On the degradation of granular materials due to internal erosion

A new state-based elasto-plastic constitutive relationship along with the discrete element model is established to estimate the degradation of granular materials due to internal erosion.Four essential effects of internal erosion such as the force network damage and relaxation are proposed and then incorporated into the constitutive relationship to formulate internal erosion impacts on the mechanical behavior of granular materials.Most manifestations in the degradation of granular materials,such as reduction of peak strength and dilatancy are predicted by the modified constitutive relationship in good agreement with the discrete element method（DEM）simulation.In particular,the sudden reduction of stress for conspicuous mass erosion in a high stress state is captured by force network damage and the relaxation mechanism.It is concluded that the new modified constitutive relationship is a potential theory to describe the degradation of granular materials due to internal erosion and would be very useful,for instance,in the prediction and assessment of piping disaster risk during the flood season.

Degradation of Soil Properties due to Erosion on Sloping Land in Southern Jiangsu Province,China

Soil erosion accelerates soil degradation. Some natural soils and cultivated soils on sloping land in southern Jiangsu Province, China were chosen to study soil degradation associated with erosion. Soil erosion intensity was investigated using the 137Cs tracer method. Soil particle-size distribution, soil organic matter (OM), total nitrogen (TN) and total phosphorus (TP) were measured, and the effects of erosion on soil physical and chemical properties were analyzed statistically using SYSTAT8.0. Results indicated that erosion intensity of cultivated soils was greater than that of the natural soils, suggesting that cultivation increased soil loss. Erosion also led to an increase of coarser soil particle proportion, especially in natural soils. In addition, silt was the primary soil particle lost due to erosion. However, in cultivated fields, coarser soil particles over time were attributed not only to soil erosion but also to mechanical eluviation as a result of farming activities. Moreover, erosion caused a decrease in soil OM, TN and TP as well as thinning of the soil layer.

Effects of Gully Erosion and Gully Filling on Soil Degradation in the Black Soil Region of Northeast China

Gully erosion has caused soil degradation and even reduced soil productivity. However, only few studies on the effects of gully erosion and artificial controlling measures on soil degradation in the Black Soil Region of Northeast China are available. Thus, this study explores the relationships between gully erosion, gully filling and soil parameters. Two sets of soil samples were collected in the field at： （1） 72 sample points in the gully erosion study area, 60 sample points in the ephemeral and classical gully erosion area （3,518 m2）, 12 sample points in the deposition zone （443 m2）, （2）1o reference points along a slope unaffected by gully erosion representing the original situation before the gully was formed. All soil samples were analyzed for gravel content （GC）, soil organic matter （SOM）, total nitrogen （TN）, available nitrogen （AN）, available phosphorus （AP）, and available potassium （AK）. The soil property values on unaffected slope were fitted by the polynomial curves as the reference values in no gully erosion area. The interpolated soil property values in gully eroded study area were compared with these polynomial curves, respectively, and then, changes of soil property values were analyzed. Gully erosion caused an increase in GC and a decrease in SOM, TN, AN, AP and AK. The change of GC, SOM, TN, AN, AP, AK was 8.8%, -9.04 g kg-1, -0.92 g kg-1, -62.28 mg kg-1, -29.61 mg kg% -79.68 mg kg-1. The soil property values in the study area were below optimal values. Thus, we concluded that gully erosion and gully filling caused both on-site and off-site soil degradation. Soil degradation area was 0.65 % of the cultivated land. In addition, it was proved that gully filling were an improper soil and water conservation measure, which seems to exacerbate the problem. Thus, it is suggested that soil where soil is deep is moved to fill the gully, and then the area around the filled gullies should be covered by grass for preventing the formation and development of the gully.

