Mesoporous titanium containing alumino-silicate materials with various titanium/silicon(Ti/Si) ratio(AlSi-Ti(n);n = Ti/Si mole ratio) have been successfully synthesized by a novel single-step sodium(Na)-free method, f...Mesoporous titanium containing alumino-silicate materials with various titanium/silicon(Ti/Si) ratio(AlSi-Ti(n);n = Ti/Si mole ratio) have been successfully synthesized by a novel single-step sodium(Na)-free method, for the first time. The obtained characterization results of the prepared materials reveal that in-situ addition of Ti into AlSi shows ordered mesoporous structure along with uniformly dispersed Ti species in +4 and +3 oxidation states suitable for selective oxidation of allylic C—H bond. The prepared mesoporouse Ti-AlSi(n) samples exhibited excellent activity in the oxidation of cyclohexene with 100%conversion and 100% selectivity to ketone-alcohol(KA) oil(cyclohex-2-en-1-ol and 2-cyclohexen-1-one) at low temperature and reaction time(35℃ and 30 min reaction time). This study suggests that AlSi-Ti(0.05) material can be a promising catalyst for the selective oxidation of cyclohexene under mild reaction conditions.展开更多
Ru-based catalysts promoted with Mn and Zn were prepared by a co-precipitation method. In liquid-phase hydrogenation of benzene, the Ru-Mn-Zn catalysts exhibited superior catalytic performance to the catalysts promote...Ru-based catalysts promoted with Mn and Zn were prepared by a co-precipitation method. In liquid-phase hydrogenation of benzene, the Ru-Mn-Zn catalysts exhibited superior catalytic performance to the catalysts promoted with Zn or Mn alone. The optimum Mn/Zn molar ratio was determined to be 0.3. With the addition of 0.5 g NaOH, the Ru-Mn-Zn-0.3 catalyst, which was reduced at 150 ? C, afforded a cyclohexene selectivity of 81.1% at a benzene conversion of 60.2% at 5 min and a maximum cyclohexene yield of 59.9% at 20 min. Based on characterizations, the excellent performance of Ru-Mn-Zn catalyst was ascribed to the suitable pore structure, the appropriate reducibility and the homogenous chemical environment of the catalyst.展开更多
Ru-Ce catalysts were prepared by a co-precipitation method.The effects of Ce precursors with different valences and Ce contents on the catalytic performance of Ru-Ce catalysts were investigated in the presence of ZnSO...Ru-Ce catalysts were prepared by a co-precipitation method.The effects of Ce precursors with different valences and Ce contents on the catalytic performance of Ru-Ce catalysts were investigated in the presence of ZnSO4.The Ce species in the catalysts prepared with different valences of the Ce precursors all exist as CeO2 on the Ru surface.The promoter CeO2alone could not improve the selectivity to cyclohexene of Ru catalysts.However,almost all the CeO2 in the catalysts could react with the reaction modifier ZnSO4 to form(Zn(OH)2)3(ZnSO4)(H2O)3 salt.The amount of the chemisorbed salt increased with the CeO2 loading,resulting in the decrease of the activity and the increase of the selectivity to cyclohexene of Ru catalyst.The Ru-Ce catalyst with the optimum Ce/Ru molar ratio of 0.19 gave a maximum cyclohexene yield of 57.4%.Moreover,this catalyst had good stability and excellent reusability.展开更多
Oxygenation constants and thermodynamic parameters DeltaH degrees and DeltaS degrees of cobalt (II) complexes with bis-(furaldehyde) Schiff bases (1, 2, 3, 4)were obtained by mearsuring saturated dioxygen uptake of th...Oxygenation constants and thermodynamic parameters DeltaH degrees and DeltaS degrees of cobalt (II) complexes with bis-(furaldehyde) Schiff bases (1, 2, 3, 4)were obtained by mearsuring saturated dioxygen uptake of these complexes in pyridine at different temperature. These complexes could activate molecular oxygen and were used as catalysts in cyclohexene oxidation. The influence of ligand structure on the dioxygen affinity and catalytic activity of the complexes were discussed.展开更多
