Pore-pressure and stress-coupled creep behavior in deep coal:Insights from real-time NMR analysis

Understanding the variations in microscopic pore-fracture structures(MPFS) during coal creep under pore pressure and stress coupling is crucial for coal mining and effective gas treatment. In this manuscript, a triaxial creep test on deep coal at various pore pressures using a test system that combines in-situ mechanical loading with real-time nuclear magnetic resonance(NMR) detection was conducted.Full-scale quantitative characterization, online real-time detection, and visualization of MPFS during coal creep influenced by pore pressure and stress coupling were performed using NMR and NMR imaging(NMRI) techniques. The results revealed that seepage pores and microfractures(SPM) undergo the most significant changes during coal creep, with creep failure gradually expanding from dense primary pore fractures. Pore pressure presence promotes MPFS development primarily by inhibiting SPM compression and encouraging adsorption pores(AP) to evolve into SPM. Coal enters the accelerated creep stage earlier at lower stress levels, resulting in more pronounced creep deformation. The connection between the micro and macro values was established, demonstrating that increased porosity at different pore pressures leads to a negative exponential decay of the viscosity coefficient. The Newton dashpot in the ideal viscoplastic body and the Burgers model was improved using NMR experimental results, and a creep model that considers pore pressure and stress coupling using variable-order fractional operators was developed. The model’s reasonableness was confirmed using creep experimental data. The damagestate adjustment factors ω and β were identified through a parameter sensitivity analysis to characterize the effect of pore pressure and stress coupling on the creep damage characteristics(size and degree of difficulty) of coal.

Theory,technology and application of grouted bolting in soft rock roadways of deep coal mines

The grouted bolt,combining rock bolting with grouting techniques,provides an effective solution for controlling the surrounding rock in deep soft rock and fractured roadways.It has been extensively applied in numerous deep mining areas characterized by soft rock roadways,where it has demonstrated remarkable control results.This article systematically explores the evolution of grouted bolting,covering its theoretical foundations,design methods,materials,construction processes,monitoring measures,and methods for assessing its effectiveness.The overview encompassed several key elements,delving into anchoring theory and grouting reinforcement theory.The new principle of high pretensioned high-pressure splitting grouted bolting collaborative active control is introduced.A fresh method for dynamic information design is also highlighted.The discussion touches on both conventional grouting rock bolts and cable bolts,as well as innovative grouted rock bolts and cables characterized by their high pretension,strength,and sealing hole pressure.An examination of the merits and demerits of standard inorganic and organic grouting materials versus the new inorganic–organic composite materials,including their specific application conditions,was conducted.Additionally,the article presents various methods and instruments to assess the support effect of grouting rock bolts,cable bolts,and grouting reinforcement.Furthermore,it provides a foundation for understanding the factors influencing decisions on grouted bolting timing,the sequence of grouting,the pressure applied,the volume of grout used,and the strategic arrangement of grouted rock bolts and cable bolts.The application of the high pretensioned high-pressure splitting grouted bolting collaborative control technology in a typical kilometer-deep soft rock mine in China—the soft coal seam and soft rock roadway in the Kouzidong coal mine,Huainan coal mining area,was introduced.Finally,the existing problems in grouted bolting control technology for deep soft rock roadways are analyzed,and the future development trend of grouted bolting control technology is anticipated.

Study of a low-disturbance pressure-preserving corer and its coring performance in deep coal mining conditions

With the increasing depth of coal mining,the requirements for coring devices that maintain pressure are increasing.To adapt to the special environment in deep coal seams and improve the accuracy of testing gas content,a low-disturbance pressure-preserving corer was developed.The measurement of gas content using this corer was analyzed.The coring test platform was used to complete a coring function test.A pressurized core with a diameter of 50 mm was obtained.The pressure was 0.15 MPa,which was equal to the pressure of the liquid column of the cored layer,indicating that the corer can be successfully used in a mud environment.Next,a pressure test of the corer was conducted.The results showed that under conditions of low pressure(8 MPa)and high pressure(25 MPa),the internal pressure of the corer remained stable for more than 1 h,indicating that the corer has good ability to maintain pressure.Therefore,the corer can be applied at deep coal mine sites.The results of this research can be used to promote the safe exploitation of deep coal mines and the exploitation of methane resources in coalbeds.

