Mineral Chemistry,Trace Elements,Isotopic Analysis and Zircon U-Pb Dating in the Hesar Pluton,Northern UDMA,Iran:Implications for Pre-Collisional Magma Mixing

The Hesar pluton in the northern Urumieh-Dokhtar magmatic arc hosts numerous mafic-microgranular enclaves(MMEs).Whole rock geochemistry,mineral chemistry,zircon U-Pb and Sr-Nd isotopes were measured.It is suggested that the rocks are metaluminous(A/CNK=1.32-1.45),subduction-related I-type calc-alkaline gabbro to diorite with similar mineral assemblages and geochemical signatures.The host rocks yielded an U-Pb crystallization age of 37.3±0.4 Ma for gabbro-diorite.MMEs have relatively low SiO_(2) contents(52.9-56.6 wt%)and high Mg^(#)(49.8-58.7),probably reflecting a mantle-derived origin.Chondrite-and mantle-normalized trace element patterns are characterized by LREE and LILE enrichment,HREE and HFSE depletion with slight negative Eu anomalies(Eu/Eu^(*)=0.86-1.03).The host rocks yield(^(87)Sr/^(86)Sr)_(i) ratios of 0.70492-0.70510,positive ε_(Nd)(t)values of+1.55-+2.06 and T_(DM2)of 707-736 Ma,which is consistent with the associated mafic microgranular enclaves((^(87)Sr/^(86)Sr)_(i)=0.705014,ε_(Nd)(t)=+1.75,T_(DM2)=729 Ma).All data suggest magma-mixing for enclave and host rock formation,showing a complete equilibration between mixed-mafic and felsic magmas,followed by rapid diffusion.The T_(DM1)(Nd)and T_(DM2)(Nd)model ages and U-Pb dating indicate that the host pluton was produced by partial melting of the lower continental crust and subsequent mixing with injected lithospheric mantlederived magmas in a pre-collisional setting of Arabian-Eurasian plates.Clinopyroxene composition indicates a crystallization temperature of~1000℃ and a depth of~9 km.

Decoding Provenance and Tectonothermal Events by Detrital Zircon Fission-Track and U-Pb Double Dating: A Case of the Southern Ordos Basin

Multi-dating on the same detrital grains allows for determining multiple different geo-thermochronological ages simultaneously and thus could provide more details about regional tectonics.In this paper,we carried out detrital zircon fission-track and U-Pb double dating on the Permian-Middle Triassic sediments from the southern Ordos Basin to decipher the tectonic information archived in the sediments of intracratonic basins.The detrital zircon U-Pb ages and fission-track ages,together with lag time analyses,indicate that the Permian-Middle Triassic sediments in the southern Ordos Basin are characterized by multiple provenances.The crystalline basement of the North China Craton(NCC)and recycled materials from pre-Permian sediments that were ultimately sourced from the basement of the NCC are the primary provenance,while the Permian magmatites in the northern margin of NCC and Early Paleozoic crystalline rocks in Qinling Orogenic Collage act as minor provenance.In addition,the detrital zircon fission-track age peaks reveal four major tectonothermal events,including the Late Triassic-Early Jurassic post-depositional tectonothermal event and three other tectonothermal events associated with source terrains.The Late Triassic-Early Jurassic(225–179 Ma)tectonothermal event was closely related to the upwelling of deep material and energy beneath the southwestern Ordos Basin due to the coeval northward subduction of the Yangze Block and the following collision of the Yangze Block and the NCC.The Mid-Late Permian(275–263 Ma)tectonothermal event was associated with coeval denudation in the northern part of the NCC and North Qinling terrane,resulting from the subduction of the Paleo-Asian Ocean and Tethys Ocean toward the NCC.The Late Devonian-early Late Carboniferous(348±33 Ma)tectonothermal event corresponded the long-term denudation in the hinterland and periphery of the NCC because of the arc-continent collisions in the northern and southern margins of the NCC.The Late Neoproterozoic(813–565 Ma)tectonothermal event was associated with formation of the Great Unconformity within the NCC and may be causally related to the Rodinia supercontinent breakup driven by a large-scale mantle upwelling.

