The greatest difficulties in recognizing geochemical hydrocarbon anomalies are: (1) how to objectively and accurately separate anomalies from background; (2) how to distinguish hydrocarbon pool related apical anomal...The greatest difficulties in recognizing geochemical hydrocarbon anomalies are: (1) how to objectively and accurately separate anomalies from background; (2) how to distinguish hydrocarbon pool related apical anomalies from lateral anomalies controlled by faults; and (3) how to eliminate interferences. These uncertainties are serious obstacles for the wide acceptance and use of geochemical techniques in hydrocarbon exploration. In this paper, the features of hydrocarbon anomalies were analyzed based on the micro migration mechanisms. In most cases, there are two anomalous populations or point groups, which are produced by two distinct mechanisms: (1) a population that directly reflects oil and gas fields, and (2) one that is related to structures such as faults. Statistical studies show that background anomalous populations and the boundaries between them can be described by the population means, prior probabilities, which are the proportions of population sizes, and covariance matrices, when background and anomalous populations have normal distributions. When this normality condition is met, a series of formulas can be derived. The method is designed on the basis of these allows: (1) univariate anomaly recognition, (2) elimination of interferences, (3) multivariate anomaly recognition, and (4) multivariate anomaly combination which depicts a more representative picture of morphology of the anomalous target than individual anomalies. The univariate and multivariate anomaly recognition can not only separate anomalies from background objectively, but also simultaneously distinguish the two types of anomalies objectively. This method was applied to the hydrocarbon data in Yangshuiwu region, Hebei Province. The interferences from regional variation of background were eliminated, and the interpretation uncertainty was reduced greatly as the anomalous populations were separated. The method was also used in Daxing region within the confines of Beijing City, and Aershan and Jiergalangtu regions in Inner Mongolia.展开更多
Fractal and multi-fractal content area method finds application in a wide variety of geological,geochemical and geophysical fields.In this study,the fractal content-gradient method was used on1:10,000 scale to deline...Fractal and multi-fractal content area method finds application in a wide variety of geological,geochemical and geophysical fields.In this study,the fractal content-gradient method was used on1:10,000 scale to delineate geochemical anomalies associated with copper mineralization.Analysis of geochemical data from the Yangla super large Cu-Pb-Zn polymetallic ore district using the fractal content-gradient method,combined with other geological data from this area,indicates that oreprospecting in the ore district should focus on Cu as the main metal and Pb-Zn and Au as the auxiliary metals.The types of deposits include(in chronological order) re-formed sedimentary exhalative(SEDEX),skarns,porphyries,and hydrothermal vein-type deposits.Three ore-prospecting targets are divided on a S-N basis:(1) the Qulong exploration area,in which the targets are porphyry-type Cu deposits;(2) the Zongya exploration area,where the targets are porphyry-type Cu and hydrothermal vein-type Cu-Pb polymetallic deposits;and(3) the Zarelongma exploration area,characterized mainly skarn-type "Yangla-style" massive sulfide Cu-Pb deposits.Our study demonstrates that the fractal content-gradient method is convenient,simple,rapid,and direct for delineating geochemical anomalies and for outlining potential exploration targets.展开更多
Based on the results of researches and applications for many years, it has been discovered that new methods and techniques for geochemical exploration of oil and gas such as δC, altered carbonate, Hg in absorption ph...Based on the results of researches and applications for many years, it has been discovered that new methods and techniques for geochemical exploration of oil and gas such as δC, altered carbonate, Hg in absorption phase, Ks, Fe2+, δ13C, fluorescence in two and three dimensions, and N2 and O2 in heat release can give full play in the following five fields: (1) optimization of the favourable target or hollow zones and structural zones in a region; (2) evaluation of oil traps and delineation of prospective oil and gas areas; (3) prediction of deep-seated oil-bearing horizons; (4) evaluation of the genesis of oil and gas geochemical anomalies and determination of the types of oil and gas accumulations; (5) forecast of the burial depths of oil and gas pools.展开更多