A drone‑and feld‑based investigation of the land degradation and soil erosion at an opencast coal mine dump after 5 years’evolution of natural processes

Opencast coal mining has a large impact on the land surface,both at the mining pits themselves and at waste sites.After artifcial management is stopped,a reclaimed opencast coal mine dump is afected by wind and water erosion from natural processes,resulting in land degradation and even safety incidents.In this paper,the soil erosion and land degradation after 5 years of such natural processes,at the Xilinhot opencast coal mine dump in Inner Mongolia,were investigated.A multisource data acquisition method was applied:the vegetation fraction coverage(VFC)was extracted from GF-1 satellite imagery,high-precision terrain characteristics and the location and degree of soil erosion were obtained using a drone,and the physical properties of the topsoil were obtained by feld sampling.On this basis,the degree and spatial distribution of erosion cracks were identifed,and the causes of soil erosion and land degradation were analyzed using the geographical detector.The results show that(1)multi-source data acquisition method can provide efective basic data for the quantitative evaluation of the ecological environment at dumps,and(2)slope aspect and VFC are the main factors afecting the degree of degradation and soil erosion.Based on above analysis,several countermeasures are proposed to mitigate land degradation:(1)The windward slope be designed to imitate the natural landform.(2)Reasonable engineering measures should be applied at the slope to restrain soil erosion.(3)The Pioneer plants should be widely planted on the platform at the early stage of reclamation.

A soil quality index for evaluation of degradation under land use and soil erosion categories in a small mountainous catchment, Iran

Soil erosion and land use type have long been viewed as being particularly important drivers of soil degradation.The objectives of this study,therefore,were to select a new soil quality index(SQI)which varies significantly with land use/soil erosion,and to evaluate the new SQI using expert opinion.In total,18 soil physical,chemical,and biochemical properties(indicators)were measured on 56 soil samples collected from four land use/soil erosion categories(rangeland/surface erosion,rangeland/subsurface erosion,cultivated land/surface erosion and dry-farming land/surface erosion).Principal component and classification analysis(PCCA)identified five PCs that explained 77.7%of the variation in soil properties with the biochemical PC varying significantly with land use/soil erosion.General discriminant analysis(GDA)selected urease and clay as the most sensitive properties distinguishing the land use/soil erosion categories.The GDA canonical scores for the new SQI were significantly correlated with expert opinion soil surface summed scores(for soil movement,surface litter,pedestalling,rills and flow pattern)derived using the U.S.Department of the Interior Bureau of Land Management(BLM)method.A forward stepwise general regression model revealed that the new SQI values were explained by soil movement,surface litter,and the summed values of the soil surface factors.Overall,this study confirmed that soil quality in the study area in Iran is controlled by land use and corresponding soil erosion.

Effects of Soil Compaction in the Fight against Unpaved Roads Degradation Due to Erosion Caused by Heavy Rain: Proposition of a Specific CBR Evaluation Model

Unpailt roads are generally subject to erosion, when they need to be bitumen, civil engineers need to know the geotechnical capabilities of the soil layers to be used as support, among these capabilities, for example, soil characteristics to withstand erosion. CBR has often been used to classify these soils according to their compaction. In this article, we propose a correlation between CBR and eroded soil mass through a simulator. Indeed, in this article we show that using a simulator, soils can be classified according to their ability to withstand water erosion, whether internal or external. Indeed it is shown that the mass of eroded soil is related to the compaction capacity of the soil just as the CBR also has. We study the effects and influence of soil compaction on the ability of an unpaved road to resist erosion caused by falling raindrops. To do this, lateritic soil is submitted to different compaction pressures. The compacted soil is then submitted to CBR test and rain fall through a mini rain simulator. Correlations between eroded soil masse and compaction pressure as well as CBR are derived. The study shows that the compaction reduces the erodibility and increases the bearing capacity of soil. The formula obtained is significant because we have a new way of evaluating soils in the laboratory.

Inhibition of protein degradation increases the Bt protein concentration in Bt cotton

