A method of estimating the safe storage life (τ), self-accelerating decomposition temperature (TsADT) and critical temperature of thermal explosion (Tb) of double-base propellant using isothermal and non-isothe...A method of estimating the safe storage life (τ), self-accelerating decomposition temperature (TsADT) and critical temperature of thermal explosion (Tb) of double-base propellant using isothermal and non-isothermal decomposition behaviours is presented. For double-base propellant composed of 56±1wt% of nitrocellulose (NC), 27±0.5wt% of nitroglycerine (NG), 8.15±0.15wt% of dinitrotoluene (DNT), 2.5±0.1wt% of methyl centralite, 5.0±0.15wt% of catalyst and 1.0±0.1wt% of other, the values of r of 49.4 years at 40℃, of TSAOT of 151.35℃ and of Tb of 163.01℃ were obtained.展开更多
Delta carbonate (Delta C, AC) method is a commonly- used surface geochemical exploration method for petroleum surveys. Delta C holds that light hydrocarbon gases leak into near-surface soils or sediments from underl...Delta carbonate (Delta C, AC) method is a commonly- used surface geochemical exploration method for petroleum surveys. Delta C holds that light hydrocarbon gases leak into near-surface soils or sediments from underlying petroleum accumulations, then partly oxidized to CO2, resulting in a special carbonate precipitation, which is termed as Delta carbonate (△C).展开更多
The decomposition temperatures of the lanthanide organic complexes (η 5-C 5H 5) 2Ln(C 6H 5CONHO) involving cyclopentadienyl and benzohydroxamic acid ligands were calculated and predicted by the model based on A...The decomposition temperatures of the lanthanide organic complexes (η 5-C 5H 5) 2Ln(C 6H 5CONHO) involving cyclopentadienyl and benzohydroxamic acid ligands were calculated and predicted by the model based on ANNs (artificial neural networks) method. The comparison was carried out between results from ANNs method and traditional regression method. It is proved that ANNs could be used more efficiently for the prediction of decomposition temperature of lanthanide organic complexes.展开更多
The microstructures and superconducting properties of melt textured(Y_(1-x)Gd_x)BCO bulk samples were studied. It was found that the peritectic decomposition temperature(T_m)of(Y_(1-x)Gd_x)BCO samples increases with i...The microstructures and superconducting properties of melt textured(Y_(1-x)Gd_x)BCO bulk samples were studied. It was found that the peritectic decomposition temperature(T_m)of(Y_(1-x)Gd_x)BCO samples increases with increasing x. Large single domain growth in air is readily obtained in all the composites. The results of X-ray distribution maps of x=0.4 composite indicate that the RE123 matrix is homogeneous and Y and Gd elements in the RE site forms a perfect solid solution. The onset T_c values exceeding 91 K with relatively broad transitions are obtained for almost all the samples. Magnetization measurements show no marked indication for the formation of a peak effect in the J_c-B curves, and the highest J_c measured is 3.08×10~4 A·cm^(-2) for x=0.4 sample at 77 K and self-field. The results clearly indicate that Y dominates the superconducting properties of x=0.2 and (0.4) composites.展开更多
The properties of resin transfer molding(RTM)cyanate ester and its T800 grade carbon fiber composites were studied with the rheometer,differential scanning calorimetry(DSC),FT-IR,dynamic mechanical analyzer(DMA),therm...The properties of resin transfer molding(RTM)cyanate ester and its T800 grade carbon fiber composites were studied with the rheometer,differential scanning calorimetry(DSC),FT-IR,dynamic mechanical analyzer(DMA),thermal gravimetric analysis(TGA),mechanical property testing,and scanning electron microscopy(SEM).The results showed that the temperature of cyanate ester suitable for RTM process was 70℃.Curing process of the resin was 130℃/2 h+160℃/2 h+200℃/2 h+220℃/4 h.Glass transition temperature and heat decomposition temperature of the cured resin are 289℃and 415℃,respectively.Mechanical properties of T800/RTM cyanate composites are 13.5%higher than that of T700/RTM cyanate composites and equal to that of T800/Prepreg cyanate composites.Tg of T800/RTM cyanate composites was proved to be 291℃.Fracture pattern of the composites was flat,which proved excellent interface properties between fiber and resin in this composite.展开更多
In this paper, with consideration of the nonlinear and non-stationary properties of the temperature time series, we employ the Hilbert-Huang Transform, based on the empirical mode decomposition(EMD), to analyze the ...In this paper, with consideration of the nonlinear and non-stationary properties of the temperature time series, we employ the Hilbert-Huang Transform, based on the empirical mode decomposition(EMD), to analyze the temperature time series from 1959 to 2012 in the Fengxian district of Shanghai, obtained from a certain monitoring station. The oscillating mode is drawn from the data, and its characteristics of the time series are investigated. The results show that the intrinsic modes of 1, 2 and 6 represent the periodic properties of 1 year, 2.5 years, and 27 years. The mean temperature shows periodic variations, but the main trend of this fluctuation is the rising of the temperature in the recent 50 years. The analysis of the reconstructed modes with the wave pattern shows that the variations are quite large from 1963 to 1964, from 1977 to 1982 and from 2003 to 2006, which indicates that the temperature rises and falls dramatically in these periods. The volatility from 1993 to 1994 is far more dramatic than in other periods. And the volatility is the most remarkable in recent 50 years. The log-linear plots of the mean time scales T and M show that each mode associated with a time scale almost twice as large as the time scale of the preceding mode. The Hilbert spectrum shows that the energy is concentrated in the range of low frequency from 0.05 to 0.1 Hz, and a very small amount of energy is distributed in the range of higher frequency over 0.1 Hz. In conclusion, the HHT is better than other traditional signal analysis methods in processing the nonlinear signals to obtain the periodic variation and volatility's properties of different time scales.展开更多
基金We are grateful to the National Natural Science Foundation of China (No. 20573098)
文摘A method of estimating the safe storage life (τ), self-accelerating decomposition temperature (TsADT) and critical temperature of thermal explosion (Tb) of double-base propellant using isothermal and non-isothermal decomposition behaviours is presented. For double-base propellant composed of 56±1wt% of nitrocellulose (NC), 27±0.5wt% of nitroglycerine (NG), 8.15±0.15wt% of dinitrotoluene (DNT), 2.5±0.1wt% of methyl centralite, 5.0±0.15wt% of catalyst and 1.0±0.1wt% of other, the values of r of 49.4 years at 40℃, of TSAOT of 151.35℃ and of Tb of 163.01℃ were obtained.