A new compound, subglain B, was isolated from the stems of Uvaria tonkinensis var. subglabra and its structure was identified as 1S, 2R, 3S, 6R-1-benzoyloxymethylene-1,2- dihydroxy-3-benzoyloxy-6-chlorocyclohex-4-ene ...A new compound, subglain B, was isolated from the stems of Uvaria tonkinensis var. subglabra and its structure was identified as 1S, 2R, 3S, 6R-1-benzoyloxymethylene-1,2- dihydroxy-3-benzoyloxy-6-chlorocyclohex-4-ene (1), by spectral evidences.展开更多
Acidic poly(ionic liquid)s(PILs)with swelling ability were synthesized by free radical copolymerization of N-vinylimidazolium ionic liquids,divinylbenzene(DVB)and sodium acrylate(NaAA),and further acidification by sul...Acidic poly(ionic liquid)s(PILs)with swelling ability were synthesized by free radical copolymerization of N-vinylimidazolium ionic liquids,divinylbenzene(DVB)and sodium acrylate(NaAA),and further acidification by sulfuric acid.The swelling ability of acidic PILs was greatly affected by cross-linker content and chain length of 3-alkyl-substituents on imidazolium.Cross-linked network structures could be observed from the cryogenic scanning electron microscopy(cryo-SEM)images of the swollen acidic PILs in formic acid.Acidic PILs with network structures in swollen state exhibited excellent activities in the esterification of cyclohexene and formic acid,and the catalytic activities were in positive correlation with their swelling abilities.Acidic PIL with 3-octyl-substituent and 2.5 mol%DVB(PIL-C8-2.5DVB-HSO4)had the highest swelling ability in formic acid and exhibited comparable catalytic activities with homogeneous catalysts such as sulfuric acid and p-toluenesulfonic acid.展开更多
ZSM-5 zeolite prepared by a hydrothermal method with the addition of seeds was treated with different concentrations of NaOH.The obtained samples were characterized by XRD,N_2 adsorption,NH_3-TPD,FT-IR,SEM,and studied...ZSM-5 zeolite prepared by a hydrothermal method with the addition of seeds was treated with different concentrations of NaOH.The obtained samples were characterized by XRD,N_2 adsorption,NH_3-TPD,FT-IR,SEM,and studied in the catalytic performance of the hydration of cyclohexene to cyclohexanol.The characterization results showed that with the increase of NaOH concentration,the crystallinity of the treated samples decreased monotonously,and the acid sites of ZSM-5 zeolites first increased and then decreased,while more mesopores formed inside the ZSM-5zeolites.The experimental results of catalytic performance showed that cyclohexene conversion can be improved through introducing the mesopores and enhancing the acidity of ZSM-5 with the NaOH treatment at a low concentration.The highest cyclohexene conversion of 12.8%was obtained when the concentrations of NaOH solution were in the range of 0.2-0.6 mol/L.The selectivity of cyclohexanol on all samples was higher than 99.6%.展开更多
A Ru-La/ZrO2 catalyst was prepared by the precipitation method, in which Ru was an active component, La was a promoter and ZrO2 was a dispersant. Comparing with the catalyst prepared by the chemical reduction method, ...A Ru-La/ZrO2 catalyst was prepared by the precipitation method, in which Ru was an active component, La was a promoter and ZrO2 was a dispersant. Comparing with the catalyst prepared by the chemical reduction method, the Ru-La/ZrO2 exhibited higher activity and better selectivity. At 140 ℃ and hydrogen pressure of 5 MPa, the C6H10 selectivity reached 70% at a C6H6 conversion of 35% for a reaction time was 5 min and the total La/Ru loading was 10%. Textural parameters of the catalyst were obtained by physical adsorption, BET surface area and specific pore volume measurements. The catalyst sample gave a BET area of 41 m2/g and a specific pore volume of 1.1 cm^3/g, and the most probable pore distribution was located at 5 to 10 nm. H2-TPR measurements showed that ruthenium oxide could be reduced to its metallic state at about 403 K. XRD determinations indicated that ruthenium and lanthanum were highly dispersed on the zirconia. A significant advantage of the Ru-La/ZrO2 catalyst is that it can be used directly in its unreduced state for the selective hydrogenation of benzene.展开更多
