N, Mr = 601.78) crystallizes in monoclinic, sp...The cyano-bridged bimetallic complex K3(TMS)2(H2O)2Cr(CN)6 with three- dimensional microporous structure was synthesized and characterized. The title complex (C14H20CrK3N, Mr = 601.78) crystallizes in monoclinic, space group C2/c with a = 14.357(4), b = 9.331(3), c = 19.180(6) ?, β = 96.754(5)o, V = 2551.6(13) ?3, Z = 4, Dc = 1.567 g/m3, μ(MoKα) = 1.141 mm-1, F(000) = 1228, the final R = 0.0440 and wR = 0.0990 for 1760 observed reflections (I > 2σ(I)). In the crystal, two [Cr(CN) ]3- units, four K+ ions and two oxygen atoms of two 6 TMS molecules are linked to form a sixteen-membered ring and an extended three-dimensional structure.展开更多
ABSTRACT A new lanthanumm-ironm complex [La（DMSO）5（H2O）]（μ-CN）2[Fe（CN）4]·H2O 1 （DMSO = dimethylsulfoxide） has been prepared by a facile approach, ball-milling method, and characterized by X-ray diffrac...ABSTRACT A new lanthanumm-ironm complex [La（DMSO）5（H2O）]（μ-CN）2[Fe（CN）4]·H2O 1 （DMSO = dimethylsulfoxide） has been prepared by a facile approach, ball-milling method, and characterized by X-ray diffraction. The crystal belongs to monoclinic, space group P21/n with a = 9.7125（3）, b = 21.5336（7）, c = 14.3804（5）A, β = 93.242（3）°, C16H34FeLaN60O7S5, Mr= 777.55, V = 3002.8（2）A^3, Z = 4, Dc = 1.720 g/cm^3, S = 1.053, μ（MoKα） = 2.278 mm^-1, F（000） = 1564, R = 0.0490 and ωR = 0.1270. The crystal structure analysis of 1 reveals a slightly distorted squareantiprism eighffold-coordinated La（Ⅲ） ion and a 1-D zigzag chain structure extending through the Fe-CN-La-NC-Fe linkages. The [La（DMSO）5（H2O）]（μ-CN）2[Fe（CN）4] species are held together via hydrogen bonds to form a three-dimensional framework.展开更多
The title complex [La(betaine)2(H2O)6Fe(CN)6]?2H2O (betaine = (CH3)3NCH2CO2) has been synthesized and characterized by X-ray single-crystal structure analysis. The crystal crystallizes in monoclinic, space group P21...The title complex [La(betaine)2(H2O)6Fe(CN)6]?2H2O (betaine = (CH3)3NCH2CO2) has been synthesized and characterized by X-ray single-crystal structure analysis. The crystal crystallizes in monoclinic, space group P21/n with a = 15.793(5), b = 8.927(3), c = 22.257(7) ?, β = 110.147(5)o, C16H38FeLaN8O12, Mr = 729.31, Z = 4, V = 2946.0(15) ?3, Dc = 1.640 g/m3, μ(MoKα) = 1.988 mm-1, F(000) =1476, R = 0.0388 and wR = 0.0827 for 4237 observed reflections (I > 2σ(I)). The La3+ ion is nine-coordinated by one cyano nitrogen atom and eight oxygen atoms of two betaine and six water molecules. Each complex molecule is connected to form a 3D network structure by some O–H…O and O–H…N hydrogen bonds.展开更多
A novel heterobimetaUic coordination polymer, {（NH4）2[Cd（H20）Fe（CN）6]}n 1, has been synthesized by using the slow diffusion method and structurally characterized by elemental analysis, 1R spectroscopy and single...A novel heterobimetaUic coordination polymer, {（NH4）2[Cd（H20）Fe（CN）6]}n 1, has been synthesized by using the slow diffusion method and structurally characterized by elemental analysis, 1R spectroscopy and single-crystal X-ray diffraction. The crystal crystallizes in the monoclinic system, space group P21/n, a = 7.4202（16）, b = 14.939（3）, c = 10.868（2） A and ,8 = 91.660（3）°. For 1, five CN groups of Fe（CN）6]4- are involved in bridging. The polymer displays a 3D open microporous framework with 5-connected uninodal （46.64） topology.展开更多
