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A macroscopic constitutive model of shape memory alloy considering cyclic effects 被引量:1
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作者 ZHOU Bo YOON Sung-Ho 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2013年第4期755-764,共10页
This paper presents a macroscopic constitutive model reproducing the hysteretic behaviors of the superelastic shape memory alloy (SMA) under cyclic loading. The progressive increase of residual strain with the increas... This paper presents a macroscopic constitutive model reproducing the hysteretic behaviors of the superelastic shape memory alloy (SMA) under cyclic loading. The progressive increase of residual strain with the increased cycle number in such materials is assumed to be a consequence of the progressive increase of residual stress-induced martensitic volume fraction upon the cyclic effects. The progressive decrease of phase transformation critical stresses with the increased cycle number in such materials is assumed to be a result from the progressive increase of phase transformation critical temperatures upon the cyclic effects. A cyclic evolution equation is supposed to describe the influences of cycle effects on the material properties of the SMA under cyclic loading. A phase transformation equation expressing the phase transformation behaviors of the SMA under cyclic loading is established based on the differential relationship between martensitic volume fraction and the free energy increment of phase transformation. A mechanical constitutive equation predicting the mechanical characteristics of the SMA under cyclic loading is developed on the basis of thermodynamics and continuum mechanics. The cyclic evolution equation, phase transformation equation, and mechanical constitutive equation together compose the presented macroscopic constitutive model considering cyclic effects. Results of the numerical simulations illustrate that it can well reproduce the superelastic hysteretic behaviors of the SMA under cyclic loading. 展开更多
关键词 shape memory alloy cyclic effect cyclic evolution equation phase transformation equation mechanical constitutive equation
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Effect of Cyclic Loading Frequency on Undrained Behaviors of Undisturbed Marine Clay 被引量:15
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作者 陈云敏 姬美秀 黄博 《海洋工程:英文版》 EI 2004年第4期643-651,共9页
Based on a series of cyclic triaxial tests, the effect of cyclic frequency on the undrained behaviors of undisturbed marine clay is investigated. For a given dynamic stress ratio, the accumulated pore water pressure a... Based on a series of cyclic triaxial tests, the effect of cyclic frequency on the undrained behaviors of undisturbed marine clay is investigated. For a given dynamic stress ratio, the accumulated pore water pressure and dynamic strain increase with the number of cycles. There exists a threshold value for both the accumulated pore water pressure and dynamic strain, below which the effect of cyclic frequency is very small, but above which the accumulated pore water pressure and dynamic strain increase intensely with the decrease of cyclic frequency for a given number of cycles. The dynamic strength increases with the increase of cyclic frequency, whereas the effect of cyclic frequency on it gradually diminishes to zero when the number of cycles is large enough, and the dynamic strengths at different frequencies tend to the same limiting minimum dynamic strength. The test results demonstrate that the reasons for the frequency effect on the undrained soil behaviors are both the creep effect induced by the loading rate and the decrease of sample effective confining pressure caused by the accumulated pore water pressure. 展开更多