In this study,methods based on the distribution model(with and without personal opinion)were used for the separation of anomalous zones,which include two different methods of U-spatial statistics and mean plus values ...In this study,methods based on the distribution model(with and without personal opinion)were used for the separation of anomalous zones,which include two different methods of U-spatial statistics and mean plus values of standard deviation(X+nS).The primary purpose is to compare the results of these methods with each other.To increase the accuracy of comparison,regional geochemical data were used where occurrences and mineralization zones of epithermal gold have been introduced.The study area is part of the Hashtjin geological map,which is structurally part of the folded and thrust belt and part of the Alborz Tertiary magmatic complex.Samples were taken from secondary lithogeochemical environments.Au element data concerning epithermal gold reserves were used to investigate the efficacy of these two methods.In the U-spatial statistics method,and criteria were used to determine the threshold,and in the method,the element enrichment index of the region rock units was obtained with grouping these units.The anomalous areas were identified by,and criteria.Comparison of methods was made considering the position of discovered occurrences and the occurrences obtained from these methods,the flexibility of the methods in separating the anomalous zones,and the two-dimensional spatial correlation of the three elements As,Pb,and Ag with Au element.The ability of two methods to identify potential areas is acceptable.Among these methods,it seems the method with criteria has a high degree of flexibility in separating anomalous regions in the case of epithermal type gold deposits.展开更多
Lithology of Triassic in southwestern Sichuan is consistent with the whole basin,and there is no discussion about stratum division,the difference is stratum denudation which is made by the uplifting of Luzhou uplift,e...Lithology of Triassic in southwestern Sichuan is consistent with the whole basin,and there is no discussion about stratum division,the difference is stratum denudation which is made by the uplifting of Luzhou uplift,especially展开更多
Given the scientific progresses as well as the invention of new methods in exploration, it is necessary to conduct some re-investigations in several exploration zones. So, in the present research, geochemical data on ...Given the scientific progresses as well as the invention of new methods in exploration, it is necessary to conduct some re-investigations in several exploration zones. So, in the present research, geochemical data on Tanurjeh exploration zone, (located in Northern Neishaboor, Khorasane Razavi province) is studied by using some modern statistical methods. Fractal methods are appropriated to study and separate the grades societies in deposits. In this article, litho-geochemical analysis results (ICP) are processed by concentration area fractal method (CA). The distribution diagrams related to the statistical populations are drawn, and anomaly populations of Copper, Gold and Molybdenum are determined besides previous studies (petrography and alteration), the results of statistic methods (CA) and aid presence of the porphyry system in depth.展开更多
Geochemical subsoil data obtained from China and European laboratories have been compared in this study. 787 C horizon subsoil samples from FOREGS (Forum of European Geological Surveys) geochemical baselines mapping...Geochemical subsoil data obtained from China and European laboratories have been compared in this study. 787 C horizon subsoil samples from FOREGS (Forum of European Geological Surveys) geochemical baselines mapping project were sent to China's IGGE (Institute of Geophysical and Geochemical Exploration) laboratory and composited to 190 samples according to the 160 kin x 160 km GNT (Global Terrestrial Network) cells. In addition to the FOREGS elemental analysis package, Au, Pt, Pd, B, Ge, Br, CI, Se, N, Li and F were also analyzed by using the IGGE's 76 element analytical scheme. Geochemical data statistics, scatter plotting, and geochemical map compilation tech- niques have been employed to investigate differences between FOREGS and IGGE analytical results. The results of two datasets, the IGGE's analysis data for composited samples, and the FOREGS average data of samples in each GNT cell, agree extremely well lor about 23 elements, viz: SiO2, St, Al2O3, Zr, Ba, Fe2O3, Ti, Rb, Mn, Gd, CaO, Ga, MgO, P, Pb, Na2O, Y, Th, As, U Sc, Cr, and Co. There are slight differences between-laboratory biases shown as proportional errors between the datasets for Ni, K2O, Tb, Tl, Cu, S, Sin, La, Ce, Pr, Nd, Eu, Ho, Er, Tin, Yb, Lu, Ta, Nb, HE and Dy. For Cd, Cs, Be, Sb, In, Mo, I, Sn, and Te, the correlation of the two datasets and the similarity of the geochemical maps are fairly good, but obvious biases exist between the two datasets at values near detection limits.展开更多
Through a survey of the literature on geology, hydrogeology and hydrogeochemistry, this paper presents a hydrogeochemical model for the groundwater system in a dross-dumping area of the Shandong Aluminium Plant. It is...Through a survey of the literature on geology, hydrogeology and hydrogeochemistry, this paper presents a hydrogeochemical model for the groundwater system in a dross-dumping area of the Shandong Aluminium Plant. It is considered that the groundwater-bearing medium is a mineral aggregate and that the interactions between groundwater and the groundwater-bearing medium can be described as a series of geochemical reactions. On that basis, the principle of minimum energy and the equations of mass balance, electron balance and electric neutrality are applied to construct a linear programming mathematical model for the calculation of mass transfer between water and rock with the simplex method.展开更多