A novel phosphate ligand, tri-(methoxyl polyethylene glycol)-phosphate (TMPGPA), has been synthesized and used in the Rhcatalyzed hydroformylation of cyclohexene in a thermoregulated PEG biphase system. Under the ...A novel phosphate ligand, tri-(methoxyl polyethylene glycol)-phosphate (TMPGPA), has been synthesized and used in the Rhcatalyzed hydroformylation of cyclohexene in a thermoregulated PEG biphase system. Under the optimized conditions, pressure = 5 MPa (H2:CO = 1:1), P/Rh = 10 (molar ratio), reaction time = 4 h and temperature = 120 ℃, the conversion of cyclohexene and the yield of aldehyde are 99%. The catalyst retained in PEG phase can be easily separated from the organic phase containing product by simple phase separation and reused ten times without obvious loss in activity.展开更多
Co-salen functionalized on graphene with an average pore size of 27.7 nm as a heterogeneous catalyst exhibited good catalytic activity and recyclability in cyclohexene oxidation.
The cyclohexene 1 was oxidized with polymer-supported 2.2-bipyridine cobalt(II) complex in the presence of CO2. The conversion and selectivity was sensitive to the pressure of CO2.
Cyclohexanol is a commonly used organic compound.Currently,the most promising industrial process for synthesizing cyclohexanol,by cyclohexene hydration,suffers from a low conversion rate and difficult separation.In th...Cyclohexanol is a commonly used organic compound.Currently,the most promising industrial process for synthesizing cyclohexanol,by cyclohexene hydration,suffers from a low conversion rate and difficult separation.In this paper,a three-column process for catalytic distillation applicable in the hydration of cyclohexene to cyclohexanol was established to solve these.Simulation with Aspen Plus shows that the process has good advantages,the conversion of cyclohexene reached 99.3%,and the product purity was>99.2%.The stable operation of the distillation system requires a good control scheme.The design of the control scheme is very important.However,at present,the reactive distillation process for cyclohexene hydration is under investigation experimentally and by steady-state simulation.Therefore,three different plant-wide control schemes were established(CS1,CS2,CS3) and the position of temperature sensitive stage was selected by using sensitivity analysis method and singular value decomposition method.The Tyreus-Luyben empirical tuning method was used to tune the controller parameters.Finally,Aspen Dynamics simulation software was used to evaluate the performance of the three control schemes.By introducing ΔF±20% and χ_(ENE)±5%,comparison the changes in product purity and yield of the three different control schemes.By comparison,we can see that the control scheme CS3 has the best performance.展开更多
The cobalt and ruthenium bimetallic complex of poly-γ-amino-propylsiloxane( abbr. as Si-CH_2-Co-Ru) was prepared, and it was found that it can catalyze the hydroformylation of cyclobexene effectively with the convers...The cobalt and ruthenium bimetallic complex of poly-γ-amino-propylsiloxane( abbr. as Si-CH_2-Co-Ru) was prepared, and it was found that it can catalyze the hydroformylation of cyclobexene effectively with the conversion amounting to over 90%. Cyclohexanecarboxaldehyde was first formed in the hydroformylation, and then further hydrogenated to form cylcohexanemethanol. The coversion was affected obviously by the Co/Ru ratio.When Co/Ru molar ratio was 100-150, i.e. in the very low content of noble metal Ru, the catalytic activity of Si-NH_2 -Co-Ru was also very high. The product composition was affected by CO/H_2 ratio in the reaction gas. Aldehyde can be got high selectively by controlling CO/H_2 ratio. Compared with other catalyst system, the Si-NH_2-Co-Ru catalyst has higher catalytic activity and efficiency with very low Ru/Co ratio. The total turnover number was more than 28,800 (based on the amount of ruthenium used).展开更多