Mechanical behaviors of coal measures and ground control technologies for China's deep coal mines-A review

This paper reviews the major achievements in terms of mechanical behaviors of coal measures,mining stress distribution characteristics and ground control in China’s deep underground coal mining.The three main aspects of this review are coal measure mechanics,mining disturbance mechanics,and rock support mechanics.Previous studies related to these three topics are reviewed,including the geo-mechanical properties of coal measures,distribution and evolution characteristics of mining-induced stresses,evolution characteristics of mining-induced structures,and principles and technologies of ground control in both deep roadways and longwall faces.A discussion is made to explain the structural and mechanical properties of coal measures in China’s deep coal mining practices,the types and dis-tribution characteristics of in situ stresses in underground coal mines,and the distribution of mining-induced stress that forms under different geological and engineering conditions.The theory of pre-tensioned rock bolting has been proved to be suitable for ground control of deep underground coal roadways.The use of combined ground control technology(e.g.ground support,rock mass modification,and destressing)has been demonstrated to be an effective measure for rock control of deep roadways.The developed hydraulic shields for 1000 m deep ultra-long working face can effectively improve the stability of surrounding rocks and mining efficiency in the longwall face.The ground control challenges in deep underground coal mines in China are discussed,and further research is recommended in terms of theory and technology for ground control in deep roadways and longwall faces.

Double-directional control bolt support technology and engineering application at large span Y-type intersections in deep coal mines

Under deep and complex geological conditions,severe deformation occurs at intersection points of Y-type roadways with large cross sections during engineering projects in coal mines,especially at junction arches.Based on in-situ investigations and theoretical studies,we have summarized typical forms of destruction and identified high stress and unrestricted support at both sides of junction arch as its main causes.In this study,we also presented double-directional control bolt support technology for a large Y-type span intersection,applied to deep intersection engineering in the Jiahe Coal Mine,which has proved effective.

Research on space-time coupling action laws of anchor-cable strengthening supporting for rock roadway in deep coal mine

In order to obtain space-time coupling relationship of anchor-cable to improve supporting effect for deep coal mine rock roadway, FLAC3D was used to investigate into mechanical characteristics of the roadway whose crosssection shape was vertical wall and semi-circular arch when the roadway was supported by bolts and metal mesh. The results show that the extent of stress concentrations, the range failure zone, and the deformation at the roof center and two spandrels of roadway are greater than those at other positions, except at the floor. The reasonable positions of anchor-cable supporting are the roof center and two spandrels of roadway. The anchor-cable should be installed at good time with bolts supporting after roadway driving be- cause it can improve the stress states of deep surrounding rock around the roadway and control the roadway deformation effec- tively. The engineering practice has proven that the sustained deformation of deep surrounding rocks is effectively controlled when the anchor-cable supporting is adopted at reasonable positions of the roadway at good time.

Surrounding rock control mechanism of deep coal roadways and its application

Aiming at the surrounding rock control problem of mining and preparation entries in Xingdong mine with large mining depth, and the comprehensive control countermeasures including high pre-stress cable truss system, this study put forward powerful anchor support system and anchor cable adaption technology to surrounding rock deformation. Furthermore, the control measures possess the supporting performance with ‘‘primary rigid-following flexible-new rigid, and primary resistance-following yield-new resistance'', which suits deep roadway surrounding rock control. The mechanical model of truss anchor supporting roof beams was established, and the inverted arch deflection produced by the cable pre-stress with stress increment effect and roof beam deflection were obtained. And then the system working mechanism was illustrated. Finally, the surrounding rock support parameters were determined by means of comprehensive methods, and put into practice. The results show that surrounding rock deformation realized secondary stability after three months. The roadway sides convergence value was less than 245mm, and roof subsidence was less than 124mm. In addition, there was no expansion and renovation during service period.

Soft–strong supporting mechanism of gob-side entry retaining in deep coal seams threatened by rockburst

When gob-side entry retaining is implemented in deep coal seams threatened by rockburst, the cementbased supporting body beside roadway will bear greater roof pressure and strong impact load. Then the supporting body may easily deform and fail because of its low strength in the early stage. This paper established the roadside support mechanical model of gob-side entry retaining. Based on this model,we proposed and used the soft–strong supporting body as roadside support in the gob-side entry retaining. In the early stage of roof movement, the soft–strong supporting body has a better compressibility, which can not only relieve roof pressure and strong impact load, but also reduce the supporting resistance and prevent the supporting body from being crushed. In the later stage, with the increase of the strength of the supporting body, it can better support the overlying roof. The numerical simulation results and industrial test show that the soft–strong supporting body as roadside support can be better applied into the gob-side entry retaining in deep coal seams threatened by rockburst.

