On-line Chatter Detection Using an Improved Support Vector Machine

On-line chatter detection can avoid unstable cutting through monitoring the machining process.In order to identify chatter in a timely manner,an improved Support Vector Machine(SVM)is developed in this paper,based on extracted features.In the SVM model,the penalty factor(e)and the core parameter(g)have important influence on the classification,more than from Kernel Functions(KFs).Hence,first the classification results are conducted using different KFs.Then two methods are presented for exploring the best parameters.The chatter identification results show that the Genetic Algorithm(GA)approach is more suitable for deciding the parameters than the Grid Explore(GE)approach.

On-Line Detection of EDM Spark Locations Using Potential Difference Method

The valuation relation of potential difference with discharging time in Electrical Discharge Machining (EDM) is analyzed theoretically and tested and verified by experiments designed in this paper and the relation between potential difference and spark location is induced and analyzed, and proceed by experiments under the condition of onedimension.

PRECONCENTRATION OF TRACE ZINC IN SEAWATER ON CPPI RESIN BY FIA AND ON-LINE DETECTION BY ICP-AFS

A quite new type of chelating resin Carboxymethylated Polyethylenimine-Polymethylenepolyphenylene Isocyanate(CPPI)is used for the preconcentration of Zn from high salt water such as seawater. The preconcentration is controlled through the technique of Flow Injection Analysis(FIA).The concentrated sample solution is then directly transferred to an Inductively Coupled Plasma-Atomic Fluorescence Spectrometer(ICP-AFS)for determination.The detection limit of Zn by the technique is about 0.06 ppb.

Microfluidic Analytical System with On-Line Luminol Chemiluminescence Detection Based on Annular Flow of Phase Separation Multiphase Flow

Microfluidic analytical system was developed based on annular flow of phase separation multiphase flow with a ternary water-hydrophilic/hydrophobic organic solvent solution. The analytical system was combined with on-line luminol chemiluminescence detection for catechin analysis. The water (10 mM phosphate buffer, pH 7.3)-acetonitrile-ethyl acetate mixed solution (3:8:4, volume ratio) containing 60 μM luminol and 2 mM hydrogen peroxide as a carrier was fed into the capillary tube (open-tubular fused-silica, 75 μm inner diameter, 110 cm effective length) at a flow rate of 1.0 μL·min-1. The carrier solution showed stable chemiluminescence as a baseline on the flow chart. Eight catechins were detected as negative peaks for their antioxidant potential with different detection times. The system was applied to analyze the amounts of catechin in commercially available green tea beverages.

Application of an Improved ISODATA Method to Pipeline Leak Detection

Increasingly serious leak problem in pipeline transportation has not only affected the operation of pipelines but also caused loss of precious resource and environmental damage. Based on the analysis of the occurrence of negative pressure waves and the unsupervised learning of pattern recognition, the Interactive Self-organizing Data Analysis Technique Algorithm （ISODATA） method was used to classify the negative pressure waves and then the states of pipelines could be determined. K L transformation was used to eliminate the correlativity of feature parameters and to reduce the dimensionality of feature vector space to speed up calculation. Experimental results validated the accuracy and practical value of this method.

Leakage Detection in Water Distribution Network Based on a New Heuristic Genetic Algorithm Model

The leakage control is an important task, because it is associated with some problems such as economic loss, safety concerns, and environmental damages. The pervious methods which have already been devised for leakage detection are not only expensive and time consuming, but also have a low efficient. As a result, the global leakage detection methods such as leak detection based on simulation and calibration of the network have been considered recently. In this research, leak detection based on calibration in two hypothetical and a laboratorial networks is considered. Additionally a novel optimization method called step-by-step elimination method (SSEM) combining with a genetic algorithm (GA) is introduced to calibration and leakage detection in networks. This method step-by-step detects and eliminates the nodes that provide no contribution in leakage among uncertain parameters of calibration of a network. The proposed method initiates with an ordinary calibration for a studied network, follow by elimination of suspicious nodes among adjusted parameters, then, the network is re-calibrated. Finally the process is repeated until the numbers of unknown demands are equal to the desired numbers or the exact leakage locations and values are determined. These investigations illustrate the capability of this method for detecting the locations and sizes of leakages.

