Application of high-frequency magnetotelluric method in porphyry copper deposit exploration：a case study of Duobaoshan deposit area

The Duobaoshan mine area in Heilongjiang is located in the northeast section of Xingmeng orogenic belt and is in the west side of Hegang Mountain-Heihe fault zone. There exist many deposits in this area,and its metallogenic conditions are superior,which has been one of the hotspots in geological prospecting and metallogenic research in Northeast China. On the basis of previous studies,the authors used the EH-4 electromagnetic imaging system to carry out the data acquisition of three survey lines in Woduhe Village,Duobaoshan Town,Nenjiang County. Through the analysis of apparent resistivity section under TE and TM polarization modes,integrating regional geological data,it is concluded that:(1) the electrical characteristics of the metal ore in this area show a relatively low resistance,and according to its resistivity difference with surrounding rocks,the geometrical structures and apparent resistivity parameters of the low resistivity bodies in the lower section of the survey line are defined,and the electrical anomalies can be identified;(2)faults F1 and F2 may have a good metallogenic environment,so they are recommended for further exploration;(3) low resistance metal ore bodies have good correlation with local small structures or faults,which may play an iconic role for the delineation of key target areas;(4) in the process of using apparent resistivity to define the geometric structures of ore bodies underground,comprehensive analysis integrating the advantages of TE and TM models should be carry out to achieve more reliable inversion results.

Rb-Sr and Sm-Nd Isochron Ages of the Dongmozhazhua and Mohailaheng Pb-Zn Ore Deposits in the Yushu area, southern Qinghai and Their Geological Implications

Located on the northeast margin of the Qiangtang terrane between the Jinshajiang suture zone and Bangonghu-Nujiang suture zone,the Dongmozhazhua and Mohailaheng Pb-Zn deposits in the Yushu area of Qinghai Province are representative Pb-Zn deposits of the Pb-Zn-Cu polymetallic mineralization belt in the northern part of the Nujiang-Lancangjiang-Jinshajiang area,which are in the front belt of the Yushu thrust nappe system.The formed environments of these two deposits are different from those of sediment-hosted base metal deposits elsewhere in the world.The authors hold that they were formed during the Indian-Asian continental collision and developed within the fold-thrust belt combined with thrust and strike-slip-related Cenozoic basins in the interior of the collisional zone.Studying on the metallogenic epochs of these two deposits is helpful to the understanding of ore-forming regularity of the regional Pb-Zn-Cu mineralization belt and also to the search for new deposits in this region.The age of the Dongmozhazhua deposit has been determined by the Rb-Sr isochron method for sphalerite residues,whereas the age of the Mohailaheng deposit has been determined by the Rb-Sr isochron method for sphalerite residues and the Sm-Nd isochron method for fluorite.The age of the Dongmozhazhua deposit is 35.0-±0.0 Ma （（87Sr/86Sr）0=0.708807） for sphalerite residues.The age of the Mohailaheng deposit is 32.2±0.4 Ma （（87Sr/86Sr）o=0.708514） for sphalerite residues and 31.8±0.3 Ma （（143Nd/144Nd）o=0.512362） for fluorite with an average of 32.0 Ma.Together with the regional geological setting during mineralization,a possible tectonic model for metallogeny of the Dongmozhazhua and Mohailaheng Pb-Zn deposits has been established.These two ages are close to the ages of the Pb-Zn deposits in the Lanping and Tuotuohe basins,indicating that it is possible that the narrow 1000-kilometer-long belt controlled by a thrust nappe system on the eastern and northern margins of the Tibetan plateau could be a giant Pb-Zn mineralized belt.

Fluid Inclusions of Orogenic Gold Deposits in the Zhongchuan Area,Western Qinling and Their Geological Significance

Orogenically-derived gold deposits of the Zhongchuan area in the western Qinling are distributed in the exo-contact thermal metamorphic zone. The country rocks hosting the deposits are predominantly of Devonian age with low-grade metamorphism and strong deformation with the ore deposits directly controlled by multi-level tectonic systems. Three types of inclusions from these deposits have been recognized: CO2-H2O, CO2-rich, and aqueous. The ore-forming fluids were mainly CO2-NaCl-H2O type characterized by rich CO2, low salinity, high temperature and immiscibility. Incorporated with earlier isotopic data, the regional geological setting and features of diagenesis and metallogeny, it can be concluded that the ore-forming fluids were derived from deep magma and mixed with meteoric and metamorphic water. The deposits formed during an intra-continent collisional orogeny, and some of the materials derived from the deep might have been involved in the ore-forming process.