Microstructure and its influence on CH_4 adsorption behavior of deep coal

In this paper we investigate the influence of microstructure on the CH4 adsorption behavior of deep coal. The coal microstructure is characterized by N2 adsorption at 77 K, scanning electron microscopy （SEM）, Raman spectroscopy, and Fourier transform infrared spectroscopy （FT-IR）. The CH4 adsorptions are measured at 298 K at pressures up to 5.0 MPa by the the volumetric method and fitted by the Langmuir model. The results show that the Langmuir model fits well with the experimental data, and there is a positive correlation with surface area, pore volume, ID/IG, and CH4 adsorption capacity. The burial depth also affects the methane adsorption capacity of the samples.

RESEARCH ON DEEP COAL SEAM MINING FLOOR STARTA WATER BURSTING INFLUENCED FACTORS BASED ON ANALYTIC HIERACHY PROCESS

Deep coal seam mining floor strata water bursting is a complicate nonlinear system, whose factors are coupling and influencing themselves. It built the analytic structure model for deep coal seam mining floor strata water bursting, the judgment matrix was found by the expert scoring method, the contribution weights of the influenced factors were given out by the equation analytic process. The thirteen controlling factors and five main controlling factors were put award by analyzing weights, so the result was basically conform to the field practice. The expert scoring method and analytic process can convert the objective fact to the subjective cognition, so it is a method that can turn the qualitative into the quantitative. This can be relative objectively and precisely to study the question of many factors and grey box.

Analysis and Design Innovation on Underground Gasifier for Medium-Deep Coal Seam

Over the past 80 years,dozens of underground coal gasification(UCG)mine field tests have been carried out around the world.However,in the early days,only a small number of shallow UCG projects in the former Soviet Union achieved commercialised production.In this century,a few pilot projects in Australia also achieved short-term small-scale commercialised production using modern UCG technology.However,the commercialisation of UCG,especially medium-deep UCG projects with good development prospects but difficult underground engineering conditions,has not progressed smoothly around the world.Considering investment economy,a single gasifier must realise a high daily output and accumulated output,as well as hold a long gasification tunnel to control a large number of coal resources.However,a long gasification tunnel can easily be affected by blockages and failure,for which the remedial solutions are difficult and expensive,which greatly restricts the investment economy.The design of the underground gasifier determines the success or failure of UCG projects,and it also requires the related petroleum engineering technology.Combining the advantages of the linear horizontal well(L-CRIP)and parallel horizontal well(P-CRIP),this paper proposes a new design scheme for an“inclined ladder”underground gasifier.That is to say,the combination of the main shaft of paired P-CRIP and multiple branch horizontal well gasification tunnels is adopted to realise the control of a large number of coal resources in a single gasifier.The completion of the main shaft by well cementation is beneficial for maintaining the integrity of the main shaft and the stability of the main structure.The branch horizontal well is used as the gasification tunnel,but the length and number of retracting injection points are limited,effectively reducing the probability of blockage or failure.The branch horizontal well spacing can be adjusted flexibly to avoid minor faults and large cracks,which is conducive to increasing the resource utilisation rate.In addition,for multi-layer thin coal seams or ultra-thick coal seams,a multi-layer gasifier sharing vertical well sections can be deployed,thereby saving investment on the vertical well sections.Through preliminary analysis,this gasifier design scheme can be realised in engineering,making it suitable for largescale deployment where it can increase the resource utilisation rate and ensure stable and controllable operations.The new gasifier has outstanding advantages in investment economy,and good prospects for application in the commercial UCG projects of medium-deep coal seams.

Discovery and geological knowledge of the large deep coal-formed Qingyang Gas Field, Ordos Basin, NW China