Detrital Zircon Records of the Banxi Group in the Western Jiangnan Orogen:Implications for Crustal Evolution of the South China Craton

The Neoproterozoic evolution of the Jiangnan Orogen is important for understanding the tectonic history of South China.As a volcanic-sedimentary sequence developed in the Nanhua rift,the Banxi Group preserves the records of important magmatic and tectonic events linked to the assembly and breakup of the Rodinia supercontinent.In this study,we report the results from whole-rock major-and trace-element concentrations,with zircon LA-(MC)-ICP-MS U-Pb ages,trace elements and Lu-Hf isotopic compositions of sandstones from the Banxi Group.The rocks are characterized by high SiO_(2)(65.88%–82.76%,with an average of 75.50%)contents,moderate(Fe_(2)O_(3)^(T)+MgO)(1.81%–7.78%,mean:3.79%)and TiO_(2)(0.39%–0.54%,mean:0.48%),low K_(2)O/Na_(2)O(0.03–0.40,mean:0.10)ratios and low Al_2O_(3)/SiO_(2)(0.11–0.24,mean:0.15)ratios.The sandstones have highΣREE contents(mean:179.1 ppm),with chondrite-normalized REE patterns similar to the upper crust and PAAS,showing enriched LREE((La/Yb)_N mean:14.85),sub-horizontal HREE curves and mild Eu(Eu/Eu^(*):0.75–0.89,mean:0.81)negative anomalies.Their geochemical characteristics resemble those of passive continental margin sandstones.Most of the zircons are magmatic in origin and yield a U-Pb age distribution with three peaks:a major age peak at 805 Ma and two subordinate age peaks at 1990 Ma and 2470 Ma,implying three major magmatic sources.The Neoproterozoic zircons haveε_(Hf)(t)values ranging from-47.4 to 12.4(mostly-20 to 0),suggesting a mixture of some juvenile arc-derived material and middle Paleoproterozoic heterogeneous crustal sources.The Hf model ages of middle Paleoproterozoic zircons(~1990 Ma)with negativeε_(Hf)(t)values(-12.65 to-6.21,Ave.=-9.8)concentrated around the Meso-Paleoarchean(mean T_(DM)^(C)=3.3–3.1 Ga).For late Neoarchean detrital zircons(~2470 Ma),ε_(Hf)(t)values are divided into two groups,one with negative values(-9.16 to-0.6)with model ages of 3.5–2.9 Ga,the other featuring positive values(1.0 to 3.9)with model ages of 2.9–2.7 Ga,recording a crustal growth event at~2.5 Ga.Neoproterozoic zircons show volcanic arc affinities with partly intraplate magmatic features.We propose that the Banxi Group formed in a rift basin within a passive continental margin setting,which derived detritus from felsic to intermediate rocks from the Yangtze Block and a small amount of arc volcanic rocks.The middle Paleoproterozoic detrital zircon data suggest Columbia-aged basement lies beneath the western Jiangnan orogen.

Zircon U-Pb geochronologic,geochemical and Sr-Nd-Pb isotope characteristics of the Beidaban granites in the North Qilian Orogenic Belt:Petrogenesis and tectonic implications

The tectonic evolution and crustal accretion process of the North Qilian Orogenic Belt(NQOB)are still under debate because of a lack of integrated constraints,especially the identifi cation of the tectonic transition from arc to initial collision.Here we present results from zircon U-Pb geochronology,whole-rock geochemistry,and Sr-Nd-Pb isotope geochemistry of the Beidaban granites to provide crucial information for geodynamic evolution of NQOB.Zircon U-Pb dating yields an age of 468±10 Ma for the Beidaban granites and most of the Beidaban samples contain amphibole,are potassium-rich,and have A/CNK values ranging from 0.7 to 0.9,illustrating that the Middle Ordovician Beidaban granites are K-rich,metaluminous,calc-alkaline granitoid.The geochemical characteristics indicate that the Beidaban granites are transitional I/S-type granitoids that formed in an arc setting.The isotopic compositions of initial(87 Sr/86 Sr)i values ranging from 0.70545 to 0.71082(0.70842 on average)andεNd(t)values ranging from−10.9 to−6.7(−8.8 on average)with two-stage Nd model ages(T DM2)of 1.74-2.08 Ga suggest that the Beidaban granites originated from Paleoproterozoic crustal materials.In addition,the initial Pb isotopic compositions(^(206)Pb/^(204)Pb=19.14-20.26;^(207)Pb/^(204)Pb=15.71-15.77;^(208)Pb/^(204)Pb=37.70-38.26)and geochemical features,such as high Th/Ta(17.43-30.12)and Rb/Nb(6.01-15.49)values,suggest that the Beidaban granite magma source involved recycled crustal components with igneous rocks.Based on these results in combination with previously published geochronological and geochemical data from other early Paleozoic igneous rocks,we suggest that the timing of the tectonic transition from arc to the initial collision to the fi nal closure of the North Qilian Ocean can be constrained to the Middle-Late Ordovician(ca.468–450 Ma).