The selective oxidation of cyclohexene to 2-cyclohexene-1-ol and 2-cyclohexene-1-one has been investi-gated over Au/HNTs (HNTs: halloysite nanotubes) catalysts with molecular oxygen in a solvent-free system. The catal...The selective oxidation of cyclohexene to 2-cyclohexene-1-ol and 2-cyclohexene-1-one has been investi-gated over Au/HNTs (HNTs: halloysite nanotubes) catalysts with molecular oxygen in a solvent-free system. The catalysts were prepared by deposition precipitation method and characterized by ICP-AES, TEM and XRD. The results show that the catalytic performance of Au/HNTs is quite well and the catalytic activity over recycled catalyst remains highly. Moreover, the nano-size effect of gold is also reported for the reaction.展开更多
Radical copolymerization of N-phenylmaleedde with cyclohexene was carried out with 2, 2' -azobisisobutyronitrile in various solvents at 60℃. The copolymer was characterized by IR and 1H-NMR
The ozonolysis of cyclohexene is an important model system for understanding the more complex reaction of O_3 with monoterpenes; however, many previous studies have come to qualitatively different conclusions about th...The ozonolysis of cyclohexene is an important model system for understanding the more complex reaction of O_3 with monoterpenes; however, many previous studies have come to qualitatively different conclusions about the composition of the secondary organic aerosol(SOA)formed in this system. In the present study, the composition of the SOA produced by cyclohexene ozonolysis in the absence of seed aerosols has been investigated online and off-line using synchrotron-based thermal desorption/tunable vacuum ultraviolet photoionization time-of-flight aerosol mass spectrometry(TD-VUV-TOF-PIAMS) in conjunction with a custom-built smog chamber. On the basis of the molecular ions observed by mass spectrometry at 11.5 e V, it was found that dicarboxylic acids, dialdehydes, and cyclic anhydrides are the predominant low molecular weight components in the particle phase. The results also indicated that TD-VUV-TOF-PIAMS coupled with filter sampling is a potentially useful tool for the investigation of SOA composition both in the field and in the laboratory.展开更多
Competition of hydrocarbon compounds with sulfides in gasoline has caused a not very high selectivity of sulfides in adsorption desulfurization so far,resulting in a reduction of catalyst lifetime as well as more sulf...Competition of hydrocarbon compounds with sulfides in gasoline has caused a not very high selectivity of sulfides in adsorption desulfurization so far,resulting in a reduction of catalyst lifetime as well as more sulfur oxide emissions.Tostudy the whole competitive process changing with the increase of the loading,the dynamic competition adsorption mechanism of cyclohexene and thiophene in siliceous faujasite(FAU)zeolite was analyzed by the Monte Carlo simulation.The results showed that with the increase of the loading,thiophene and cyclohexene had different performances before and after the inflection point of 40 molecule/UC.The adsorbates were distributed ideally at optimal sites during the stage that occurred before the inflection point,which is called the“optimal-displacement adsorption”stage.When approaching the inflection point,the competition became apparent and the displacement appeared accordingly,some thiophene molecules at S sites(refers to the sites inside the supercages)were displaced by cyclohexene.After the inflection point,the concentration of adsorbates at W sites(refers to the 12-membered ring connecting the supercages)was significantly reduced,whereas the adsorbates at S sites got more concentrated.The stage some cyclohexene molecules displaced by thiophene and inserted into the center of the supercage can be named as the“insertion-displacement adsorption”stage,and both the adsorption behavior and the competitive relationship became localized when the adsorption amount became saturated.This shift in the competitive adsorption mechanism was due to the sharp increase of interaction energy between the adsorbates.Besides,the increase in temperature and ratio of Si/Al will allow the adsorbates,especially thiophene molecules to occupy more adsorption sites,and it is beneficial to improve the desulfurization selectivity.展开更多