A new neodymiumIII-ironIII complex [Nd(DMSO)5(H2O)2](μ-CN)[Fe(CN)5] (DMSO = dimethyl sulfoxide) has been synthesized by the grinding reaction method. The crystal belongs to monoclinic, space group P21/m with a = 8....A new neodymiumIII-ironIII complex [Nd(DMSO)5(H2O)2](μ-CN)[Fe(CN)5] (DMSO = dimethyl sulfoxide) has been synthesized by the grinding reaction method. The crystal belongs to monoclinic, space group P21/m with a = 8.859(4), b = 13.684(5), c = 12.290(4) ?, ?= 91.85(2)o, C16H34FeN6NdO7S5, Mr= 782.88, V = 1489(1) ?3, Z = 2, Dc = 1.746 g/cm3, S = 0.906, μ(MoKa) = 2.606 mm-1, F(000) = 788, R = 0.0646 and wR = 0.1654. The slightly distorted square-antiprism eightfold-coordinated Nd(III) and approximately oriented octahedrally sixfold- coordinated Fe(III) are linked by a cyano-bridge group to construct a dinuclear compound. The [Nd(DMSO)5(H2O)2](μ-CN)[Fe(CN)5] species are held together via hydrogen bonds to form a three-dimensional framework.展开更多
A new bimetallic cyano-bridged complex, [NdFe(CN)6(DMF)4(H2O)3]H2O (DMF = N,N-dimethylformamide) 1, has been obtained by the reaction of hexacyanoferrate potassium with neodymium (Ⅲ) chloride in H2O/EtOH/DMF (volume ...A new bimetallic cyano-bridged complex, [NdFe(CN)6(DMF)4(H2O)3]H2O (DMF = N,N-dimethylformamide) 1, has been obtained by the reaction of hexacyanoferrate potassium with neodymium (Ⅲ) chloride in H2O/EtOH/DMF (volume ratio: 2:2:1), and its structure was determined by means of single-crystal X-ray diffraction. The compound crystallizes in space group P21/n of monoclinic system with cell parameters: a = 17.646(1), b = 8.9011(3), c = 19.945(1) ? b = 95.835(2)? V = 3116.6(3) ?, Z = 4, Dc = 1.536 g/cm3, Mr = 720.66, F(000) = 1456, m = 2.166 mm-1, R = 0.0386, wR = 0.1120 and S = 1.061. The central Nd (Ⅲ) ion is coordinated by seven oxygen atoms of four DMF molecules and three water molecules and one nitrogen atom of the bridging cyanide in a slightly distorted square-antiprism arrangement, and the Fe (Ⅲ) ion is in an almost octahedral environment coordinated to six cyano-ligands, of which one cyanide ligand bridges the Nd (Ⅲ) ion to form a bimetallic complex. Molecules of complexes in the crystal lattice are held together by hydrogen bonding, forming a three-dimensional framework.展开更多
Two new bimetallic cyano-bridged complexes [Ln（DMSO）2（H2O）（μ-CN）4Fe（CN）2] （Ln = Ce 1, Eu 2） have been prepared by the grinding reaction method and structurally characterized by X-ray single-crystal structur...Two new bimetallic cyano-bridged complexes [Ln（DMSO）2（H2O）（μ-CN）4Fe（CN）2] （Ln = Ce 1, Eu 2） have been prepared by the grinding reaction method and structurally characterized by X-ray single-crystal structure analysis. Crystallographic data for 1： C10H14CeFeN6O3S2, Mr = 526.36, monoclinic, P2/n, a = 7.852（4）, b = 10.729（5）, c = 11.181（5）A,β = 96.992（8）°, V = 935.0（7） A^3, Z = 2, Dc = 1.870 g/cm^3,/1 = 3.421 mm^-1, F（000） = 512, R = 0.0363 and wR = 0.0971; and those for 2： C10H14EuFeN6O3S2, Mr = 538.20, monoclinic, P21n, a = 7.739（5）, b = 10.668（7）, c = 11.008（7） A,β = 96.943（3）°, V = 902.1（11） A^3, Z = 2, Dc = 1.981 g/cm^3,/1 = 4.499 mm^-1, F（000） = 522, R = 0.0345 and wR = 0.0855. In each complex the lanthanide ion is seven-coordinated in a pentagonal bipyramidal arrangement, and the Fe（Ⅲ） ion is in a nearly regular octahedral environment. The title complexes can be described as two- dimensional （2-D） stair-like structures, which are further connected by hydrogen bonds to form three-dimensional （3-D） frameworks.展开更多