Garnet and Zircon U-Pb Geochronology and Geochemistry Reveal Genesis of the Dafang Au-Pb-Zn-Ag Deposit,Southern Hunan

Garnet is a primary mineral in skarn deposits and plays a significant role in recording copious mineralization and metallogenic information.This study systematically investigates the geochemistry and geochronology of garnet and zircon in the Dafang Au-Pb-Zn-Ag deposit,which represents prominent gold mineralization in southern Hunan,China.Garnet samples with distinct zoning patterns and compositional variations were identified using various analytical techniques,including Backscattered Electron(BSE)imaging,Cathodoluminescence(CL)response,textural characterization,and analysis of rare-earth elements(REE),major contents,and trace element compositions.The garnet was dated U-Pb dating,which yielded a lower intercept age of 161.06±1.93 Ma.This age is older than the underlying granodiorite porphyry,which has a concordia age of 155.13±0.95 Ma determined by zircon U-Pb dating.These results suggest that the gold mineralization may be related to the concealed granite.Two groups of garnet changed from depleted Al garnet to enriched Al garnet,and the rare earth element(REE)patterns of these groups were converted from light REE(LREE)-enriched and heavy REE(HREE)-depleted with positive europium(Eu)anomalies to medium REE(MREE)-enriched from core to rim zoning.The different REE patterns of garnet in various zones may be attributed to changes in the fluid environment and late superposition alteration.The development of distal skarn in the southern Hunan could be a significant indicator for identifying gold mineralization.

U-Pb Age and Hf Isotope Study of Detrital Zircons from the Wanzi Supracrustals:Constraints on the Tectonic Setting and Evolution of the Fuping Complex,Trans-North China Orogen

Located in the middle segment of the Trans-North China Orogen, the Fuping Complex is considered as a critical area in understanding the evolution history of the North China Craton （NCC）. The complex is composed of various high-grade and multiply deformed rocks, including gray gneiss, basic granulite, amphibolite, fine-grained gneiss and marble, metamorphosed to upper amphibolite or granulite facies. It can be divided into four rock units： the Fuping TTG gneisses, Longquanguan augen gneisses, Wanzi supracrustals, and Nanying granitic gneisses. U-Pb age and Hf isotope compositions of about 200 detrital zircons from the Wanzi supracrustals of the Fuping Complex have been analyzed. The data on metamorphic zircon rims give ages of 1.82-1.84 Ga, corresponding to the final amalgamation event of the NCC, whereas the data for igneous zircon cores yield two age populations at -2.10 and -2.51 Ga, with some inherited ages scattering between 2.5 and 2.9 Ga. These results suggest that the Wanzi supracrustals were derived from the Fuping TTG gneisses （-2.5 Ga） and the Nanying granitic gneisses （2.0-2.1 Ga） and deposited between 2.10 and 1.84 Ga. All zircons with -2.51 Ga age have positive initial εHf values from ＋1.4 to ＋10.9, suggesting an important crustal growth event at -2.5 Ga through the addition of juvenile materials from the mantle. The Hf isotope data for the detrital zircons further imply that the 2.8 Ga rocks are important components in the lower crust, which is consistent with a suggestion from Nd isotope data for the Eastern Block. The zircons of 2.10 Ga population have initial εHf values of-4.9 to ＋6.1, interpreted as mixing of crustal re-melt with minor juvenile material contribution at 2.1 Ga. These results are distinct from that for the Western Block, supporting that the Fuping Complex was emplaced in a tectonic active environment at the western margin of the Eastern Block.