Two iron-arene complex photoinitiators with different substituents in arene ligands were synthesized, their activities in initiating photopolymerization of cyclohexene oxide (CHO) were compared with that of IRGACURE 2...Two iron-arene complex photoinitiators with different substituents in arene ligands were synthesized, their activities in initiating photopolymerization of cyclohexene oxide (CHO) were compared with that of IRGACURE 261, a commercialized photoinitiator from Ciba-Geigy. A higher activity was found when the arene ligand was substituted with a stronger electron donating group. For the system initiated by IRGACURE 261 the concentration of active centers in CHO polymerization was determined and it was found that the concentration is maximum at around 35℃. The post (dark) polymerization was significant, the polymerization yield decreased with the increase of irradiation temperature and increased with the increase of post polymerization temperature. The results are interpreted based on the mechanism proposed by Lohse, et al..展开更多
文摘Mesoporous titanium containing alumino-silicate materials with various titanium/silicon(Ti/Si) ratio(AlSi-Ti(n);n = Ti/Si mole ratio) have been successfully synthesized by a novel single-step sodium(Na)-free method, for the first time. The obtained characterization results of the prepared materials reveal that in-situ addition of Ti into AlSi shows ordered mesoporous structure along with uniformly dispersed Ti species in +4 and +3 oxidation states suitable for selective oxidation of allylic C—H bond. The prepared mesoporouse Ti-AlSi(n) samples exhibited excellent activity in the oxidation of cyclohexene with 100%conversion and 100% selectivity to ketone-alcohol(KA) oil(cyclohex-2-en-1-ol and 2-cyclohexen-1-one) at low temperature and reaction time(35℃ and 30 min reaction time). This study suggests that AlSi-Ti(0.05) material can be a promising catalyst for the selective oxidation of cyclohexene under mild reaction conditions.
文摘Ru-based catalysts promoted with Mn and Zn were prepared by a co-precipitation method. In liquid-phase hydrogenation of benzene, the Ru-Mn-Zn catalysts exhibited superior catalytic performance to the catalysts promoted with Zn or Mn alone. The optimum Mn/Zn molar ratio was determined to be 0.3. With the addition of 0.5 g NaOH, the Ru-Mn-Zn-0.3 catalyst, which was reduced at 150 ? C, afforded a cyclohexene selectivity of 81.1% at a benzene conversion of 60.2% at 5 min and a maximum cyclohexene yield of 59.9% at 20 min. Based on characterizations, the excellent performance of Ru-Mn-Zn catalyst was ascribed to the suitable pore structure, the appropriate reducibility and the homogenous chemical environment of the catalyst.
基金supported by the National Nature Science Foundation of China(21273205)the Innovation Found for Technology Based Firms of China(10C26214104505)+1 种基金the Chinese Post-doctorate Science Fund 51th batch of surface subsidizes(2012M511125)the Scientific Research Foundation of Graduate School of Zhengzhou University
文摘Ru-Ce catalysts were prepared by a co-precipitation method.The effects of Ce precursors with different valences and Ce contents on the catalytic performance of Ru-Ce catalysts were investigated in the presence of ZnSO4.The Ce species in the catalysts prepared with different valences of the Ce precursors all exist as CeO2 on the Ru surface.The promoter CeO2alone could not improve the selectivity to cyclohexene of Ru catalysts.However,almost all the CeO2 in the catalysts could react with the reaction modifier ZnSO4 to form(Zn(OH)2)3(ZnSO4)(H2O)3 salt.The amount of the chemisorbed salt increased with the CeO2 loading,resulting in the decrease of the activity and the increase of the selectivity to cyclohexene of Ru catalyst.The Ru-Ce catalyst with the optimum Ce/Ru molar ratio of 0.19 gave a maximum cyclohexene yield of 57.4%.Moreover,this catalyst had good stability and excellent reusability.