关键词 cyclic triaxial test undisturbed marine clay effect of cyclic frequency dynamic strain pore water pressure dynamic strength creep effect
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A macroscopic multi-mechanism based constitutive model for the thermo-mechanical cyclic degeneration of shape memory effect of NiTi shape memory alloy 被引量:6
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作者 Chao Yu Guozheng Kang Qianhua Kan 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2017年第3期619-634,共16页
A macroscopic based multi-mechanism constitutive model is constructed in the framework of irreversible thermodynamics to describe the degeneration of shape memory effect occurring in the thermo-mechanical cyclic defor... A macroscopic based multi-mechanism constitutive model is constructed in the framework of irreversible thermodynamics to describe the degeneration of shape memory effect occurring in the thermo-mechanical cyclic deformation of NiTi shape memory alloys (SMAs). Three phases, austenite A, twinned martensite and detwinned martensite , as well as the phase transitions occurring between each pair of phases (, , , , and are considered in the proposed model. Meanwhile, two kinds of inelastic deformation mechanisms, martensite transformation-induced plasticity and reorientation-induced plasticity, are used to explain the degeneration of shape memory effects of NiTi SMAs. The evolution equations of internal variables are proposed by attributing the degeneration of shape memory effect to the interaction between the three phases (A, , and and plastic deformation. Finally, the capability of the proposed model is verified by comparing the predictions with the experimental results of NiTi SMAs. It is shown that the degeneration of shape memory effect and its dependence on the loading level can be reasonably described by the proposed model. 展开更多
关键词 NiTi SMAs Constitutive model cyclic degeneration of shape memory effect Transformation-induced plasticity Reorientation-induced plasticity
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Martensite Aging Effect and Thermal Cyclic Characteristics in Ti-Pd and Ti-Pd-Ni High Temperature Shape Memory Alloys 被引量:2
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作者 Wei Cai School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 15000k, China Kazuhiro Otsuka Institute of Materials Science, University of Tsukuba, Tsukuba, Ibaraki 305-8573, Japan E-mail: weicai@hope.hit.edu.cn 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2001年第3期359-362,共4页
The effect of thermal cycling and aging in martensitic state in Ti-Pd-Ni alloys were investigated by DSC and TEM observations. It is shown that the thermal cycling causes the decreases in M, and Af temperatures in Ti5... The effect of thermal cycling and aging in martensitic state in Ti-Pd-Ni alloys were investigated by DSC and TEM observations. It is shown that the thermal cycling causes the decreases in M, and Af temperatures in Ti50Pd50-xNix (x=10, 20, 30) alloys, but no obvious thermal cycling effect was observed in Ti50Pd50Pd40Ni10 alloys and the aging effect shows a curious feature, i.e., the Af temperature does not saturate even after relatively long time aging, which is considered to be due to the occurrence of recovery recrystallization during aging. 展开更多