Constraints on sedimentary ages of the Chuanlinggou Formation in the Ming Tombs, Beijing, North China Craton: LA-ICP-MS and SHRIMP U–Pb dating of detrital zircons

Detrital zircons in five sedimentary samples, MC1 to MC5, from the bottom of the Chuanlinggou Formation in the Ming Tombs District, Beijing, were dated with the LA-ICP-MS and SHRIMP U-Pb methods. Age spectra of the five samples show a major peak at 2500 Ma and a secondary peak at 2000 Ma, suggesting their provenances were mainly from the crystalline basement of the North China Craton and the Trans-North China Orogen. The youngest zircon has an age of 1673 d： 44 Ma, indicating that the Chuanlinggou Formation was deposited after this age. From sample MC4 to MC5, lithology changed from a clastic rock （fine-grained sandstone） to a carbonate rock （fine-grained dolomite）, suggesting that the depositional basin became progressively deeper. The age spectrum of sample MC5 shows a major peak at 2500 Ma and a secondary peak at 2000 Ma. Sample MC4, which is stratigraphically lower than sample MC5, only had one peak at 2500 Ma. We conclude that there was a transgressive event when sediments represented by MC5 was deposited, and seawater carried ca. 2000 Ma clastic materials to the basin where the Chuanlinggou Formation was deposited, leading to the addition of ca. 2000 Ma detritus. Our research indicates that the source area for the sediments became more extensive with time. We conclude that the Chuanlinggou Formation in the Ming Tombs District was deposited in a low-energy mud fiat sedimentary environment in the inter-supra tidal zone because it is mainly composed of silty mudstone and fine-grained sandstone with relatively simple sedimentary structures.

Detrital Zircon U-Pb Ages and Geochemistry of the Silurian to Permian Sedimentary Rocks in Central Inner Mongolia, China: Implications for Closure of the Paleo-Asian Ocean

The Solonker suture zone has long been considered to mark the location of the final disappearance of the PaleoAsian Ocean in the eastern Central Asian Orogenic Belt(CAOB). However, the time of final suturing is still controversial with two main different proposals of late Permian to early Triassic, and late Devonian. This study reports integrated wholerock geochemistry and LA-ICP-MS zircon U-Pb ages of sedimentary rocks from the Silurian Xuniwusu Formation, the Devonian Xilingol Complex and the Permian Zhesi Formation in the Hegenshan-Xilinhot-Linxi area in central Inner Mongolia, China. The depositional environment, provenance and tectonic setting of the Silurian-Devonian and the Permian sediments are compared to constrain the tectonic evolution of the Solonker suture zone and its neighboring zones. The protoliths of the silty slates from the Xuniwusu Formation in the Baolidao zone belong to wacke and were derived from felsic igneous rocks with steady-state weathering, poor sorting and compositional immaturity. The protoliths of metasedimentary rocks from the Xilingol Complex were wackes and litharenites and were sourced from predominantly felsic igneous rocks with variable weathering conditions and moderate sorting. The Xuniwusu Formation and Xilingol Complex samples both have two groups of detrital zircon that peak at ca. 0.9-1.0 Ga and ca. 420-440 Ma, with maximum deposition ages of late Silurian and middle Devonian age, respectively. Considering the ca. 484-383 Ma volcanic arc in the Baolidao zone, the Xuxiniwu Formation represents an oceanic trench sediment and is covered by the sedimentary rocks in the Xilingol Complex that represents a continental slope sediment in front of the arc. The middle Permian Zhesi Formation metasandstones were derived from predominantly felsic igneous rocks and are texturally immature with very low degrees of rounding and sorting, indicating short transport and rapid burial. The Zhesi Formation in the Hegenshan zone has a main zircon age peak of 302 Ma and a subordinate peak of 423 Ma and was deposited in a back-arc basin with an early marine transgression during extension and a late marine regression during contraction. The formation also crops out locally in the Baolidao zone with a main zircon age peak of 467 Ma and a minor peak of 359 Ma, and suggests it formed as a marine transgression sedimentary sequence in a restricted extensional basin and followed by a marine regressive event. Two obvious zircon age peaks of 444 Ma and 280 Ma in the Solonker zone and 435 Ma and 274 Ma in Ondor Sum are retrieved from the Zhesi Formation. This suggests as a result of the gradual closure of the Paleo-Asian Ocean a narrow ocean sedimentary environment with marine regressive sedimentary sequences occupied the Solonker and Ondor Sum zones during the middle Permian. A restricted ocean is suggested by the Permian strata in the Bainaimiao zone. Early Paleozoic subduction until ca. 381 Ma and renewed subduction during ca. 310-254 Ma accompanied by the opening and closure of a back-arc basin during ca. 298-269 Ma occurred in the northern accretionary zone. In contrast, the southern accretionary zone documented early Paleozoic subduction until ca. 400 Ma and a renewed subduction during ca. 298-246 Ma. The final closure of the Paleo-Asian ocean therefore lasted at least until the early Triassic and ended with the formation of the Solonker suture zone.