After 50 years of oil and gas exploration in Longdong area of southwest Ordos Basin,NW China,a deep coal-formed gas field was discovered for the first time in Qingyang area.Through observation of field outcrops and core,analysis of common,cast and cathode thin sections,Ro and other geochemistry indexes,carbon isotope,electron microscope and other supporting tests and analyses,the hydrocarbon generation,reserves formation and reservoir formation characteristics of gas reservoirs at different buried depths in Yishaan slope were examined and compared.The deep gas reservoir has an average buried depth of more than 4200 m,and the main gas-bearing formation is the Member 1 of Lower Permian Shanxi Formation,which is characterized by low porosity,low permeability,low pressure and low abundance.It is believed that hydrocarbon generation in thin seam coal source rocks with high thermal evolution can form large gas fields,high-quality sandstone reservoirs with dissolved pores,intergranular pores and intercrystalline pores can still develop in late diagenetic stage under deep burial depth and high thermal evolution,and fractures improve the permeability of reservoirs.High drying coefficient of natural gas and negative carbon isotope series are typical geochemical characteristics of deep coal-formed gas.The integrated exploration and development method has been innovated,and the economic and effective development mode of gas fields of"dissecting sand body by framework vertical wells,centralized development by horizontal wells"has been formed.The discovery and successful exploration of the large gas field has provided geological basis and technical support for the construction of natural gas fields of 100 billion cubic meter scale in the southwest of the basin,and has important guidance for exploration of coal-derived gas with deep buried depth and high thermal evolution widely distributed in China.

Factors Influencing Proppant Transportation and Hydraulic Fracture Conductivity in Deep Coal Methane Reservoirs

The gas production of deep coalbed methane wells in Linxing-Shenfu block decreases rapidly,the water output is high,the supporting effect is poor,the effective supporting fracture size is limited,and the migration mechanism of proppant in deep coal reservoir is not clear at present.To investigate the migration behavior of proppants in complex fractures during the volume reconstruction of deep coal and rock reservoirs,an optimization test on the conductivity of low-density proppants and simulations of proppant migration in complex fractures of deep coal reservoirs were conducted.The study systematically analyzed the impact of various fracture geometries,proppant types and fracturingfluid viscosities on proppant distribution.Furthermore,the study compared the outcomes of dynamic proppant transport experiments with simulation results.The results show that the numerical simulation is consistent with the results of the proppant dynamic sand-carrying experiment.Under the conditions of low viscosity and large pumping-rate,a high ratio of 40/70 mesh proppant can facilitate the movement of the proppant to the depths of fractures at all levels.The technical goal is to create comprehensive fracture support within intricate trapezoidal fractures in deep coal and rock reservoirs without inducing sand plugging.The sand ratio is controlled at 15%–20%,with a proppant combination ratio of 40/70:30/50:20/40=6:3:1.Proppant pumping operations can effectively address the issue of poor support in complex fractures in deep coal formations.The research results have been successfully applied to the development of deep coalbed methane in the Linxing-Shenfu block,Ordos Basin.

Performance Evaluation of Low-Carbon and Clean Transformation of China’s Coal Economy

In China,the oversupply of coal occurred in 2009,and from that year onwards,China’s coal economy began a low-carbon and clean transformation.Evaluating transformation performance is the research goal of this paper.The data collection for this paper includes data on deep processing of Chinese coal products from 2009 to 2020,as well as data on asset structure evolution and financial performance of 34 listed companies in the Chinese coal mining.Entropy value method is used to calculate the entropy value of low-carbon transformation,and the regression analysis is used to study the performance of cleaner transformation,the conclusion is as follows:(1)From 2009 to 2020,in China’s total energy consumption,coal consumption accounted for 71.6%in 2009 and 56.8%in 2020,the goals set by the state have been achieved.(2)The national goal of reducing the proportion of coal consumption and reducing carbon emissions has forced the transformation of deep processing of coal products.The transformation of coal enterprises towards low-carbon and clean production has achieved remarkable results.(3)From 2009 to 2020,the non coal industry income of 34 listed companies in China’s coal mining industry increased by 8.21%annually.At the same time,the asset structure was adjusted,and nearly 80%of the asset structure evolution showed an orderly development trend.(4)The regression analysis results show that the entropy value of coal deep processing products and the entropy value of asset structure adjustment are significantly related to transformation performance.The paper proposes to summarize the successful experience of China’s coal energy economic transformation,lay a foundation for achieving the carbon peak and carbon neutral goals in the future,further increase the intensity of coal deep processing,increase the proportion of clean energy in total energy consumption,and strive to control asset operation towards the goal of increasing the proportion of non coal industry income.