Bacillus thuringiensis(Bt)cotton production is challenged by two main problems,i.e.,the low concentration of Bt protein at the boll setting stage and the lowest insect resistance in bolls among all the cotton plant’s organs.Therefore,increasing the Bt protein concentration at the boll stage,especially in bolls,has become the main goal for increasing insect resistance in cotton.In this study,two protein degradation inhibitors(ethylene diamine tetra acetic acid(EDTA)and leupeptin)were sprayed on the bolls,subtending leaves,and whole cotton plants at the peak flowering stage of two Bt cultivars(medium maturation Sikang 1(SK1))and early maturation Zhongmian 425(ZM425)in 2019 and 2020.The Bt protein content and protein degradation metabolism were assessed.The results showed that the Bt protein concentrations were enhanced by 21.3 to 38.8%and 25.0 to 38.6%in the treated bolls of SK1 and ZM425 respectively,while they were decreased in the subtending leaves of these treated bolls.In the treated leaves,the Bt protein concentrations increased by 7.6 to 23.5%and 11.2 to 14.9%in SK1 and ZM425,respectively.The combined application of EDTA and leupeptin to the whole cotton plant increased the Bt protein concentrations in both bolls and subtending leaves.The Bt protein concentrations in bolls were higher,increasing by 22.5 to 31.0%and 19.6 to 32.5%for SK1 and ZM425,respectively.The organs treated with EDTA or/and leupeptin showed reduced free amino acid contents,protease and peptidase activities and significant enhancements in soluble protein contents.These results indicated that inhibiting protein degradation could improve the protein content,thus increasing the Bt protein concentrations in the bolls or/and leaves of cotton plants.Therefore,the increase in the Bt protein concentration without yield reduction suggested that these two protein degradation inhibitors may be applicable for improving insect resistance in cotton production.

Estimation and mapping of water erosion and soil loss:Application of Gavrilovic erosion potential model(EPM)using GIS and remote sensing in the Assif el mal Watershed,Western high Atlas

Water erosion is a serious problem that leads to soil degradation,loss,and the destruction of structures.Assessing the risk of erosion and determining the affected areas has become crucial in order to understand the main factors influencing its evolution and to minimize its impacts.This study focuses on evaluating the risk of erosion in the Assif el mal watershed,which is located in the High Atlas Mountains.The Erosion Potential Model(EPM)is used to estimate soil losses depending on various parameters such as lithology,hydrology,topography,and morphometry.Geographic information systems and remote sensing techniques are employed to map areas with high erosive potential and their relationship with the distribution of factors involved.Different digital elevation models are also used in this study to highlight the impact of data quality on the accuracy of the results.The findings reveal that approximately 59%of the total area in the Assif el mal basin has low to very low potential for soil losses,while 22%is moderately affected and 19.9%is at high to very high risk.It is therefore crucial to implement soil conservation measures to mitigate and prevent erosion risks.

Review and prospect of soil compound erosion

Soil erosion is one of the most serious environmental issues constraining the sustainable development of human society and economies.Soil compound erosion is the result of the alternation or interaction between two or more erosion forces.In recent years,fluctuations and extreme changes in climatic factors(air temperature,precipitation,wind speed,etc.)have led to an increase in the intensity and extent of compound erosion,which is increasingly considered in soil erosion research.First,depending on the involvement of gravity,compound erosion process can be divided into compound erosion with and without gravity.We systematically summarized the research on the mechanisms and processes of alternating or interacting soil erosion forces(wind,water,and freeze-thaw)considering different combinations,combed the characteristics of compound erosion in three typical regions,namely,high-elevation areas,high-latitude areas,and dry and wet transition regions,and reviewed soil compound erosion research methods,such as station observations,simulation experiments,prediction models,and artificial neural networks.The soil erosion model of wind,water,and freeze-thaw interaction is the most significant method for quantifying and predicting compound erosion.Furthermore,it is proposed that there are several issues such as unclear internal mechanisms,lack of comprehensive prediction models,and insufficient scale conversion methods in soil compound erosion research.It is also suggested that future soil compound erosion mechanism research should prioritize the coupling of compound erosion forces and climate change.

Assessing Wind Erosion: A Review of Recent Measurement Techniques

Wind erosion represents a formidable environmental challenge and has serious negative impacts on soil health and agricultural productivity, particularly in arid and semi-arid areas. The complex dynamics of wind erosion make its large-scale monitoring and quantification a daunting task. To facilitate the monitoring and quantification of wind erosion, various scientific approaches and methods have been employed. These include sophisticated wind erosion equations and models, wind tunnel experiments, and the application of radionuclides. Additionally, researchers have assessed soil physicochemical properties, used anemometers for wind speed measurement, and deployed dust collectors for particle capture. Remote sensing technologies, wind erosion monitoring stations, and evaluations of wind barriers have also been utilized. Recently, the adoption of machine learning methods has gained popularity. Despite their value, each of these techniques has limitations in capturing the full spectrum of the wind erosion process. This paper examines these limitations and assesses the effectiveness of each method in the context of wind erosion studies. It also outlines directions for future research and suggests pathways that could enhance the understanding and management of wind erosion.