New detrital zircon U-Pb ages from BIF-related metasediments in the Ntem Complex (Congo craton) of southern Cameroon, West Africa

Banded Iron Formations (BIFs) were formed by contemporaneous events of active sediments supply and the venting of a hydrothermal fluid source at the Mid-Ocean-Ridge. BIFs within the Ntem Complex at the northern edge of the Congo Craton are intercalated with metasandstones and siltstones. SHRIMP U-Pb analysis on detrital zircons obtained from these metasediments gave variable ages from over 3000 Ma to 1000 Ma with the maximum age of deposition clustered around 1200 Ma and the peak of deposition at 1800 Ma. This age range suggested that the sub-basin was opened sometime in the Archean and remained active up till the Neoproterozoic. Zircons with Archean ages have a provenance linked to the charnockitic suite and the high-K granites within the Ntem Complex. The Paleoproterozoic ages are attributed to clastic inputs from the neigbouring Nyong Series west of the Ntem Complex. Also the peak of deposition in the Proterozoic could probably be explained by the globally recognized intense crust-forming processes in the Early Proterozoic time. The provenance of the younger Neoproterozoic ages is tied to various lithologies within the northern mobile belts of the Adamawa-Yade massifs and correlates with Neoproterozoic sedimentation ages in the Yaoundé, Lom and Poli series. The Neoproterozoic ages obtained are comparable to those obtained from metasediments of the Amazonian Craton and provide evidence of Pre-Gondwana assemblage of the Congo and the S?o Francisco Cratons.

Detrital Zircon U-Pb Geochronology： New Insight into the Provenance of Sanya Formation in the Yinggehai Basin

Objective The NNW-SSE trending Yinggehai Basin, located on the continental shelf at water depths of 50-200 m in the northwestern South China Sea, is a Cenozoic conversion extensional basin. Over the past decades, a number of hydrocarbon reservoirs have been discovered in the deepwater area of the basin, including the Lingtou Formation （Eocene）, Yacheng and Lingshui formations （Oligocene）, Sanya, Meishan and Huangliu formations （Miocene） and Yinggehai Formation （Pliocene）, which are covered by Quaternary sediments and underlain by pre- Paleogene strata.

Detrital zircon U-Pb age perspective on the sediment provenance and its geological significance of sandstones in the Lamandau region, SW Borneo, Indonesia

The Southwest Borneo(SW Borneo)block belongs to Sundaland and is the oldest continental fragment of Borneo that is believed to derive from the Gondwana land.The U-Pb isotopic dating ages of 113 detrital zircons from sandstones of the Ketapang Complex in SW Borneo range from 3298 Ma to 78 Ma,and show six major age populations:2476-2344 Ma,2016-1831 Ma,1296-759 Ma,455-406 Ma,262-210 Ma,and 187-78 Ma.The youngest age of these detrital zircons is 78 Ma,indicating that the maximum depositional age of the sandstones is Campanian.Permian-Late Cretaceous detrital zircons are interpreted as having been derived from the nearby Schwaner Mountains and the Permian-Triassic tin belt granitoids in Southeast Asia(SE Asia).Archean-Carboniferous detrital zircons have a continental Gondwana provenance,with their age spectra similar to those of northwestern Australia,indicating that these zircons could be derived from the orogenic belts and cratons in northwestern and central Australia.The provenance of these detrital zircons in this study indicates the SW Borneo block was located on the northwestern margin of Australia during the Paleozoic,in the region of the Banda Embayment.SW Borneo rifted from Australia and moved northward in the Early Jurassic,and this block was added to Sundaland in the Early Cretaceous.The Luconia-Dangerous Grounds continental fragment derived from East Asia collided with SW Borneo after subduction in the Cretaceous,which induced the widespread magmatism in the Schwaner Mountains in SW Borneo.