Conventional geochemical exploration for gold deposits has not always been very satisfactory, especially for buried and blind ones. New considerations and methodology in sampling, analysis and interpretation have been...Conventional geochemical exploration for gold deposits has not always been very satisfactory, especially for buried and blind ones. New considerations and methodology in sampling, analysis and interpretation have been developed in China during the past decade. Important considerations for unconventional gold exploration in this paper are that (1) gold is active in surface environments; (2) gold occurs not only as discrete grains, but also as ultrafine particles (submicron?to nanometer-sized particles of gold) and other complex forms; (3) regional low anomalies and superimposed anomalies over buried gold deposits are produced by ultrafine gold grains and other complex forms of gold. The methodology based on these considerations has been developed both in regional and in local geochemical exploration for gold. Examples of the preliminary application of these methods in two areas covered by transported overburden are given.展开更多
In order to obtain effective parameters for complex sand reservoirs,a log evaluation method for relevant reservoir parameters is established based on an analysis in the gas-bearing sandstone with high porosity and low...In order to obtain effective parameters for complex sand reservoirs,a log evaluation method for relevant reservoir parameters is established based on an analysis in the gas-bearing sandstone with high porosity and low permeability,low porosity and permeability and on various characteristics of log responses to reservoir lithologies and physical properties in the Neopleozoic sand reservoir of the Ordos basin.This log evaluation method covers the Cook method that is used to evaluate the porosity and oiliness in high porosity and low permeability reservoirs and another method in which the mineral content,derived from geochemical logs,is used to identify formation lithologies.Some areas have high calcium and low silt content,not uniformly distributed,the results of which show up in the complex formation lithologies and conventional log responses with great deviation.The reliability of the method is verified by comparison with conventional log data and core analyses.The calculation results coincide with the core analytical data and gas tests,which indicate that this log evaluation method is available,provides novel ideas for study of similar complex reservoir lithologies and has some reference value.展开更多
1.Objectives The laboratory of Xi’an Center,China Geological Survey has long been engaged in the testing of oil and gas geochemical samples.Among the different indexes,the measurement of the polycyclic aromatic hydro...1.Objectives The laboratory of Xi’an Center,China Geological Survey has long been engaged in the testing of oil and gas geochemical samples.Among the different indexes,the measurement of the polycyclic aromatic hydrocarbon needs to be completed by the fluorescence spectrophotometer which is made in PE Company.According to the standard method,the fluorescence intensity values of three emission wavelengths under a certain excitation wavelength should be provided.展开更多
文摘The greatest difficulties in recognizing geochemical hydrocarbon anomalies are: (1) how to objectively and accurately separate anomalies from background; (2) how to distinguish hydrocarbon pool related apical anomalies from lateral anomalies controlled by faults; and (3) how to eliminate interferences. These uncertainties are serious obstacles for the wide acceptance and use of geochemical techniques in hydrocarbon exploration. In this paper, the features of hydrocarbon anomalies were analyzed based on the micro migration mechanisms. In most cases, there are two anomalous populations or point groups, which are produced by two distinct mechanisms: (1) a population that directly reflects oil and gas fields, and (2) one that is related to structures such as faults. Statistical studies show that background anomalous populations and the boundaries between them can be described by the population means, prior probabilities, which are the proportions of population sizes, and covariance matrices, when background and anomalous populations have normal distributions. When this normality condition is met, a series of formulas can be derived. The method is designed on the basis of these allows: (1) univariate anomaly recognition, (2) elimination of interferences, (3) multivariate anomaly recognition, and (4) multivariate anomaly combination which depicts a more representative picture of morphology of the anomalous target than individual anomalies. The univariate and multivariate anomaly recognition can not only separate anomalies from background objectively, but also simultaneously distinguish the two types of anomalies objectively. This method was applied to the hydrocarbon data in Yangshuiwu region, Hebei Province. The interferences from regional variation of background were eliminated, and the interpretation uncertainty was reduced greatly as the anomalous populations were separated. The method was also used in Daxing region within the confines of Beijing City, and Aershan and Jiergalangtu regions in Inner Mongolia.