关键词 Ti Martensite Aging effect and Thermal cyclic Characteristics in Ti-Pd and Ti-Pd-Ni High Temperature Shape Memory Alloys PD Ni
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An improved model for predicting effective Young's modulus of the twisted structure under cyclic loading:taking into account the untwisting effect
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作者 Hexin Cui Donghua Yue +1 位作者 Xingyi Zhang Youhe Zhou 《Theoretical & Applied Mechanics Letters》 CAS CSCD 2018年第2期132-136,共5页
Twist structures have diverse applications, ranging from dragline, electrical cable, and intelligent structure. Among these applications, tension deformation can't be avoided during the fabrication and working proces... Twist structures have diverse applications, ranging from dragline, electrical cable, and intelligent structure. Among these applications, tension deformation can't be avoided during the fabrication and working processes, which often leads to the twist structure rotation (called untwisting effect) and twist pitch increasing. As a consequence, this untwisting behavior has a large effect on the effective Young's modulus. In this paper, we present an improved model based on the classical Costello's theory to predict the effective Young's modulus of the basic structure, twisted by three same copper strands under cyclic loading. Series of experiments were carried out to verify the present model taking into account the untwisting effect. The experimental results have better agreements with the presented model than the common Costello's model. 展开更多
关键词 Twist structure Young's modulus cyclic loading Untwisting effect
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CYCLIC VISCOPLASTIC DESCRIPTION FOR THE MEAN STRAIN EFFECT
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作者 Yang Xianjie(Southwest Jiaotong University)Chengdu,China,610031 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 1995年第2期111-117,共7页
CYCLICVISCOPLASTICDESCRIPTIONFORTHEMEANSTRAINEFFECTCYCLICVISCOPLASTICDESCRIPTIONFORTHEMEANSTRAINEFFECT¥YangX... CYCLICVISCOPLASTICDESCRIPTIONFORTHEMEANSTRAINEFFECTCYCLICVISCOPLASTICDESCRIPTIONFORTHEMEANSTRAINEFFECT¥YangXianjie(SouthwestJ... 展开更多
关键词 strain rate effectS cyclic VISCOPLASTICITY constitutive equations
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BAUSCHINGER EFFECT AND DISLOCATION STRUCTURE IN STAINLESS STEEL DURING CYCLIC DEFORMATION
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作者 XIA Yuebo WANG Zhongguang DU Xiukui Institute of Metal Research,Academia Sinica,Shenyang,China XIA Yuebo,Associate Professor,Institute of Metal Research,Academia Sinica,Shenyang,China 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 1989年第1期1-6,共6页
Cyclic deformation in symmetrical push-pull mode was carried out at room temperature in air using a Schenck hydropuls machine.The total strain amplitude which was kept constant dur- ing the test ranged from ±0.00... Cyclic deformation in symmetrical push-pull mode was carried out at room temperature in air using a Schenck hydropuls machine.The total strain amplitude which was kept constant dur- ing the test ranged from ±0.004 to±0.012.The 0.2% offset yield stress σ_(0.2f) in tension and σ_(0.2r) in compression and peak stress σ were measured from the stress-strain hysteresis loop at various cycles.The Bauschinger strenghth differential factor(BSDF)was then calcu- lated from