Theoretical Study of the Structure,Mechanism of Detonation Initiation and Stability of Transition Metal Carbohydrazide Nitrates

The geometric structure, mechanism of detonation initiation and stability of transition metal carbohydrazide （CHZ） nitrates are investigated via density functional theory. The obtained results show that the Heyd-Scuseria-Ernzerhof （HSE） functional yields the most accurate geometry. The initiating reaction of detonation in [Mn（CHZ）3]（NO3）2 and [Zn（CHZ）3]（NO3）2 is the formation of NO3 radicals. The calculated heat of formation and energy gap predict that the Mn and Zn complexes, which have the half-filled （3d5） and full-filled （3d10） electron configurations for the transition metal ions, respectively are more stable than the Co, Ni and Cu complexes. This indicates that the electron configuration of transition metal ion plays an important role in the stabilities of these energetic complexes.

Numerical Investigation on the Propagation Mechanism of Steady Cellular Detonations in Curved Channels

The propagation mechanism of steady cellular detonations in curved channels is investigated numerically with a detailed chemical reaction mechanism, The numerical results demonstrate that as the radius of the curvature decreases, detonation fails near the inner wall due to the strong expansion effect. As the radius of the curvature increases, the detonation front near the inner wall can sustain an underdriven detonation. In the case where deto- nation fails, a transverse detonation downstream forms and re-initiates the quenched detonation as it propagates toward the inner wall. Two kinds of propagation modes exist as the detonation is propagating in the curved channel. One is that the detonation fails first, and then a following transverse detonation initiates the quenched detonation and this process repeats itself. The other one is that without detonation failure and re-initiation, a steady detonation exists which consists of an underdriven detonation front near the inner wall subject to the diffraction and an overdriven detonation near the outer wall subject to the compression.

Propagating Characteristic of Premixed Methane-Oxygen Deflagration in the Coal Mine Lane Including a Refuge Chamber

In order to investigate detonation propagation and distribution problems of premixed CH_4 ＋ 2O_2 mixture around a concrete structure such as a refuge chamber,detonation experiments in one small size tube were conducted. A simulation method was developed to obtain the flow field load distribution in the coal mine lane and pressure load of each part for the refuge chamber. Firstly,a physical model of a full-size explosiontest lane was established,which included the refuge chamber. With the calculations of the exact initial detonation pressure,the propagation characteristics of CH_4 ＋ 2O_2 premixed mixture detonation in the lane was simulated. Simulation results of various parts from AUTODYN are recorded,and the shock wave arrival time and the pressure peak can be observed from the detonation pressure-time curve over the changing propagation distance. So curve differences in different locations cannot be ignored. Then by detonation experiments in the small size tube,detonation pressure-time curves and velocity were obtained. Finally the simulation waveform of variation curve agreed well with the experimental results,which validated the detonation simulation method. The difference between shockwaves of the two sensors confirmed that detonation wave changed along with distance and time. These results should be taken into serious consideration for the detonation progration and distribution problem in future researches.

Detonation Mechanism in Double Vertical Explosive Welding of Stainless Steel/Steel

One-dimensional detonation model and two-dimensional P-M （Prandtl-Meyer） expanding model of double vertical explosive welding were established. A one-dimensional formula of flyer plate velocity was obtained and the bending angle curve representing flying attitude of flyer plate in double vertical was deduced as well. Compared with single parallel explosive welding, the double vertical explosive welding combines two cladding plates in one explosion. Due to closed charging structure, the influence of rarefaction wave on the plate＇s surface in double vertical explosive welding is eliminated and explosion loading time and displacement are increased, resulting in the increase of flyer velocity and energy utilization rate by 1.3 times to 1.6 times in different mass ratios. The analysis of microstructure in bonding zone of double vertical cladding plate under traditional charging shows that there is a clear over-melting near the interface, which is in line with the conclusion of detonation mechanism.