文摘Oxygenation constants and thermodynamic parameters DeltaH degrees and DeltaS degrees of cobalt (II) complexes with bis-(furaldehyde) Schiff bases (1, 2, 3, 4)were obtained by mearsuring saturated dioxygen uptake of these complexes in pyridine at different temperature. These complexes could activate molecular oxygen and were used as catalysts in cyclohexene oxidation. The influence of ligand structure on the dioxygen affinity and catalytic activity of the complexes were discussed.
基金the National Natural Science Foundation of China(No.39970084)the Chinese Doctoral Grants of the Ministry of Science and Technology of China(No.96-901-96-54)for financial support
文摘A new compound, subglain B, was isolated from the stems of Uvaria tonkinensis var. subglabra and its structure was identified as 1S, 2R, 3S, 6R-1-benzoyloxymethylene-1,2- dihydroxy-3-benzoyloxy-6-chlorocyclohex-4-ene (1), by spectral evidences.
基金This work was supported by the National Natural Science Foundation of China(21773068,21811530273,21573072)the National Key Research and Development Program of China(2017YFA0403102)Shanghai Leading Academic Discipline Project(B409).
文摘Acidic poly(ionic liquid)s(PILs)with swelling ability were synthesized by free radical copolymerization of N-vinylimidazolium ionic liquids,divinylbenzene(DVB)and sodium acrylate(NaAA),and further acidification by sulfuric acid.The swelling ability of acidic PILs was greatly affected by cross-linker content and chain length of 3-alkyl-substituents on imidazolium.Cross-linked network structures could be observed from the cryogenic scanning electron microscopy(cryo-SEM)images of the swollen acidic PILs in formic acid.Acidic PILs with network structures in swollen state exhibited excellent activities in the esterification of cyclohexene and formic acid,and the catalytic activities were in positive correlation with their swelling abilities.Acidic PIL with 3-octyl-substituent and 2.5 mol%DVB(PIL-C8-2.5DVB-HSO4)had the highest swelling ability in formic acid and exhibited comparable catalytic activities with homogeneous catalysts such as sulfuric acid and p-toluenesulfonic acid.
基金Supported by the National Natural Science Foundation of China (No.21276183)
文摘ZSM-5 zeolite prepared by a hydrothermal method with the addition of seeds was treated with different concentrations of NaOH.The obtained samples were characterized by XRD,N_2 adsorption,NH_3-TPD,FT-IR,SEM,and studied in the catalytic performance of the hydration of cyclohexene to cyclohexanol.The characterization results showed that with the increase of NaOH concentration,the crystallinity of the treated samples decreased monotonously,and the acid sites of ZSM-5 zeolites first increased and then decreased,while more mesopores formed inside the ZSM-5zeolites.The experimental results of catalytic performance showed that cyclohexene conversion can be improved through introducing the mesopores and enhancing the acidity of ZSM-5 with the NaOH treatment at a low concentration.The highest cyclohexene conversion of 12.8%was obtained when the concentrations of NaOH solution were in the range of 0.2-0.6 mol/L.The selectivity of cyclohexanol on all samples was higher than 99.6%.
文摘A Ru-La/ZrO2 catalyst was prepared by the precipitation method, in which Ru was an active component, La was a promoter and ZrO2 was a dispersant. Comparing with the catalyst prepared by the chemical reduction method, the Ru-La/ZrO2 exhibited higher activity and better selectivity. At 140 ℃ and hydrogen pressure of 5 MPa, the C6H10 selectivity reached 70% at a C6H6 conversion of 35% for a reaction time was 5 min and the total La/Ru loading was 10%. Textural parameters of the catalyst were obtained by physical adsorption, BET surface area and specific pore volume measurements. The catalyst sample gave a BET area of 41 m2/g and a specific pore volume of 1.1 cm^3/g, and the most probable pore distribution was located at 5 to 10 nm. H2-TPR measurements showed that ruthenium oxide could be reduced to its metallic state at about 403 K. XRD determinations indicated that ruthenium and lanthanum were highly dispersed on the zirconia. A significant advantage of the Ru-La/ZrO2 catalyst is that it can be used directly in its unreduced state for the selective hydrogenation of benzene.