Degradation Rate Assessment of Biodegradable Magnesium Alloys

Biodegradable magnesium alloys have been widely used in medical implants. But safety concerns were put forward for the high degradation rate of biodegradable magnesium alloy. The optimal biodegradable magnesium alloys that give rise to the desired degradation rate hasn’t yet to be defined. Assessing the degradation rate of biodegradable magnesium alloys involves in vitro testing, in vivo testing, numerical modeling, understanding the factors influencing their degradation in physiological environments, biocompatibility testing, and clinical studies. It is important to standardize analytical tools aimed at assessing the degradation rate of biodegradable magnesium alloys. It is advisable to identify the threshold for safe degradation rate of biodegradable magnesium alloys in biomedical applications.

Analysis on Status and Development Trend of Wind Erosion in Black Earth Region of Northeast China

In this paper,areas and main factors of wind erosion in black earth region of Northeast China were systematically analyzed,as well as the development trend of wind erosion in black earth region of Northeast China.In addition,development trend of wind erosion in black earth region of Northeast China was analyzed from the aspects of the geographic position,climatic change law in recent 40 years and effects of northeast sand land desertification on wind erosion in black earth region,which had provided references for the research and prevention of wind erosion in soil of black earth region of Northeast China.

Assessment of soil erosion in the Irga watershed on the eastern edge of the Chota Nagpur Plateau,India

Human activities to improve the quality of life have accelerated the natural rate of soil erosion.In turn,these natural disasters have taken a great impact on humans.Human activities,particularly the conversion of vegetated land into agricultural land and built-up area,stand out as primary contributors to soil erosion.The present study investigated the risk of soil erosion in the Irga watershed located on the eastern fringe of the Chota Nagpur Plateau in Jharkhand,India,which is dominated by sandy loam and sandy clay loam soil with low soil organic carbon(SOC)content.The study used the Revised Universal Soil Loss Equation(RUSLE)and Geographical Information System(GIS)technique to determine the rate of soil erosion.The five parameters(rainfall-runoff erosivity(R)factor,soil erodibility(K)factor,slope length and steepness(LS)factor,cover-management(C)factor,and support practice(P)factor)of the RUSLE were applied to present a more accurate distribution characteristic of soil erosion in the Irga watershed.The result shows that the R factor is positively correlated with rainfall and follows the same distribution pattern as the rainfall.The K factor values in the northern part of the study area are relatively low,while they are relatively high in the southern part.The mean value of the LS factor is 2.74,which is low due to the flat terrain of the Irga watershed.There is a negative linear correlation between Normalized Difference Vegetation Index(NDVI)and the C factor,and the high values of the C factor are observed in places with low NDVI.The mean value of the P factor is 0.210,with a range from 0.000 to 1.000.After calculating all parameters,we obtained the average soil erosion rate of 1.43 t/(hm^(2)•a),with the highest rate reaching as high as 32.71 t/(hm^(2)•a).Therefore,the study area faces a low risk of soil erosion.However,preventative measures are essential to avoid future damage to productive and constructive activities caused by soil erosion.This study also identifies the spatial distribution of soil erosion rate,which will help policy-makers to implement targeted soil erosion control measures.