σ_(0.2f) and σ_(0.2r).The energy loss △E of each cycle was determined from hysteresis loop areas.These parameters,BSDF,σ and △E,appear to have two distinctively different stages. The dislocation structures were observed using TEM in specimens deformed cyclically,for various cycles.The observation shows that the dislocations pile-up mainly against grain boundaries and there exist large amount of deformation twins.The addition of 0.25 wt-% ni- trogen reduced the stacking fault energy of the alloy significantly.Cross-slip and climb are therefore rather difficult to occur during the cyclic deformation at room temperature,and well-defined dislocation cells and walls can only be seen at the final stage of fatigue. 展开更多
关键词 Bausckinger effect cyclic deformation dislocation structure
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The Effectiveness of Cyclic Blockwise Distribution
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作者 Mark R. Roest(Parallel Algorithms Group Delft University Of Technology, the Netherlands)(email: roest@dutind3. two. tudelft.nl) 《Wuhan University Journal of Natural Sciences》 CAS 1996年第Z1期410-419,共10页
In spite of the wealth Of existing data distribution methods, most parallel programming languages support only some form of cyclic blockwise distribution. The main reason why only this single method is supported is th... In spite of the wealth Of existing data distribution methods, most parallel programming languages support only some form of cyclic blockwise distribution. The main reason why only this single method is supported is that it is relatively simple to implement. However, it is as yet nuclear whether cyclic blockwise distribution is sufficiently powerful for a wide class of distribution problems. In this paper the method will be analysed, showing that for a wide range of problems it is indeed sufficient. It will also be shown in which cases cyclic blockwise distribution can be effected to fail. From this analysis, it is possible to formulate practical guidelines to assist Programmers in choosing the cycle frequency for cyclic blockwise distribution that leads to an optimal result. 展开更多
关键词 The effectiveness of cyclic Blockwise Distribution
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Effects of cyclic uniaxial stress on mitosis orientation
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作者 Lei Zhao1,Chun Yang2,Fengyuan Zhuang1(1.School of Biological Science and Medical Engineering,Beihang University,Beijing 100191 2.IBME,Engineering Mechanics Department,School of Aerospace,Tsinghua University,Beijing 100084) 《医用生物力学》 EI CAS CSCD 2009年第S1期98-98,共1页
Background:Cell division is one of the key roles in the cell development,cell differentiation,embryogenesis and recovery of tissues.Independent studies have shown that spindle alignment during not only asymmetric but ... Background:Cell division is one of the key roles in the cell development,cell differentiation,embryogenesis and recovery of tissues.Independent studies have shown that spindle alignment during not only asymmetric but also symmetric cell divisions is essential 展开更多
关键词 effects of cyclic uniaxial stress on mitosis orientation
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Vibration Effect and Damage Evolution Characteristics of Tunnel Surrounding Rock Under Cyclic Blasting Loading 被引量:1
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作者 Guosheng Zhong Yongzhong Lou Yuhua Fu 《Journal of Beijing Institute of Technology》 EI CAS 2017年第3期324-333,共10页
