By altering the electrochemical properties of slag, the decarburization reaction of Fe3+-based slag withFe-C droplet was studied. The results showed that a lot of free electrons and holes exist in the slag containing ...By altering the electrochemical properties of slag, the decarburization reaction of Fe3+-based slag withFe-C droplet was studied. The results showed that a lot of free electrons and holes exist in the slag containing transition metal oxides (such as TiO2 and Fe2O3). So electronic conduction in the slag increases. Finally, it led to the increment of the decarburization reaction rate between slag and Fe-C droplet, and mass fraction of carbon remaining indroplet decreases to a lower level.展开更多
The reaction of CO2 gas with hot metal was investigated based on the thermodynamic analysis and experi- mental results. It shows that both silicon and carbon in hot metal can be oxidized by CO2 gas in the temperature ...The reaction of CO2 gas with hot metal was investigated based on the thermodynamic analysis and experi- mental results. It shows that both silicon and carbon in hot metal can be oxidized by CO2 gas in the temperature range of 1300-1 500 ℃. When using graphite crucible, temperature has little influence on final mass percent of car bon w[c] because of the carburization effect. Decarburization degree rises significantly with increasing gas injection rate and w[c] can be reduced to 3.2% at most when using MgO crucible. I.ower temperature or higher gas injection rate is propitious to promote desilication reaction, but only 5%- 10% of desilication ratio could be obtained in 20 rain. The final mass percent of silicon W[si] when using MgO crucible is lower than that when using graphite crucible. Ex- perimental results also demonstrate that CO2 injection has no effect on the concentration of manganese, sulfur and phosphorus in hot metal. In view of the weak oxidation ability and temperature drop of hot metal, CO2 gas is sugges- ted to be used as carrier gas in desilication process rather than oxidizing agent.展开更多
文摘By altering the electrochemical properties of slag, the decarburization reaction of Fe3+-based slag withFe-C droplet was studied. The results showed that a lot of free electrons and holes exist in the slag containing transition metal oxides (such as TiO2 and Fe2O3). So electronic conduction in the slag increases. Finally, it led to the increment of the decarburization reaction rate between slag and Fe-C droplet, and mass fraction of carbon remaining indroplet decreases to a lower level.
基金Item Sponsored by National Natural Science Foundation of China and Baosteel Group Corporation of China(51074206)Fundamental Research Funds for Central Universities of China(N120402011)
文摘The reaction of CO2 gas with hot metal was investigated based on the thermodynamic analysis and experi- mental results. It shows that both silicon and carbon in hot metal can be oxidized by CO2 gas in the temperature range of 1300-1 500 ℃. When using graphite crucible, temperature has little influence on final mass percent of car bon w[c] because of the carburization effect. Decarburization degree rises significantly with increasing gas injection rate and w[c] can be reduced to 3.2% at most when using MgO crucible. I.ower temperature or higher gas injection rate is propitious to promote desilication reaction, but only 5%- 10% of desilication ratio could be obtained in 20 rain. The final mass percent of silicon W[si] when using MgO crucible is lower than that when using graphite crucible. Ex- perimental results also demonstrate that CO2 injection has no effect on the concentration of manganese, sulfur and phosphorus in hot metal. In view of the weak oxidation ability and temperature drop of hot metal, CO2 gas is sugges- ted to be used as carrier gas in desilication process rather than oxidizing agent.