Quantitative risk assessment & leak detection criteria for a subsea oil export pipeline

A quantitative risk assessment （QRA） based on leak detection criteria （LDC） for the design of a proposed subsea oil export pipeline is presented in this paper. The objective of this QRA/LDC study was to determine if current leak detection methodologies were sufficient, based on QRA results, while excluding the use of statistical leak detection; if not, an appropriate LDC for the leak detection system would need to be established. The famous UK PARLOC database was used for the calculation of pipeline failure rates, and the software POSVCM from MMS was used for oil spill simulations. QRA results revealed that the installation of a statistically based leak detection system （LDS） can significantly reduce time to leak detection, thereby mitigating the consequences of leakage. A sound LDC has been defined based on QRA study results and comments from various LDS vendors to assist the emergency response team （ERT） to quickly identify and locate leakage and employ the most effective measures to contain damage.

Pipeline Potential Leak Detection Technologies: Assessment and Perspective in the Nigeria Niger Delta Region

This paper examines the advances in pipeline third party encroachment alert systems and leak control methods in the oil/gas industry. It also highlights the extent of spill/pollution issues in the Niger Delta region due to intended/unin- tended damages and suggests a possible method of control. It is believed that the best option to avoid pollution due to pipeline failure is to ensure that hydrocarbon does not exit from the pipeline. With the different methods considered in this review, acoustic monitoring of change in the operational sound generated from a given pipeline section is suggested to be practicable to identifying sound abnormalities of third party encroachments. One established challenge of the acoustic system for buried pipelines protection is attenuation of acoustic transmission. An attempt to check the performance of an acoustic transmission on steel pipelines submerged in water points to a similar research on plastic water pipelines that attenuation is small compared with pipe buried in soil. Fortunately, Niger Delta of Nigeria is made of wetland, swamps and shallow water and could therefore offer an opportunity to deploy acoustic system for the safety of pipelines against third party attacks in this region. However, the numerous configuration and quantity of oil installation in this region imply that cost of application will be enormous. It is therefore suggested that a combination of impressed alternating cycle current (IACC) which traces encroachment on the pipeline coating and an acoustic system be used to manage intended and unintended pipeline potential damages. The IACC should be used for flow lines and other short distance delivery lines within the oilfield, while the relatively large diameter and long length delivery, trunk and transmission lines should be considered for acoustic protection. It is, however, noted that further efforts are required to reduce cost and improve effectiveness of these systems.

Leak Detection in Offshore Pipelines of Conveying Fluid

Leakage from pipelines has caused serious environmental pollution and economic losses. Usually, leak detection can reduce the damage. The paper mainly discusses a hydraulic gradient-based leak detection method. The basic idea is outlined first, followed by a description of a laboratory experiment in a water pipeline. Several pressure curves are established based on different leak locations under the condition of a constant total flow rate. It is demonstrated that the leak of a large leak quantity can be detected reliably by the hydraulic gradient method.

Leak Detection of Gas Pipelines Based on Characteristics of Acoustic Leakage and Interfering Signals

When acoustic method is used in leak detection for natural gas pipelines,the external interferences including operation of compressor and valve,pipeline knocking,etc.,should be distinguished with acoustic leakage signals to improve the accuracy and reduce false alarms.In this paper,the technologies of extracting characteristics of acoustic signals were summarized.The acoustic leakage signals and interfering signals were measured by experiments and the characteristics of time-domain,frequency-domain and time-frequency domain were extracted.The main characteristics of time-domain are mean value,root mean square value,kurtosis,skewness and correlation function,etc.The features in frequency domain were obtained by frequency spectrum analysis and power spectrum density,while time-frequency analysis was accomplished by short time Fourier transform.The results show that the external interferences can be removed effectively by the characteristics of time domain,frequency domain and time-frequency domain.It can be drawn that the acoustic leak detection method can be applied to natural gas pipelines and the characteristics can help reduce false alarms and missing alarms.

Leak Detection in Water Distribution Systems Using Bayesian Theory and Fisher’s Law

A leak detection method based on Bayesian theory and Fisher’s law was developed for water distribution systems. A hydraulic model was associated with the parameters of leaks (location, extent). The randomness of parameter values was quantified by probability density function and updated by Bayesian theory. Values of the parameters were estimated based on Fisher’s law. The amount of leaks was estimated by back propagation neural network. Based on flow characteristics in water distribution systems, the location of leaks can be estimated. The effectiveness of the proposed method was illustrated by simulated leak data of node pressure head and flow rate of pipelines in a test pipe network, and the leaks were spotted accurately and renovated on time.