Ar-Ar Dating on the Metallogenesis of the Dongchuang Gold Deposit in the Xiaoqinling Area

The Dongchuang gold deposit in the Xiaoqinling area is an orogenic-type lodegold deposit. It is one of the few superlarge (>100 t Au) deposits in China. Although it has beenargued that it was formed in the Mesozoic, related isotopic age data have not been reported inprevious studies. Based on detailed geological study, the authors have carried out isotopic datingon various metallogenic generations. The ore-forming process of the Dongchuang gold deposit consistsof four stages: coarse-grained pyrite-bearing quartz veins (stage I), fine-grained pyrite-quartzveinlets (stage II), multi-sulfides (stage III) and carbonate-quartz veinlets (stage IV). Ar-Ardating on mineral separates of stages I, II and III yields plateau ages of 142.9 +- 2.9 Ma, 132.2 +-2.6 Ma and 128.3 +- 6.2 Ma, respectively. Sericite separates from stage II assemblage also yield anAr-Ar isochron age of 132.6 +- 2.7 Ma, similar to the Ar-Ar plateau age. These results suggest thatthe Dongchuang gold deposit was mainly formed during 143-128 Ma, coinciding with the authors'geological observations and previous hypothesis. This ore formation is coeval with theregional-tectonic transition from collisional compression to extension, strongly showing that thedecompression-geothermal increase regime during compression-to-extension transition is the mostconducive geodynamic environment to orogenic-type gold mineralization.

Lead Isotope Studies of Massive Surphur-Iron-Gold Deposits in the Tongling Area, Anhui Province

Pb isotope ratios and their variation have been measured and explained on ores of massive S-Fe-Au depos-its hosted in the Middle-Upper Carboniferous, on feldspars from diorite bodies closely related tomineralization and on whole rocks from ore-hosting strata (carbonate rocks) in the Tongling area, Anhui Prov-ince. Through a comparison of Pb isotope features of these geological bodies, it has been suggested that oresubstances of the deposits were derived from ore-hosting strata. In the meanwhile, the measurement of ore Pbisotopes of different mineralization types of the same deposit indicates that different mineralization types havedistinct Pb isotope characteristics, showing the potentiality of the Pb isotopic method used in mineral explora-tion.

Ore-forming Fluid and Mineral Source of the Hongshi Copper Deposit in the Kalatage Area, East Tianshan, Xinjiang, NW China

The Hongshi copper deposit is located in the middle of the Kalatage ore district in the northern segment of the Dananhu-Tousuquan island-arc belt in East Tianshan, Xinjiang, NW China. This study analyses the fluid inclusions and H, O, and S stable isotopic compositions of the deposit. The fluid-inclusion data indicate that aqueous fluid inclusions were trapped in chalcopyrite-bearing quartz veins in the gangue minerals. The homogenization temperatures range from 108°C to 299°C, and the salinities range from 0.5% to 11.8%, indicating medium to low temperatures and salinities. The trapping pressures range from 34.5 MPa to 56.8 MPa. The δ^（18）O_（H_2O） values and δD values of the fluid range from -6.94‰ to -5.33‰ and from -95.31‰ to -48.20‰, respectively. The H and O isotopic data indicate that the ore-forming fluid derived from a mix of magmatic water and meteoric water and that meteoric water played a significant role. The S isotopic composition of pyrite ranges from 1.9‰ to 5.2‰, with an average value of 3.1‰, and the S isotopic composition of chalcopyrite ranges from -0.9‰ to 4‰, with an average value of 1.36‰, implying that the S in the ore-forming materials was derived from the mantle. The introduction of meteoric water decreased the temperature, volatile content, and pressure, resulting in immiscibility. These factors may have been the major causes of the mineralization of the Hongshi copper deposit. Based on all the geologic and fluid characteristics, we conclude that the Hongshi copper deposit is an epithermal deposit.