LA-ICP-MS U-Pb Geochronology of Detrital Zircons in Eastern Liaoning Province： An Early Paleozoic Formation Associated with the Gondwana Supercontinent Event

Objective The Liao-Ji orogenic belt is a famous Paleoproterozoic orogenic belt in the East Block of the North China Craton(NCC),which extend in NE-SW direction.The geological mass in the Paleoproterozoic Liao-Ji belt is mainly composed of the Liaoji granites and metamorphic volcanic-sedimentary rocks of the Liaohe group(and its

Detrital Zircon U-Pb Ages of the Zhaojiazhuang Formation, Middle–South Section, Taihang Mountains, China and their Geological Significance

The sedimentary Zhaojiazhuang Formation overlies the ancient Paleo-proterozoic crystalline basement in the middle-south sections of the Taihang Mountains,China.It is a complete stratigraphic sequence with clear boundaries.The formation has an angular unconformity with the underlying Paleo-proterozoic Tongyu Formation and a parallel unconformity with the overlying Changzhougou Formation from the Changcheng System,which is widely distributed throughout the W utai-Zhongtiao-T aihang Mountains.Qiu Zhen et al.(2007)and Wang Qingchun et al.

The Tectonic Implications of the Hongliuhe-Xichangjing Ophiolitic Mélanges Belt in the Central Region of the Beishan Orogen, NW China——Constrained by the U-Pb Ages of Detrital Zircons of the Metasandstones

The tectonic attributes of different blocks within orogenic belts are of great significance for the study of accretionary processes and the evolution of Earth. The Hongliuhe-Niujianzi-Baiyunshan-Xichangjing ophiolitic mélange belt(HXOMB) is distributed in the heart of the Beishan Orogen, the Shuangyingshan and Minshui-Hanshan blocks being distributed in the south and north of the HXOMB respectively, and a large number of Early Paleozoic geological units are exposed on the blocks. According to the zircon age populations of the metasandstones in the Baiyunshan area recovered in this paper, when compared with the zircon age populations of the Paleozoic metasandstones reported in the Niujuanzi and Hanshan areas, we found that the metasandstones of the Shuangyingshan Block have age peaks at c. 598 Ma, 742 Ma, 828 Ma, 941 Ma, 990 Ma, 1168 Ma, 1636 Ma, 2497 Ma with non-significant age populations of 1500–1300 Ma, showing a possible affinity with the Tarim Craton;the metasandstones of the Minshui-Hanshan Block have age peaks at c. 606 Ma, 758 Ma, 914 Ma, 1102 Ma, 1194 Ma, 1304 Ma, 1672 Ma with significant age populations of 1500-1300 Ma, showing a possible affinity with the Chinese Central Tianshan Block. Therefore, the HXOMB of the Beishan Orogen is of great significance in plate segmentation, which separates the Tarim Craton in the south and the Chinese Central Tianshan Block in the north. Based on the evolutionary process of the Hongliuhe-Xichangjing ocean in the Beishan Orogen, we believe that break-up and convergence can be recognized as having occurred twice between the Chinese Central Tianshan Block and the Tarim Craton since the Mesoproterozoic in the Beishan area. This was related firstly to the break-up of the Columbia Supercontinent and the convergence of the Rodinia Supercontinent, mainly during the Middle Mesoproterozoic to Early Neoproterozoic, and secondly to the opening and closing of the Hongliuhe-Xichangjing ocean, mainly during the Early Paleozoic.

LA-ICP-MS U-Pb Geochronology of Detrital Zircon in the Guanzhong Basin, China and Its Tectonic Response

Objective The Guanzhong Basin in the transitional zone of the Qinling orogenic belt and the southern margin of the Ordos Basin has been extensively studied in recent years.Although some results have been obtained,some problems such as whether the materials from the North China craton and the Qinling orogenic belt are detrital sedimentary rocks of the Guanzhong Basin still remain unresolved.