The complexity of the IH-635 Managed Lanes Project, located in Dallas County, Texas, posed several technical and constructive challenges, leading to the adoption of solutions different from the traditional. Two altern...The complexity of the IH-635 Managed Lanes Project, located in Dallas County, Texas, posed several technical and constructive challenges, leading to the adoption of solutions different from the traditional. Two alternative solutions for the pier cap on one of the bridge crossings over IH-35E in the IH-635 project were analyzed in this case study, a cast-in-place post-tensioned concrete cap and an innovative prefabricated steel-concrete com- posite cap. The approach was to use an estimation of direct costs for material and labor and consideration of con- struction time schedules. A supplementary numerical modeling confirmed that both alternatives behave elasti- cally under imposed loads. The direct cost of material and labor for the two alternatives were close. However, the composite alternative required 13 days less construction time, resulting in substantial cost savings from traffic closing in the very busy traffic corridor. Traffic closing costs were substantially higher than the direct costs, especially for the post-tensioned cap. The quantification of the benefits allows more confidence in the utilization of the composites caps, leading to faster completion of bridge projects and substantial economic savings.展开更多
A dinuclear complex [DyFe(CN)6(DMF)4(H2O)3]·1.25H2O (DMF=N, N dimethylformamide) 1 based on the cyanide as linkage was prepared and structurally characterized by X ray single crystal structure analysis. The Dy?io...A dinuclear complex [DyFe(CN)6(DMF)4(H2O)3]·1.25H2O (DMF=N, N dimethylformamide) 1 based on the cyanide as linkage was prepared and structurally characterized by X ray single crystal structure analysis. The Dy?ion is eight coordinations in a square antiprism arrangement and the Fe?ion is six coordinations oriented octahedrally. The neutral units [DyFe(CN)6(DMF)4(H2O)3] are held together by hydrogen bonds formed by lattice water molecules, coordinated water molecules and nitrogen atoms of cyanide coming from other distinct complex units to afford a three dimensional framework. CCDC: 192314.展开更多
文摘Two cyano bridged dimeric 4f 3d complexes [Nd(DMF) 4(H 2O) 3Co(CN) 6]·H 2O (A) and [Sm(pyr) 4(H 2O) 3Cr(CN) 6]·2H 2O (B) (DMF=N,N dimethylformamide, pyr=2 pyrrolidone) were prepared and structurally characterized. Single crystal X ray diffraction analysis revealed that the complexes contain cyano bridged 3 and [Ln(L) 4(H 2O) 3] 3+ groups. The Ln 3+ is eight coordinate, and is coordinated by seven oxygen atoms of three water molecules and four organic ligands (DMF or pyr). Each terminal CN ligand of the 3- entity is hydrogen bonded to some oxygen atoms of the coordinated water molecules yielding a hydrogen bonded three dimensional network. Crystal data for A: monoclinic, space group P 2(1)/ n , a = 1.7525(4) nm, b =0.8879(2) nm, c =1.9876(4) nm, β =95.92(3)°, V =3.0763(12) nm 3, Z =4, D c= 1.563 mg·m -3 . Complex B crystallizes in the P 1 space group, with lattice parameters of a =1.22720(4) nm, b =1.45550(8) nm, c =0.91310(4) nm, α =92.5869(17)°, β = 90.9569(12)°, γ =89.822(3)°, V =1.62908(13) nm 3, Z =2, D c=1.608 mg·m -3 .