基金supported by National Natural Science Foundation of China(grant No.41302099)Open Foundation of State Key Laboratory of Organic Geochemistry(grant No.OG2015-03)Open Foundation of Key Laboratory of Marine Mineral Resources,Ministry of Land and Resources(grant No.KLMMR-2013-A-25)
文摘Delta carbonate (Delta C, AC) method is a commonly- used surface geochemical exploration method for petroleum surveys. Delta C holds that light hydrocarbon gases leak into near-surface soils or sediments from underlying petroleum accumulations, then partly oxidized to CO2, resulting in a special carbonate precipitation, which is termed as Delta carbonate (△C).
基金ProjectsupportedbytheNaturalScienceFoundation (No .0 0 0 46 5 0 9)ofAnhuiProvince ,theNaturalScienceFoundation (No .2 0 0j10 90 )ofAnhuiEducationCommitteeandtheYouthFoundationofAnhuiNormalUniversity
文摘The decomposition temperatures of the lanthanide organic complexes (η 5-C 5H 5) 2Ln(C 6H 5CONHO) involving cyclopentadienyl and benzohydroxamic acid ligands were calculated and predicted by the model based on ANNs (artificial neural networks) method. The comparison was carried out between results from ANNs method and traditional regression method. It is proved that ANNs could be used more efficiently for the prediction of decomposition temperature of lanthanide organic complexes.
文摘The microstructures and superconducting properties of melt textured(Y_(1-x)Gd_x)BCO bulk samples were studied. It was found that the peritectic decomposition temperature(T_m)of(Y_(1-x)Gd_x)BCO samples increases with increasing x. Large single domain growth in air is readily obtained in all the composites. The results of X-ray distribution maps of x=0.4 composite indicate that the RE123 matrix is homogeneous and Y and Gd elements in the RE site forms a perfect solid solution. The onset T_c values exceeding 91 K with relatively broad transitions are obtained for almost all the samples. Magnetization measurements show no marked indication for the formation of a peak effect in the J_c-B curves, and the highest J_c measured is 3.08×10~4 A·cm^(-2) for x=0.4 sample at 77 K and self-field. The results clearly indicate that Y dominates the superconducting properties of x=0.2 and (0.4) composites.
文摘The properties of resin transfer molding(RTM)cyanate ester and its T800 grade carbon fiber composites were studied with the rheometer,differential scanning calorimetry(DSC),FT-IR,dynamic mechanical analyzer(DMA),thermal gravimetric analysis(TGA),mechanical property testing,and scanning electron microscopy(SEM).The results showed that the temperature of cyanate ester suitable for RTM process was 70℃.Curing process of the resin was 130℃/2 h+160℃/2 h+200℃/2 h+220℃/4 h.Glass transition temperature and heat decomposition temperature of the cured resin are 289℃and 415℃,respectively.Mechanical properties of T800/RTM cyanate composites are 13.5%higher than that of T700/RTM cyanate composites and equal to that of T800/Prepreg cyanate composites.Tg of T800/RTM cyanate composites was proved to be 291℃.Fracture pattern of the composites was flat,which proved excellent interface properties between fiber and resin in this composite.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11102114,11172179 and 11332006)the Inovation Program of Shanghai Municipal Education Commission(Grant No.13YZ124)
文摘In this paper, with consideration of the nonlinear and non-stationary properties of the temperature time series, we employ the Hilbert-Huang Transform, based on the empirical mode decomposition(EMD), to analyze the temperature time series from 1959 to 2012 in the Fengxian district of Shanghai, obtained from a certain monitoring station. The oscillating mode is drawn from the data, and its characteristics of the time series are investigated. The results show that the intrinsic modes of 1, 2 and 6 represent the periodic properties of 1 year, 2.5 years, and 27 years. The mean temperature shows periodic variations, but the main trend of this fluctuation is the rising of the temperature in the recent 50 years. The analysis of the reconstructed modes with the wave pattern shows that the variations are quite large from 1963 to 1964, from 1977 to 1982 and from 2003 to 2006, which indicates that the temperature rises and falls dramatically in these periods. The volatility from 1993 to 1994 is far more dramatic than in other periods. And the volatility is the most remarkable in recent 50 years. The log-linear plots of the mean time scales T and M show that each mode associated with a time scale almost twice as large as the time scale of the preceding mode. The Hilbert spectrum shows that the energy is concentrated in the range of low frequency from 0.05 to 0.1 Hz, and a very small amount of energy is distributed in the range of higher frequency over 0.1 Hz. In conclusion, the HHT is better than other traditional signal analysis methods in processing the nonlinear signals to obtain the periodic variation and volatility's properties of different time scales.