海南岛雷鸣盆地鹿母湾组碎屑岩地球化学特征、锆石U-Pb年龄和Hf同位素组成:对物源及构造环境的启示

海南岛雷鸣盆地鹿母湾组的确切沉积时限和沉积物来源是研究的空白区域。本文选取雷鸣盆地鹿母湾组作为研究对象,通过全岩地球化学、碎屑锆石U-Pb年代学和Lu-Hf同位素分析,旨在限定其沉积时限及物质来源,并探讨其沉积构造环境。鹿母湾组碎屑沉积岩的最年轻碎屑锆石年龄峰(113.3 Ma)与侵入其中的花岗闪长岩岩体年龄(~107 Ma)限定鹿母湾组沉积时限为109.9~113.3 Ma。全岩地球化学研究表明,鹿母湾组碎屑沉积岩的分异指数(ICV)为0.78~1.52(平均值0.96)、化学风化指数(CIA)为51.11~73.45(平均值65.27),反映其源区岩石具有中等成熟度并经历了弱的化学风化作用。结合微量元素、稀土元素含量及相关比值(如La、Th、Sc、Zr、Hf、∑REE及δEu)、源区判别图和构造环境判别图解,本文认为鹿母湾组碎屑沉积岩可能沉积于活动大陆边缘相关的盆地,主要来源于同时代的长英质火山岩或火山物质,少量碎屑来自华南内陆和海南岛早古生代岩浆岩。

Chronology and Sources of Mesozoic Intrusive Complexes in the Xuzhou-Huainan Region, Central China: Constraints from SHRIMP Zircon U-Pb Dating

SHRIMP zircon U-Pb dating in the Liguo and Jiagou intrusives indicates that they were formed at -130 Ma in the Early Cretaceous. Most inherited zircons in the Liguo intrusive were formed at 2509±43 Ma. Most inherited and detrital zircons in the Jiagou intrusive were formed at -2500 Ma, -2000 Ma and -1800 Ma. The SHRIMP zircon U-Pb dating in two gneiss xenoliths from the Jiagou intrusive yields the ages of 2461±22 Ma and 2508±15 Ma, respectively. The dating results from inherited and detrital zircons in the intrusives and the gneiss xenoliths imply that the magmas could be derived from the partial melting of the basement of the North China Block (NCB). The magmatism is strong and extensive in the periods from 115 to 132 Ma, which is of typical bimodal characteristics. It is suggested that the lithospheric thinning in the eastern North China Block reached its peak in 115-132 Ma.

An Important Spreading Event of the Neo-Tethys Ocean during the Late Jurassic and Early Cretaceous: Evidence from Zircon U-Pb SHRIMP Dating on Diabase in Nagarze, Southern Tibet

Widely distributed in Gyangzê-Chigu area, southern Tibet, NW- and nearly E-W-trending diabase（gabbro）-gabbro diorite dykes are regarded as the product of the large-scale spreading of the late Neo-Tethys Ocean. In order to constrain the emplacement age of these dykes, zircons of two samples from diabases in Nagarzê were dated by using the U-Pb SHRIMP method. Two nearly the same weighted mean ^206pb/^23SU ages were obtained in this paper, which are 134.9±1.8 Ma （MSWD=0.65） and 135.5 ± 2.1 Ma （MSWD=1.40）, respectively. They not only represent the crystallization age of the diabase, but also documented an important spreading event of the Neo-Tethys Ocean during the late Jurassic and early Cretaceous. This dating result is of great significance to reconstruct the temporal framework of the late Neo-Tethys Ocean in the Qinghai-Tibet Plateau.