Origin of Ore-Forming Fluids of Mississippi Valley-Type (MVT) Pb-Zn Deposits in Kangdian Area, China

Analyses of fluid\|inclusion leachates from ore deposits show that Na/Br ratios are within the range of 75-358 and Cl/Br 67-394, respectively, and this variation trend coincides with the seawater evaporation trajectory on the basis of the Na/Br and Cl/Br ratios. The average Cl/Br and Na/Br ratios of mineralizing fluids are 185 and 173 respectively, which are very close to the ratios (120 and 233) of the residual evaporated seawater past the point of halite precipitation. It is suggested that the original mineralizing brine was derived from highly evaporated seawater with a high salinity. However, the inclusion fluids have absolute Na values of \{69.9\}-\{2606.2\} mmol kg\+\{-1\} and Cl values of \{106.7\}-\{1995.5\} mmol kg\+\{-1\}. Most of the values are much less than those of seawater: Na, 485 mmol kg\+\{-1\} and Cl, 566 mmol kg\+\{-1\}, respectively; the salinity measured from fluid inclusions of the deposits ranges from \{2.47 wt%\} to \{15.78 wt%\} NaCl equiv. The mineralizing brine has been diluted. The \{δ\{\}\+\{18\}O\} and δD values of ore\|forming fluids vary from \{-8.21‰\} to \{9.51‰\} and from \{-40.3‰\} to \{-94.3‰\}, respectively. The δD values of meteoric water in this region varied from \{-80‰\} to \{-100‰\} during the Jurassic. This evidenced that the ore\|forming fluids are the mixture of seawater and meteoric water. Highly evaporated seawater was responsible for leaching and extracting Pb, Zn and Fe, and mixed with and diluted by descending meteoric water, which resulted in the formation of ores.

Discovery of the World's Second Largest Molybdenum Deposit in the Shapinggou Area,Jinzhai County,Anhui Province

In the year of 2011, a superlarge molybdenum deposit was discovered in the Shapinggou area, Jinzhai county, Anhui Province by the Bureau of Geology and Mineral Exploration of Anhui Province, with its reserve more than 2.2 million ton, just next to the Klimax molybdenum deposit （〉3.3 million ton） in Colorado. It has ranged the world＇s second largest molybdenum deposit, with potential economic value up to 100 billion dollars.

Magmatic Evolution and Mineralization of Porphyry Copper-Gold Deposits in the Duolong Ore Concentration Area, Tibet

The Bangong Lake-Nujiang River metallogenic belt is located between the Qiangtang Block and Lhasa Block, and the Duolong ore concentration area is located in the western section of the Bangong Lake-Nujiang River metallogenic belt. Till now, several large and super large copper-gold deposits, such as Duobuza, Bolong, Dibaonamugang, Naruo and Rongna deposits have been discovered in this area, mainly porphyry copper-gold ones.

Kaolin Deposits of Weathering-Residual in the Coastal Area of Guangdong Province

Kaolin deposits of weathering-residual type make up a large proportion in different types of kaolin depos-its and are widely used in ceramics, electron ceramics, rubber and paper industries. This paper discusses sys-tematically this type of kaolin deposit with respect to their features of occurrence, mineralogical and chemicalcomposition and transformation of minerals during supergene processes, thus providing some basic data forthe rational exploitation and utilization of the kaolin resources.

Discovery of Lorandite TlAsS_2 at the Distal Au-Tl Deposit in a Skarn system,Fengshan Area,Middle-Lower Yangtze River,Eastern China

Thallium has been used geochemical exploration of gold deposits. However, as an indicator element in searching for hydrothermal the T1 minerals and mineralization are rare in nature. Lorandite T1AsS2, a relatively uncommon mineral, has been dominantly discovered in some Carlin gold deposits, and minor Sb- Hg, U and Pb-Zn-Ag deposits.

Sediment-hosted Pb-Zn Deposits in Southwest Sanjiang Tethys and Kangdian Area on the Western Margin of Yangtze Craton