基金This work was supported by the National Natural Science Foundation of China (No. 50242001)
文摘The title complex [La(DMSO)3(H2O)3Cr(CN)6]H2O was obtained by the reaction of LaCl37H2O, DMSO and K3[Cr(CN)6] in aqueous solution on a hot water bath. The crystal crystallizes in orthorhombic, space group P212121 with a = 9.827(3), b = 15.037(4), c = 17.633(5) ? C12H26CrLaN6O7S3, Mr = 653.48, Z = 4, V = 2605.7(13) ?, Dc = 1.666 g/m3, (MoKa) = 2.314 mm-1, F(000) = 1300, R = 0.0205 and wR = 0.0481 for 5038 observed reflec- tions (I > 2s(I)). La3+ ion is eight-coordinated by three DMSO molecules, three H2O molecules and two [Cr(CN)6]3- units. The structure of the title complex possesses a cyano-bridged one- dimensional zigzag chain structure with alternating La(DMSO)3(H2O)3 and Cr(CN)6 moieties, which are linked by some hydrogen bonds to form a 3D network structure.
基金Supported by the Innovation Foundation for College Students of Nankai University and the National Natural Science Foundation of China (No. 50242001)
文摘The cyano-bridged bimetallic complex K3(TMS)2(H2O)2Cr(CN)6 with three- dimensional microporous structure was synthesized and characterized. The title complex (C14H20CrK3N, Mr = 601.78) crystallizes in monoclinic, space group C2/c with a = 14.357(4), b = 9.331(3), c = 19.180(6) ?, β = 96.754(5)o, V = 2551.6(13) ?3, Z = 4, Dc = 1.567 g/m3, μ(MoKα) = 1.141 mm-1, F(000) = 1228, the final R = 0.0440 and wR = 0.0990 for 1760 observed reflections (I > 2σ(I)). In the crystal, two [Cr(CN) ]3- units, four K+ ions and two oxygen atoms of two 6 TMS molecules are linked to form a sixteen-membered ring and an extended three-dimensional structure.
基金the NNSFC (20571075, 20521101)the NSF for Distinguished Young Scientist of China (20425104)the NSF of Fujian Province (E0510028)
文摘ABSTRACT A new lanthanumm-ironm complex [La（DMSO）5（H2O）]（μ-CN）2[Fe（CN）4]·H2O 1 （DMSO = dimethylsulfoxide） has been prepared by a facile approach, ball-milling method, and characterized by X-ray diffraction. The crystal belongs to monoclinic, space group P21/n with a = 9.7125（3）, b = 21.5336（7）, c = 14.3804（5）A, β = 93.242（3）°, C16H34FeLaN60O7S5, Mr= 777.55, V = 3002.8（2）A^3, Z = 4, Dc = 1.720 g/cm^3, S = 1.053, μ（MoKα） = 2.278 mm^-1, F（000） = 1564, R = 0.0490 and ωR = 0.1270. The crystal structure analysis of 1 reveals a slightly distorted squareantiprism eighffold-coordinated La（Ⅲ） ion and a 1-D zigzag chain structure extending through the Fe-CN-La-NC-Fe linkages. The [La（DMSO）5（H2O）]（μ-CN）2[Fe（CN）4] species are held together via hydrogen bonds to form a three-dimensional framework.