Model test studies based on the similarity theory were conducted to investigate vibration effect and damage evolution characteristics of tunnel surrounding rock under push-type cyclic blasting excavation.The model was... Model test studies based on the similarity theory were conducted to investigate vibration effect and damage evolution characteristics of tunnel surrounding rock under push-type cyclic blasting excavation.The model was constructed with a ratio of 1∶15.By simulating the tunnel excavation of push-type cyclic blasting,the influence of the blasting parameter change on vibration effect was explored.The damage degree of tunnel surrounding rock was evaluated by the change of the acoustic wave velocity at the same measuring point after blasting.The relationship between the damage evolution of surrounding rock and blasting times was established.The research results show that:(1)In the same geological environment,the number of delay initiation is larger,the main vibration frequency of blasting seismic wave is higher,and the attenuation of high frequency signal in the rock and soil is faster.The influence of number of delay initiation on blasting vibration effect cannot be ignored;(2)Under push-type cyclic blasting excavation,there were great differences in the decreasing rates of acoustic wave velocity of the measuring points which have the same distance to the blasting region at the same depth,and the blasting damage ranges of surrounding rock were typically anisotropic at both depth and breadth;(3)When blasting parameters were basically kept as the same,the growth trend of the cumulative acoustic wave velocity decreasing rate at the measuring point was nonlinear under different cycle blasting excavations;(4)There were nonlinear evolution characteristics between the blasting cumulative damage(D)of surrounding rock and blasting times(n)under push-type cyclic blasting loading,and different measuring points had corresponding blasting cumulative damage propagation models,respectively.The closer the measuring point was away from the explosion source,the faster the cumulative damage extension.Blasting cumulative damage effect of surrounding rock had typically nonlinear evolution properties and anisotropic characteristics. 展开更多
关键词 cyclic blasting loading tunnel excavation vibration effect surrounding rock damage
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Experimental investigation of the cyclic degradation of the one-way shape memory effect of NiTi alloys
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作者 Tian-xing Zhao Guo-zheng Kang +1 位作者 Chao Yu Qian-hua Kan 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2019年第12期1539-1550,共12页
Based on stress-and strain-controlled cyclic tension-unloading-heat-cooling tests,cyclic degradation of the one-way shape memory effect(OWSME)of NiTi shape memory alloys(SMAs)was investigated.It was seen,in thermo-mec... Based on stress-and strain-controlled cyclic tension-unloading-heat-cooling tests,cyclic degradation of the one-way shape memory effect(OWSME)of NiTi shape memory alloys(SMAs)was investigated.It was seen,in thermo-mechanical coupled cyclic tests,that residual strain after each cycle accumulated,but the martensite reorientation stress and dissipation energy-per-cycle decreased as the number of cycles increased.Meanwhile,the cyclic degradation of OWSME was aggravated by increasing the stress/strain amplitude.In addition,the stress-strain response of NiTi SMAs was further investigated by performing simultaneous thermo-mechanical coupled cyclic tests with various phase-angle differences between the mechanical and thermal cyclic loadings.It can be concluded that such cyclic response depends significantly on prescribed phase-angle differences.Obtained experimental results are helpful for both the development of constitutive models and engineering applications of NiTi SMAs. 展开更多