Evolution characteristics of precursor information of coal and gas outburst in deep rock cross‑cut coal uncovering

As mines become deeper,the potential for coal and gas outbursts in deep rock cross-cut coal uncovering is enhanced.The outburst precursors are unclear,which restricts the effectiveness and reliability of warning systems.To reveal the evolution characteristics of coal and gas outburst precursor information in deep rock cross-cut coal uncovering,briquette specimens are constructed and experiments are conducted using a self-developed true triaxial outburst test system.Using acoustic emission monitoring technology,the dynamic failure of coal is monitored,and variations in the root mean square(RMS)of the acoustic emissions allow the effective cracking time and effective cracking gas pressure to be defined.These characteristics are obviously different in deep and shallow coal.The characteristic parameters of gas outburst exhibit stepwise variations at different depths.The RMS and cumulative RMS have stepped failure characteristics with respect to changes in gas pressure.The characteristic parameters of coal failure are negatively correlated with the average in-situ stress and effective stress,but positively correlated with the lateral pressure coefficient of in-situ stress and the critical gas pressure.The transition characteristics are highly sensitive in all cases.The critical depth between deep and shallow coal and gas outbursts is 1700 m.The expansion multiple of acoustic emission intensity from the microfracture stage to the sharp-fracture stage of coal is defined as the outburst risk index,N1.For depths of 1100–1700 m,N1≥7 denotes a higher risk of outburst,whereas at depths of 1700–2500 m,N1≥3 indicates enhanced risk.

Gas-solid coupling laws for deep high-gas coal seams

A better understanding of gas-solid coupling laws for deep, gassy coal seams is vital for preventing the compound dynamic disasters such as rock burst and gas outburst. In this paper, a gas-solid coupling theoretical model under the influence of ground stress, gas pressure, and mining depth is established and simulated by using COMSOL Multiphysics software. Research results indicate that under the influence of factors such as high ground stress and gas pressure, the mutual coupling interaction between coal and gas is much more significant, which leads to the emergence of new characteristics of gas compound dynamic disasters. Reducing the ground stress concentration in front of the working face can not only minimize the possibility of rock burst accidents, which are mainly caused by ground stress, but also can weaken the role of ground stress as a barrier to gas, thereby decreasing the number of outburst accidents whose dominant factor is gas. The results have a great theoretical and practical significance in terms of accident prevention, enhanced mine safety, disaster prevention system design, and improved accident emergency plans.

煤炭原位开发地质保障

“双碳”目标下,面对“缺油、少气、相对富煤”的资源禀赋特征,煤炭在一段时期内仍占据中国的主体能源地位,但煤炭的低碳、清洁开发转型势在必行。地下原位热解、气化、干馏、制氢等方式有望成为未来煤炭开发的重要抓手。当前对煤炭原位开发已有较多探索,但地质选址和开发过程的地质安全性、可靠性和环保性仍是制约其规模化和商业化的科学难题。因此,煤炭原位开发地质保障的理论和技术研究亟待深入。秉持“安全、经济、环保、可持续”原则,从煤炭资源禀赋特征和地质条件出发,分析了煤炭原位开发研究现状;基于煤炭开发全生命周期的科学理念,提出了“煤炭原位开发地质保障”的科学内涵;在查明采前地质条件的基础上,从物理机制角度揭示深部原位开发过程中围岩地质体响应特征和损害规律,阐明原位开发中岩体工程地质力学行为,构建原位开发地质条件动态评价模型,形成原位开发减损保障策略和方法,提出原位开发空间的再利用途径,并以煤炭地下气化和地下热解2种开发模式为例阐述了原位开发阶段性,明确了原位开发区设计的地质条件要素,强调开发过程中实时动态监测和评价围岩地质体响应保证开发区密封性与安全性,实现地质条件时空演化的评价及地质风险可控性,此外注重协同开发深部热能与共伴生资源,实现残余资源利用和地下空间再利用。煤炭原位地质保障研究体现了资源赋存条件、地质环境约束、原位开发技术、地质风险防控、资源协同开发等层面的要求,突出了原位扰动条件下的地质条件变化,强调开发扰动与地质体结构的整体研究,理解原位开发时空效应范畴的多相场耦合损伤机制,从多圈层角度揭示原位开发扰动效应下地质风险模式,破解资源开发与地质环境制约之间矛盾,对于推动未来煤炭低碳开发,实现煤炭工业高质量发展具有重要的理论和实践指导意义。