基金Financial support from Fok Ying Tung Education Foundation(No.91071)the National Natural Science Foundation of China(No.20376013)are gratefully acknowledged.
文摘A novel phosphate ligand, tri-(methoxyl polyethylene glycol)-phosphate (TMPGPA), has been synthesized and used in the Rhcatalyzed hydroformylation of cyclohexene in a thermoregulated PEG biphase system. Under the optimized conditions, pressure = 5 MPa (H2:CO = 1:1), P/Rh = 10 (molar ratio), reaction time = 4 h and temperature = 120 ℃, the conversion of cyclohexene and the yield of aldehyde are 99%. The catalyst retained in PEG phase can be easily separated from the organic phase containing product by simple phase separation and reused ten times without obvious loss in activity.
基金the National Natural Science Foundation of China(20973079 and U1162201)Graduate Innovation Fund of Jilin University(20121051)
文摘Co-salen functionalized on graphene with an average pore size of 27.7 nm as a heterogeneous catalyst exhibited good catalytic activity and recyclability in cyclohexene oxidation.
文摘The cyclohexene 1 was oxidized with polymer-supported 2.2-bipyridine cobalt(II) complex in the presence of CO2. The conversion and selectivity was sensitive to the pressure of CO2.
基金the Natural Science Foundation of Shandong Province China (ZR2017QB006)Focus on Research and Development Plan in Yantai city (2018XSCC038)the Qingchuang Science and Technology Plan Innovation Team of Shandong Province (2019KJC012)。
文摘Cyclohexanol is a commonly used organic compound.Currently,the most promising industrial process for synthesizing cyclohexanol,by cyclohexene hydration,suffers from a low conversion rate and difficult separation.In this paper,a three-column process for catalytic distillation applicable in the hydration of cyclohexene to cyclohexanol was established to solve these.Simulation with Aspen Plus shows that the process has good advantages,the conversion of cyclohexene reached 99.3%,and the product purity was>99.2%.The stable operation of the distillation system requires a good control scheme.The design of the control scheme is very important.However,at present,the reactive distillation process for cyclohexene hydration is under investigation experimentally and by steady-state simulation.Therefore,three different plant-wide control schemes were established(CS1,CS2,CS3) and the position of temperature sensitive stage was selected by using sensitivity analysis method and singular value decomposition method.The Tyreus-Luyben empirical tuning method was used to tune the controller parameters.Finally,Aspen Dynamics simulation software was used to evaluate the performance of the three control schemes.By introducing ΔF±20% and χ_(ENE)±5%,comparison the changes in product purity and yield of the three different control schemes.By comparison,we can see that the control scheme CS3 has the best performance.
文摘The cobalt and ruthenium bimetallic complex of poly-γ-amino-propylsiloxane( abbr. as Si-CH_2-Co-Ru) was prepared, and it was found that it can catalyze the hydroformylation of cyclobexene effectively with the conversion amounting to over 90%. Cyclohexanecarboxaldehyde was first formed in the hydroformylation, and then further hydrogenated to form cylcohexanemethanol. The coversion was affected obviously by the Co/Ru ratio.When Co/Ru molar ratio was 100-150, i.e. in the very low content of noble metal Ru, the catalytic activity of Si-NH_2 -Co-Ru was also very high. The product composition was affected by CO/H_2 ratio in the reaction gas. Aldehyde can be got high selectively by controlling CO/H_2 ratio. Compared with other catalyst system, the Si-NH_2-Co-Ru catalyst has higher catalytic activity and efficiency with very low Ru/Co ratio. The total turnover number was more than 28,800 (based on the amount of ruthenium used).