Theory analysis and experimental research on on-line contamination detecting technology in hydraulic oil

A system of on-line contamination detecting in hydraulic oil based on silting principle is accomplished, where, metal filter membrane as detector, solenoid as active force to propel piston to blotter and gain differential pressure, step motor drives the membrane to filtrate and counter-flush, LabVIEW as detecting software platform, oil's contamination detecting indirectly by gauging differential pressure. Based on theory analysis, accomplished is relation between contamination level and differential pressure, realizing polynomial curve fitting, and calibration experiment. Field experiment is simulated in the condition of experimental laboratory, has credible precision and real-time performance, which can popularize to the field of production.

Performing Reliable Early Leak Detection on Storage Tank Terminals:Retrofitting of Existing Facilities and New Buildings

Liquid leak detection may represent a challenge for Oil&Gas operators,as indicated by operational feed-back and independent studies.Despite the availability of many different leak detection technologies,some systems may either fail to detect spills or generate frequent false alarms.In particular,possible soil contamination from pre-existing leaks and pollution carry-over by rain water is difficult to filter out by a leak sensing system.Typical case of false alarms relates to punctual sensors installed upstream the drain valve within the storage tank bunds,monitoring possible presence of leaks in rain water.Besides old soil contamination,other criteria should also be considered when selecting a spill detection technology,such as asset type to be monitored(storage tank,pipeline,…),system accuracy(minimum detectable quantity,ability to localize the leak),detection time,reliability over time,capital,installation and operating costs.The paper will include an evaluation of different external leak detection technologies with respect to the above-mentioned criteria,pointing out the capabilities and limitations of each system.Focus will be placed on reliability of leak monitoring systems in challenging environments.A new generation of digital,reusable sensing cables and probes,as well as the impact of sensitivity for different applications,will be discussed.Since leak sensor installation environment(positioning,adoption of special precautions,…)may significantly affect the system performance,different above ground and underground configurations will be presented,both for new builds and existing facilities.

In-Line Inspection of Pipeline Defects Detection Using Ring-Type Laser

Pipeline plays a vital role in transporting fluids like oils, water, and petrochemical substances for longer distances. Based on the materials they carry, prolonged usage may cause the initiation of defects in the pipeline. These defects occur due to the formed salt deposits, chemical reaction happens between the inner surface and the transferring substance, prevailing environmental conditions, etc. These defects, if not identified earlier may lead to significant losses to the industry. In this work, an in-line inspection system utilizes the nondestructive way for analyzing the internal defects in the petrochemical pipeline. This system consists of a pipeline inspection robot having two major units namely the visual inspection unit and the power carrier unit. The visual inspection unit makes use of a ring-type laser diode and the camera. The laser diode serves as a light source for capturing good quality images of inspection. This unit is controlled by the Arduino in the power carrier unit which provides the necessary movement throughout the pipe. The inspected images captured by the camera are further processed with the aid of NI vision assistant software. After applying the processing function parameters provided by this software, the defect location can be clearly visualized with high precision. Three sets of defects are introduced in a Polylactide (PLA) pipe based on its position and angle along the circumference of the pipe. Further, this robot system serves as a real-time interactive image synchronization system for acquiring the inspected images. By comparing the actual and calculated defect size, the error percentage obtained was less than 5%.

Flow-Injection Microcolumn on-Line Preconcentration for theDetermination of Chromium(Ⅵ)

A rapid and sensitive on-line preconcentration method for spectrophotometric determination of chromium (VI) in nature water is described. Preconcentration and determination are based on (i) the quantitative and fast adsorption of chromium (VI) on the high surface area nanometer-size TiO2 (anatase) powders, which prepared by a sol-gel method from hydrolysis of TiCI4 and (ii) the quantitative and reproducible elution of Cr (VI) by 2. 0 mol. L-1 HCI. A mini-column system for preconcentration is developed, Cr(VI)on the mini-column is eluted and merged with a stream water and DPCB (1, 5-diphenylcarbazide ) as the chromogenic reagent. The Proposed system permits throughputs of 6 sample h--l (0. 001 μg mL-1 Cr(VI) ) or 20 sample h-1 (0. 1 μg mL-1Cr (VI) . The preconcentration factor is 55. The detection limit is 0. 8 ng·mL-1 Cr(VI). The reproducibility is satisfactory with a relative standard deviation of less than 3. 35% (0. Of μg'mL-1Cr (VI), n = 5).

Detection and analysis of gas tightness of continuous annealing furnaces

When a cold rolled strip is being treated in a continuous annealing furnace which is full of protective gas, the gas tightness of the furnace body, the connected facilities and the gas channels become an important indicator that directly affects the product＇s surface quality and shows the technical level of the design, the manufacture and the installation. By considering the problems of the gas tightness of a vertical annealing furnace in the installation and maintenance, this thesis evaluates the gas tightness indicator and gas tightness related level of the furnace body and the circulation duct, while studying and analyzing the technologies of negative-pressure leak detection and sealing.