深部煤层地下气化选址研究——以东胜气田J148地区为例

从地质构造、水文地质、煤层气化适用性等角度,系统研究了东胜气田J148地区中生界侏罗系中下统延安组延9煤层地下气化的可行性,并探讨了利用深部煤层气化燃空区孔隙层、含水层及该区致密气层进行碳封存的前景。研究结果表明,该区延9煤层埋深1 264~1 285 m、倾角小于1°,煤层稳定性好。气化目标选区内地层断层、节理裂隙不发育,偶有裂隙但断面新鲜、闭合,煤层气化后空腔有较好的密闭性,对煤炭地下气化影响小,有利于气化炉的建设和扩展,可满足规模化煤炭地下气化项目实施。延9煤层顶底板存在连续的隔水层,能阻截地下水对煤层直接充水,有利于地下气化炉布置;顶板隔水层厚度小于导水裂隙带高度,存在垮落导通顶板含水层间接充水的风险,但顶板含水层属弱富水含水层,涌水量小,风险可控;底板隔水层厚度大于隔水层的安全厚度,能有效阻截煤层底板含水层对煤层直接充水的风险。总体而言,延9煤层厚度适中、夹矸少,属低灰、低硫、高热值不黏煤,煤焦反应活性高,具有良好开发前景。针对深部煤层规模化气化开采产生大量的CO_(2)排放,初步探讨了利用煤层燃空区、顶底板含水层和下部致密天然气层进行CO_(2)安全封存可行性。分析认为,在延9煤层气化燃空区孔隙层和顶底板含水层中,可封存煤层气化产生的CO_(2)的60.8%~88.2%;若结合东胜气田上古生界致密天然气开发,用煤气化产生CO_(2)进行天然气驱替与封存,有望实现深部煤层气化开采过程近零碳排放。

基于组合赋权三维云评估技术的深部煤矿顶板事故风险分析

为了更好地对深部煤矿顶板事故展开风险评价,提出了组合赋权三维云评估技术。基于事故统计及事故致因理论,对深部煤矿顶板事故风险指标体系展开研究,采用博弈论对改进层次分析法(Analytic Hierarchy Process,AHP)和熵权法进行博弈分析,以实现风险指标的组合赋权,通过构建三维云模型,对深部煤矿顶板事故危险性进行可视化分析。结果表明:包括行为、技术、设备、环境、管理5大风险因素在内的一级指标并其下20个二级风险指标是深部煤矿顶板事故风险评价指标体系的主体内容,且以环境风险权重最大;由三维云评估技术分析可知,平煤九矿的顶板事故风险级别为Ⅲ级,即修复后可接受,与该矿生产实际情况相符。组合赋权三维云评估技术的提出有助于完善深部煤矿顶板事故风险评价方法,可应用于工程实践。

深部煤层CO_(2)地质封存量化评估及案例研究

地质封存CO_(2)作为理想的减碳技术,有望成为缓解温室效应的重要手段,因此量化评估深部煤层CO_(2)地质封存潜力与研究超临界CO_(2)与深部煤岩之间相互作用成为了“双碳”背景下的研究热点。以焦作矿区九里山煤样为试验研究对象,分析了深部煤层超临界CO_(2)吸附与封存机理,分别开展了35和45℃下煤样的CO_(2)等温吸附试验,解释并校正了CO_(2)吸附等温线高压异常下拐现象,得到了不同温度下煤样的CO_(2)实际吸附量。提出了一种新方法计算CO_(2)地质封存量,能够校正吸附相体积造成的封存量计算误差,并能精确评估不同埋深煤层CO_(2)理论和有效封存量。研究结果表明:①当高压吸附饱和时,煤样表面所有的吸附位被完全占据,此时吸附相体积和密度不再发生改变,吸附量应趋于稳定,但实验室测得的吸附量却在高压饱和阶段随压力增大而减小,这并不符合Langmuir吸附原理,因此必须对实验室测试的吸附等温线进行校正,才能应用于深部煤层CO_(2)封存量评估;②煤中CO_(2)封存量主要由吸附和游离封存量组成,吸附封存量需要采用吸附相密度和Gibbs吸附量进行反算,游离封存量则需要掌握煤中游离相占据的孔隙体积,它只能根据煤中孔隙总体积减去吸附相体积进行计算,因此,吸附相是精确评估吸附和游离封存量的决定性因素;③采用修正的煤层CO_(2)地质封存量化方法,以焦作修武研究区800~2000 m深部煤层为例,得出其单位质量煤中CO_(2)理论封存量为1.52~2.16 mmol/g,CO_(2)有效封存总量为11.19×10^(9)m^(3),换算为封存总质量为21.97 Mt。本研究案例不仅校正了吸附试验数据的物质平衡错误,而且考虑了吸附相占据孔隙空间对游离封存量的影响,这对深部煤层CO_(2)地质封存量精准评估具有重要的应用意义。