The classical thermodynamics reflects the significant relationship between the heat and the temperature. On the basis of the relationships, according to the mathematical derivation, this paper structures the conceptio...The classical thermodynamics reflects the significant relationship between the heat and the temperature. On the basis of the relationships, according to the mathematical derivation, this paper structures the conceptions of generalized heat, generalized thermodynamic temperature, generalized entropy and so on. The series of conceptions in the classical thermodynamics is merely a special case of the generalized thermodynamics. Based on these conceptions of generalized thermodynamics, this paper presents the new expressions of the first law and the second law of thermodynamics. In other words, these expressions are endued with new explanations. The Eq. LZ = kTS given by this paper provides theoretical basis for these new expressions.展开更多
文摘The classical thermodynamics reflects the significant relationship between the heat and the temperature. On the basis of the relationships, according to the mathematical derivation, this paper structures the conceptions of generalized heat, generalized thermodynamic temperature, generalized entropy and so on. The series of conceptions in the classical thermodynamics is merely a special case of the generalized thermodynamics. Based on these conceptions of generalized thermodynamics, this paper presents the new expressions of the first law and the second law of thermodynamics. In other words, these expressions are endued with new explanations. The Eq. LZ = kTS given by this paper provides theoretical basis for these new expressions.