关键词 NITI SHAPE MEMORY alloys one-way SHAPE MEMORY effect cyclic degradation THERMO-MECHANICAL coupling MARTENSITE orientation
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温度和湿度对P-CNT自感知混凝土压敏性的影响
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作者 孙敏 朱浩然 庄伟 《河海大学学报(自然科学版)》 CAS CSCD 北大核心 2024年第3期72-78,共7页
为研究温度与湿度对自感知混凝土(SSC)感知性能的影响,通过低温等离子体改性处理技术对碳纳米管(CNT)进行官能团嫁接,使其在水性体系下获得较好的分散性,并将改性后的CNT(P-CNT)加入混凝土中制备P-CNT/SSC传感器,通过改变含水率与温度... 为研究温度与湿度对自感知混凝土(SSC)感知性能的影响,通过低温等离子体改性处理技术对碳纳米管(CNT)进行官能团嫁接,使其在水性体系下获得较好的分散性,并将改性后的CNT(P-CNT)加入混凝土中制备P-CNT/SSC传感器,通过改变含水率与温度条件研究P-CNT/SSC传感器的极化效应与循环加载下的自感知性能。试验结果表明:过高或过低的含水率均不利于SSC的感知性能,其中变化最为明显的是饱水状态下的P-CNT/SSC传感器,其应力敏感系数下降89.8%,并且压敏曲线极不稳定;在变温试验中,P-CNT/SSC传感器的电阻率与温度之间呈现负相关性,高温和低温下的应力敏感系数相较于常温组试件,分别下降了约35.66%和44.53%,并且压敏曲线整体出现了上移或下滑的趋势;P-CNT/SSC传感器在工程应用中的最佳测试环境为常温、自然含水率。 展开更多
关键词 自感知混凝土 碳纳米管 压敏性 低温等离子体改性 极化效应 循环加载
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循环加卸载条件下考虑温度的煤体本构模型
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作者 周宏伟 侯魏 +3 位作者 张龙丹 谢森林 贾文豪 史贝贝 《煤炭学报》 EI CAS CSCD 北大核心 2024年第1期442-453,共12页
随着煤炭资源深部开采趋于“常态化”,深入了解处于高地应力和高地温环境中深部煤体在扰动条件下的力学性质及其损伤演化规律,对煤矿深部开采具有重要意义。选取平煤十二矿己16-17-17200工作面的煤体为研究对象,开展了在不同温度条件下... 随着煤炭资源深部开采趋于“常态化”,深入了解处于高地应力和高地温环境中深部煤体在扰动条件下的力学性质及其损伤演化规律,对煤矿深部开采具有重要意义。选取平煤十二矿己16-17-17200工作面的煤体为研究对象,开展了在不同温度条件下三轴循环加卸载试验,分析了温度对试件峰值强度、变形模量、泊松比等基本力学参数的影响。将不同加卸载速率相关的应力-应变问题转化为时间-应力-应变问题,同时引入分数阶导数理论和连续介质损伤理论,提出了一个考虑了热-力耦合作用的分数阶粘弹塑性本构方程,通过试验数据验证了其有效性。结果表明:煤体变形模量随着循环次数的增加呈出现线性减小的趋势,而煤体泊松比减速上升,在峰值应力处达到极值,然后降低,表明循环加卸载作用对煤体基本力学性能有劣化作用。随着温度的升高,煤体峰值强度非线性减小,损伤累积变缓,对应的应变逐渐增大,表明升温能增强煤体延性变形能力,加速煤体损伤的发展。在循环加卸载过程中,输入能密度、弹性能密度和耗散能密度在煤体破坏失稳阶段随温度升高呈现出明显的衰减现象,说明高温加剧了煤体内部的损伤,降低了煤体强度,使得破坏所需外界输入能量减少。考虑温度影响的分数阶粘弹塑性模型可以较好地描述深部煤体在循环加卸载条件下的力学行为。模型适用于热力耦合下深部煤体的复杂应力状态。 展开更多
关键词 深部煤体 分数阶导数 循环加卸载 温度效应 热力耦合
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各向异性层状千枚岩渗透率及有效孔隙率试验研究 被引量:1
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作者 王伟 陈超维 +3 位作者 刘世藩 曹亚军 段雪雷 聂文俊 《岩土工程学报》 EI CAS CSCD 北大核心 2024年第2期445-451,共7页
采用岩石全自动三轴伺服仪和气体渗透装置,对一种致密的各向异性层状千枚岩开展了气体渗透率及有效孔隙率试验,研究常规三轴压缩和围压循环加卸载2种应力路径下,气体渗透率、有效孔隙率随层理倾角及偏应力的演化规律。结果表明:围压相同... 采用岩石全自动三轴伺服仪和气体渗透装置,对一种致密的各向异性层状千枚岩开展了气体渗透率及有效孔隙率试验,研究常规三轴压缩和围压循环加卸载2种应力路径下,气体渗透率、有效孔隙率随层理倾角及偏应力的演化规律。结果表明:围压相同时,岩样的初始气体渗透率k0随着层理倾角β的增大呈“W”型变化,在β=45°时取最大值;在围压循环加卸载过程中,气体渗透率先随围压的加载而减小,后随围压的卸载而增大,卸载时的气体渗透率小于加载时的渗透率;层状千枚岩有效孔隙率和气体渗透率呈指数关系;平行于层理方向的气体渗透率远大于垂直于层理方向的气体渗透率;岩样有效孔隙率和气体渗透率随偏应力变化经历初始压密阶段、线弹性阶段和塑性变形阶段,随着偏应力的增大,岩样有效孔隙率和气体渗透率先减小,接着保持稳定,最后快速增大,并在岩样应力-应变曲线斜率接近于0时达到最大值。 展开更多
关键词 层状岩石 各向异性 气体渗透率 有效孔隙率 常规三轴压缩 围压循环加卸载
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考虑泄漏和温度效应的黏滞阻尼器性能演变研究
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作者 杨孟刚 曹恺悦 +1 位作者 李新 胡尚韬 《振动与冲击》 EI CSCD 北大核心 2024年第8期169-177,共9页
黏滞阻尼器作为一种广泛使用的被动减振/震装置,其力学性能在全寿命周期内会发生演变。为探究其力学参数改变模式,揭示其性能演变机理,以油液泄漏和温度效应为主要影响因素开展了试验及仿真研究。首先,对不同漏油程度和环境温度下的黏... 黏滞阻尼器作为一种广泛使用的被动减振/震装置,其力学性能在全寿命周期内会发生演变。为探究其力学参数改变模式,揭示其性能演变机理,以油液泄漏和温度效应为主要影响因素开展了试验及仿真研究。首先,对不同漏油程度和环境温度下的黏滞阻尼器分别开展了滞回试验研究和黏温关系分析;其次,对黏滞阻尼器进行了流体动力学仿真,获得其性能演变规律;最后,建立了漏油与温度联合作用下黏滞阻尼器性能演变的力学模型,并对其进行了验证。研究结果表明,油液泄漏将导致滞回圈出现零力平台段,且平台长度与漏油比例成正比;温度升高会导致阻尼系数的减小,从而影响阻尼力峰值;所建立的性能演变模型能够较为精确地反映黏滞阻尼器力学性能的改变。 展开更多