PMOXA/PAA Brushes toward on-Line Preconcentration for BSA in Capillary Electrophoresis

In this work, a binary-mixed-brushes-coated (BBC) capillary with switchable protein adsorption/desorption properties was developed and applied for on-line preconcentration of proteins. Firstly, amine-terminated poly(2-methyl-2-oxazoline)(PMOXA-NH2) and thiolterminated poly(acrylic acid)(PAA-SH) were synthesized by using cationic ring-opening polymerization (CROP) and reversible addition fragmentation chain transfer (RAFT) polymerization, respectively. Then, the BBC capillary based on poly(2-methyl-2-oxazoline)(PMOXA) and poly(acrylic acid)(PAA) was prepared by sequentially grafting of PMOXA-NH2 and PAA-SH onto fused-silica capillary inner surface through poly(dopamine)(PDA) as an anchor. The obtained PMOXA/PAA coating formed on the capillary or capillary's raw material was characterized in terms of the thickness, surface chemical composition by using scanning electron microscope (SEM) and X-ray photoelectron spectrum (XPS). The switchable protein adsorption/desorption performance of the BBC capillary was investigated by using fluorescence microscope under di erent solutions with certain pH and ionic strength(I). The results showed that bovine serum albumin (BSA) could be adsorbed on BBC capillary at pH=5.0 (I=10^-5 mol/L), and then the adsorbed BSA could be released at pH=9.0 (I=0.1 mol/L). This switchable protein adsorption/desorption property of coated capillary was then used to preconcentrate proteins on-line for increasing the detection sensitivity of BSA in capillary electrophoresis (CE). With this method, a sensitivity enhancement factor (SEF) more than 5000 for BSA detection was obtained.

On-line coupling of derivatization with pre-concentration to determine trace levels of methotrexate

A new simple, sensitive and precise green analytical procedure using an automated packed-reactor derivatization technique coupled with on-line solid-phase enrichment （SPEn） has been developed and evaluated to determine trace levels of methotrexate （MTX）. The method was based on injection of MTX into a flowing stream of phosphate buffer （0.04 M, ptt 3.4）, carried through the packed oxidant reactor of Cerium （IV） trihydroxyhydroperoxide for oxidative cleavage of the drug into highly fluorescent product, 2,4-diaminopteridine- 6-carboxylic acid, followed by SPEn on a head of short ODS column （10mm x 4.6 mm i.d., 5 I＋tm particle size）. The flow rate was 0.25 mL/min and packed reactor temperaturc was 40 ~C. The trapped product was back-flush eluted from the ODS column to the detector by column-switching with an environmentally friendly mobile phase consisting of ethanol and phosphate buffer （0.04 M, pH 3.4） in the ratio of 5：95 （v/v）. The eluent was monitored at emission and excitation wavelengths of 460 and was linear over the concentration range of 1.25-50 360 nm, respectively. The calibration curve ng/mL with a detection limit of 0.08 ug/ml..The method was successfully applied to determine MTX in pharmaceutical formulations with mean percentage recovery ranging from 99.48 to 99.60.

Automatic System for Failure Detection in Hydro-Power Generators

This paper presents an automatic system for failure detection in hydro-power generators. The main idea of this system is to detect failure using current and voltage signals acquired without any type of internal interference in the generator operation. The detected failures could be mechanical or electrical origins, such as: problems in bearings, unwanted vibrations, partial discharges, misalignment, unbalancing, among others. It is possible because the generator acts as a transducer for mechanical problems, and they appear in current and voltage signals. This automatic system based on electric signature analysis has been installed in Itapebi Power Plant generators since 2012. Some results are presented in this paper.

Overview of Industrial Materials Detection Based on Prompt Gamma Neutron Activation Analysis Technology

Prompt gamma neutron activation analysis (PGNAA) is a non-destructive online measurement nuclear analysis method. With its unique advantages, it has been widely used in online analysis of industrial materials such as coal, cement, and minerals in recent years. However, there are many kinds of literature on PGNAA in the field of industrial materials detection, and there are still a few concluding articles. To this end, based on the principle of PGNAA online analysis, the status quo and development of the real-time online detection of industrial material components in the field are reviewed and discussed by consulting a large number of domestic and foreign PGNAA related literature and data, to facilitate the reference of relevant scientific researchers.