The western margin of Yangtze Craton is known as a significant sediment-hosted base-metal aggregate cluster,especially for Pb-Zn deposits in China,e.g.Jinding,Daliangzi,Tianbaoshan, Kuangshanchang and Qinlinchang deposits.In comparison with the classic MVT deposits in the world, based on the basic geology of the sediment-hosted Pb-Zn deposits,this paper focuses on temporal-spatial distribution of this deposit to further discuss its large scale mineralization and tectonic evolution history.In the SW Sanjiang Thethys,Jinding deposit is typically thrust fault-controlled and hosted mainly in the sandstones and breccia-bearing sandstones,whereas MVT-type deposits are controlled by lithology and faulting/fracturing with a strong preference for carbonate-hosted rocks.Most importantly,Jinding Pb-Zn deposit differs from the other types of sediment-hosted Pb-Zn deposits in which it was formed in a strongly deformed foreland basin within a continental collision zone.In the Kangdian area,the sediment-hosted Pb-Zn deposits were formed in the extensional basin on the side of the continental orogenic belt along the Yangtze Craton.Compared with classic MVT deposits,the Pb-Zn deposits in the Kangdian area belong to MVT deposits.This paper is significant not only for interpretation of the genesis of sediment-hosted Pb-Zn deposits but also for exploiting large base metal deposits in large sedimentary target areas.

The Palaeomagnetic Study of the MineralizationAge of Gold Deposits in the Xiong' ershan Area,Henan Province

Based on palaeomagnetic studies of the Precambrian gold deposits in the Xiong'ershan area, Henan Province, the authors infer that the ore-forming processes of the Beiling alteration-type gold ore deposit and the Dianfang breccia-type gold ore deposit started in the Proterozoic, and was superimposed by later mineralization, whereas the mineralization age of the Jiguanshan quartz- vein type gold ore deposit is Yanshanian.

World's Third-Largest Molybdenum Deposit Discovered in Caosiyao Area, Xinghe County, Inner Mongolia

On l lth September 2013, the Inner Mongolia Mineral Resources and Reserves Evaluation Center estimated that the world＇s third-largest molybdenum deposit had been found in the Caosiyao area of Xinghe County, Inner Mongolia, NE China. The find has 130235.60×10^4 t of （122b）＋（333） molybdenum ores, a metal amount of 1327649.27 t, with Mo grade of 0.102-a super-large one.

New Insights into the Depositional Environments of Ordovician Carbonate Formations in the Yubei Area of Tarim Basin Based on Standard Microfacies Types

Objective The Yubei area is located in the mid-east Maigaiti slope of southwestern Tarim Basin, China, with an exploration history of several years. Recent exploration has preliminarily indicated that the Ordovician carbonate formations in this area have some oil and gas potential. Carbonate microfacies provides material basis for reservoir development, seal formation and hydrocarbon generation. Therefore, this work utilized the standard microfacies （SMF） types to study the microfacies of the Ordovician formations in the Yubei area in order to provide theoretical basis for the next exploration.

Metallogenic Age of Dapinggou Gold Deposit in Northern Altun Area, Northwestern China

Studying the metallogenic age of Dapinggou gold deposit may provide important material not only for the study of metallization and the further prospecting of gold deposits but also for research into tectonic evolution in the Altun area. In this study, we used Rb-Sr isotopic dating method of fluid inclusion in the Au-bearing quartz, combining field investigation, REE, sulfur isotopes, lead isotopes, strontium isotopes and hydrogen-oxygen isotope, to determine the metallogenic age of the Dapinggou gold deposit. The only newly-discovered medium-sized gold deposit in the northern Altun area, Dapinggou gold deposit, is controlled by a ductile shear zone. It is characterized by mainly altered mylonite-types with a little K-feldspar quartz vein-types. Data from REE, sulfur isotopes, lead isotopes and strontium isotopes show that the source materials of the deposit were derived mainly from the metamorphic rocks. The data from the inclusion and hydrogen-oxygen isotope indicate that the ore-forming fluid came mainly from dynamic metamorphic water and partly from remelting magmatic water, with a little influence from meteoric water. The density of the ore-forming fluid is 0. 791 - 0. 971g/cm^3 and it contains 2.36 %-5.5 % salinity, The gold deposit was formed at 1.61-2.68 km below the surface at a temperature of 198--290 ℃ and a pressure of （420-700） × 10^5 Pa. The isotopic age from the Rb-Sr isochron of fluid inclusion in quartz is 487 Ma, which indicates that the mineralization occurred in the early Caledonian epoch. The study on the metallogenic age of Dapinggou gold deposit may provide important material not only for the study of metallization and the further prospecting of gold deposits but also for research into tectonic evolution in the Altun area.