基金Supported by the National Natural Science Foundation of China (No. 50242001)
文摘The title complex [La(betaine)2(H2O)6Fe(CN)6]?2H2O (betaine = (CH3)3NCH2CO2) has been synthesized and characterized by X-ray single-crystal structure analysis. The crystal crystallizes in monoclinic, space group P21/n with a = 15.793(5), b = 8.927(3), c = 22.257(7) ?, β = 110.147(5)o, C16H38FeLaN8O12, Mr = 729.31, Z = 4, V = 2946.0(15) ?3, Dc = 1.640 g/m3, μ(MoKα) = 1.988 mm-1, F(000) =1476, R = 0.0388 and wR = 0.0827 for 4237 observed reflections (I > 2σ(I)). The La3+ ion is nine-coordinated by one cyano nitrogen atom and eight oxygen atoms of two betaine and six water molecules. Each complex molecule is connected to form a 3D network structure by some O–H…O and O–H…N hydrogen bonds.
基金supported by the National Natural Science Foundation of China(No.20771083)
文摘A novel heterobimetaUic coordination polymer, {（NH4）2[Cd（H20）Fe（CN）6]}n 1, has been synthesized by using the slow diffusion method and structurally characterized by elemental analysis, 1R spectroscopy and single-crystal X-ray diffraction. The crystal crystallizes in the monoclinic system, space group P21/n, a = 7.4202（16）, b = 14.939（3）, c = 10.868（2） A and ,8 = 91.660（3）°. For 1, five CN groups of Fe（CN）6]4- are involved in bridging. The polymer displays a 3D open microporous framework with 5-connected uninodal （46.64） topology.
基金The project was supported by NNSFC (20001007 20131020) and NSF of the Chinese Academy of Sciences (KJCX2-H3) and Fujian Province (2000F006)
文摘A new neodymiumIII-ironIII complex [Nd(DMSO)5(H2O)2](μ-CN)[Fe(CN)5] (DMSO = dimethyl sulfoxide) has been synthesized by the grinding reaction method. The crystal belongs to monoclinic, space group P21/m with a = 8.859(4), b = 13.684(5), c = 12.290(4) ?, ?= 91.85(2)o, C16H34FeN6NdO7S5, Mr= 782.88, V = 1489(1) ?3, Z = 2, Dc = 1.746 g/cm3, S = 0.906, μ(MoKa) = 2.606 mm-1, F(000) = 788, R = 0.0646 and wR = 0.1654. The slightly distorted square-antiprism eightfold-coordinated Nd(III) and approximately oriented octahedrally sixfold- coordinated Fe(III) are linked by a cyano-bridge group to construct a dinuclear compound. The [Nd(DMSO)5(H2O)2](μ-CN)[Fe(CN)5] species are held together via hydrogen bonds to form a three-dimensional framework.
基金This work was supported by the National Natural Science Foundation of China (No. 20001007 20131020) Natural Science Foundation of the Chinese Academy of Sciences (KJCX2-H3) and Fujian province (2000F006)
文摘A new bimetallic cyano-bridged complex, [NdFe(CN)6(DMF)4(H2O)3]H2O (DMF = N,N-dimethylformamide) 1, has been obtained by the reaction of hexacyanoferrate potassium with neodymium (Ⅲ) chloride in H2O/EtOH/DMF (volume ratio: 2:2:1), and its structure was determined by means of single-crystal X-ray diffraction. The compound crystallizes in space group P21/n of monoclinic system with cell parameters: a = 17.646(1), b = 8.9011(3), c = 19.945(1) ? b = 95.835(2)? V = 3116.6(3) ?, Z = 4, Dc = 1.536 g/cm3, Mr = 720.66, F(000) = 1456, m = 2.166 mm-1, R = 0.0386, wR = 0.1120 and S = 1.061. The central Nd (Ⅲ) ion is coordinated by seven oxygen atoms of four DMF molecules and three water molecules and one nitrogen atom of the bridging cyanide in a slightly distorted square-antiprism arrangement, and the Fe (Ⅲ) ion is in an almost octahedral environment coordinated to six cyano-ligands, of which one cyanide ligand bridges the Nd (Ⅲ) ion to form a bimetallic complex. Molecules of complexes in the crystal lattice are held together by hydrogen bonding, forming a three-dimensional framework.