Numerical simulation on sand sedimentation and erosion characteristics around HDPE sheet sand barrier under different wind angles

For the safety of railroad operations,sand barriers are utilized to mitigate wind-sand disaster effects.These disasters,characterized by multi-directional wind patterns,result in diverse angles among the barriers.In this study,using numerical simulations,we examined the behavior of High Density Polyethylene(HDPE)sheet sand barriers under different wind angles,focusing on flow field distribution,windproof efficiency,and sedimentation erosion dynamics.This study discovered that at a steady wind speed,airflow velocity varies as the angle between the airflow and the HDPE barrier changes.Specifically,a 90°angle results in the widest low-speed airflow area on the barrier’s downwind side.If the airflow is not perpendicular to the barrier,it prompts a lateral airflow movement which decreases as the angle expands.The windproof efficiency correlates directly with this angle but inversely with the wind’s speed.Notably,with a wind angle of 90°,wind speed drops by 81%.The minimum wind speed is found at 5.1H(the sand barrier height)on the barrier’s downwind side.As the angle grows,the barrier’s windproof efficiency improves,extending its protective reach.Sedimentation is most prominent on the barrier’s downwind side,as the wind angle shifts from 30°to 90°,the sand sedimentation area on the barrier’s downwind side enlarges by 14.8H.As the angle grows,sedimentation intensifies,eventually overtakes the forward erosion and enlarges the sedimentation area.

Achieving high-efficient photocatalytic persulfate-activated degradation of tetracycline via carbon dots modified MIL-101(Fe)octahedrons

The synergistic reaction of photocatalysis and advanced oxidation is a valid strategy for the degradation of harmful antibiotic wastewater.Herein,carbon dots(CDs)modified MIL-101(Fe)octahedrons to form CDs/MIL-101(Fe)composite photocatalyst was synthesized for visible light-driven photocatalytic/persulfate(PS)-activated tetracycline(TC)degradation.The electron spin resonance(ESR)spectra,scavenging experiment and electrochemical analysis were carried out to reveal that the high visible light-driven photocatalytic degradation activity of TC over CDs/MIL-101(Fe)photocatalysts is not only ascribed to the production of free active radicals in the CDs/MIL-101(Fe)/PS system(·OH,·SO_(4-),^(1)O_(2),h^(+)and·O_(2)^(-))but also attributed to the consumption of electrons caused by the PS,which can suppress the recombination of photo-generated carriers as well as strong light scattering and electron trapping effects of CDs.Finally,the possible degradation pathways were proposed by analyzing intermediates via liquid chromatography-mass spectrometry technique.This research presents a rational design conception to construct a CDs/PS-based photocatalysis/advanced oxidation technology with high-efficient degradation activity for the remediation of organic antibiotic pollutant wastewater and for the improvement of carrier transport kinetics of photocatalysts.

Carbon-doped CuFe_(2)O_(4) with C-O-M channels for enhanced Fenton-like degradation of tetracycline hydrochloride: From construction to mechanism

Carbon-doped copper ferrite(C–CuFe_(2)O_(4))was synthesized by a simple two-step hydrothermal method,which showed enhanced tetracycline hydrochloride(TCH)removal efficiency as compared to the pure CuFe_(2)O_(4) in Fenton-like reaction.A removal efficiency of 94%was achieved with 0.2 g L^(-1) catalyst and 20 mmol L^(-1) H_(2)O_(2) within 90 min.We demonstrated that 5%C–CuFe_(2)O_(4) catalyst in the presence of H_(2)O_(2) was significantly efficient for TCH degradation under the near-neutral pH(5–9)without buffer.Multiple techniques,including SEM,TEM,XRD,FTIR,Raman,XPS M€ossbauer and so on,were conducted to investigate the structures,morphologies and electronic properties of as-prepared samples.The introduction of carbon can effectively accelerate electron transfer by cooperating with Cu and Fe to activate H_(2)O_(2) to generate·OH and·O_(2)^(-).Particularly,theoretical calculations display that the p,p,d orbital hybridization of C,O,Cu and Fe can form C–O–Cu and C–O–Fe bonds,and the electrons on carbon can transfer to metal Cu and Fe along the C–O–Fe and C–O–Cu channels,thus forming electron-rich reactive centers around Fe and Cu.This work provides lightful reference for the modification of spinel ferrites in Fenton-like application.