Geological Characteristics and Zircon U-Pb Dating of Volcanic Rocks from the Beizhan Iron Deposit in Western Tianshan Mountains, Xinjiang, NW China

The Beizhan large iron deposit located in the east part of the Awulale metallogenic belt in the western Tianshan Mountains is hosted in the Unit 2 of the Dahalajunshan Formation as lens, veinlets and stratoid, and both of the hanging wall and footwall are quartz-monzonite; the dip is to the north with thick and high-grade ore bodies downwards. Ore minerals are mainly magnetite with minor sulfides, such as pyrite, pyrrhotite, chalcopyrite and sphalerite. Skarnization is widespread around the ore bodies, and garnet, diopside, wollastonite, actinolite, epidote, uralite, tourmaline sericite and calcite are ubiquitous as gangues. Radiating outwards from the center of the ore body the deposit can be classified into skarn, calcite, serpentinite and marble zones. LA-ICP-MS zircon U-Pb dating of the rhyolite and dacite from the Dahalajunshan Formation indicates that they were formed at 301.3±0.8 Ma and 303.7±0.9 Ma, respectively, which might have been related to the continental arc magmatism during the late stage of subduction in the western Tianshan Mountains. Iron formation is genetically related with volcanic eruption during this interval. The Dahalajunshan Formation and the quartz-monzonite intrusion jointly control the distribution of ore bodies. Both ore textures and wall rock alteration indicate that the Beizhan iron deposit is probably skarn type.

Geochemical Characteristics and LA-ICP-MS Zircon U-Pb Dating of Amphibolites in the Songshugou Ophiolite in the Eastern Qinling

Geochemical studies on the arnphibolites in the Songshugou ophiolite from Shangnan County, Shaanxi Province demonstrate that the protolith of the amphibolites is tholeiitic. The arnphibolites can be classified into two groups according to their REE patterns and trace element features. Rocks of the first group are depleted in LREE while rocks of the second group are slightly depleted in LREE or flat from LREE to HREE without significant Eu anomaly. The first group of rocks have (La/Yb)N=0.33-0.55, (La/Sm)N= 0.45-0.65, and their La/Nb, Ce/Zr, Zr/Nb, Zr/Y and Ti/Y ratios are averaged at 1.20, 0.12, 31.02, 2.92 and 198, respectively, close to those of typical N-MORB. The second group of rocks have (La/Yb)N=0.63-0.95, (La/ Sm)N = 0.69--0.90, and their average La/Nb, Ce/Zr, Zr/Nb, Zr/Y and Ti/Y ratios are 0.82, 0.83, 1.15, 0.16, 19.00, 2.58 and 225, respectively, which lie between those of typical N-MORB and E-MORB but closer to the former. The two groups of rocks both exhibit flat patterns from Th to Yb in the highly incompatible elements spider diagram, but the first group of rocks have lower element abundances than the modern N-MORB, indicating a derivation of their mantle source from more depleted mantle source than the present N-MORB. The abundances of Th, Ta, Nb, La and Ce in the second group of rocks are slightly higher than those of the present N-MORB, and other elements, such as Hf, Zr, Sm, Ti, Y and Yb, are close to those of the N-MORB, indicating that the original magma was derived from depleted mantle but mixed with the enriched mantle. These characteristics, combined with the regional geology and previous studies, provide further evidence that the mafic-ultramafic rocks have the features of a typical ophiolite.Zircon grains from the amphibolite are generally rounded, and in most of them a distinguishable core-mantle texture is preserved as shown in the cathodoluminescence (CL) images. The core or core-mantle parts of the zircon grains are also rounded, same as those in basalts from other regions of the world. The LA-ICP-MS trace element and U-Pb isotopic analyses show that the zircon grains from the amphibolites are similar to the typical magmatic zircon in terms of their very low U and Th contents (62.36-0.10 μg/g and 78.47-0.003 μg/g, respectively). Seven pits from the core and core-mantle parts of the zircon grains yielded an average weighted 206Pb/ 238U age of 973±35 (2σ) Ma with the Th/U ratios range from 0.01 to 8.38 and mostly greater than 0.23. This age is consistent within the error range with the whole-rock Sm-Nd isochron age of 1030±46 Ma for the same kind of rocks reported by Dong et al. (1997a). In a combined analysis with the zircon positions on the CL images and the corresponding Th/U ratios, the age of 973±35 Ma is probably the formation age of tholeiite, the protolith of the Songshugou amphibolite. The geochronological determination gives further evidence that the Songshugou ophiolite was formed during the Neoproterozoic. In addition, there is one pit from the rim of a zircon grain giving a 206Pb/ 238U age of 5721199 (1σ) Ma with a Th/U ratio of 0.08. It may represent the age of the accretionary zircon in the amphibolite-facies metamorphism.