Effects of specific surface area of metallic nickel particles on carbon deposition kinetics

Carbon deposition on nickel powders in methane involves three stages in different reaction temperature ranges. Temperature programing oxidation test and Raman spectrum results indicated the formation of complex and ordered carbon structures at high deposition temperatures. The values of I（D）/I（G） of the deposited carbon reached 1.86, 1.30, and 1.22 in the first, second, and third stages, respectively. The structure of carbon in the second stage was similar to that in the third stage. Carbon deposited in the first stage rarely contained homogeneous pyrolytic deposit layers. A kinetic model was developed to analyze the carbon deposition behavior in the first stage. The rate-determining step of the first stage is supposed to be interfacial reaction. Based on the investigation of carbon deposition kinetics on nickel powders from different resources, carbon deposition rate is suggested to have a linear relation with the square of specific surface area of nickel particles.

Geological Characteristics of Epithermal Ore Concentrated Areas and Epithermal Ore Deposits in China

The epithermal ore concentrated area is located in Southwestern China. We systematically study the regional geological characteristics such as the basement of Proterozoic, the capping bed, Moho, geothermal feature and tectonics, and discuss the relationship between distributed characteristics of the epithermal ore deposits and ore control factors in this paper. It is concluded that the conditions, under which the epithermal ore deposits form, are huge thick basement of Proterozoic, long time and wide scope developed capping bed and weak magmatic activity. The basement of Proterozoic that enriches volcanic matters and carbon and the carbonaceous bearing and paleo pool bearing capping bed provides main ore source. The large and deep faults and paleopool accordance with gravity anomaly gradient control the distribution of epithermal ore deposits. The lithologic assembles of microclastic rocks and carbonate rocks in the capping bed provide spaces of ore precipitation and create conditions of ore precipitation. The coincidence of many geological factors above forms the epithermal ore concentrated area.

Characteristics of the ore forming fluid from the zinc poly-metallic deposit in the Mopan mine area,Guangxi Nandan

Fluid inclusions from samples from the layered and veined mineralized belt in the Mopan mine area were studied using microscopic temperature measurements and laser Raman spectroscopy.Further studies were conducted on the nature and source of the ore forming fluid and on the mechanism of deposit formation.The results show that there are three types of inclusions that occur in both the layered and veined ore body.These are liquid inclusions,CO 2 inclusions with a liquid phase,and NaCl-H 2 O multiphase inclusions.The fluid inclusions in both the layered and veined ore bodies have similar characteristics.The ore forming fluid is strongly reducing,was exposed to low to medium temperatures,salinity,and pressures.The source of this ore forming fluid was a mix of submarine volcanic spring(blow-piping),magmatic hydrothermal jet,and underground water.

Geochemical Tracing of Ore-forming Material Sources of Carlin-type Gold Deposits in the Yunnan-Guizhou-Guangxi Triangle Area --A Case Study of the Application of the Combined Silicon Isotopes Geochemistry and Siliceous Cathodoluminescence Analysis

Abstract This paper deals with characteristics of silicon isotope compositions and siliceous cathodoluminescence of host rocks, ores and hydrothermal silicified quartz of the Carlin-type ore deposits in the Yunnan-Guizhou-Guangxi triangle area. The study shows that primary silicified quartz is nonluminescent but quartz in host rocks and secondary silicified quartz are luminescent by the action of cathode rays. Correspondingly, silicon isotope compositions of host rocks, ores and hydro6thermal quartz veins are clearly distinguished. In strata from the Middle Triassic to the “Dachang” host bed, δ30Si of the host rocks ranges from 0.0% ?0.3%, while that of primary ore-forming silicified fluids from ?0.1% to ?0.4%; in the Upper Permian and Lower Carboniferous strata and Indosinian diabase host beds, δ30Si of the host rocks is from ?0.1% to ?0.2% and that of the primary silicified quartz veins from 0.3 % ?0.5 %. This pattern demonstrates the following geochemical mineralization process, primary ore-forming siliceous fluids migrated upwards quickly along the main passages of deep-seated faults from mantle to crust and entered secondary faults where gold deposits were eventually formed as a result of permeation and replacement of the siliceous ore-forming fluids into different ore-bearing strata. This gives important evidence for the fact that ore-forming fluids of this type of gold deposits were mainly derived from upper mantle differentiation and shows good prospects for deep gold deposits and geochemical background for large and superlarge gold deposits.