We provide a way to precisely control the geometry of a SiNx nanopore by adjusting the applied electric pulse. The pore is generated by applying the current pulse across a SiNx membrane, which is immersed in potassium...We provide a way to precisely control the geometry of a SiNx nanopore by adjusting the applied electric pulse. The pore is generated by applying the current pulse across a SiNx membrane, which is immersed in potassium chloride solution. We can generate single conical and cylindrical pores with different electric pulses. A theoretical model based on the Poisson and Nernst-Planck equations is employed to simulate the ion transport properties in the channel. In turn, we can analyze pore geometries by fitting the experimental current-voltage （I-V） curves. for the conical pores with a pore size of 0.5-2nm in diameter, the slope angles are around -2.5% to -10%. Moreover, the pore orifice can be enlarged slightly by additional repeating pulses. The conic pore lumen becomes close to a cylindrical channel, resulting in a symmetry I-V transport under positive and negative biases. A qualitative understanding of these effects will help us to prepare useful solid-nanopores as demanded.展开更多
Ventilated cavitation plays an important role on the drag reduction of underwater vehicles and surface ships. For the modelling of ventilated cavitation, the minimum speed of the pressure wave is a crucial parameter f...Ventilated cavitation plays an important role on the drag reduction of underwater vehicles and surface ships. For the modelling of ventilated cavitation, the minimum speed of the pressure wave is a crucial parameter for the closure of the pressure-density coupling relationship. In this study, the minimum wave speed is determined based on a theoretical model coupling the wave equation and the bubble interface motion equation. The influences of several paramount parameters （e.g., frequency, bubble radius and void fraction） on the minimum wave speed are quantitatively demonstrated and discussed. Compared with the minimum wave speed in the traditional cavitation, values for the ventilated cavitation are much higher. The physical mechanisms for the above difference are briefly discussed with the suggestions on the usage of the present findings.展开更多
The equilibrium and kinetic characteristics of the adsorption of erythromycin to Sepabeads SP825 were determined.The equilibrium data in a batch system was well described by a Langmuir isotherm.The separation performa...The equilibrium and kinetic characteristics of the adsorption of erythromycin to Sepabeads SP825 were determined.The equilibrium data in a batch system was well described by a Langmuir isotherm.The separation performance was investigated in a fixed-bed system with respect to the adsorption superficial velocity,ionic strength and pH.A mathematical model was used to simulate the mass transfer mechanism,taking film mass transfer,pore diffusion and axial dispersion into account.The model predictions were consistent with the experi-mental data and were consequently used to determine the mass transfer coefficients.展开更多
基金Supported by the National Natural Science Foundation of China under Grant Nos 61471336,51503207 and 61504146the Joint-Scholar of West Light Foundation of Chinese Academy of Sciences
文摘We provide a way to precisely control the geometry of a SiNx nanopore by adjusting the applied electric pulse. The pore is generated by applying the current pulse across a SiNx membrane, which is immersed in potassium chloride solution. We can generate single conical and cylindrical pores with different electric pulses. A theoretical model based on the Poisson and Nernst-Planck equations is employed to simulate the ion transport properties in the channel. In turn, we can analyze pore geometries by fitting the experimental current-voltage （I-V） curves. for the conical pores with a pore size of 0.5-2nm in diameter, the slope angles are around -2.5% to -10%. Moreover, the pore orifice can be enlarged slightly by additional repeating pulses. The conic pore lumen becomes close to a cylindrical channel, resulting in a symmetry I-V transport under positive and negative biases. A qualitative understanding of these effects will help us to prepare useful solid-nanopores as demanded.
基金Supported by the National Natural Science Foundation of China under Grant No 51506051
文摘Ventilated cavitation plays an important role on the drag reduction of underwater vehicles and surface ships. For the modelling of ventilated cavitation, the minimum speed of the pressure wave is a crucial parameter for the closure of the pressure-density coupling relationship. In this study, the minimum wave speed is determined based on a theoretical model coupling the wave equation and the bubble interface motion equation. The influences of several paramount parameters （e.g., frequency, bubble radius and void fraction） on the minimum wave speed are quantitatively demonstrated and discussed. Compared with the minimum wave speed in the traditional cavitation, values for the ventilated cavitation are much higher. The physical mechanisms for the above difference are briefly discussed with the suggestions on the usage of the present findings.
文摘The equilibrium and kinetic characteristics of the adsorption of erythromycin to Sepabeads SP825 were determined.The equilibrium data in a batch system was well described by a Langmuir isotherm.The separation performance was investigated in a fixed-bed system with respect to the adsorption superficial velocity,ionic strength and pH.A mathematical model was used to simulate the mass transfer mechanism,taking film mass transfer,pore diffusion and axial dispersion into account.The model predictions were consistent with the experi-mental data and were consequently used to determine the mass transfer coefficients.
