An Al-5.3%Zn-5.3%Mg alloy was unidirectionally solidified to determine morphological transition and solute distribution by a modification of the Bridgman technique for crystal growth with growth rates ranging from 4-5...An Al-5.3%Zn-5.3%Mg alloy was unidirectionally solidified to determine morphological transition and solute distribution by a modification of the Bridgman technique for crystal growth with growth rates ranging from 4-500 μm/s and a temperature gradient of 25 K/cm. It was determined that growth rates from 6.5-9.5 μm/s generated a cell morphology, where the lower limit corresponds to the plane front to cellular transition and the upper limit indicates the cellular to columnar dendrite transition. The microstructures of the alloys solidified from 30 μm/s to growth rates less than 500 μm/s were mainly composed of columnar dendrites, while the microstructures solidified at growth rates greater than 500 μm/s were equiaxed. Regarding experimental results on solute distribution, a prediction of the model developed by Rappaz and Boettinger for dendrite solidification of multicomponent alloys was applied with excellent agreement. Results of solute distribution were employed to derive the precipitation fraction of τ-phase needed to increase the electrochemical properties of the alloy to be used as an Al-sacrificial anode.展开更多
The quantitative phase-field simulations were reviewed on the processes of solidification of pure metals and alloys.The quantitative phase-field equations were treated in a diffuse thin-interface limit,which enabled t...The quantitative phase-field simulations were reviewed on the processes of solidification of pure metals and alloys.The quantitative phase-field equations were treated in a diffuse thin-interface limit,which enabled the quantitative links between interface dynamics and model parameters in the quasi-equilibrium simulations.As a result,the quantitative modeling is more effective in dealing with microstructural pattern formation in the large scale simulations without any spurious kinetic effects.The development of the quantitative phase-field models in modeling the formation of microstructures such as dendritic structures,eutectic lamellas,seaweed morphologies,and grain boundaries in different solidified conditions was also reviewed with the purpose of guiding to find the new prospect of applications in the quantitative phase-field simulations.展开更多
基金the financial support from Consejo Nacional de Ciencia y Tecnología (CONACYT) Project N° 129780PAPIIT-UNAM project N° IN213912-3
文摘An Al-5.3%Zn-5.3%Mg alloy was unidirectionally solidified to determine morphological transition and solute distribution by a modification of the Bridgman technique for crystal growth with growth rates ranging from 4-500 μm/s and a temperature gradient of 25 K/cm. It was determined that growth rates from 6.5-9.5 μm/s generated a cell morphology, where the lower limit corresponds to the plane front to cellular transition and the upper limit indicates the cellular to columnar dendrite transition. The microstructures of the alloys solidified from 30 μm/s to growth rates less than 500 μm/s were mainly composed of columnar dendrites, while the microstructures solidified at growth rates greater than 500 μm/s were equiaxed. Regarding experimental results on solute distribution, a prediction of the model developed by Rappaz and Boettinger for dendrite solidification of multicomponent alloys was applied with excellent agreement. Results of solute distribution were employed to derive the precipitation fraction of τ-phase needed to increase the electrochemical properties of the alloy to be used as an Al-sacrificial anode.
基金supported by National Natural Science Foundation of China(No.51174177)the Fund of the State Key Solidification Laboratory of Solidification Processing in Northwestern Polytechnical University(No.SKLSP 201714)
文摘The quantitative phase-field simulations were reviewed on the processes of solidification of pure metals and alloys.The quantitative phase-field equations were treated in a diffuse thin-interface limit,which enabled the quantitative links between interface dynamics and model parameters in the quasi-equilibrium simulations.As a result,the quantitative modeling is more effective in dealing with microstructural pattern formation in the large scale simulations without any spurious kinetic effects.The development of the quantitative phase-field models in modeling the formation of microstructures such as dendritic structures,eutectic lamellas,seaweed morphologies,and grain boundaries in different solidified conditions was also reviewed with the purpose of guiding to find the new prospect of applications in the quantitative phase-field simulations.