基金supported by the fund"Metallogenic Geodynamic Background,Process and Quantitative Evaluation of Super Large Fe-Cu Polymetallic Deposits,Qinghai Qimantag Area"(Grant No.1212011220929)from Beijing Key Laboratory of Land Resources Information Research and Development,China University of Geosciences,Beijing
文摘Fractal and multi-fractal content area method finds application in a wide variety of geological,geochemical and geophysical fields.In this study,the fractal content-gradient method was used on1:10,000 scale to delineate geochemical anomalies associated with copper mineralization.Analysis of geochemical data from the Yangla super large Cu-Pb-Zn polymetallic ore district using the fractal content-gradient method,combined with other geological data from this area,indicates that oreprospecting in the ore district should focus on Cu as the main metal and Pb-Zn and Au as the auxiliary metals.The types of deposits include(in chronological order) re-formed sedimentary exhalative(SEDEX),skarns,porphyries,and hydrothermal vein-type deposits.Three ore-prospecting targets are divided on a S-N basis:(1) the Qulong exploration area,in which the targets are porphyry-type Cu deposits;(2) the Zongya exploration area,where the targets are porphyry-type Cu and hydrothermal vein-type Cu-Pb polymetallic deposits;and(3) the Zarelongma exploration area,characterized mainly skarn-type "Yangla-style" massive sulfide Cu-Pb deposits.Our study demonstrates that the fractal content-gradient method is convenient,simple,rapid,and direct for delineating geochemical anomalies and for outlining potential exploration targets.
文摘Based on the results of researches and applications for many years, it has been discovered that new methods and techniques for geochemical exploration of oil and gas such as δC, altered carbonate, Hg in absorption phase, Ks, Fe2+, δ13C, fluorescence in two and three dimensions, and N2 and O2 in heat release can give full play in the following five fields: (1) optimization of the favourable target or hollow zones and structural zones in a region; (2) evaluation of oil traps and delineation of prospective oil and gas areas; (3) prediction of deep-seated oil-bearing horizons; (4) evaluation of the genesis of oil and gas geochemical anomalies and determination of the types of oil and gas accumulations; (5) forecast of the burial depths of oil and gas pools.
文摘In this study,methods based on the distribution model(with and without personal opinion)were used for the separation of anomalous zones,which include two different methods of U-spatial statistics and mean plus values of standard deviation(X+nS).The primary purpose is to compare the results of these methods with each other.To increase the accuracy of comparison,regional geochemical data were used where occurrences and mineralization zones of epithermal gold have been introduced.The study area is part of the Hashtjin geological map,which is structurally part of the folded and thrust belt and part of the Alborz Tertiary magmatic complex.Samples were taken from secondary lithogeochemical environments.Au element data concerning epithermal gold reserves were used to investigate the efficacy of these two methods.In the U-spatial statistics method,and criteria were used to determine the threshold,and in the method,the element enrichment index of the region rock units was obtained with grouping these units.The anomalous areas were identified by,and criteria.Comparison of methods was made considering the position of discovered occurrences and the occurrences obtained from these methods,the flexibility of the methods in separating the anomalous zones,and the two-dimensional spatial correlation of the three elements As,Pb,and Ag with Au element.The ability of two methods to identify potential areas is acceptable.Among these methods,it seems the method with criteria has a high degree of flexibility in separating anomalous regions in the case of epithermal type gold deposits.
文摘Lithology of Triassic in southwestern Sichuan is consistent with the whole basin,and there is no discussion about stratum division,the difference is stratum denudation which is made by the uplifting of Luzhou uplift,especially
文摘Given the scientific progresses as well as the invention of new methods in exploration, it is necessary to conduct some re-investigations in several exploration zones. So, in the present research, geochemical data on Tanurjeh exploration zone, (located in Northern Neishaboor, Khorasane Razavi province) is studied by using some modern statistical methods. Fractal methods are appropriated to study and separate the grades societies in deposits. In this article, litho-geochemical analysis results (ICP) are processed by concentration area fractal method (CA). The distribution diagrams related to the statistical populations are drawn, and anomaly populations of Copper, Gold and Molybdenum are determined besides previous studies (petrography and alteration), the results of statistic methods (CA) and aid presence of the porphyry system in depth.