Research on Leading Edge Erosion and Aerodynamic Characteristics of Wind Turbine Blade Airfoil

The effects of the erosion present on the leading edge of a wind turbine airfoil(DU 96-W-180)on its aerodynamic performances have been investigated numerically in the framework of a SST k–ωturbulence model based on the Reynolds Averaged Navier-Stokes equations(RANS).The results indicate that when sand-induced holes and small pits are involved as leading edge wear features,they have a minimal influence on the lift and drag coefficients of the airfoil.However,if delamination occurs in the same airfoil region,it significantly impacts the lift and resistance characteristics of the airfoil.Specifically,as the angle of attack grows,there is a significant decrease in the lift coefficient accompanied by a sharp increase in the drag coefficient.As wear intensifies,these effects gradually increase.Moreover,the leading edge wear can exacerbate flow separation near the trailing edge suction surface of the airfoil and cause forward displacement of the separation point.

Microbial Degradation of Organic Contaminants in Streambed/Floodplain Sediments in Passaic River—New Jersey Area

This paper is intended to explore soil organic matter and carbon isotope fractionation at three locations of the Passaic River to determine if microbial degradation of organic contaminants in soil is correlated to the surrounding physical environment. Microbial degradation of organic contaminants is important for the detoxification of toxic substances thereby minimizing stagnation in the environment and accumulating in the food chain. Since organic contaminants are not easily dissolved in water, they will penetrate sediment and end up enriching the adjacent soil. The hypothesis that we are testing is microbial activity and carbon isotope fractionation will be greater in preserved soils than urban soils. The reason why this is expected to be the case is the expectation of higher microbial activity in preserved environments due to less exposure to pollutants, better soil structure, higher organic matter content, and more favorable conditions for microbial growth. This is contrasted with urban soils, which are impacted by pollutants and disturbances, potentially inhibiting microbial activity. We wish to collect soil samples adjacent to the Passaic River at a pristine location, Great Swamp Wildlife Refuge, a suburban location, Goffle Brook Park, Hawthorne NJ, and an urban location, Paterson NJ. These soil samples will be weighed for soil organic matter (SOM) and weighed for isotope ratio mass spectrometry (IRMS) to test organic carbon isotopes. High SOM and δ13C depletion activity indicate microbial growth based on the characteristics of the soil horizon rather than the location of the soil sample which results in degradation of organic compounds.

Photocatalytic Degradation of Plastic Waste: Recent Progress and Future Perspectives

Microplastics are persistent anthropogenic pollutants that have become a global concern due to their widespread distribution and unfamiliar threat to the environment and living organisms. Conventional technologies are unable to fully decompose and mineralize plastic waste. Therefore, there is a need to develop an environmentally friendly, innovative and sustainable photocatalytic process that can destroy these wastes with much less energy and chemical consumption. In photocatalysis, various nanomaterials based on wide energy band gap semiconductors such as TiO2 and ZnO are used for the conversion of plastic contaminants into environmentally friendly compounds. In this work, the removal of plastic fragments by photocatalytic reactions using newly developed photocatalytic composites and the mechanism of photocatalytic degradation of microplastics are systematically investigated. In these degradation processes, sunlight or an artificial light source is used to activate the photocatalyst in the presence of oxygen.

Biodegradation of Crystalline Chitin:A Review of Recent Advancement,Challenges,and Future Study Directions

Chitin is the second most abundant renewable polysaccharide on Earth.The degradation of chitin into soluble and bioactive N-acetyl chitooligosaccharides(NCOSs)and N-acetyl-D-glucosamine(GlcNAc)has emerged as a pivotal step in the efficient and sustainable utilization of chitin resources.However,because of its dense structure,high crystallinity,and poor solubility,chitin typically needs pretreatment via chemical,physical,and other methods before enzymatic conversion to enhance the accessibility between substrates and enzyme molecules.Consequently,there has been considerable interest in exploring the direct biological degradation of crystalline chitin as a cost-effective and environment-friendly technology.This review endeavors to present several biological methods for the direct degradation of chitin.We primarily focused on the importance of chitinase containing chitin-binding domain(CBD).Additionally,various modification strategies for increasing the degradation efficiency of crystalline chitin were introduced.Subsequently,the review systematically elucidated critical components of multi-enzyme catalytic systems,highlighting their potential for chitin degradation.Furthermore,the application of microorganisms in the degradation of crystalline chitin was also discussed.The insights in this review contribute to the explorations and investigations of enzymatic and microbial approaches for the direct degradation of crystalline chitin,thereby fostering advancements in biomass conversion.