文摘The selective oxidation of cyclohexene to 2-cyclohexene-1-ol and 2-cyclohexene-1-one has been investi-gated over Au/HNTs (HNTs: halloysite nanotubes) catalysts with molecular oxygen in a solvent-free system. The catalysts were prepared by deposition precipitation method and characterized by ICP-AES, TEM and XRD. The results show that the catalytic performance of Au/HNTs is quite well and the catalytic activity over recycled catalyst remains highly. Moreover, the nano-size effect of gold is also reported for the reaction.
文摘Radical copolymerization of N-phenylmaleedde with cyclohexene was carried out with 2, 2' -azobisisobutyronitrile in various solvents at 60℃. The copolymer was characterized by IR and 1H-NMR
基金supported by the National Natural Science Foundation of China(Nos.11575178,91544105,U1532137,91544228,and U1232130)
文摘The ozonolysis of cyclohexene is an important model system for understanding the more complex reaction of O_3 with monoterpenes; however, many previous studies have come to qualitatively different conclusions about the composition of the secondary organic aerosol(SOA)formed in this system. In the present study, the composition of the SOA produced by cyclohexene ozonolysis in the absence of seed aerosols has been investigated online and off-line using synchrotron-based thermal desorption/tunable vacuum ultraviolet photoionization time-of-flight aerosol mass spectrometry(TD-VUV-TOF-PIAMS) in conjunction with a custom-built smog chamber. On the basis of the molecular ions observed by mass spectrometry at 11.5 e V, it was found that dicarboxylic acids, dialdehydes, and cyclic anhydrides are the predominant low molecular weight components in the particle phase. The results also indicated that TD-VUV-TOF-PIAMS coupled with filter sampling is a potentially useful tool for the investigation of SOA composition both in the field and in the laboratory.
基金the National Natural Science Foundation of China(21822810,21838011)the National Key Research and Development Program(2018YFC1902603).
文摘Competition of hydrocarbon compounds with sulfides in gasoline has caused a not very high selectivity of sulfides in adsorption desulfurization so far,resulting in a reduction of catalyst lifetime as well as more sulfur oxide emissions.Tostudy the whole competitive process changing with the increase of the loading,the dynamic competition adsorption mechanism of cyclohexene and thiophene in siliceous faujasite(FAU)zeolite was analyzed by the Monte Carlo simulation.The results showed that with the increase of the loading,thiophene and cyclohexene had different performances before and after the inflection point of 40 molecule/UC.The adsorbates were distributed ideally at optimal sites during the stage that occurred before the inflection point,which is called the“optimal-displacement adsorption”stage.When approaching the inflection point,the competition became apparent and the displacement appeared accordingly,some thiophene molecules at S sites(refers to the sites inside the supercages)were displaced by cyclohexene.After the inflection point,the concentration of adsorbates at W sites(refers to the 12-membered ring connecting the supercages)was significantly reduced,whereas the adsorbates at S sites got more concentrated.The stage some cyclohexene molecules displaced by thiophene and inserted into the center of the supercage can be named as the“insertion-displacement adsorption”stage,and both the adsorption behavior and the competitive relationship became localized when the adsorption amount became saturated.This shift in the competitive adsorption mechanism was due to the sharp increase of interaction energy between the adsorbates.Besides,the increase in temperature and ratio of Si/Al will allow the adsorbates,especially thiophene molecules to occupy more adsorption sites,and it is beneficial to improve the desulfurization selectivity.
基金Supported by the National Natural Science Foundation of China
文摘Two iron-arene complex photoinitiators with different substituents in arene ligands were synthesized, their activities in initiating photopolymerization of cyclohexene oxide (CHO) were compared with that of IRGACURE 261, a commercialized photoinitiator from Ciba-Geigy. A higher activity was found when the arene ligand was substituted with a stronger electron donating group. For the system initiated by IRGACURE 261 the concentration of active centers in CHO polymerization was determined and it was found that the concentration is maximum at around 35℃. The post (dark) polymerization was significant, the polymerization yield decreased with the increase of irradiation temperature and increased with the increase of post polymerization temperature. The results are interpreted based on the mechanism proposed by Lohse, et al..