基金given to the Ministry of Land and Resources and the Ministry of Science and Technology for the research funding of the projects: SinoProbe 04 and 863 Project 2007AA06Z133
文摘Geochemical subsoil data obtained from China and European laboratories have been compared in this study. 787 C horizon subsoil samples from FOREGS (Forum of European Geological Surveys) geochemical baselines mapping project were sent to China's IGGE (Institute of Geophysical and Geochemical Exploration) laboratory and composited to 190 samples according to the 160 kin x 160 km GNT (Global Terrestrial Network) cells. In addition to the FOREGS elemental analysis package, Au, Pt, Pd, B, Ge, Br, CI, Se, N, Li and F were also analyzed by using the IGGE's 76 element analytical scheme. Geochemical data statistics, scatter plotting, and geochemical map compilation tech- niques have been employed to investigate differences between FOREGS and IGGE analytical results. The results of two datasets, the IGGE's analysis data for composited samples, and the FOREGS average data of samples in each GNT cell, agree extremely well lor about 23 elements, viz: SiO2, St, Al2O3, Zr, Ba, Fe2O3, Ti, Rb, Mn, Gd, CaO, Ga, MgO, P, Pb, Na2O, Y, Th, As, U Sc, Cr, and Co. There are slight differences between-laboratory biases shown as proportional errors between the datasets for Ni, K2O, Tb, Tl, Cu, S, Sin, La, Ce, Pr, Nd, Eu, Ho, Er, Tin, Yb, Lu, Ta, Nb, HE and Dy. For Cd, Cs, Be, Sb, In, Mo, I, Sn, and Te, the correlation of the two datasets and the similarity of the geochemical maps are fairly good, but obvious biases exist between the two datasets at values near detection limits.
文摘Through a survey of the literature on geology, hydrogeology and hydrogeochemistry, this paper presents a hydrogeochemical model for the groundwater system in a dross-dumping area of the Shandong Aluminium Plant. It is considered that the groundwater-bearing medium is a mineral aggregate and that the interactions between groundwater and the groundwater-bearing medium can be described as a series of geochemical reactions. On that basis, the principle of minimum energy and the equations of mass balance, electron balance and electric neutrality are applied to construct a linear programming mathematical model for the calculation of mass transfer between water and rock with the simplex method.
基金This research represents a portion of the State Eighth Five-Year Plan Key ScienceTechnology Project "Unconventional Geochemical Exploration for Gold" supported by the State Science and Technology Commission of Chinathe National Gold Bureau of China
文摘Conventional geochemical exploration for gold deposits has not always been very satisfactory, especially for buried and blind ones. New considerations and methodology in sampling, analysis and interpretation have been developed in China during the past decade. Important considerations for unconventional gold exploration in this paper are that (1) gold is active in surface environments; (2) gold occurs not only as discrete grains, but also as ultrafine particles (submicron?to nanometer-sized particles of gold) and other complex forms; (3) regional low anomalies and superimposed anomalies over buried gold deposits are produced by ultrafine gold grains and other complex forms of gold. The methodology based on these considerations has been developed both in regional and in local geochemical exploration for gold. Examples of the preliminary application of these methods in two areas covered by transported overburden are given.
基金supported by the Program for New Century Excellent Talents in Universities
文摘In order to obtain effective parameters for complex sand reservoirs,a log evaluation method for relevant reservoir parameters is established based on an analysis in the gas-bearing sandstone with high porosity and low permeability,low porosity and permeability and on various characteristics of log responses to reservoir lithologies and physical properties in the Neopleozoic sand reservoir of the Ordos basin.This log evaluation method covers the Cook method that is used to evaluate the porosity and oiliness in high porosity and low permeability reservoirs and another method in which the mineral content,derived from geochemical logs,is used to identify formation lithologies.Some areas have high calcium and low silt content,not uniformly distributed,the results of which show up in the complex formation lithologies and conventional log responses with great deviation.The reliability of the method is verified by comparison with conventional log data and core analyses.The calculation results coincide with the core analytical data and gas tests,which indicate that this log evaluation method is available,provides novel ideas for study of similar complex reservoir lithologies and has some reference value.
基金This study was funded by the project“Research on general technical standards of land reclamation and ecological restoration,determination of petroleum in reclaimed land samples”(2017YFF0206804-24).
文摘1.Objectives The laboratory of Xi’an Center,China Geological Survey has long been engaged in the testing of oil and gas geochemical samples.Among the different indexes,the measurement of the polycyclic aromatic hydrocarbon needs to be completed by the fluorescence spectrophotometer which is made in PE Company.According to the standard method,the fluorescence intensity values of three emission wavelengths under a certain excitation wavelength should be provided.