基金Financially supported by the NSF for Distinguished Young Scientist of China (20425104)the NSF of Fujian Province (E0510028, E0510029)
文摘Two new bimetallic cyano-bridged complexes [Ln（DMSO）2（H2O）（μ-CN）4Fe（CN）2] （Ln = Ce 1, Eu 2） have been prepared by the grinding reaction method and structurally characterized by X-ray single-crystal structure analysis. Crystallographic data for 1： C10H14CeFeN6O3S2, Mr = 526.36, monoclinic, P2/n, a = 7.852（4）, b = 10.729（5）, c = 11.181（5）A,β = 96.992（8）°, V = 935.0（7） A^3, Z = 2, Dc = 1.870 g/cm^3,/1 = 3.421 mm^-1, F（000） = 512, R = 0.0363 and wR = 0.0971; and those for 2： C10H14EuFeN6O3S2, Mr = 538.20, monoclinic, P21n, a = 7.739（5）, b = 10.668（7）, c = 11.008（7） A,β = 96.943（3）°, V = 902.1（11） A^3, Z = 2, Dc = 1.981 g/cm^3,/1 = 4.499 mm^-1, F（000） = 522, R = 0.0345 and wR = 0.0855. In each complex the lanthanide ion is seven-coordinated in a pentagonal bipyramidal arrangement, and the Fe（Ⅲ） ion is in a nearly regular octahedral environment. The title complexes can be described as two- dimensional （2-D） stair-like structures, which are further connected by hydrogen bonds to form three-dimensional （3-D） frameworks.
基金financially supported by the National Natural Science Foudation of China(Grants No.22103009,22025101,22222103,22173015,21871039,21801037,91961114,and 22071017)financial support by the Fundamental Research Funds for the Central Universities of China(Grants No.PA2021GDSK0063 and PA2020GDJQ0028)。
基金herein for allowing the use of various data from the LBJ Project in the development of this paper
文摘The complexity of the IH-635 Managed Lanes Project, located in Dallas County, Texas, posed several technical and constructive challenges, leading to the adoption of solutions different from the traditional. Two alternative solutions for the pier cap on one of the bridge crossings over IH-35E in the IH-635 project were analyzed in this case study, a cast-in-place post-tensioned concrete cap and an innovative prefabricated steel-concrete com- posite cap. The approach was to use an estimation of direct costs for material and labor and consideration of con- struction time schedules. A supplementary numerical modeling confirmed that both alternatives behave elasti- cally under imposed loads. The direct cost of material and labor for the two alternatives were close. However, the composite alternative required 13 days less construction time, resulting in substantial cost savings from traffic closing in the very busy traffic corridor. Traffic closing costs were substantially higher than the direct costs, especially for the post-tensioned cap. The quantification of the benefits allows more confidence in the utilization of the composites caps, leading to faster completion of bridge projects and substantial economic savings.
文摘A dinuclear complex [DyFe(CN)6(DMF)4(H2O)3]·1.25H2O (DMF=N, N dimethylformamide) 1 based on the cyanide as linkage was prepared and structurally characterized by X ray single crystal structure analysis. The Dy?ion is eight coordinations in a square antiprism arrangement and the Fe?ion is six coordinations oriented octahedrally. The neutral units [DyFe(CN)6(DMF)4(H2O)3] are held together by hydrogen bonds formed by lattice water molecules, coordinated water molecules and nitrogen atoms of cyanide coming from other distinct complex units to afford a three dimensional framework. CCDC: 192314.