关键词 黏滞阻尼器 油液泄漏 温度效应 性能演变模型 滞回试验 流体动力学仿真
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316L不锈钢在Cl^(-)与SO_(4)^(2-)协同作用下的腐蚀行为研究
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作者 赵恒瑞 侯政煜 +4 位作者 杨海燕 梁守才 程龙生 王丹 谢飞 《材料保护》 CAS CSCD 2024年第6期81-87,共7页
为了降低腐蚀对海洋油气管道正常运行的危害,利用电化学试验中的交流阻抗技术以及循化极化技术研究了模拟南海海洋环境中Cl^(-)与SO_(4)^(2-)的协同作用对316L不锈钢腐蚀行为的影响,并结合扫描电子显微镜(SEM)对316L不锈钢表面的腐蚀形... 为了降低腐蚀对海洋油气管道正常运行的危害,利用电化学试验中的交流阻抗技术以及循化极化技术研究了模拟南海海洋环境中Cl^(-)与SO_(4)^(2-)的协同作用对316L不锈钢腐蚀行为的影响,并结合扫描电子显微镜(SEM)对316L不锈钢表面的腐蚀形貌进行表征。结果表明,当SO_(4)^(2-)含量恒定时,Cl^(-)含量的升高会使容抗弧半径、极化电阻R_(p)以及点蚀电位E_(b)均降低,当Cl^(-)含量从0升至50 g/L时,316L不锈钢表面出现了明显的腐蚀情况。当Cl^(-)含量恒定时,SO_(4)^(2-)含量的升高会使容抗弧半径、R_(p)以及E_(b)值均减小,同时试件表面的腐蚀坑直径扩大,深度出现逐渐加深的情况。 展开更多
关键词 316L不锈钢 海洋环境 Cl^(-) SO_(4)^(2-) 协同作用 循环极化
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镍铁镓多晶合金弹热效应的循环稳定性研究
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作者 官磊 刘继辰 +1 位作者 陈枫 佟运祥 《功能材料》 CAS CSCD 北大核心 2024年第7期7116-7121,7208,共7页
弹热制冷是一种新型固态制冷技术,具有对环境友好和能量利用效率高等优点,有望替代传统的蒸气压缩制冷技术。实现弹热制冷应用的关键在于获得兼具大弹热效应和高循环稳定性的弹热材料作为制冷剂。Ni-Fe-Ga记忆合金是一种很有潜力的弹热... 弹热制冷是一种新型固态制冷技术,具有对环境友好和能量利用效率高等优点,有望替代传统的蒸气压缩制冷技术。实现弹热制冷应用的关键在于获得兼具大弹热效应和高循环稳定性的弹热材料作为制冷剂。Ni-Fe-Ga记忆合金是一种很有潜力的弹热材料。该合金采用常规熔炼方法易形成γ相,然而有关γ相对合金弹热性能的影响却缺乏系统和深入的研究。有鉴于此,制备了一种含γ相的Ni_(53.6)Fe_(19.3)Ga_(27.1)多晶合金,采用X射线衍射仪、透射电子显微镜、差示扫描量热仪、电子万能材料试验机以及自制的弹热效应测试系统,分析了其显微组织、力学性能和弹热性能。结果表明,Ni_(53.6)Fe_(19.3)Ga_(27.1)多晶合金的基体是β相,γ相同时分布于晶粒内和晶界上,这种两相结构有助于合金获得大且稳定的弹热效应,室温绝热温变值超过-5 K。 展开更多
关键词 镍铁镓 应力诱发马氏体相变 弹热效应 循环稳定性 显微组织
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多位点离子液体聚合物催化CO_(2)环加成反应研究
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作者 王昊 岳成光 +1 位作者 王美岩 马新宾 《化学工业与工程》 CAS CSCD 北大核心 2024年第2期2-11,共10页
CO_(2)与环氧化物环加成反应制备环状碳酸酯是一条绿色经济的CO_(2)利用途径。针对现有CO_(2)与环氧化物环加成反应中非均相离子液体催化剂活性低和活性组分易流失等问题,设计制备了系列多位点离子液体超交联聚合物HCPs-[DmPhe]Br,研究... CO_(2)与环氧化物环加成反应制备环状碳酸酯是一条绿色经济的CO_(2)利用途径。针对现有CO_(2)与环氧化物环加成反应中非均相离子液体催化剂活性低和活性组分易流失等问题,设计制备了系列多位点离子液体超交联聚合物HCPs-[DmPhe]Br,研究了多位点协同作用、超交联聚合物组成和结构等因素对其催化CO_(2)与环氧化物环加成反应性能的影响。其中,同时含有双季铵-卤素离子对、羟基和叔胺结构的HCP-[DmPhe]Br-DCX离子液体超交联聚合物催化剂,在1.3 MPa,130℃,8 h的条件下,可实现94%的碳酸丁烯酯收率,且催化剂循环稳定性好,重复使用5次,催化活性没有明显降低。另外,超交联聚合物的多孔结构以及大比表面积促进了离子液体的较好分散,使其与离子液体单体具有相当的活性。该工作对CO_(2)与环氧化物环加成反应高效非均相离子液体催化剂的开发与优化具有一定的借鉴意义。 展开更多
关键词 CO_(2)利用 环状碳酸酯 离子液体 协同作用 超交联聚合
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CFRP约束插槽式双柱墩抗震性能研究
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作者 李帆 左武旭 刘中宪 《河北工业大学学报》 CAS 2024年第2期85-90,共6页
研究了CFRP约束插槽式双柱墩的抗震性能,利用ABAQUS软件建立考虑了钢筋循环退化效应的桥墩模型,重点分析了CFRP的厚度和约束范围对桥墩抗震性能的影响。在横向地震荷载作用下,双柱墩发生弯曲破坏,基础和盖梁的塑性铰区混凝土被压碎。CFR... 研究了CFRP约束插槽式双柱墩的抗震性能,利用ABAQUS软件建立考虑了钢筋循环退化效应的桥墩模型,重点分析了CFRP的厚度和约束范围对桥墩抗震性能的影响。在横向地震荷载作用下,双柱墩发生弯曲破坏,基础和盖梁的塑性铰区混凝土被压碎。CFRP厚度增加,混凝土的被动约束增强,桥墩的屈服荷载、极限荷载和耗能等抗震性能指标提高,且残余位移减小;CFRP约束在塑性铰区比约束在非塑性铰区,抗震性能改善显著。 展开更多
关键词 装配式双柱墩 CFRP约束 插槽式 钢筋循环退化效应
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基底温度对磁控溅射制备NiO_(x)薄膜综合电致变色性能的影响
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作者 蔡晓佳 黄家健 +3 位作者 孙丹丹 梁嘉盈 唐秀凤 张炯 《人工晶体学报》 CAS 北大核心 2024年第8期1453-1463,共11页
为研究基底温度对NiO_(x)薄膜综合电致变色性能的影响,在基底温度分别为室温、50、100、200和300℃下,采用直流反应磁控溅射法制备了NiO_(x)薄膜,并对薄膜的形貌、循环稳定性、光学调制率、记忆效应、响应时间和附着力等性能进行测试表... 为研究基底温度对NiO_(x)薄膜综合电致变色性能的影响,在基底温度分别为室温、50、100、200和300℃下,采用直流反应磁控溅射法制备了NiO_(x)薄膜,并对薄膜的形貌、循环稳定性、光学调制率、记忆效应、响应时间和附着力等性能进行测试表征和对比分析。研究结果表明,基底温度对NiO_(x)薄膜的电致变色性能影响较为复杂,基底温度为100℃时制备的薄膜综合性能最优,具有电荷容量密度衰减率低、记忆效应好、响应速度快、调制率高和与基底附着力较好等特点。本研究对NiO_(x)基电致变色器件的设计和制备具有一定的参考意义。 展开更多
关键词 电致变色 NiO_(x) 响应时间 记忆效应 循环稳定性 附着力
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